CN105544229B - 一种装饰用基材的隔热保温涂层整理工艺 - Google Patents

一种装饰用基材的隔热保温涂层整理工艺 Download PDF

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CN105544229B
CN105544229B CN201610103067.7A CN201610103067A CN105544229B CN 105544229 B CN105544229 B CN 105544229B CN 201610103067 A CN201610103067 A CN 201610103067A CN 105544229 B CN105544229 B CN 105544229B
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parts
coating
thermal insulation
decorative substrate
finishing technique
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CN105544229A (zh
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倪海霞
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Tianjin Jingzi Building Materials Co Ltd
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Abstract

本发明涉及一种装饰用基材的隔热保温涂层整理工艺，将涂层剂以泡沫体的形式连续施加至平坦的柔性基材上，在高于80℃的温度下将施加的涂层通过红外辐照器和/或采用热空气进行干燥，之后对所述涂层进行冷压印，该制备方法克服已有隔热保温装饰涂料涂层的缺点，提供一种保温隔热型、无污染、装饰性好的弹性薄层隔热保温涂层整理工艺。

Description

一种装饰用基材的隔热保温涂层整理工艺
技术领域
本发明涉及一种装饰材料整理工艺，特别涉及一种装饰用基材的隔热保温涂层整理工艺
背景技术
目前用来作为保温隔热的材料大致可分为两种：低导热系数轻质材料，热反射材料。低导热系数轻质 材料主要依靠材料本身的结构及化学性质达到隔热的目的，主要材料有：多孔轻质材料，闭孔空心(或填 充气体)材料，特殊纤维类材料等。热反射材料则依靠其能够反射波长在红外区域的电磁波而达到隔热的 目的，主要材料为一些高红外热反射率的金属、合金及化合物，如四氧化三铁，金属镍，铝箔，二氧化钛 等。
目前应用于化工工业领域，特别是高温储罐、泵体、管道外隔热保温的隔热保温材料，基本上都是用 玻璃棉类、矿物棉类缠绕罐体，外加镀锌铁皮或者铝箔纸包覆。这种材料只有保温隔热作用，起不到防腐、 防水功能，不利于南方潮湿区域以及埋藏在地下的设备；并且这些材料对皮肤有很大刺激性，易呼入呼吸 道，材料含有致癌物质，造成施工和后期维护难度大；同时生产这种材料属高耗能行业，目前在大部分城 市已经被限制使用。因此寻找一种节能环保、使用年限长的新型保温材料具有非常重要的意义。
发明内容
本发明所要解决的技术问题是克服已有隔热保温装饰涂料涂层的缺点，提供一种保温隔热型、无污染、装饰性好的弹性薄层隔热保温涂层整理工艺。
为了实现上述目的，本发明采用如下技术方案：一种装饰用基材的隔热保温涂层整理工艺，将涂层剂以泡沫体的形式连续施加至平坦的柔性基材上，在高于80℃的温度下将施加的涂层通过红外辐照器和/或采用热空气进行干燥，之后对所述涂层进行冷压印；所述涂层的层厚度为4-6mm；其中以泡沫体的形式施加所述涂层剂，并且通过向所述涂层剂中引入空气、 氮气、CO2或它们的混合物作为气体，来形成所述泡沫体；所述涂层剂包含下列重量份的组分：
乙烯-醋酸乙烯共聚树脂组成的基体乳液 100份，
三(2，3-二溴丙基)异三聚氰酸酯 10-23份，
缔合型水性聚氨酯乳液 1-3份，
聚丙烯酸酯乳液 5-10份，
气相二氧化硅 2-4份，
磺基琥珀酸酯 1-1.5份，
磺基琥珀酰胺 0.3-0.8份，
硅氮化合物 6-16份，
环氧乙烷/环氧丙烷嵌段共聚物 5-13份，
改性剂 12-20份；
木纤维粉 20-35份；
铝酸酯 1-10 份；
所述改性剂由下列重量份的原料制成：硅藻土40-45、丙烯酸二甲基氨基乙酯4-5、二缩三丙二醇二丙烯酸酯2-3、氧化锌5-6、玉石4-5、3-氨丙基三甲氧基硅烷2-3、交联剂TAC1-2、葡萄糖酸锌1-2、硬脂酸锌1-2、玫瑰精油0.1-0.2。
进一步地，所述涂层剂的含固量为30-50％，粘度为1000-5000mpa·s。
进一步地，所述发泡比控制在1∶1.2-10之间。
进一步地，所述基材选自聚酯纤维、纤维素纤维或木质素纤维构成的亲水性聚合物构成。
本发明涂层的有益效果如下：针对已有技术不足而提供一种集弹性、薄层、隔热、保温等优点于一体的多功能隔热涂层，同时，本发明的装饰用涂层除具有隔热保温性能外，还具有很强的耐候性能，以保证涂层在较薄(总厚度小于等于0.6毫米)的情况下仍能保持良好的保温隔热性；通过配置特殊的弹性树脂乳液，使组成的涂层具有良好的弹性，并在很广范的光谱内具有反射效果，漆膜延伸率可高达370％，对墙体所产生的龟裂具有较强的自动封闭性能；并采用了表面改性剂改性保护技术，延长了涂层的保温特性。
具体实施方式
下面通过实施例，对本发明的技术方案作进一步具体的说明。
实施例一：
一种装饰用基材的隔热保温涂层整理工艺，将涂层剂以泡沫体的形式连续施加至平坦的柔性基材上，在85℃的温度下将施加的涂层通过红外辐照器和/或采用热空气进行干燥，之后对所述涂层进行冷压印；所述涂层的层厚度为4mm；其中以泡沫体的形式施加所述涂层剂，并且通过向所述涂层剂中引入空气、 氮气、CO2或它们的混合物作为气体，来形成所述泡沫体；所述涂层剂包含下列重量份的组分：
乙烯-醋酸乙烯共聚树脂组成的基体乳液 100份，
三(2，3-二溴丙基)异三聚氰酸酯 10份，
缔合型水性聚氨酯乳液 1份，
聚丙烯酸酯乳液 5份，
气相二氧化硅 2份，
磺基琥珀酸酯 1份，
磺基琥珀酰胺 0.3份，
硅氮化合物 6份，
环氧乙烷/环氧丙烷嵌段共聚物 5份，
改性剂 12份；
木纤维粉 20份；
铝酸酯 1份；
所述改性剂由下列重量份的原料制成：硅藻土40、丙烯酸二甲基氨基乙酯4、二缩三丙二醇二丙烯酸酯2、氧化锌5、玉石4、3-氨丙基三甲氧基硅烷2、交联剂TAC 1、葡萄糖酸锌1、硬脂酸锌1、玫瑰精油0.1。所述涂层剂的含固量为30-50％，粘度为1000-5000mpa·s。发泡比控制在1∶1.2-10之间。所述基材选自聚酯纤维和纤维素纤维构成的亲水性聚合物构成。
实施例二：
一种装饰用基材的隔热保温涂层整理工艺，将涂层剂以泡沫体的形式连续施加至平坦的柔性基材上，在98℃的温度下将施加的涂层通过红外辐照器和/或采用热空气进行干燥，之后对所述涂层进行冷压印；所述涂层的层厚度为6mm；其中以泡沫体的形式施加所述涂层剂，并且通过向所述涂层剂中引入空气、 氮气、CO2或它们的混合物作为气体，来形成所述泡沫体；所述涂层剂包含下列重量份的组分：
乙烯-醋酸乙烯共聚树脂组成的基体乳液 100份，
三(2，3-二溴丙基)异三聚氰酸酯 23份，
缔合型水性聚氨酯乳液 3份，
聚丙烯酸酯乳液 10份，
气相二氧化硅 4份，
磺基琥珀酸酯 1.5份，
磺基琥珀酰胺 0.8份，
硅氮化合物 16份，
环氧乙烷/环氧丙烷嵌段共聚物 13份，
改性剂 20份；
木纤维粉 35份；
铝酸酯 10 份；
所述改性剂由下列重量份的原料制成：硅藻土45、丙烯酸二甲基氨基乙酯5、二缩三丙二醇二丙烯酸酯3、氧化锌6、玉石5、3-氨丙基三甲氧基硅烷3、交联剂TAC 2、葡萄糖酸锌2、硬脂酸锌2、玫瑰精油0.2。所述涂层剂的含固量为30-50％，粘度为1000-5000mpa·s。发泡比控制在1∶1.2-10之间。所述基材选自聚酯纤维和木质素纤维构成的亲水性聚合物构成。
以上所述，仅为本发明的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本领域的技术人员在本发明所揭露的技术范围内，可不经过创造性劳动想到的变化或替换，都应涵盖在本发明的保护范围之内。因此，本发明的保护范围应该以权利要求书所限定的保护范围为准。

Claims (4)

1.一种装饰用基材的隔热保温涂层整理工艺，其特征在于：将涂层剂以泡沫体的形式连续施加至平坦的柔性基材上，在高于80℃的温度下将施加的涂层通过红外辐照器和/或采用热空气进行干燥，之后对所述涂层进行冷压印；所述涂层的层厚度为4-6mm；其中以泡沫体的形式施加所述涂层剂，并且通过向所述涂层剂中引入空气、氮气、CO2或它们的混合物作为气体，来形成所述泡沫体；所述涂层剂包含下列重量份的组分：
乙烯-醋酸乙烯共聚树脂组成的基体乳液 100份，
三(2，3-二溴丙基)异三聚氰酸酯 10-23份，
缔合型水性聚氨酯乳液 1-3份，
聚丙烯酸酯乳液 5-10份，
气相二氧化硅 2-4份，
磺基琥珀酸酯 1-1.5份，
磺基琥珀酰胺 0.3-0.8份，
硅氮化合物 6-16份，
环氧乙烷/环氧丙烷嵌段共聚物 5-13份，
改性剂 12-20份；
木纤维粉 20-35份；
铝酸酯 1-10 份；
所述改性剂由下列重量份的原料制成：硅藻土 40-45、丙烯酸二甲基氨基乙酯4-5、二缩三丙二醇二丙烯酸酯 2-3、氧化锌 5-6、玉石 4-5、3-氨丙基三甲氧基硅烷 2-3、交联剂TAC 1-2、葡萄糖酸锌 1-2、硬脂酸锌 1-2、玫瑰精油 0.1-0.2。
2.根据权利要求1所述的一种装饰用基材的隔热保温涂层整理工艺，其特征在于：所述涂层剂的含固量为30-50％，粘度为1000-5000mPa·s。
3.根据权利要求1所述的一种装饰用基材的隔热保温涂层整理工艺，其特征在于：泡沫发泡比控制在1∶1.2-10之间。
4.根据权利要求1或2所述的一种装饰用基材的隔热保温涂层整理工艺，其特征在于：所述基材选自聚酯纤维、纤维素纤维或木质素纤维构成的亲水性聚合物构成。
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