CN105566968A - Water-based fireproof coating and preparing method thereof - Google Patents
Water-based fireproof coating and preparing method thereof Download PDFInfo
- Publication number
- CN105566968A CN105566968A CN201610093192.4A CN201610093192A CN105566968A CN 105566968 A CN105566968 A CN 105566968A CN 201610093192 A CN201610093192 A CN 201610093192A CN 105566968 A CN105566968 A CN 105566968A
- Authority
- CN
- China
- Prior art keywords
- parts
- hcpe
- proof coating
- pentaerythritol triacrylate
- mill base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 63
- 239000011248 coating agent Substances 0.000 title claims abstract description 56
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 238000000034 method Methods 0.000 title abstract description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 38
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 29
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 24
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 24
- 239000008367 deionised water Substances 0.000 claims abstract description 20
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 20
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 19
- 229920005989 resin Polymers 0.000 claims description 43
- 239000011347 resin Substances 0.000 claims description 43
- 238000003756 stirring Methods 0.000 claims description 41
- 239000003795 chemical substances by application Substances 0.000 claims description 37
- 239000000463 material Substances 0.000 claims description 34
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 32
- NCWQJOGVLLNWEO-UHFFFAOYSA-N methylsilicon Chemical compound [Si]C NCWQJOGVLLNWEO-UHFFFAOYSA-N 0.000 claims description 31
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 22
- 230000008719 thickening Effects 0.000 claims description 20
- 238000004581 coalescence Methods 0.000 claims description 19
- 239000013530 defoamer Substances 0.000 claims description 19
- 239000006185 dispersion Substances 0.000 claims description 19
- 238000002360 preparation method Methods 0.000 claims description 18
- 239000002994 raw material Substances 0.000 claims description 15
- 238000000227 grinding Methods 0.000 claims description 8
- 239000012467 final product Substances 0.000 claims description 7
- 229920000877 Melamine resin Polymers 0.000 abstract description 6
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004709 Chlorinated polyethylene Substances 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 238000005336 cracking Methods 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 229920013716 polyethylene resin Polymers 0.000 abstract 1
- 229920005749 polyurethane resin Polymers 0.000 abstract 1
- 229920002050 silicone resin Polymers 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 230000001988 toxicity Effects 0.000 abstract 1
- 231100000419 toxicity Toxicity 0.000 abstract 1
- 239000003973 paint Substances 0.000 description 15
- 239000000839 emulsion Substances 0.000 description 11
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 10
- 239000003063 flame retardant Substances 0.000 description 9
- -1 polypropylene Polymers 0.000 description 9
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 6
- 239000006260 foam Substances 0.000 description 6
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 229920001971 elastomer Polymers 0.000 description 4
- 235000019353 potassium silicate Nutrition 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000004640 Melamine resin Substances 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000010985 leather Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- 239000000123 paper Substances 0.000 description 3
- 229940059574 pentaerithrityl Drugs 0.000 description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000000052 vinegar Substances 0.000 description 3
- 235000021419 vinegar Nutrition 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 239000004801 Chlorinated PVC Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000004908 Emulsion polymer Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000012271 agricultural production Methods 0.000 description 2
- 230000002742 anti-folding effect Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 229920002681 hypalon Polymers 0.000 description 2
- 238000009776 industrial production Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000037452 priming Effects 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 230000000979 retarding effect Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 230000009967 tasteless effect Effects 0.000 description 2
- 239000010455 vermiculite Substances 0.000 description 2
- 229910052902 vermiculite Inorganic materials 0.000 description 2
- 235000019354 vermiculite Nutrition 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 1
- VAJVDSVGBWFCLW-UHFFFAOYSA-N 3-Phenyl-1-propanol Chemical compound OCCCC1=CC=CC=C1 VAJVDSVGBWFCLW-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- DYUQAZSOFZSPHD-UHFFFAOYSA-N Phenylpropyl alcohol Natural products CCC(O)C1=CC=CC=C1 DYUQAZSOFZSPHD-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 241000219000 Populus Species 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 239000005030 aluminium foil Substances 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000006157 aromatic diamine group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000011094 fiberboard Substances 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 238000009415 formwork Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 239000002649 leather substitute Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 210000002706 plastid Anatomy 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000011527 polyurethane coating Substances 0.000 description 1
- 229920003225 polyurethane elastomer Polymers 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003351 stiffener Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 235000013618 yogurt Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a water-based fireproof coating and a preparing method thereof. The water-based fireproof coating is prepared from, by weight, 16-23 parts of ammonium polyphosphate, 8-14 parts of melamine, 7-10 parts of pentaerythritol triacrylate, 10-16 parts of high-chlorinated polyethylene resin, 6-9 parts of polyurethane resin, 4-8 parts of methyl silicone resin, 2-5 parts of sodium carbonate, 17-21 parts of deionized water, 1.5-2.1 parts of a thickening agent, 1.5-4.5 parts of a dispersing agent, 0.22-0.32 part of an antifoaming agent and an appropriate amount of color paste. The water-based fireproof coating has the advantages of being long in flame-retarding time, high in adhesive strength, not prone to cracking, excellent in fire resistance and the like, and is free of toxicity, safe and environmentally friendly.
Description
Technical field
The present invention relates to paint field, particularly relate to a kind of aqueous fire-proof coating and preparation method thereof.
Background technology
At present, organic mainly with excellent performance of aqueous fire-proof coating, expanding fire-proof paint that is inorganic and organic and inorganic compounding is main.Latex type frie retardant coating makes base-material with emulsion polymer (relative molecular mass of emulsion polymer is high, so have good mechanical property as the film forming matter of coating), use water as solvent, the coating that the auxiliary agent adding suitable kind and quantity is prepared into through grinding, the emulsion being commonly used for aqueous fire-proof coating base-material has: polyacrylate emulsion, styrene-modified polypropylene yogurt liquid, polyvinyl acetate emulsion, polyvinylidene chloride emulsion etc.In addition, require that the polymer emulsion selected must have good sticking power to base material, weather resistance and water-tolerant, pure third (methacrylic acid junket one propylene vinegar copolymer emulsion, second third (propylene vinegar one vinyl acetate copolymer) emulsion and phenylpropyl alcohol (propylene vinegar one styrol copolymer) emulsion, nontoxic odorless, there is higher winter hardiness and gloss retention, strong adhesion, normal temperature solidified, all good letex polymerization base-materials, but its flame retardant resistance, thermotolerance is poor, high temperature easily returns sticky, easy binding dust, easily become fragile during low temperature, ventilation property is poor, for improving these performances, can come to spell by emulsion to use, synthesis modification resin (forming silicon one third resin with Acrylic Acid Monomer and organosilane monomer copolymerization) or increase the methods such as fire retardant.Organic expander flame-retardant system has attractive coat, the features such as sticking power is good, but easily produce smog during its back-fire relief and release poisonous gas to some extent, cost is also higher, so, inorganic expansion type frie retardant coating based on silicate just arises at the historic moment, it take water glass as base-material and foamed matrix, add other materials formed, when coating meets fiery high temperature action, in crystal water contained by alkalimetal silicate and water glass, oxygen chain makes coating congruent melting deliquescing through the dehydration of base, viscosity increases, at this moment can not discharge owing to decomposing the gas produced freely thus foam, define the porous plastid with heat insulating function, silicate foam shape thermofin.
Application publication number CN104610843A(application number 201510029581.6) Chinese patent literature disclose a kind of frie retardant coating, this frie retardant coating is prepared from by the raw material of following mass fraction: epoxy resin 18 parts ~ 30 parts, ether of cellulose 15 parts ~ 25 parts, expanded vermiculite 2 parts ~ 8 parts, magnesium hydroxide 3 parts ~ 6 parts, water glass 1 part ~ 8 parts, dimethyl silicone oil 5 parts ~ 10 parts, isobutyl ketone 25 parts ~ 45 parts, clorafin 1 part ~ 6 parts.The Chinese patent literature of application publication number CN104387983A (application number 201410741589.0) discloses a kind of frie retardant coating, comprises the composition of following content ratio: pearlstone 10 ~ 15 parts; Aluminum silicate fiber 8 ~ 12 parts; Flexible emulsion 15 ~ 20 parts; Tetramethylolmethane 3 ~ 5 parts; Fluorocarbon resin 8 ~ 16 parts; Thickening material 2 ~ 4 parts; Auxiliary agent 10 ~ 18 parts of antiseptic-germicides 2 ~ 6 parts.Application publication number CN104789022(application number 201410028028.6) Chinese patent literature disclose a kind of frie retardant coating, it is characterized in that: consist of trimeric cyanamide 10-20 part, deionized water 20-40 part, talcum powder 2-10 part, water glass 5-20 part, titanium dioxide 5-10 part, expanded vermiculite 1-5 part, tetramethylolmethane 1-5 part, mica powder 1-10 part by weight.
Through the development of decades, aqueous fire-proof coating has at home and abroad obtained extensively to be promoted and uses, and at the iron and steel object of structures, the steelframe in house, hotel, mansion, airport, the buildingss such as station, structures have employed aqueous fire-proof coating all in a large number.Prior art frie retardant coating there is adhesion strength and fire performance is lower, easily the shortcoming such as dry and cracked.
Summary of the invention
For the deficiencies in the prior art, the object of this invention is to provide a kind of aqueous fire-proof coating and preparation method thereof.It is long that products obtained therefrom of the present invention has duration of fire resistance, and adhesion strength is high, not easily dry and cracked, the advantages such as excellent fire retarding performance, and non-toxic and safe environmental protection.
A kind of aqueous fire-proof coating, takes off the main raw material stating weight proportion and is prepared from: ammonium polyphosphate 16-23, trimeric cyanamide 8-14, pentaerythritol triacrylate 7-10, HCPE 10-16, urethane resin 6-9, methyl silicon resin 4-8, sodium carbonate 2-5, deionized water 17-21, thickening material 1.5-2.1, dispersion agent 1.5-4.5, defoamer 0.22-0.32, mill base is appropriate.
A kind of aqueous fire-proof coating, preferred scheme is, takes off the main raw material stating weight proportion and is prepared from: ammonium polyphosphate 18-22, trimeric cyanamide 10-13, pentaerythritol triacrylate 8-9, HCPE 13-15, urethane resin 7-8, methyl silicon resin 5-7, sodium carbonate 3-4, deionized water 18-20, thickening material 1.7-1.9, dispersion agent 2.3-4.2, defoamer 0.25-0.28, mill base is appropriate.
A kind of aqueous fire-proof coating, the scheme be more preferably is, takes off the main raw material stating weight proportion and is prepared from: ammonium polyphosphate 20, trimeric cyanamide 12, pentaerythritol triacrylate 8.4, HCPE 14, urethane resin 7.6, methyl silicon resin 6, sodium carbonate 3.5, deionized water 19, thickening material 1.8, dispersion agent 3.4, defoamer 0.27, mill base is appropriate.
The preparation method of above-mentioned aqueous fire-proof coating is:
(1) pentaerythritol triacrylate, HCPE, urethane resin and methyl silicon resin are mixed, add deionized water, stir 30-70 minute, add film coalescence aid, the amount of film coalescence aid is the 0.3-0.8% of pentaerythritol triacrylate, HCPE, urethane resin and methyl silicon resin gross weight, then ultrasonic disperse 25-35 minute;
(2) ammonium polyphosphate, trimeric cyanamide, sodium carbonate and step (1) gained are mixed, add thickening material, dispersion agent and defoamer, stir with the speed of 250-360r/min, stir 40-80 minute, grinding;
(3) in step (2) gained, add mill base, the amount of mill base is the 0.4-0.8% of step (2) gained gross weight, stirs evenly, to obtain final product.
Preferably be in step (1), stir 35-60 minute.
Preferably be in step (1), the amount of film coalescence aid is the 0.4-0.7% of pentaerythritol triacrylate, HCPE, urethane resin and methyl silicon resin gross weight.
Preferably be in step (1), then ultrasonic disperse 27-32 minute.
Preferably be, in step (2), to stir with the speed of 280-340r/min.
Preferably be in step (2), stir 50-70 minute (preferably stirring 60 minutes).
Preferably be in step (3), the amount of mill base is the 0.5-0.7% of step (2) gained gross weight.
Be more preferably, stir 55 minutes in step (1).
Be more preferably, in step (1), the amount of film coalescence aid is 0.6% of pentaerythritol triacrylate, HCPE, urethane resin and methyl silicon resin gross weight.
Be more preferably, ultrasonic disperse 30 minutes again in step (1).
Be more preferably, step stirs with the speed of 320r/min in (2).
Be more preferably, stir 60 minutes in step (2).
Be more preferably, in step (3), the amount of mill base is 0.6% of step (2) gained gross weight.
Aqueous fire-proof coating preparation method provided by the invention is simple.In addition, excellent results of the present invention also shows:
1, have duration of fire resistance long, adhesion strength is high, not easily dry and cracked, the advantages such as excellent fire retarding performance;
2, non-toxic and safe environmental protection;
3, cost is lower.
Embodiment
Describe technical scheme of the present invention in detail below in conjunction with embodiment and experimental example, but protection domain is not limited thereto.
The present invention's thickening material used can purchased from Han Tai Chemical Co., Ltd. of Nantong City; Dispersion agent can purchased from Anhui water bodyguard Environmental Protection Technology Co., Ltd; Defoamer can purchased from Ao Na polymkeric substance company limited of Foshan City; Film coalescence aid can purchased from Nantong Shengda Chemical Co., Ltd..
Embodiment 1 one kinds of aqueous fire-proof coatings, the main raw material getting following weight parts is prepared from (every part is 2kg): ammonium polyphosphate 16 parts, trimeric cyanamide 8 parts, pentaerythritol triacrylate 7 parts, HCPE 10 parts, urethane resin 6 parts, methyl silicon resin 4 parts, 2 parts, sodium carbonate, deionized water 17 parts, thickening material 1.5 parts, dispersion agent 1.5 parts, defoamer 0.22 part, mill base is appropriate.
The preparation method of above-mentioned aqueous fire-proof coating is:
(1) pentaerythritol triacrylate, HCPE, urethane resin and methyl silicon resin are mixed, add deionized water, stir 30 minutes, add film coalescence aid, the amount of film coalescence aid is 0.3% of pentaerythritol triacrylate, HCPE, urethane resin and methyl silicon resin gross weight, then ultrasonic disperse 25 minutes;
(2) ammonium polyphosphate, trimeric cyanamide, sodium carbonate and step (1) gained are mixed, add thickening material, dispersion agent and defoamer, stir with the speed of 250r/min, stir 40 minutes, grinding;
(3) in step (2) gained, add mill base, the amount of mill base is 0.4% of step (2) gained gross weight, stirs evenly, to obtain final product.
Embodiment 2 one kinds of aqueous fire-proof coatings, the main raw material getting following weight parts is prepared from (every part is 2kg): ammonium polyphosphate 23 parts, trimeric cyanamide 14 parts, pentaerythritol triacrylate 10 parts, HCPE 16 parts, urethane resin 9 parts, methyl silicon resin 8 parts, 5 parts, sodium carbonate, deionized water 21 parts, thickening material 2.1 parts, dispersion agent 4.5 parts, defoamer 0.32 part, mill base is appropriate.
The preparation method of above-mentioned aqueous fire-proof coating is:
(1) pentaerythritol triacrylate, HCPE, urethane resin and methyl silicon resin are mixed, add deionized water, stir 70 minutes, add film coalescence aid, the amount of film coalescence aid is 0.8% of pentaerythritol triacrylate, HCPE, urethane resin and methyl silicon resin gross weight, then ultrasonic disperse 35 minutes;
(2) ammonium polyphosphate, trimeric cyanamide, sodium carbonate and step (1) gained are mixed, add thickening material, dispersion agent and defoamer, stir with the speed of 360r/min, stir 80 minutes, grinding;
(3) in step (2) gained, add mill base, the amount of mill base is 0.8% of step (2) gained gross weight, stirs evenly, to obtain final product.
Embodiment 3 one kinds of aqueous fire-proof coatings, the main raw material getting following weight parts is prepared from (every part is 2kg): ammonium polyphosphate 18 parts, trimeric cyanamide 10 parts, pentaerythritol triacrylate 8 parts, HCPE 13 parts, urethane resin 7 parts, methyl silicon resin 5 parts, 3 parts, sodium carbonate, deionized water 18 parts, thickening material 1.7 parts, dispersion agent 2.3 parts, defoamer 0.25 part, mill base is appropriate.
The preparation method of above-mentioned aqueous fire-proof coating is:
(1) pentaerythritol triacrylate, HCPE, urethane resin and methyl silicon resin are mixed, add deionized water, stir 35 minutes, add film coalescence aid, the amount of film coalescence aid is 0.4% of pentaerythritol triacrylate, HCPE, urethane resin and methyl silicon resin gross weight, then ultrasonic disperse 27 minutes;
(2) ammonium polyphosphate, trimeric cyanamide, sodium carbonate and step (1) gained are mixed, add thickening material, dispersion agent and defoamer, stir with the speed of 280r/min, stir 50 minutes, grinding;
(3) in step (2) gained, add mill base, the amount of mill base is 0.5% of step (2) gained gross weight, stirs evenly, to obtain final product.
Embodiment 4 one kinds of aqueous fire-proof coatings, the main raw material getting following weight parts is prepared from (every part is 2kg): ammonium polyphosphate 22 parts, trimeric cyanamide 13 parts, pentaerythritol triacrylate 9 parts, HCPE 15 parts, urethane resin 8 parts, methyl silicon resin 7 parts, 4 parts, sodium carbonate, deionized water 20 parts, thickening material 1.9 parts, dispersion agent 4.2 parts, defoamer 0.28 part, mill base is appropriate.
The preparation method of above-mentioned aqueous fire-proof coating is:
(1) pentaerythritol triacrylate, HCPE, urethane resin and methyl silicon resin are mixed, add deionized water, stir 60 minutes, add film coalescence aid, the amount of film coalescence aid is 0.7% of pentaerythritol triacrylate, HCPE, urethane resin and methyl silicon resin gross weight, then ultrasonic disperse 32 minutes;
(2) ammonium polyphosphate, trimeric cyanamide, sodium carbonate and step (1) gained are mixed, add thickening material, dispersion agent and defoamer, stir with the speed of 340r/min, stir 70 minutes, grinding;
(3) in step (2) gained, add mill base, the amount of mill base is 0.7% of step (2) gained gross weight, stirs evenly, to obtain final product.
Embodiment 5 one kinds of aqueous fire-proof coatings, the main raw material getting following weight parts is prepared from (every part is 2kg): ammonium polyphosphate 20 parts, trimeric cyanamide 12 parts, pentaerythritol triacrylate 8.4 parts, HCPE 14 parts, urethane resin 7.6 parts, methyl silicon resin 6 parts, 3.5 parts, sodium carbonate, deionized water 19 parts, thickening material 1.8 parts, dispersion agent 3.4 parts, defoamer 0.27 part, mill base is appropriate.
The preparation method of above-mentioned aqueous fire-proof coating is:
(1) pentaerythritol triacrylate, HCPE, urethane resin and methyl silicon resin are mixed, add deionized water, stir 55 minutes, add film coalescence aid, the amount of film coalescence aid is 0.6% of pentaerythritol triacrylate, HCPE, urethane resin and methyl silicon resin gross weight, then ultrasonic disperse 30 minutes;
(2) ammonium polyphosphate, trimeric cyanamide, sodium carbonate and step (1) gained are mixed, add thickening material, dispersion agent and defoamer, stir with the speed of 320r/min, stir 60 minutes, grinding;
(3) in step (2) gained, add mill base, the amount of mill base is 0.6% of step (2) gained gross weight, stirs evenly, to obtain final product.
The present invention's main raw material used:
Ammonium polyphosphate: ammonium polyphosphate is also known as ammonium polyphosphate or polycondensation ammonium phosphate (being called for short APP).Ammonium polyphosphate is nonpoisonous and tasteless, does not produce etchant gas, and water absorbability is little, and thermostability is high, is a kind of non-halogen fire retardant of excellent property.Characteristic and purposes: APP is widely used in expanding fire-proof paint, polyethylene, polypropylene, urethane, epoxy resin, rubber item, fiberboard and powder extinguishing agent etc., is a kind of efficient phosphorus system halogen-free smoke resistance flame resistance agent of use safety.APP has very high flame retardant resistance, dimensional stability, hydrolytic resistance and thermotolerance in hard polyurethane foam.Ammonium polyphosphate has expandable flame retardant function, therefore is more conducive to falling cigarette and anti-dripping melt, although be solid, is easy to disperse in polyvalent alcohol.In general, the polyurethane component containing more polyester polyol is more suitable for APP fire-retardant than polyether polyatomic alcohol component.APP, except being applicable to rigid urethane foam and polyester flexible urethane foam, is also applicable to other resins, tackiness agent and coating.
Trimeric cyanamide: trimeric cyanamide, is commonly called as melamine, extract of protein, is a kind of triazines nitrogen heterocyclic ring organic compound, is used as industrial chemicals.It is white monoclinic crystal, almost tasteless, is slightly soluble in water (3.1g/L normal temperature), dissolves in methyl alcohol, formaldehyde, acetic acid, hot ethylene glycol, glycerine, pyridine etc., is insoluble to acetone, ethers, is harmful to health, be not useable for food-processing or food additives.Main application: be polymerized with formaldehyde condensation and can obtain melamine resin, can be used for plastics and coatings industry, also can do the anti-folding of yarn fabric, anti-shrinking agent.Its modified resin can do lovely luster, the metallic paint that durable, hardness is good.It also can be used for firm, heat-resisting fancy veneer, and building paper and grey leather are tanned the caking agent of skin agent, synthesizing fireproof laminate, the fixing agent of water-resisting agent or stiffening agent etc.Be obtained 582 melamine resins of raw material by trimeric cyanamide, formaldehyde, butanols.As the flow agent of solvent borne polyurethane coating, effect spy is good.Manufacture the main raw material of terpolycyantoamino-formaldehyde resin, as organic element analysis reagent, also make tanning agent and the weighting agent of leather processing for synthesis that is organic and resin.Be polymerized with formaldehyde condensation and can obtain melamine resin, can be used for plastics and coatings industry, also can do the anti-folding of yarn fabric, anti-shrinking agent.Its modified resin can do lovely luster, the metallic paint that durable, hardness is good.Be polymerized with formaldehyde condensation the melamine resin made be widely used in Wood construction formwork manufacture and in processing.Can be used for the waterproof of template surface and the adhesion of block board, what increase template reuses number of times.
Pentaerythritol triacrylate: pentaerythritol triacrylate is the acrylate that 1 part of tetramethylolmethane and three parts of vinylformic acid generation esterifications obtain, possesses Typical acrylates feature, in addition, also have a pendant hydroxyl group in molecule, the existence of hydroxyl enhances the polarity of molecule on the one hand, reduces volatility, on the other hand, can as reaction site, be connected on other materials by the method for grafting, for the preparation of matrix material.
HCPE: HCPE is the high molecular polymer with excellent comprehensive performance, the chemistry of its excellence, physicals be other materials incomparable, it produces a new generation to have anticorrosion, the high gloss of band rust of several functions, have the optimum feed stock of the coating of decorate properties.Thus the materials such as substituted epoxy resin, chlorinated rubber, chlorosulfonated polyethylene, chlorinated polyvinyl chloride, its main characteristic shows: 1, excellent chemical stability, the corrosive goodses such as strong acid, highly basic, strong oxidizer are verified, and it does not play corrosive nature, and its erosion resistance is higher 1-2 times than chlorinated polyvinyl chloride, chlorosulfonated polyethylene.2, excellent weather resisteant.After making and painting film, extremely low to water, gas and oxygen permeability, expose in an atmosphere all the year round, its property indices remains unchanged.3, because it contains high chlorine composition, can effectively gas defence, mildew-resistant, difficult combustion, flame retardant properties are splendid.Range of application: the application of HCPE is mainly in coating: 1, protective system: bridge, steel frame, chemical industry equipment, saltern, the important protective system of fishing ground equipment, band rust anti-corrosion primer, pipeline coating.2, marine finish (comprising the outer coating materials of hull and the inner coating of cabin)-cabin priming paint and steamer decorate finish paint and maintenance paint entirely.3, frie retardant coating (anti-flaming dope)-comprise the outer frie retardant coating of timber structure and the outer frie retardant coating of steel construction.4, building coating-comprise skin (decoration) coating, the priming paint etc. of the reinforcement of concrete.5, coating container.6, machine poplar, road, mark and marking paint (paint for lines on road surface) HCPE are in the application of other field: can be used as paper, the heat-proof modifier of the tackiness agent of the rubber series such as fireproofing agent (flame retardant resistance), neoprene latex, butadiene acrylonitrile rubber of fiber, and paper, aluminium foil ink properties-correcting agent.
Urethane resin: urethane resin as a kind of macromolecular material with high strength, anti tear, the characteristic such as wear-resisting, in field widespread uses such as daily life, industrial and agricultural production, medical science.Be used for preparing polyether(poly)urethane.Polymerization process is different with material character.First prepare low molecular weight diol during synthetic elastomer, then react with excessive aromatic isocyanate, generating isocyanic ester is the prepolymer of end group, more same chain expansion of succinic acid, obtains thermoplastic elastomer; If also crosslinked further with aromatic diamine chain extension, obtain casting type elastomerics.Purposes: urethane resin as a kind of macromolecular material with high strength, anti tear, the characteristic such as wear-resisting, in field widespread uses such as daily life, industrial and agricultural production, medical science.Polyurethane elastomer is used as cylinder, travelling belt, flexible pipe, auto parts, sole, synthetic leather, electric wire and medical artificial organ etc.; Flexible foam is used for the liner of vehicle, room, clothes, hard foam is as heat insulation, sound-absorbing, packaging, insulation and low ratio foamed synthetic wood, coating is used for advanced vehicle, furniture, wood and metal protection, pond dam and building anti-seepage material, and fabric coating etc.Tackiness agent has good clinging power to metal, glass, pottery, leather, fiber etc.In addition urethane also can be made into emulsion, magneticsubstance etc.
Methyl silicon resin: methyl silicon resin take siloxane bond as the polysiloxane of main chain, becomes slightly elasticity, have the cross-linked resin of toughness after curing cross-linked.Be a kind of novel fire resistant insulating material of excellent property, this resin has high temperature resistant, and electrical insulation capability is good, and moisture resistance waterproof, fire-retardant, protection against corrosion etc. are multiple.Be widely used in the industries such as aerospace industry, household electrical appliance, electronics, motor, chemical industry, modified oxidized metal, mica insulator.
Mill base: mill base is the work piece be dispersed in by pigment or pigment and stopping composition in paint vehicle.The title oil pastes being tackiness agent with pure oil.The title resin mill base being tackiness agent with resin paint vehicle.With water be medium add surfactant-dispersed color stuffing slurry be called aqueous color paste.Because paint vehicle kind is a lot, mill base kind is also a lot.In order to make pigment etc. be dispersed in better in paint vehicle, often in the fabrication process, add a small amount of tensio-active agent, add zinc naphthenate etc.
Test example is in order to test the performance of gained aqueous fire-proof coating of the present invention (embodiment 5), and measure its each index, result is as shown in table 1.
Table 1: products obtained therefrom testing performance index of the present invention
Can be drawn by table 1, products obtained therefrom duration of fire resistance of the present invention is long, and adhesion strength is high, has excellent fire performance.
Finally it should be noted that, embodiment is the embodiment of optimum of the present invention, be not limited to the present invention, although with reference to previous embodiment to invention has been detailed description, for a person skilled in the art, it still can be modified to the technical scheme described in foregoing embodiments, or carries out equivalent replacement to wherein portion of techniques feature.Within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. an aqueous fire-proof coating, is characterized in that, takes off the main raw material stating weight proportion and is prepared from: ammonium polyphosphate 16-23, trimeric cyanamide 8-14, pentaerythritol triacrylate 7-10, HCPE 10-16, urethane resin 6-9, methyl silicon resin 4-8, sodium carbonate 2-5, deionized water 17-21, thickening material 1.5-2.1, dispersion agent 1.5-4.5, defoamer 0.22-0.32, mill base is appropriate.
2. aqueous fire-proof coating as claimed in claim 1, is characterized in that, take off the main raw material stating weight proportion and be prepared from: ammonium polyphosphate 18-22, trimeric cyanamide 10-13, pentaerythritol triacrylate 8-9, HCPE 13-15, urethane resin 7-8, methyl silicon resin 5-7, sodium carbonate 3-4, deionized water 18-20, thickening material 1.7-1.9, dispersion agent 2.3-4.2, defoamer 0.25-0.28, mill base is appropriate.
3. aqueous fire-proof coating as claimed in claim 1, is characterized in that, take off the main raw material stating weight proportion and be prepared from: ammonium polyphosphate 20, trimeric cyanamide 12, pentaerythritol triacrylate 8.4, HCPE 14, urethane resin 7.6, methyl silicon resin 6, sodium carbonate 3.5, deionized water 19, thickening material 1.8, dispersion agent 3.4, defoamer 0.27, mill base is appropriate.
4. the preparation method of the aqueous fire-proof coating as described in as arbitrary in claims 1 to 3, it is characterized in that, step is as follows:
(1) pentaerythritol triacrylate, HCPE, urethane resin and methyl silicon resin are mixed, add deionized water, stir 30-70 minute, add film coalescence aid, the amount of film coalescence aid is the 0.3-0.8% of pentaerythritol triacrylate, HCPE, urethane resin and methyl silicon resin gross weight, then ultrasonic disperse 25-35 minute;
(2) ammonium polyphosphate, trimeric cyanamide, sodium carbonate and step (1) gained are mixed, add thickening material, dispersion agent and defoamer, stir with the speed of 250-360r/min, stir 40-80 minute, grinding;
(3) in step (2) gained, add mill base, the amount of mill base is the 0.4-0.8% of step (2) gained gross weight, stirs evenly, to obtain final product.
5. the preparation method of aqueous fire-proof coating as claimed in claim 4, is characterized in that, stirs 35-60 minute (preferably stirring 55 minutes) in step (1).
6. the preparation method of aqueous fire-proof coating as claimed in claim 4, it is characterized in that, the amount of film coalescence aid is pentaerythritol triacrylate in step (1), the amount of the preferred film coalescence aid of 0.4-0.7%(of HCPE, urethane resin and methyl silicon resin gross weight is 0.6% of pentaerythritol triacrylate, HCPE, urethane resin and methyl silicon resin gross weight).
7. the preparation method of aqueous fire-proof coating as claimed in claim 4, is characterized in that, ultrasonic disperse 27-32 minute again (preferably again ultrasonic disperse 30 minutes) in step (1).
8. the preparation method of aqueous fire-proof coating as claimed in claim 4, is characterized in that, stir (preferably stirring with the speed of 320r/min) in step (2) with the speed of 280-340r/min.
9. the preparation method of aqueous fire-proof coating as claimed in claim 4, is characterized in that, stirs 50-70 minute (preferably stirring 60 minutes) in step (2).
10. the preparation method of aqueous fire-proof coating as claimed in claim 4, is characterized in that, in step (3), the amount of mill base is the amount of the preferred mill base of 0.5-0.7%(of step (2) gained gross weight is 0.6% of step (2) gained gross weight).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610093192.4A CN105566968B (en) | 2016-02-19 | 2016-02-19 | A kind of aqueous fire-proof coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610093192.4A CN105566968B (en) | 2016-02-19 | 2016-02-19 | A kind of aqueous fire-proof coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105566968A true CN105566968A (en) | 2016-05-11 |
| CN105566968B CN105566968B (en) | 2018-04-20 |
Family
ID=55877632
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610093192.4A Active CN105566968B (en) | 2016-02-19 | 2016-02-19 | A kind of aqueous fire-proof coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105566968B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105885629A (en) * | 2016-05-25 | 2016-08-24 | 马鞍山市顺达环保设备有限公司 | Fire-resistant coating for high-temperature environmental protection equipment and preparation method thereof |
| CN106189769A (en) * | 2016-07-04 | 2016-12-07 | 浙江工贸职业技术学院 | A kind of Environmental Protective Water-paint and preparation technology thereof |
| CN109644978A (en) * | 2019-02-28 | 2019-04-19 | 国网河南省电力公司邓州市供电公司 | A kind of electric power cable scarer |
| CN110436809A (en) * | 2019-09-06 | 2019-11-12 | 石家庄易辰防火保温材料有限公司 | A kind of fire-type expanded vermiculite and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001207108A (en) * | 2000-01-25 | 2001-07-31 | Mitsuboshi Belting Ltd | Formable fire-retardant coating composition for waterproof sheet and fireproofing work of building using the composition |
| CN1380368A (en) * | 2002-04-11 | 2002-11-20 | 海洋化工研究院 | Expanding fire-proof paint |
| CN104194508A (en) * | 2014-09-18 | 2014-12-10 | 苏州圣谱拉新材料科技有限公司 | Fire retardant coating for indoor decoration and preparation method thereof |
| CN104693854A (en) * | 2013-12-06 | 2015-06-10 | 青岛大运机械有限公司 | Transparent fireproof paint used for lost foam |
-
2016
- 2016-02-19 CN CN201610093192.4A patent/CN105566968B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001207108A (en) * | 2000-01-25 | 2001-07-31 | Mitsuboshi Belting Ltd | Formable fire-retardant coating composition for waterproof sheet and fireproofing work of building using the composition |
| CN1380368A (en) * | 2002-04-11 | 2002-11-20 | 海洋化工研究院 | Expanding fire-proof paint |
| CN104693854A (en) * | 2013-12-06 | 2015-06-10 | 青岛大运机械有限公司 | Transparent fireproof paint used for lost foam |
| CN104194508A (en) * | 2014-09-18 | 2014-12-10 | 苏州圣谱拉新材料科技有限公司 | Fire retardant coating for indoor decoration and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 马一平等: "《建筑功能材料》", 31 March 2014, 同济大学出版社 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105885629A (en) * | 2016-05-25 | 2016-08-24 | 马鞍山市顺达环保设备有限公司 | Fire-resistant coating for high-temperature environmental protection equipment and preparation method thereof |
| CN106189769A (en) * | 2016-07-04 | 2016-12-07 | 浙江工贸职业技术学院 | A kind of Environmental Protective Water-paint and preparation technology thereof |
| CN106189769B (en) * | 2016-07-04 | 2018-09-18 | 浙江工贸职业技术学院 | A kind of Environmental Protective Water-paint and its preparation process |
| CN109644978A (en) * | 2019-02-28 | 2019-04-19 | 国网河南省电力公司邓州市供电公司 | A kind of electric power cable scarer |
| CN110436809A (en) * | 2019-09-06 | 2019-11-12 | 石家庄易辰防火保温材料有限公司 | A kind of fire-type expanded vermiculite and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105566968B (en) | 2018-04-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101649153B (en) | Organic silicon modified acrylic ester aqueous wood lacquer latex and synthesizing method thereof | |
| CN104130671B (en) | A kind of aqueous ultra-thin expansion type fireproof coating for steel construction and preparation method thereof | |
| CN105566968A (en) | Water-based fireproof coating and preparing method thereof | |
| CN101323727A (en) | Environment-friendly aqueous expansion type fireproof coating and preparation thereof | |
| CN109439083A (en) | A kind of ultrathin expansion type steel structure aqueous fire-proof coating and preparation method thereof | |
| CN102850881A (en) | Environment-friendly fire-retardant paint | |
| CN112266679A (en) | Preparation method of flame-retardant and waterproof water-based core-shell resin coating and paint | |
| CN109777223A (en) | Colorful stone-like coating and preparation method thereof | |
| CN109233490A (en) | A kind of fire-retardant alkali-resistant primer of aqueous environmental friendly indoor and preparation method thereof | |
| CN102876172A (en) | Water-based fireproof paint | |
| CN104745071A (en) | Polyurethane waterproof flame-retardant paint and preparation method thereof | |
| CN107760190A (en) | Fire-retardant coatings for furniture and production method | |
| CN105219197A (en) | A kind of production formula of true mineral varnish and technique | |
| CN105542587A (en) | Steel structure fireproof coating and preparation method thereof | |
| CN109096920A (en) | A kind of exterior wall alkali-resistant primer and preparation method thereof | |
| CN107815240A (en) | Anti-corrosion coatings for furniture and production method | |
| CN107502102A (en) | A kind of high weather resistant water-thinned multicolor finish of water resistant low temperature and preparation method thereof | |
| CN104745070A (en) | Polyurethane exterior-wall anti-corrosive flame-retarded coating and preparation method thereof | |
| CN113999583A (en) | Ultrathin flame-retardant water-based paint for manufacturing tank and preparation method thereof | |
| CN102051114B (en) | Rubber substrate base coat and preparation method thereof | |
| CN107974176A (en) | Alkyd resin exterior coating | |
| CN113354966A (en) | Development and preparation method of water-based inorganic real stone paint | |
| CN104762015A (en) | Polyurethane internal wall sound-absorption fireproof paint and preparation method thereof | |
| CN104341877A (en) | Novel fireproof coating | |
| CN106752189A (en) | A kind of flame retardant type water-repellent paint used for building exterior wall and its production method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: 810600 Qinghai Haidong City Ping min Road No. 77 sea area 3 building 1-301 Applicant after: Xu Ran Address before: Huaiyin District of Ji'nan City, Shandong province 250000 West Shili River Street No. 102 Applicant before: Xu Ran |
|
| CB02 | Change of applicant information | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Liu Yingwu Inventor after: Liu Fengyu Inventor before: Request for anonymity |
|
| TA01 | Transfer of patent application right |
Effective date of registration: 20180313 Address after: 266000, Shandong, Qingdao province Chengyang District, Hong Kong beach after the streets of the community Applicant after: QINGDAO TIANDICAI COATING CO.,LTD. Address before: 810600 Qinghai Haidong City Ping min Road No. 77 sea area 3 building 1-301 Applicant before: Xu Ran |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 266000 houhaixi community, Jihongtan street, Chengyang District, Qingdao City, Shandong Province Patentee after: Shandong Tiandi Cai New Materials Co.,Ltd. Address before: 266000 houhaixi community, Jihongtan street, Chengyang District, Qingdao City, Shandong Province Patentee before: QINGDAO TIANDICAI COATING CO.,LTD. |
|
| CP01 | Change in the name or title of a patent holder |