CN105567040A - Novel water-in-water multicolor paint - Google Patents
Novel water-in-water multicolor paint Download PDFInfo
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- CN105567040A CN105567040A CN201510998203.9A CN201510998203A CN105567040A CN 105567040 A CN105567040 A CN 105567040A CN 201510998203 A CN201510998203 A CN 201510998203A CN 105567040 A CN105567040 A CN 105567040A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to a paint, and in particular, relates to a novel water-in-water multicolor paint. The novel water-in-water multicolor paint includes a base paint, a mixed auxiliary material, and a blended auxiliary material, wherein the ratio of the base paint to the mixed auxiliary material to the blended auxiliary material is (80-120) to (70-90) to (130-150). The base paint includes deionized water, cellulose, a defoaming agent, a pH regulator, a dispersing agent, titanium dioxide, kaolin, a film-forming auxiliary agent, propylene glycol, a silicone acrylic emulsion, a preservative, and a protection glue solution. The novel water-in-water multicolor paint can be used for adjusting thousands of kinds of colors, and has high simulation degree. Through different grid seam designs, and with combination of a modernization concept and a traditional natural style, luxurious and solemn decorative effects are formed with lower cost.
Description
Technical field
The present invention relates to a kind of coating, be specifically related to a kind of novel water-water multicolor finish.
Background technology
Along with rapid development of economy, the total energy consumption of China occupies the second in the world, and China is populous, and Energy resources lack relatively, and per capita energy is only 40% of world average level.Under the situation of sternness, Sixteenth CPC National Congress proposes the year two thousand twenty gross domestic product and will quadruple on the basis of 2000, builds a well-off society in an all-round way; realize the target of Sustainable development; thus, save energy, protection of the environment becomes fundamental state policy that is outstanding, that stand summary property.According to data, accounted for about 30% of social total energy consumption at China's building energy consumption, and had ever-increasing trend, building energy conservation is very urgent.Outer wall body area accounts for 45% of floor area of building, and the energy lost by exterior wall accounts for 30% of energy for building, therefore strengthens exterior-wall heat insulation and plays a part saving energy and reduce the cost very important.The Eleventh Five-Year Plan period, Shanghai City building energy conservation assume responsibility for the decomposition goal of 15%, and newly-built public building is by the energy conservation object of round Realization 50%, and newly-built residential architecture is accelerated to be transitioned into energy-conservation 65% from energy-conservation 50%.
From the nineties, people recognize the harm of oil-in-water multicolor finish to human body and environment, unanimously thinking to only have adopts water-water multicolor finish really could substitute and address this problem, therefore people transfer to set about from water-borne coatings, are mixed into by multiple solid-state look grain on the one hand " solids coating " of " novel colorful " coating in coating; " technique is colorful " coating that two shower nozzle and many shower nozzles spray gun or employing combined type spraying method are made is adopted on the other hand in construction.Which kind of but no matter adopt method all not reach desirable effect, so cannot open up a market.Thus make domestic many large-scale coatings enterprises, research institution, universities and colleges, coating scientific research brainstrust all put into these ranks of research water-soluble colorful coating, pass through years of researches, but finally because of multicolor finish be polychrome, heterogeneous mix particles coexists, there is many problems in the stability of quality product, cannot realize target industrialization.
Summary of the invention
In order to effectively solve the problem, the invention provides a kind of novel water-water multicolor finish.
Technical solution of the present invention is specific as follows: a kind of novel water-water multicolor finish, and described water-water many ability coating comprises base paint, mixing helps material, allotment helps material;
Described base paint, mixing help material and allotment to help the component ratio of material to be 80-120:70-90:130-150.
Further, described base paint, mixing help material, allocate and help the component ratio of material to be 100:80:140.
Further, described base paint comprises deionized water, Mierocrystalline cellulose, defoamer, pH adjusting agent, dispersion agent, titanium dioxide, kaolin, film coalescence aid, propylene glycol, organosilicon crylic acid latex, sanitas, protecting glue solution;
The component of described ionized water, Mierocrystalline cellulose, defoamer, pH adjusting agent, dispersion agent, titanium dioxide, kaolin, film coalescence aid, propylene glycol, organosilicon crylic acid latex, sanitas, protecting glue solution is than being 41.1:0.9:0.4:0.2:0.45-0.5:0.1-5:2-7:0.75:1:37.5:0.25:10.
Further, described mixing helps material to comprise deionized water, liquid protecting glue, wilkinite and sanitas, and the component of described deionized water, liquid protecting glue, wilkinite and sanitas is than being 74.5:25.3:0.5:0.15.
Further, described allotment helps material to comprise organosilicon crylic acid latex, film coalescence aid, propylene glycol, sanitas, thickening material, deionized water;
The component of described organosilicon crylic acid latex, film coalescence aid, propylene glycol, sanitas, thickening material, deionized water is than being 83.3:2.7:2:0.3:0.8:10.9.
Further, described base paint can add mill base.
A preparation method for novel water-water multicolor finish, for the preparation of above-mentioned novel water-water multicolor finish, it is characterized in that, described preparation method comprises the steps:
A) base paint and mixing are helped material mixing, and apply tablets press and carry out granulation;
B) help with allotment after granulation and expect to mix, mixing fully, namely obtains novel water-water multicolor finish.
Further, described preparation method is in described steps A) frontly also comprise base paint, mixing helps material and allotment helps the preparation process of material, the preparation process of described base paint comprises:
A11) first defoamer, titanium dioxide and Mierocrystalline cellulose are added in deionized water, and be placed in stirrer and stir, described stirring velocity is 200-400r/min, and described churning time is 20-25min;
A12) after completion of stirring, carry out being warming up to 70-80 DEG C, add organosilicon crylic acid latex, propylene glycol, film coalescence aid, dispersion agent and kaolin, be incubated and vacuumize stirring, stirring velocity is 400-500r/min, and the hold-time is 1h-1.2h;
A13) completing steps A12) add pH adjusting agent afterwards, adjustment pH is 7.5-8.0, add sanitas and protecting glue solution subsequently again, vacuumize airtight, after adding nitrogen, regulation and control pressure is to 1.5-1.8mpa, and intensification value 120-150 DEG C, and carry out density stirring, stir 3-5min with 100-120r/min, after stirring 20-30min with 200-250r/min, complete the preparation of base paint;
Can in steps A 12) in add mill base;
Described mixing helps the preparation of material to comprise the steps:
After deionized water, liquid protecting glue, wilkinite and sanitas being mixed, at room temperature carry out high-speed stirring, described stirring velocity is 60-120r/min;
Described allotment helps the preparation of material to comprise the steps:
A21) described organosilicon crylic acid latex and deionized water are proportionally mixed, stir after mixing, described stirring velocity is 100-200r/min, and described churning time is 10-15min;
A22) to steps A 21) add sanitas, thickening material, film coalescence aid in the solution that completes, proceed to stir, stir 3-5min with 100-120r/min, after stirring 20-30min with 200-250r/min;
A23) to steps A 22) in add propylene glycol again, at room temperature stir after, leave standstill 10min prepared.
Further, described steps A) in after base paint and mixing help material mixing, carry out granulation by tablets press, the diameter dimension after described granulation is 0.3-0.5mm.
Beneficial effect of the present invention: proved by time and experiment, its water-water multicolor finish made has exceeded 1 year storage period, and by oscillatory surge simulated experiment, there is not the bad phenomenon such as color grain spreads and dissolves, shelf-stable.Test by HG/T4343-2012 " aqueous colorful building coating ", basic mechanical design feature is good: weather resistance, water resistance accord with and Standard completely, and abrasion resistance is also higher than national standard.
Novel water-water multicolor finish VOC content is extremely low, Water-borne modification completely: unique technique for packing makes its complete Water-borne modification, environment-protecting asepsis, substitutes day by day rare natural granite, meets the energy-conserving and environment-protective advances calls of country.Coating deadweight only accounts for 1/500 of stone material, and it is overweight not only fundamentally to have freed stone material dry suspending load, the hidden danger come off for a long time in year, and is cost-savingly only 1/3 of stone material, meets power conservation requirement.
Novel water-water multicolor finish, color-adjustable ten million kind, fidelity is high.Seam meter by different lattice, the combination of modern theory and the natural style of tradition, brings up and builds luxurious, serious decorative effect with lower cost.
The snappiness of novel water-water multicolor finish color dot and good leveling property, make color dot not allow frangible in spraying process, and color dot is at the better drawout of basal plane energy, and glue spread reduces, and water resistance improves.The superiority of new type water bag water-based energy is better than traditional water-water multicolor finish greatly.
Embodiment
Below by way of specific embodiment the present invention done and explain further.
Embodiments of the invention provide a kind of novel water-water multicolor finish, and described water-water many ability coating comprises base paint, mixing helps material, allotment helps material;
Described base paint, mixing help material and allotment to help the component ratio of material to be 80-120:70-90:130-150.Be preferably: according to component A: B component: component C=100:80:140,
Table one component A
B component formula is in table two:
Table two B component
| Material | Proportioning |
| Deionized water | 74.05％ |
| Liquid protecting glue | 25.3％ |
| Wilkinite | 0.5％ |
| Sanitas | 0.15％ |
Component C formula is in table three:
Table three component C
Described base paint can add mill base.
A preparation method for novel water-water multicolor finish, for the preparation of above-mentioned novel water-water multicolor finish, it is characterized in that, described preparation method comprises the steps:
A) base paint and mixing are helped material mixing, and apply tablets press and carry out granulation;
B) help with allotment after granulation and expect to mix, mixing fully, namely obtains novel water-water multicolor finish.
Further, described preparation method is in described steps A) frontly also comprise base paint, mixing helps material and allotment helps the preparation process of material, the preparation process of described base paint comprises:
A11) first defoamer, titanium dioxide and Mierocrystalline cellulose are added in deionized water, and be placed in stirrer and stir, described stirring velocity is 200-400r/min, and described churning time is 20-25min;
A12) after completion of stirring, carry out being warming up to 70-80 DEG C, add organosilicon crylic acid latex, propylene glycol, film coalescence aid, dispersion agent and kaolin, be incubated and vacuumize stirring, stirring velocity is 400-500r/min, and the hold-time is 1h-1.2h;
A13) completing steps A12) add pH adjusting agent afterwards, adjustment pH is 7.5-8.0, add sanitas and protecting glue solution subsequently again, vacuumize airtight, after adding nitrogen, regulation and control pressure is to 1.5-1.8mpa, and intensification value 120-150 DEG C, and carry out density stirring, stir 3-5min with 100-120r/min, after stirring 20-30min with 200-250r/min, complete the preparation of base paint;
Can in steps A 12) in add mill base;
Described mixing helps the preparation of material to comprise the steps:
After deionized water, liquid protecting glue, wilkinite and sanitas being mixed, at room temperature carry out high-speed stirring, described stirring velocity is 60-120r/min;
Described allotment helps the preparation of material to comprise the steps:
A21) described organosilicon crylic acid latex and deionized water are proportionally mixed, stir after mixing, described stirring velocity is 100-200r/min, and described churning time is 10-15min;
A22) to steps A 21) add sanitas, thickening material, film coalescence aid in the solution that completes, proceed to stir, stir 3-5min with 100-120r/min, after stirring 20-30min with 200-250r/min;
A23) to steps A 22) in add propylene glycol again, at room temperature stir after, leave standstill 10min prepared.
Further, described steps A) in after base paint and mixing help material mixing, carry out granulation by tablets press, the diameter dimension after described granulation is 0.3-0.5mm.
Claims (9)
1. a novel water-water multicolor finish, is characterized in that, described water-water many ability coating comprises base paint, mixing helps material, allotment helps material;
Described base paint, mixing help material and allotment to help the component ratio of material to be 80-120:70-90:130-150.
2. the novel water-water multicolor finish of one according to claim 1, is characterized in that, described base paint, mixing help material, allotment helps the component ratio of material to be 100:80:140.
3. the novel water-water multicolor finish of one according to claim 1, it is characterized in that, described base paint comprises deionized water, Mierocrystalline cellulose, defoamer, pH adjusting agent, dispersion agent, titanium dioxide, kaolin, film coalescence aid, propylene glycol, organosilicon crylic acid latex, sanitas, protecting glue solution;
The component of described ionized water, Mierocrystalline cellulose, defoamer, pH adjusting agent, dispersion agent, titanium dioxide, kaolin, film coalescence aid, propylene glycol, organosilicon crylic acid latex, sanitas, protecting glue solution is than being 41.1:0.9:0.4:0.2:0.45-0.5:0.1-5:2-7:0.75:1:37.5:0.25:10.
4. the novel water-water multicolor finish of one according to claim 3; it is characterized in that; described mixing helps material to comprise deionized water, liquid protecting glue, wilkinite and sanitas, and the component of described deionized water, liquid protecting glue, wilkinite and sanitas is than being 74.5:25.3:0.5:0.15.
5. the novel water-water multicolor finish of one according to claim 4, is characterized in that, described allotment helps material to comprise organosilicon crylic acid latex, film coalescence aid, propylene glycol, sanitas, thickening material, deionized water;
The component of described organosilicon crylic acid latex, film coalescence aid, propylene glycol, sanitas, thickening material, deionized water is than being 83.3:2.7:2:0.3:0.8:10.9.
6. the novel water-water multicolor finish of one according to claim 3, it is characterized in that, described base paint can add mill base.
7. a preparation method for novel water-water multicolor finish, for the preparation of the novel water-water multicolor finish one of the claims 1-6 Suo Shu, it is characterized in that, described preparation method comprises the steps:
A) base paint and mixing are helped material mixing, and apply tablets press and carry out granulation;
B) help with allotment after granulation and expect to mix, mixing fully, namely obtains novel water-water multicolor finish.
8. preparation method according to claim 7, is characterized in that, described preparation method is in described steps A) frontly also comprise base paint, mixing helps material and allotment helps the preparation process of material, the preparation process of described base paint comprises:
A11) first defoamer, titanium dioxide and Mierocrystalline cellulose are added in deionized water, and be placed in stirrer and stir, described stirring velocity is 200-400r/min, and described churning time is 20-25min;
A12) after completion of stirring, carry out being warming up to 70-80 DEG C, add organosilicon crylic acid latex, propylene glycol, film coalescence aid, dispersion agent and kaolin, be incubated and vacuumize stirring, stirring velocity is 400-500r/min, and the hold-time is 1h-1.2h;
A13) completing steps A12) add pH adjusting agent afterwards, adjustment pH is 7.5-8.0, add sanitas and protecting glue solution subsequently again, vacuumize airtight, after adding nitrogen, regulation and control pressure is to 1.5-1.8mpa, and intensification value 120-150 DEG C, and carry out density stirring, stir 3-5min with 100-120r/min, after stirring 20-30min with 200-250r/min, complete the preparation of base paint;
Can in steps A 12) in add mill base;
Described mixing helps the preparation of material to comprise the steps:
After deionized water, liquid protecting glue, wilkinite and sanitas being mixed, at room temperature carry out high-speed stirring, described stirring velocity is 60-120r/min;
Described allotment helps the preparation of material to comprise the steps:
A21) described organosilicon crylic acid latex and deionized water are proportionally mixed, stir after mixing, described stirring velocity is 100-200r/min, and described churning time is 10-15min;
A22) to steps A 21) add sanitas, thickening material, film coalescence aid in the solution that completes, proceed to stir, stir 3-5min with 100-120r/min, after stirring 20-30min with 200-250r/min;
A23) to steps A 22) in add propylene glycol again, at room temperature stir after, leave standstill 10min prepared.
9. preparation method according to claim 7, is characterized in that, described steps A) in after base paint and mixing help material mixing, carry out granulation by tablets press, the diameter dimension after described granulation is 0.3-0.5mm.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510998203.9A CN105567040A (en) | 2015-12-26 | 2015-12-26 | Novel water-in-water multicolor paint |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510998203.9A CN105567040A (en) | 2015-12-26 | 2015-12-26 | Novel water-in-water multicolor paint |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105925096A (en) * | 2016-06-06 | 2016-09-07 | 浙江科达新型建材有限公司 | Production method of water-in-water colorful paint containing color sand |
| CN106085062A (en) * | 2016-06-06 | 2016-11-09 | 浙江科达新型建材有限公司 | A kind of containing color sand water-in-water multicolor coating |
| CN106349856A (en) * | 2016-08-31 | 2017-01-25 | 铃鹿复合建材（上海）有限公司 | Colorful cast stone and preparation method thereof |
| CN107189605A (en) * | 2017-05-09 | 2017-09-22 | 河北晨阳工贸集团有限公司 | Reflective insulation water-in-water multicolor coating and preparation method thereof |
| CN107722739A (en) * | 2017-09-14 | 2018-02-23 | 中华制漆（深圳）有限公司 | Water-in-water multicolor coating its preparation method and application |
| CN107974123A (en) * | 2017-12-29 | 2018-05-01 | 平阳瑞丰新材料科技有限公司 | A kind of multi-color and its application |
| CN108003731A (en) * | 2017-11-09 | 2018-05-08 | 河北晨阳工贸集团有限公司 | A kind of rust-proof type multicolor finish and preparation method thereof |
| CN108485437A (en) * | 2018-04-25 | 2018-09-04 | 廊坊旭博涂立德新型材料科技有限公司 | A kind of colorful paint formula |
| CN108864872A (en) * | 2018-08-07 | 2018-11-23 | 广州立邦涂料有限公司 | Aqueous pottery stone coating and preparation method thereof |
| CN109735185A (en) * | 2018-12-27 | 2019-05-10 | 兰州梓苑环保科技有限公司 | A kind of novel water-in-water multicolor coating and preparation method thereof |
| CN110358384A (en) * | 2019-06-14 | 2019-10-22 | 河北晨阳工贸集团有限公司 | A kind of water burnt-in sand multicolor finish and preparation method thereof |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105925096B (en) * | 2016-06-06 | 2019-02-22 | 浙江科达新型建材有限公司 | A kind of production method of water-in-water multicolor coating containing color sand |
| CN106085062A (en) * | 2016-06-06 | 2016-11-09 | 浙江科达新型建材有限公司 | A kind of containing color sand water-in-water multicolor coating |
| CN105925096A (en) * | 2016-06-06 | 2016-09-07 | 浙江科达新型建材有限公司 | Production method of water-in-water colorful paint containing color sand |
| CN106085062B (en) * | 2016-06-06 | 2019-05-24 | 浙江科达新型建材有限公司 | A kind of water-in-water multicolor coating containing color sand |
| CN106349856A (en) * | 2016-08-31 | 2017-01-25 | 铃鹿复合建材（上海）有限公司 | Colorful cast stone and preparation method thereof |
| CN107189605A (en) * | 2017-05-09 | 2017-09-22 | 河北晨阳工贸集团有限公司 | Reflective insulation water-in-water multicolor coating and preparation method thereof |
| CN107722739A (en) * | 2017-09-14 | 2018-02-23 | 中华制漆（深圳）有限公司 | Water-in-water multicolor coating its preparation method and application |
| CN108003731A (en) * | 2017-11-09 | 2018-05-08 | 河北晨阳工贸集团有限公司 | A kind of rust-proof type multicolor finish and preparation method thereof |
| CN107974123A (en) * | 2017-12-29 | 2018-05-01 | 平阳瑞丰新材料科技有限公司 | A kind of multi-color and its application |
| CN108485437A (en) * | 2018-04-25 | 2018-09-04 | 廊坊旭博涂立德新型材料科技有限公司 | A kind of colorful paint formula |
| CN108864872A (en) * | 2018-08-07 | 2018-11-23 | 广州立邦涂料有限公司 | Aqueous pottery stone coating and preparation method thereof |
| CN109735185A (en) * | 2018-12-27 | 2019-05-10 | 兰州梓苑环保科技有限公司 | A kind of novel water-in-water multicolor coating and preparation method thereof |
| CN110358384A (en) * | 2019-06-14 | 2019-10-22 | 河北晨阳工贸集团有限公司 | A kind of water burnt-in sand multicolor finish and preparation method thereof |
| CN110358384B (en) * | 2019-06-14 | 2023-07-14 | 河北晨阳工贸集团有限公司 | Sand-in-water multicolor paint and preparation method thereof |
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