CN105543879A - Metal surface cleaning agent based on maple ball extract and preparation method thereof - Google Patents
Metal surface cleaning agent based on maple ball extract and preparation method thereof Download PDFInfo
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- CN105543879A CN105543879A CN201510939707.3A CN201510939707A CN105543879A CN 105543879 A CN105543879 A CN 105543879A CN 201510939707 A CN201510939707 A CN 201510939707A CN 105543879 A CN105543879 A CN 105543879A
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/032—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing oxygen-containing compounds
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- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
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Abstract
The invention discloses a metal surface cleaning agent based on maple ball extract and a preparation method thereof. The preparation method comprises the steps that 1, maple balls, nano bamboo charcoal ash and organic solvent are mixed and subjected to heat treatment, and then filter liquor is extracted through filtration; and 2, the filter liquor, quaternary ammonium salt, isopropyl alcohol, nano attapulgite, magnesium stearate, coconut oil monoethanolamide, sodium citrate, sodium lauryl ether sulfate, glycerinum, sulfadiazine, pyrrolidone, propylene glycol mono-n-butyl ether and ethyl alcohol are mixed, and thus the metal surface cleaning agent based on the maple ball extract is prepared. The metal surface cleaning agent prepared through the method has an excellent cleaning effect.
Description
Technical field
The present invention relates to sanitising agent, particularly, relate to a kind of metal surface detergent based on maple ball extract and preparation method thereof.
Background technology
In the course of processing of copper artware, need to carry out surface cleaning to copper material, this is because copper material is in production and sale transportation, often by external Substances Pollution, as the machine oil in production, dust in transportation etc., makes to form the closely knit schmutzband of one deck on the surface of copper material thus.This schmutzband not only have impact on the brightness excessively on copper material surface, and long-time existence simultaneously also can cause the corrosion of copper material.Therefore, in the course of processing of copper artware, must effectively clean to copper material the product phase improving obtained copper artware.
Although there is a feast for the eyes sanitising agent in the market, these sanitising agents are unsatisfactory for the cleaning effect of the long-time copper material placed, thus cause the product of the copper artware obtained mutually poor.
Summary of the invention
The object of this invention is to provide a kind of metal surface detergent based on maple ball extract and preparation method thereof, the metal surface detergent obtained by the method has excellent cleaning effect.
To achieve these goals, the invention provides a kind of preparation method of the metal surface detergent based on maple ball extract, comprising:
1) maple ball, bamboo charcoal nano ash and organic solvent mixed and heat-treat, then crossing leaching filtrate;
2) filtrate, quaternary ammonium salt, Virahol, nano-attapulgite, Magnesium Stearate, Coconut Fatty Acid Monoethanolamide, Trisodium Citrate, sodium lauryl tri(oxyethyl) sulfate, glycerine, Sulphadiazine Sodium, pyrrolidone, propylene glycol monobutyl ether and ethanol are mixed with the obtained metal surface detergent based on maple ball extract.
Present invention also offers a kind of metal surface detergent based on maple ball extract, this metal surface detergent is obtained by the preparation of above-mentioned method.
Pass through technique scheme, first the present invention extracts with obtained extract by bamboo charcoal nano ash and organic solvent to maple ball, then utilizes extract quaternary ammonium salt, Virahol, nano-attapulgite, Magnesium Stearate, Coconut Fatty Acid Monoethanolamide, Trisodium Citrate, sodium lauryl tri(oxyethyl) sulfate, glycerine, Sulphadiazine Sodium, pyrrolidone, synergy between propylene glycol monobutyl ether and ethanol makes the metal surface detergent obtained have the cleaning capacity of excellence to metallic surface.
Other features and advantages of the present invention are described in detail in embodiment part subsequently.
Embodiment
Below the specific embodiment of the present invention is described in detail.Should be understood that, embodiment described herein, only for instruction and explanation of the present invention, is not limited to the present invention.
The invention provides a kind of preparation method of the metal surface detergent based on maple ball extract, comprising:
1) maple ball, bamboo charcoal nano ash and organic solvent mixed and heat-treat, then crossing leaching filtrate;
2) filtrate, quaternary ammonium salt, Virahol, nano-attapulgite, Magnesium Stearate, Coconut Fatty Acid Monoethanolamide, Trisodium Citrate, sodium lauryl tri(oxyethyl) sulfate, glycerine, Sulphadiazine Sodium, pyrrolidone, propylene glycol monobutyl ether and ethanol are mixed with the obtained metal surface detergent based on maple ball extract.
In step 1 of the present invention) in, the consumption of each material can be selected in wide scope, but for being that obtained metal surface detergent has more excellent cleaning effect, preferably, in step 1) in, relative to the maple ball of 100 weight parts, the consumption of bamboo charcoal nano ash is 32-35 weight part, and the consumption of organic solvent is 300-500 weight part.
In step 1 of the present invention) in, heat treated condition can be selected in wide scope, but for being that obtained metal surface detergent has more excellent cleaning effect, preferably, in step 1) in, thermal treatment at least meets the following conditions: thermal treatment temp is 180-200 DEG C, and heat treatment time is 3-5h.
In step 1 of the present invention) in, the concrete kind of organic solvent can be selected in wide scope, but for being that obtained metal surface detergent has more excellent cleaning effect, preferably, in step 1) in, organic solvent be selected from ethanol, sherwood oil, hexalin, ethylene glycol ether and trolamine one or more.
In step 1 of the present invention) in, the particle diameter of bamboo charcoal nano ash can be selected in wide scope, but for being that obtained metal surface detergent has more excellent cleaning effect, preferably, in step 1) in, the particle diameter of bamboo charcoal nano ash is 5-10nm.
In step 2 of the present invention) in, the consumption of each material can be selected in wide scope, but for being that obtained metal surface detergent has more excellent cleaning effect, preferably, in step 2) in, relative to the filtrate of 100 weight parts, the consumption of quaternary ammonium salt is 3-5 weight part, the consumption of Virahol is 40-55 weight part, the consumption of nano-attapulgite is 0.7-1.5 weight part, the consumption of Magnesium Stearate is 3-5 weight part, the consumption of Coconut Fatty Acid Monoethanolamide is 10-17 weight part, the consumption of Trisodium Citrate is 2-2.5 weight part, the consumption of sodium lauryl tri(oxyethyl) sulfate is 7-9 weight part, the consumption of glycerine is 16-20 weight part, the consumption of Sulphadiazine Sodium is 4-9 weight part, the consumption of pyrrolidone is 4-11 weight part, the consumption of propylene glycol monobutyl ether is 35-46 weight part, the consumption of ethanol is 150-200 weight part.
In step 2 of the present invention) in, the kind of quaternary ammonium salt can be selected in wide scope, but for being that obtained metal surface detergent has more excellent cleaning effect, preferably, quaternary ammonium salt is selected from one or more in benzyltriethylammonium chloride, hydrogen sulfate TBuA, dodecyl dimethyl benzene oxygen ethyl phosphonium bromide ammonium, octadecyldimethyl hydroxyethyl ammonium nitrate and octadecyldimethyl hydroxyethyl ammonium perchlorate.
In step 2 of the present invention) in, the particle diameter of nano-attapulgite can be selected in wide scope, but for being that obtained metal surface detergent has more excellent cleaning effect, preferably, the particle diameter of nano-attapulgite is 10-15nm.
Present invention also offers a kind of metal surface detergent based on maple ball extract, this metal surface detergent is obtained by the preparation of above-mentioned method.
Below will be described the present invention by embodiment.
Embodiment 1
1) heat-treat 4h at maple ball, bamboo charcoal nano ash (particle diameter is 8nm) and organic solvent (sherwood oil) being incorporated in 190 DEG C according to the weight ratio of 100:33:400 is mixed, then cross leaching filtrate;
2) filtrate, quaternary ammonium salt (benzyltriethylammonium chloride), Virahol, nano-attapulgite (particle diameter is 13nm), Magnesium Stearate, Coconut Fatty Acid Monoethanolamide, Trisodium Citrate, sodium lauryl tri(oxyethyl) sulfate, glycerine, Sulphadiazine Sodium, pyrrolidone, propylene glycol monobutyl ether and ethanol are mixed according to the weight ratio of 100:4:50:0.9:4:15:2.3:8:18:7:8:42:180 with the obtained metal surface detergent A1 based on maple ball extract.
Embodiment 2
1) heat-treat 3h at maple ball, bamboo charcoal nano ash (particle diameter is 5nm) and organic solvent (hexalin) being incorporated in 180 DEG C according to the weight ratio of 100:32:300 is mixed, then cross leaching filtrate;
2) filtrate, quaternary ammonium salt (dodecyl dimethyl benzene oxygen ethyl phosphonium bromide ammonium), Virahol, nano-attapulgite (particle diameter is 10nm), Magnesium Stearate, Coconut Fatty Acid Monoethanolamide, Trisodium Citrate, sodium lauryl tri(oxyethyl) sulfate, glycerine, Sulphadiazine Sodium, pyrrolidone, propylene glycol monobutyl ether and ethanol are mixed according to the weight ratio of 100:3:40:0.7:3:10:2:7:16:4:4:35:150 with the obtained metal surface detergent A2 based on maple ball extract.
Embodiment 3
1) heat-treat 5h at maple ball, bamboo charcoal nano ash (particle diameter is 10nm) and organic solvent (trolamine) being incorporated in 200 DEG C according to the weight ratio of 100:35:500 is mixed, then cross leaching filtrate;
2) by filtrate, quaternary ammonium salt (octadecyldimethyl hydroxyethyl ammonium perchlorate), Virahol, nano-attapulgite (particle diameter is 15nm), Magnesium Stearate, Coconut Fatty Acid Monoethanolamide, Trisodium Citrate, sodium lauryl tri(oxyethyl) sulfate, glycerine, Sulphadiazine Sodium, pyrrolidone, propylene glycol monobutyl ether and ethanol mix according to the weight ratio of 100:5:55:1.5:5:17:2.5:9:20:9:11:46:200 with the obtained metal surface detergent A3 based on maple ball extract.
Comparative example 1
Obtain metal surface detergent B1 according to the method for embodiment 1, unlike, step 1) in do not use maple ball.
Comparative example 2
Obtain metal surface detergent B2 according to the method for embodiment 1, unlike, step 1) in do not use bamboo charcoal nano ash.
Comparative example 3
Obtain metal surface detergent B3 according to the method for embodiment 1, unlike, step 2) in do not use quaternary ammonium salt.
Comparative example 4
Obtain metal surface detergent B4 according to the method for embodiment 1, unlike, step 2) in do not use Sulphadiazine Sodium.
Test case 1
Get 15cm × 15cm copper metal sheet, check weighing W1, aluminium metal sheet applies the dirt of one deck 25 grams, 5 grams of metal detergents are evenly sprayed and shine in aluminium metal sheet by roasting 1h at 120 DEG C, check weighing W2, place 2 hours at 25 DEG C, then under 60 DEG C of hot water flowings, sponge rinsing is used, oven for drying, check weighing W3.By weighting method, draw
concrete outcome is in table 1.
Table 1
| Metal sheet is apparent | Soil removal efficiency | |
| A1 | Surface-brightening | 96 |
| A2 | Surface-brightening | 93 |
| A3 | Surface-brightening | 95 |
| B1 | Surface is gloomy | 67 |
| B2 | Surface is gloomy | 70 |
| B3 | Surface is gloomy | 73 |
| B4 | Surface is gloomy | 80 |
From above-described embodiment, comparative example and test example, the metal surface detergent based on maple ball extract provided by the invention has excellent cleaning capacity to the dirt on metal sheet.
More than describe the preferred embodiment of the present invention in detail; but the present invention is not limited to the detail in above-mentioned embodiment, within the scope of technical conceive of the present invention; can carry out multiple simple variant to technical scheme of the present invention, these simple variant all belong to protection scope of the present invention.
It should be noted that in addition, each concrete technical characteristic described in above-mentioned embodiment, in reconcilable situation, can be combined by any suitable mode, in order to avoid unnecessary repetition, the present invention illustrates no longer separately to various possible array mode.
In addition, also can carry out arbitrary combination between various different embodiment of the present invention, as long as it is without prejudice to thought of the present invention, it should be considered as content disclosed in this invention equally.
Claims (9)
1., based on a preparation method for the metal surface detergent of maple ball extract, it is characterized in that, comprising:
1) maple ball, bamboo charcoal nano ash and organic solvent mixed and heat-treat, then crossing leaching filtrate;
2) described filtrate, quaternary ammonium salt, Virahol, nano-attapulgite, Magnesium Stearate, Coconut Fatty Acid Monoethanolamide, Trisodium Citrate, sodium lauryl tri(oxyethyl) sulfate, glycerine, Sulphadiazine Sodium, pyrrolidone, propylene glycol monobutyl ether and ethanol are mixed with the obtained described metal surface detergent based on maple ball extract.
2. preparation method according to claim 1, wherein, in step 1) in, relative to the described maple ball of 100 weight parts, the consumption of described bamboo charcoal nano ash is 32-35 weight part, and the consumption of described organic solvent is 300-500 weight part.
3. preparation method according to claim 2, wherein, in step 1) in, described thermal treatment at least meets the following conditions: thermal treatment temp is 180-200 DEG C, and heat treatment time is 3-5h.
4. preparation method according to claim 2, wherein, in step 1) in, described organic solvent be selected from ethanol, sherwood oil, hexalin, ethylene glycol ether and trolamine one or more.
5. preparation method according to claim 2, wherein, in step 1) in, the particle diameter of described bamboo charcoal nano ash is 5-10nm.
6. according to the preparation method in claim 1-5 described in any one, wherein, in step 2) in, relative to the described filtrate of 100 weight parts, the consumption of described quaternary ammonium salt is 3-5 weight part, the consumption of described Virahol is 40-55 weight part, the consumption of described nano-attapulgite is 0.7-1.5 weight part, the consumption of described Magnesium Stearate is 3-5 weight part, the consumption of described Coconut Fatty Acid Monoethanolamide is 10-17 weight part, the consumption of described Trisodium Citrate is 2-2.5 weight part, the consumption of described sodium lauryl tri(oxyethyl) sulfate is 7-9 weight part, the consumption of described glycerine is 16-20 weight part, the consumption of described Sulphadiazine Sodium is 4-9 weight part, the consumption of described pyrrolidone is 4-11 weight part, the consumption of described propylene glycol monobutyl ether is 35-46 weight part, the consumption of described ethanol is 150-200 weight part.
7. preparation method according to claim 6, wherein, described quaternary ammonium salt is selected from one or more in benzyltriethylammonium chloride, hydrogen sulfate TBuA, dodecyl dimethyl benzene oxygen ethyl phosphonium bromide ammonium, octadecyldimethyl hydroxyethyl ammonium nitrate and octadecyldimethyl hydroxyethyl ammonium perchlorate.
8. preparation method according to claim 6, wherein, the particle diameter of described nano-attapulgite is 10-15nm.
9. based on a metal surface detergent for maple ball extract, it is characterized in that, described metal surface detergent is obtained by the method preparation in claim 1-8 described in any one.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510939707.3A CN105543879A (en) | 2015-12-15 | 2015-12-15 | Metal surface cleaning agent based on maple ball extract and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510939707.3A CN105543879A (en) | 2015-12-15 | 2015-12-15 | Metal surface cleaning agent based on maple ball extract and preparation method thereof |
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| CN105543879A true CN105543879A (en) | 2016-05-04 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510939707.3A Pending CN105543879A (en) | 2015-12-15 | 2015-12-15 | Metal surface cleaning agent based on maple ball extract and preparation method thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103643250A (en) * | 2013-12-19 | 2014-03-19 | 青岛聚蚨源机电有限公司 | Environment-friendly paraffin cleaner |
| CN103774167A (en) * | 2012-10-22 | 2014-05-07 | 姜亭伊 | Cleaning liquid for industrial part |
| CN104046992A (en) * | 2014-06-25 | 2014-09-17 | 青岛扎西生物科技有限公司 | Metal surface treating agent |
-
2015
- 2015-12-15 CN CN201510939707.3A patent/CN105543879A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103774167A (en) * | 2012-10-22 | 2014-05-07 | 姜亭伊 | Cleaning liquid for industrial part |
| CN103643250A (en) * | 2013-12-19 | 2014-03-19 | 青岛聚蚨源机电有限公司 | Environment-friendly paraffin cleaner |
| CN104046992A (en) * | 2014-06-25 | 2014-09-17 | 青岛扎西生物科技有限公司 | Metal surface treating agent |
Non-Patent Citations (2)
| Title |
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| 刘文彬 等: "《汽车美容保养用精细化学品》", 31 January 2007, 化学工业出版社 * |
| 陈洪章: "《生物基产品过程工程》", 31 January 2010, 化学工业出版社 * |
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Application publication date: 20160504 |
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