CN105552113B - A kind of radiosensitive field-effect transistor and preparation method thereof - Google Patents

A kind of radiosensitive field-effect transistor and preparation method thereof Download PDF

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CN105552113B
CN105552113B CN201610111860.1A CN201610111860A CN105552113B CN 105552113 B CN105552113 B CN 105552113B CN 201610111860 A CN201610111860 A CN 201610111860A CN 105552113 B CN105552113 B CN 105552113B
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preparation
silicon dioxide
electrode
radfet
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CN105552113A (en
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王漪
张晓密
伦志远
丛瑛瑛
董俊辰
赵飞龙
韩德栋
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Peking University
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/06Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
    • H01L29/10Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions with semiconductor regions connected to an electrode not carrying current to be rectified, amplified or switched and such electrode being part of a semiconductor device which comprises three or more electrodes
    • H01L29/1025Channel region of field-effect devices
    • H01L29/1029Channel region of field-effect devices of field-effect transistors
    • H01L29/1033Channel region of field-effect devices of field-effect transistors with insulated gate, e.g. characterised by the length, the width, the geometric contour or the doping structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/12Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/16Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only elements of Group IV of the Periodic Table
    • H01L29/1606Graphene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET

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Abstract

The invention discloses the radiosensitive field-effect transistors (RadFET) and preparation method thereof on a kind of silicon substrate.The isolation trench channel layer of the device is followed successively by:Silicon dioxide layer, graphene film and the silicon dioxide layer of dry process prepared by wet method.Multi-layer graphene material enhances RadFET detector sensitivities as channel layer;And loose silicon oxide layer prepared by wet method plays cushioning effect, can effectively slow down the device damage that High energy particles Radiation is brought, while avoiding graphene film and being in direct contact the interface problem brought with source-drain electrode, improve service life and the performance of device.In addition, carrying out ion implantation technology to the silica of dry process, introduce the particle trap of higher concentration, can effective adjusting device threshold voltage, while reducing source-drain contact resistance, enhance device sensitivity.The RadFET detectors are simple for process, manufacturing cost is low, are suitable for the detection of total radiation dose, are with a wide range of applications.

Description

A kind of radiosensitive field-effect transistor and preparation method thereof
Technical field
The invention belongs to field of manufacturing semiconductor devices, and in particular to the radiosensitive field effect transistor on a kind of silicon substrate Manage the design and preparation method of (RadFET).
Background technology
RadFET detectors are mainly used for the measurement of space radiation accumulated dose, can be evaluated whether spacecraft electronics member device Part, material and facility by space radiation influence degree.Since total radiation dosage is one of the factor of electronic component failure, The monitoring of space radiation accumulated dose can design for the satellite long-life and provide engineering data.There is complicated radiation ring in space Border includes mainly particle radiation and electromagnetic radiation.These space radiations are to aircraft material, electronic device, equipment and highflyer Safety of member etc. constitutes serious threat, therefore develops advanced radiation detector and correlation detection technology, research space environment Influence to spacecraft and spacefarer becomes one of the important content of aerospace engineering safety guarantee.In addition, in non-space field, RadFET detectors are also applied to detection (such as radiating medical, radiation experiments, the integrated circuit system of various terrestrial surface radiation meterings Make processing line and various large and medium-sized detecting devices etc.).
The operation principle of radiation detector is mainly used to based on the interaction between particle and substance to radiation and particle Microphenomenon observed and studied.The principle of the gate oxide charge sensitive of device can be obtained according to MOSFET RadFET detectors.In RadFET detectors, thick grating oxide layer is excited under the action of ray, is ionized, and generates electron-hole It is right.Electronics escapes under electric field action from grid, and hole is then fixed to Oxide trapped charge, to change the threshold value electricity of MOSFET Pressure, and by relevant reading circuit and be amplified, the absorbed dose of radiation one of obtained output voltage signal and region It causes, radiation source is detected.
According to the difference of the substance to interact with high energy particle, common radiation detector can be divided into detection of gas Device, scintillation detector, semiconductor detector and other detectors.In contrast, semiconductor RadFET detectors have convenient for collection At, it is small, light-weight, low in energy consumption the advantages that, be it is a kind of preferably penetrating radiation dose detector, can be widely applied to aviation and navigate The fields such as its detection, nuclear industry protection and medical radiation.
Currently, the exploration of preparation research and its irradiation model in relation to RadFET detectors is deepening continuously, for example aoxidize The factors such as layer thickness, technique inject the research of detector sensitivity and adjusting thresholds the research etc. to detector performance.Stone The excellent specific property of black alkene material makes it relatively be suitably applied RadFET detectors, and the RadFET detectors based on graphene Correlative study is in the infancy.
Invention content
The purpose of the present invention is to provide a kind of preparation methods of radiosensitive field-effect transistor (RadFET), it is intended to carry The performance of high RadFET detectors.
The technical scheme is that:
A kind of field-effect transistor based on graphene film material, including substrate, gate electrode, gate medium, channel layer and Source-drain electrode.Wherein, substrate is monocrystalline silicon, forms gate electrode on substrate, and gate dielectric layer is formed on gate electrode, in gate medium Isolation trench channel layer is formed on layer, loose silicon dioxide layer that insulated trenches layer material is prepared by wet method, semiconductor graphene film Layer (improves sensitivity), and one layer of compact silicon dioxide layer of dry process is constituted on graphene film, at the both ends of channel layer point Source electrode and drain electrode is not formed.
The preparation method of the radiosensitive field-effect transistor of the present invention includes the following steps:
1) layer of conductive film is grown on a silicon substrate, and chemical wet etching forms gate electrode;
2) photoetching gate dielectric layer and raceway groove layer pattern, prepared by continuous dry process grows gate dielectric layer, in isolation trench channel layer Loose silicon dioxide layer using wet processing prepare, cover graphene film layer, one layer of dry process on graphene film Compact silicon dioxide layer is then doped top layer silicon dioxide by ion implanting, obtains channel layer;
3) layer of conductive film is grown, chemical wet etching forms source electrode and drain electrode;
4) grow one layer of passivation dielectric layer, chemical wet etching formed gate electrode, source electrode and drain electrode fairlead;
5) one layer of metallic film is grown, chemical wet etching forms metal electrode and interconnection.
Wherein:
In step 1), gate electrode uses the conductive materials such as metallic aluminium Al or Titanium Ti;
In step 2), the material of gate dielectric layer is the insulating materials such as silica;Isolation trench channel layer silica passes through Wet process oxidation technology obtains, and structure is more loose silicon dioxide layer.
In step 2), using the graphene film with highly conductive characteristic of semiconductor, film thickness is single layer or 2~4 layers, stone The silicon oxide layer covered on black alkene film is obtained by dry oxidation.It selects phosphorus or boron ion to carry out ion implanting, forms N or P The silica of type doping;
In step 3), the conductive film of source electrode and drain electrode is transparent using tin indium oxide ITO or zinc oxide aluminum AZO etc. Conductive material.
The design parameter of radiosensitive field-effect transistor is:The breadth length ratio (W/L) of device is 300/15~700/100 (micron);Raceway groove layer thickness at 200~800 nanometers, wherein:Loose silicon dioxide layer prepared by wet method is at 150~700 nanometers.
Beneficial effects of the present invention:
The present invention provides the designs and its preparation of the radiosensitive field-effect transistor (RadFET) on a kind of silicon substrate Method, the channel layer using the single-layer or multi-layer grapheme material of highly conductive characteristic of semiconductor as device, enhances RadFET Detector sensitivity, the loose silicon oxide layer under graphene film layer play cushioning effect, can effectively slow down high energy particle The device damage that radiation zone comes, while avoiding graphene film and being in direct contact the interface problem brought with electrode, improve device The service life of part and performance.In addition, carrying out ion implantation technology to the silica in channel layer, the impurity for introducing higher concentration is fallen into Trap, can effective adjusting device threshold voltage, while reducing source-drain contact resistance, enhance device sensitivity.The RadFET Detector is simple for process, manufacturing cost is low, is suitable for the detection of total radiation dose, is with a wide range of applications.
Description of the drawings
Fig. 1 is the sectional view of the radiosensitive field-effect transistor (RadFET) of the present invention;
Fig. 2 is the vertical view of the radiosensitive field-effect transistor (RadFET) of the present invention;
Fig. 3 (a)~(g) sequentially show the radiosensitive field-effect transistor (RadFET) of the present invention preparation method and The main technological steps of the device one embodiment.Wherein, (a) is the structural schematic diagram of silicon substrate;(b) it is to form gate electrode Processing step;(c) it is the processing step for forming gate dielectric layer and channel layer first layer;(d) it is to prepare graphene in channel layer to turn The processing step of shifting;(e) it is the processing step of channel layer top layer silicon dioxide layer;(f) it is ion implanting to prepare channel layer Processing step;(g) it is the processing step for forming source electrode and drain electrode.
Specific implementation mode
Below in conjunction with the accompanying drawings, by specific embodiment, the present invention is further explained.
As depicted in figs. 1 and 2, field-effect transistor of the invention includes:Substrate 1, gate electrode 2, gate dielectric layer 3, insulation Wet oxygen silicon dioxide layer 4, graphene film 5, dry oxygen silicon dioxide layer 6 in channel layer, source-drain electrode 7.Wherein, in substrate 1 Upper formation gate electrode 2 forms gate dielectric layer 3 on gate electrode 2, isolation trench channel layer 4,5,6 is formed on gate dielectric layer 3, in ditch Both ends in channel layer 6 are respectively formed source-drain electrode 7.
One embodiment of the field transistor preparation method of the present invention is by shown in Fig. 3 (a) to (g), including the following steps:
1) it uses monocrystalline silicon as device substrate 1, as shown in Fig. 3 (a), is grown using dc sputtering processes on substrate 1 The metal Ti of one layer of 10~150 nanometer thickness, then etches gate electrode 2, as shown in Fig. 3 (b);
2) it uses dry method-wet oxidation to form the silicon dioxide layer of 100~500 nanometer thickness, obtains gate dielectric layer 3 and insulation The first layer 4 of channel layer.Gate oxide and raceway groove layer pattern are obtained using photoetching process, as shown in Fig. 3 (c);Wherein dry method is given birth to After 50 nanometers of long silica, direct wet method grows 50~700 nanometers of silica 1.
3) by the single layer of the highly conductive semiconductor prepared or 2~4 layer graphene films be transferred to isolation trench channel layer 4 it On, as shown in 4 in Fig. 3 (d).
4) 6 silicon dioxide growth of isolation trench channel layer is carried out, 50 nanometers of silica is grown using dry method, as 6 in Fig. 3 (e) It is shown;
5) boron ion doping is carried out to the top layer silicon dioxide obtained by step 4) as ion implanting.Such as Fig. 3 (f) institutes Show;
6) magnetron sputtering technique is used to grow one layer of ITO conductive film, thickness is 20~200 nanometers, photoetching, etching shape At source electrode and drain electrode 7, as shown in Fig. 3 (g);
7) one layer of silicon nitride passivation dielectric layer is grown according to standard technology, photoetching, etching form gate electrode, source electrode and leakage The fairlead of electrode;
8) one layer of metal Al or transparent conductive film are grown, photoetching, etching form electrode and interconnection.
It is finally noted that the purpose for publicizing and implementing example is to help to further understand the present invention, but this field Technical staff be appreciated that:Without departing from the spirit and scope of the invention and the appended claims, various to replace and repair It is all possible for changing.Therefore, the present invention should not be limited to embodiment disclosure of that, and the scope of protection of present invention is to weigh Subject to the range that sharp claim defines.

Claims (6)

1. a kind of preparation method of the field-effect transistor based on graphene film material, includes the following steps:
1) layer of conductive film is grown on a silicon substrate, and chemical wet etching forms gate electrode;
2) photoetching gate dielectric layer and raceway groove layer pattern, continuously grow gate dielectric layer, and wet processing prepares silicon dioxide layer, then covers Lid graphene film layer, dry method grows one layer of compact silicon dioxide on graphene film, then by ion implanting to top layer Silica is doped, and obtains channel layer;
3) layer of conductive film is grown, chemical wet etching forms source electrode and drain electrode;
4) grow one layer of passivation dielectric layer, chemical wet etching formed gate electrode, source electrode and drain electrode fairlead;
5) one layer of metallic film is grown, chemical wet etching forms metal electrode and interconnection.
2. preparation method as described in claim 1, which is characterized in that in step 1), gate electrode uses metallic aluminium Al or gold Belong to titanium Ti.
3. preparation method as described in claim 1, which is characterized in that in step 2), gate dielectric layer is prepared by dry process Silicon dioxide insulator material.
4. preparation method as described in claim 1, which is characterized in that in step 2), phosphorus or boron ion is selected to carry out ion Injection forms N or the silica of p-type doping.
5. preparation method as described in claim 1, which is characterized in that in step 3), the conductive thin of source electrode and drain electrode Film uses tin indium oxide ITO or zinc oxide aluminum AZO transparent conductive materials.
6. preparation method as described in claim 1, which is characterized in that the graphene film is single layer or 2~4 layer graphenes Material.
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KR101840114B1 (en) 2016-05-30 2018-03-19 재단법인 멀티스케일 에너지시스템 연구단 Highly sensitive sensor comprising cracked transparent conductive thin film and process for preparing same
CN108615786B (en) * 2018-05-30 2020-01-17 上海大学 Cadmium zinc telluride radiation sensitive field effect transistor and preparation method thereof
CN110911521B (en) * 2019-11-22 2021-07-13 西安交通大学 Multi-band graphene detector with multilayer coupling structure and preparation process thereof
CN111142146A (en) * 2019-12-26 2020-05-12 兰州空间技术物理研究所 Portable radiation dosimeter
CN113410135B (en) * 2021-06-15 2023-06-30 西安微电子技术研究所 Manufacturing method of anti-radiation junction field effect transistor
CN114864708A (en) * 2022-05-06 2022-08-05 北京交通大学 Multi-grid graphene field effect transistor type photoelectric sensor and preparation method thereof
CN115188825B (en) * 2022-07-04 2024-01-30 弘大芯源(深圳)半导体有限公司 Method for manufacturing radiation-resistant metal oxide semiconductor field effect device

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CN102184858A (en) * 2011-04-07 2011-09-14 复旦大学 Preparation method of graphene field effect transistor
US9105853B2 (en) * 2011-12-01 2015-08-11 International Business Machines Corporation N-dopant for carbon nanotubes and graphene

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