CN105543979A - Wet texturizing process for diamond wire sawed polycrystalline silicon wafer under catalysis of metal - Google Patents
Wet texturizing process for diamond wire sawed polycrystalline silicon wafer under catalysis of metal Download PDFInfo
- Publication number
- CN105543979A CN105543979A CN201510911553.7A CN201510911553A CN105543979A CN 105543979 A CN105543979 A CN 105543979A CN 201510911553 A CN201510911553 A CN 201510911553A CN 105543979 A CN105543979 A CN 105543979A
- Authority
- CN
- China
- Prior art keywords
- diamond wire
- wet
- wire cutting
- manufacturing process
- metal catalytic
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B33/00—After-treatment of single crystals or homogeneous polycrystalline material with defined structure
- C30B33/08—Etching
- C30B33/10—Etching in solutions or melts
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/02—Elements
- C30B29/06—Silicon
Abstract
The invention provides a wet texturizing process for a diamond wire sawed polycrystalline silicon wafer under catalysis of metal. The method comprises the following steps: (a) preparation of a texturizing solution; (b) texturizing: a step of placing the silicon wafer in the texturizing solution; (c) alkali washing; (d) acid pickling; and (e) water washing. In the step (b), the silicon wafer is placed into a HF-H2O2 or HNO3-HF mixed solution containing Ni<2+> for a reaction so as to prepare a texturized surface, wherein reaction temperature is 30 to 90 DEG C and reaction time is 5 to 30 min. The method provided by the invention employs a direct silicon wafer texturizing manner, so production steps are simplified, polycrystalline silicon wafer texturizing cost is effectively reduced, and product market competitiveness is improved.
Description
Technical field
The present invention relates to the wet-method texturing manufacturing process that a kind of metal catalytic diamond wire cuts many jin of silicon chips.
Background technology
Sun power be with not to the utmost, the energy without cease got, is also considered to the product of most potential alternative traditional fossil energy.Photovoltaic module is device solar radiation being converted into electric energy, and photovoltaic module mechanical is moved, and long service life, the features such as maintenance cost is low are current optimal photoelectric conversion devices.
Recent silicon wafer cut by diamond wire technology is because it is with low cost, save silicon material, clipping time is short, become industrial hot spot to advantages such as link pollution are few, but because silicon chip surface after diamond wire cutting is smooth, microdefect makes the problems such as making herbs into wool difficulty exist less, restriction silicon wafer cut by diamond wire technology is further promoted and uses.
Have for silicon wafer cut by diamond wire metal catalytic making herbs into wool such as adopting Ag or Au at present or adopt plasma etching making herbs into wool, reducing reflectivity.
The etching method of the such as patent No. a kind of polysilicon of diamond wire cutting disclosed in 201410430817.2, is characterized in that, comprise step: (a) adopts mixed acid solution to process silicon chip surface, make silicon chip surface form porous
Structure; (b) DI water cleaning silicon chip surface; (c) making herbs into wool; D () mixed acid solution cleans: immersed by silicon chip in the mixed acid solution of hydrofluoric acid solution and hydrochloric acid soln mixing and clean; E () DI water cleans and dries; The present invention, by first processing the silicon chip surface that diamond wire cuts with mixed acid solution, makes silicon chip surface form vesicular structure, thus increases the reactive behavior of silicon chip; By alkaline mixed solution, making herbs into wool process is carried out to silicon chip again, silicon chip surface is formed there is the good matte falling into light effect, effectively can reduce the reflectivity after diamond wire cutting polycrystalline silicon texturing.Transformation of the way velvet figures method beneficial effect is obvious, but its making herbs into wool cost is higher, and in the face of day by day fierce photovoltaic industry, such etching method does not have competitive power.
Therefore, work out that a kind of step is simple, with low cost and the etching method that effectively can ensure the diamond wire cutting polysilicon chip of making herbs into wool effect is one of major issue that current photovoltaic art needs to solve.
Summary of the invention
Goal of the invention: for the problems referred to above, the object of this invention is to provide a kind of step simple, with low cost and can effectively ensure making herbs into wool effect metal catalytic diamond wire cutting polysilicon chip method of preparing fleece through wet.。
Technical scheme: in order to overcome the above problems, the invention provides the wet-method texturing manufacturing process of a kind of metal catalytic diamond wire cutting polysilicon chip, comprises the configuration of step (a) Woolen-making liquid; (b) making herbs into wool: silicon chip is positioned in Woolen-making liquid; (c) alkali cleaning; (d) pickling; E () washes; Making herbs into wool described in described step (b) is for put into silicon chip containing Cu
2+the HF-H of ion
2o
2or HNO
3carry out in-HF mixing solutions reacting obtained matte, temperature of reaction is 30 DEG C-90 DEG C, and the reaction times is 5-30min; Present invention eliminates the step of alkali cleaning after first pickling, effective material saving cost; And metal catalytic is cheap, the technique of cutting polycrystalline silicon texturing with existing ordinary mortar has good compatibility, effectively saves production cost, and improves the market competitiveness.
Step (b) mixing solutions comprises catalyzer, and described catalyzer is containing Cu
2+ionic species can be CuCl
2, CuSO
4, Cu (NO
3)
2.
Described Cu
2+content is 0.01-5mmol/L.
Described making herbs into wool reaction system is HF-H
2o
2or HNO
3-HF pickling system.
Described HF-H
2o
2or HNO
3in-HF mixing solutions, HF massfraction is 1%-30%, HNO
3or H
2o
2massfraction is 1%-30%, and other compositions are pure water solvent.
Beneficial effect: compared with prior art, the present invention has the following advantages:
1. cost of manufacture is low: the etching method of a kind of polysilicon chip provided by the invention, eliminates the step of alkali cleaning after first pickling, effective material saving cost; And metal catalytic is cheap, the technique of cutting polycrystalline silicon texturing with existing ordinary mortar has good compatibility, effectively saves production cost, and improves the market competitiveness;
2. making herbs into wool is effective: the polysilicon chip adopting Woolen-making liquid making herbs into wool of the present invention, its reflectance reduction 5%, and solar battery sheet photoelectric transformation efficiency improves 0.15%.
Accompanying drawing explanation
Fig. 1 is the surperficial SEM figure adopting the silicon wafer cut by diamond wire of prior art making herbs into wool;
After Fig. 2 adopts Woolen-making liquid making herbs into wool of the present invention, silicon chip surface SEM schemes.
Embodiment
Below in conjunction with drawings and Examples, embodiments of the present invention are described in further detail.Following examples for illustration of the present invention, but can not be used for limiting the scope of the invention.Orientation or the position relationship of the instruction such as D score, "left", "right", " interior ", " outward ", " front end ", " rear end ", " head ", " afterbody " are based on orientation shown in the drawings or position relationship, only the present invention for convenience of description and simplified characterization, instead of indicate or imply that the device of indication or element must have specific orientation, with specific azimuth configuration and operation, therefore can not be interpreted as limitation of the present invention.In addition, term " first ", " second ", " the 3rd " etc. only for describing object, and can not be interpreted as instruction or hint relative importance.
In describing the invention, it should be noted that, unless otherwise clearly defined and limited, term " installation ", " being connected ", " connection " should be interpreted broadly, and such as, can be fixedly connected with, also can be removably connect, or connect integratedly; Can be mechanical connection, also can be electrical connection; Can be directly be connected, also indirectly can be connected by intermediary.For the ordinary skill in the art, particular case above-mentioned term concrete meaning in the present invention can be understood.
A wet-method texturing manufacturing process for metal catalytic diamond wire cutting polysilicon chip, comprises the configuration of step (a) Woolen-making liquid; (b) making herbs into wool: silicon chip is positioned in Woolen-making liquid; (c) alkali cleaning; (d) pickling; E () DI washes; Making herbs into wool described in described step (b) is for put into silicon chip containing Cu
2+the HF-H of ion
2o
2or HNO
3carry out in-HF mixing solutions reacting obtained matte, temperature of reaction is 30 DEG C-90 DEG C, and the reaction times is 5-30min; Step (b) mixing solutions comprises catalyzer, and described catalyzer is containing Cu
2+ionic species can be CuCl
2, CuSO
4, Cu (NO
3)
2; Described Cu
2+content is 0.01-5mmol/L; Described making herbs into wool reaction system is HF-H
2o
2or HNO
3-HF pickling system; Described HF-H
2o
2or HNO
3in-HF mixing solutions, HF massfraction is 1%-30%, HNO
3or H
2o
2massfraction is 1%-30%, and other compositions are pure water solvent.
Embodiment 1
1) to test the silicon chip that adopts be 156mm × 156mm resistivity is the P type diamond wire cutting polysilicon chip of 2.0ohmcm.
2) preparation of Woolen-making liquid: add 100L pure water in texturing slot, treats that temperature is upgraded to 50 DEG C, adds the HF of 40% of 10L, 10L 60% HNO
3stir, add 1.32gCuCl
2, stir, keep temperature to 50 DEG C.
3) diamond wire cuts concrete operation step prepared by polysilicon chip matte: diamond wire cutting polysilicon chip inserts silicon wafer bearing box, and silicon wafer bearing box puts into floc making flower basket.Floc making flower basket is carried in texturing slot, close texturing slot lid, after making herbs into wool 15min, the gaily decorated basket is proposed at 50 DEG C.Silicon chip in floc making flower basket, after alkali cleaning, pickling, the cleaning of DI water, is put into drier and is dried, and namely obtains the diamond wire cutting polysilicon chip preparing matte, as shown in Figure 2.
Embodiment 2:
1) to test the silicon chip that adopts be 156mm × 156mm resistivity is the P type diamond wire cutting polysilicon chip of 3.0ohmcm.
2) preparation of Woolen-making liquid: add 100L pure water in texturing slot, treats that temperature is upgraded to 60 DEG C, adds the HF of 40% of 20L, 20L 60% HNO
3stir, add 3gCu (NO
3)
2, stir, keep temperature to 60 DEG C.
3) not the existing together for the time of making herbs into wool is 8min of the specific operation process prepared of diamond wire cutting polysilicon chip matte and embodiment 1.
Embodiments of the invention provide in order to example with for the purpose of describing, and are not exhaustively or limit the invention to disclosed form.Many modifications and variations are apparent for the ordinary skill in the art.Selecting and describing embodiment is in order to principle of the present invention and practical application are better described, and enables those of ordinary skill in the art understand the present invention thus design the various embodiments with various amendment being suitable for specific end use.
Claims (8)
1. a wet-method texturing manufacturing process for metal catalytic diamond wire cutting polysilicon chip, is characterized in that: comprise the configuration of step (a) Woolen-making liquid; (b) making herbs into wool: silicon chip is positioned in Woolen-making liquid; (c) alkali cleaning; (d) pickling; E () washes;
Making herbs into wool described in described step (b) is for put into silicon chip containing Cu
2+the HF-H of ion
2o
2or HNO
3carry out in-HF mixing solutions reacting obtained matte, temperature of reaction is 30 DEG C-90 DEG C, and the reaction times is 5-30min.
2. the wet-method texturing manufacturing process of a kind of metal catalytic diamond wire cutting polysilicon chip according to claim 1, it is characterized in that: step (b) mixing solutions comprises catalyzer, described catalyzer is containing Cu
2+ionic species can be CuCl
2, CuSO
4, Cu (NO
3)
2.
3. the wet-method texturing manufacturing process of a kind of metal catalytic diamond wire cutting polysilicon chip according to claim 2, is characterized in that: described Cu
2+content is 0.01-5mmol/L.
4. the wet-method texturing manufacturing process of a kind of metal catalytic diamond wire cutting polysilicon chip according to claim 1, is characterized in that: described making herbs into wool reaction system is HF-H
2o
2or HNO
3-HF pickling system.
5. the wet-method texturing manufacturing process of a kind of metal catalytic diamond wire cutting polysilicon chip according to claim 1, is characterized in that: described HF-H
2o
2or HNO
3in-HF mixing solutions, HF massfraction is 1%-30%, HNO
3or H
2o
2massfraction is 1%-30%, and other compositions are pure water solvent.
6. the wet-method texturing manufacturing process of a kind of metal catalytic diamond wire cutting polysilicon chip according to claim 1, is characterized in that: described alkali cleaning is massfraction is infiltrate 2-10 minute under the NaOH aqueous solution normal temperature of 0.05-10%.
7. the wet-method texturing manufacturing process of a kind of metal catalytic diamond wire cutting polysilicon chip according to claim 1, is characterized in that: described pickling is massfraction is infiltrate 2-10 minute under the HF aqueous solution normal temperature of 0.05-10%.
8. the wet-method texturing manufacturing process of a kind of metal catalytic diamond wire cutting polysilicon chip according to claim 1, is characterized in that: described washing is for infiltrating 1-5 minute in flowing DI pure water.
Priority Applications (1)
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|---|---|---|---|
| CN201510911553.7A CN105543979A (en) | 2015-12-11 | 2015-12-11 | Wet texturizing process for diamond wire sawed polycrystalline silicon wafer under catalysis of metal |
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|---|---|---|---|
| CN201510911553.7A CN105543979A (en) | 2015-12-11 | 2015-12-11 | Wet texturizing process for diamond wire sawed polycrystalline silicon wafer under catalysis of metal |
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| CN105543979A true CN105543979A (en) | 2016-05-04 |
Family
ID=55823527
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| CN201510911553.7A Pending CN105543979A (en) | 2015-12-11 | 2015-12-11 | Wet texturizing process for diamond wire sawed polycrystalline silicon wafer under catalysis of metal |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107623053A (en) * | 2017-09-11 | 2018-01-23 | 中节能太阳能科技（镇江）有限公司 | Diamond wire silicon chip based on chain-type texture-etching equipment receives micro- matte preparation method |
| CN107868983A (en) * | 2017-10-19 | 2018-04-03 | 维科诚（苏州）光伏科技有限公司 | A kind of etching method of Buddha's warrior attendant wire cutting polysilicon chip |
| CN107887458A (en) * | 2017-10-11 | 2018-04-06 | 昆明理工大学 | A kind of method that copper catalysis etching silicon prepares morphology controllable matte |
| CN109727895A (en) * | 2018-12-25 | 2019-05-07 | 保定光为绿色能源科技有限公司 | A kind of crystalline silicon metal cleaning equipment |
| CN113044845A (en) * | 2021-03-05 | 2021-06-29 | 昆明理工大学 | Method for efficiently purifying silicon wafer cutting waste |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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| CN107887458A (en) * | 2017-10-11 | 2018-04-06 | 昆明理工大学 | A kind of method that copper catalysis etching silicon prepares morphology controllable matte |
| CN107868983A (en) * | 2017-10-19 | 2018-04-03 | 维科诚（苏州）光伏科技有限公司 | A kind of etching method of Buddha's warrior attendant wire cutting polysilicon chip |
| CN109727895A (en) * | 2018-12-25 | 2019-05-07 | 保定光为绿色能源科技有限公司 | A kind of crystalline silicon metal cleaning equipment |
| CN113044845A (en) * | 2021-03-05 | 2021-06-29 | 昆明理工大学 | Method for efficiently purifying silicon wafer cutting waste |
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Application publication date: 20160504 |
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