CN105542499A - Flame-resistant waterproof antibacterial wood-plastic material - Google Patents
Flame-resistant waterproof antibacterial wood-plastic material Download PDFInfo
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- CN105542499A CN105542499A CN201610036751.8A CN201610036751A CN105542499A CN 105542499 A CN105542499 A CN 105542499A CN 201610036751 A CN201610036751 A CN 201610036751A CN 105542499 A CN105542499 A CN 105542499A
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- 239000000463 material Substances 0.000 title claims abstract description 34
- 229920003023 plastic Polymers 0.000 title claims abstract description 33
- 239000004033 plastic Substances 0.000 title claims abstract description 33
- 230000000844 anti-bacterial Effects 0.000 title abstract description 6
- -1 polyethylene Polymers 0.000 claims abstract description 55
- 239000002023 wood Substances 0.000 claims abstract description 43
- 239000000843 powder Substances 0.000 claims abstract description 34
- FPYJFEHAWHCUMM-UHFFFAOYSA-N Maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 33
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 33
- 239000000835 fiber Substances 0.000 claims abstract description 18
- FJKVRVFGUXMMAO-UHFFFAOYSA-N (3-methylphenyl) diphenyl phosphate Chemical compound CC1=CC=CC(OP(=O)(OC=2C=CC=CC=2)OC=2C=CC=CC=2)=C1 FJKVRVFGUXMMAO-UHFFFAOYSA-N 0.000 claims abstract description 17
- WNROFYMDJYEPJX-UHFFFAOYSA-K Aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 17
- 239000004135 Bone phosphate Substances 0.000 claims abstract description 17
- DSSYKIVIOFKYAU-UHFFFAOYSA-N Camphor Chemical compound C1CC2(C)C(=O)CC1C2(C)C DSSYKIVIOFKYAU-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229960000846 Camphor Drugs 0.000 claims abstract description 17
- 239000004709 Chlorinated polyethylene Substances 0.000 claims abstract description 17
- CRQQGFGUEAVUIL-UHFFFAOYSA-N Chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 claims abstract description 17
- 241000723346 Cinnamomum camphora Species 0.000 claims abstract description 17
- REZZEXDLIUJMMS-UHFFFAOYSA-M Dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 claims abstract description 17
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 17
- 239000004698 Polyethylene (PE) Substances 0.000 claims abstract description 17
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 17
- LWIHDJKSTIGBAC-UHFFFAOYSA-K Tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims abstract description 17
- 229930007890 camphor Natural products 0.000 claims abstract description 17
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims abstract description 17
- 229920000573 polyethylene Polymers 0.000 claims abstract description 17
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 17
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 17
- 235000009566 rice Nutrition 0.000 claims abstract description 17
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims abstract description 17
- 239000010902 straw Substances 0.000 claims abstract description 17
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000002360 preparation method Methods 0.000 claims abstract description 8
- 239000006185 dispersion Substances 0.000 claims description 30
- 230000003115 biocidal Effects 0.000 claims description 25
- 101700015827 FYPP3 Proteins 0.000 claims description 16
- PIJPYDMVFNTHIP-UHFFFAOYSA-L Lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 claims description 16
- 241000209094 Oryza Species 0.000 claims description 16
- 239000004743 Polypropylene Substances 0.000 claims description 16
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 16
- OGIDPMRJRNCKJF-UHFFFAOYSA-N TiO Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 16
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 16
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 claims description 16
- 101700004450 phpP Proteins 0.000 claims description 16
- 229920001155 polypropylene Polymers 0.000 claims description 16
- 229910001929 titanium oxide Inorganic materials 0.000 claims description 16
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 5
- QOSTVEDABRQTSU-UHFFFAOYSA-N 1,4-bis(methylamino)anthracene-9,10-dione Chemical group O=C1C2=CC=CC=C2C(=O)C2=C1C(NC)=CC=C2NC QOSTVEDABRQTSU-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 3
- KEQXNNJHMWSZHK-UHFFFAOYSA-L 1,3,2,4$l^{2}-dioxathiaplumbetane 2,2-dioxide Chemical compound [Pb+2].[O-]S([O-])(=O)=O KEQXNNJHMWSZHK-UHFFFAOYSA-L 0.000 abstract 1
- 239000005747 Chlorothalonil Substances 0.000 abstract 1
- 240000007594 Oryza sativa Species 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- CRHLEZORXKQUEI-UHFFFAOYSA-N dialuminum;cobalt(2+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Al+3].[Co+2].[Co+2] CRHLEZORXKQUEI-UHFFFAOYSA-N 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 229920001911 maleic anhydride grafted polypropylene Polymers 0.000 abstract 1
- 229910052901 montmorillonite Inorganic materials 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000006011 modification reaction Methods 0.000 description 2
- 230000000979 retarding Effects 0.000 description 2
- 101710014322 MDV028 Proteins 0.000 description 1
- 229920001587 Wood-plastic composite Polymers 0.000 description 1
- 229940089401 Xylon Drugs 0.000 description 1
- 230000000845 anti-microbial Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000011155 wood-plastic composite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention relates to a flame-resistant waterproof antibacterial wood-plastic material which comprises the following ingredients in parts by mass: 186-190 parts of straw powder, 188-192 parts of rice hull powder, 184-188 parts of wood hull, 14-18 parts of lead sulphate tribasic, 10-14 parts of polyethylene wax, 14-18 parts of aluminum hydroxide, 10-14 parts of maleic anhydride, 16-20 parts of a polytetrafluoroethylene fiber, 10-14 parts of nano-montmorillonite, 14-18 parts of nano-titanium dioxide, 10-14 parts of chlorinated polyethylene, 14-18 parts of maleic anhydride grafted polypropylene, 10-14 parts of chlorothalonil, 14-18 parts of dimethyl distearylammonium chloride, 10-14 parts of cresyl diphenyl phosphate, 14-18 parts of camphor, 10-14 parts of cobalt aluminate, 14-18 parts of sodium lauryl sulfate and 10-14 parts of sodium tripolyphosphate. A preparation process or method for the lame-resistant waterproof antibacterial wood-plastic material is simple; the prepared product has relatively excellent flame-resistant, acid/alkali-resistant, waterproof and antibacterial properties, and is applicable to various fields; and by adoption of the preparation process or method, the product performance is improved.
Description
Technical field
The present invention relates to a kind of fire-resistant waterproof antibiosis wood plastic material, belong to Wood-plastic material formula technique field.
Background technology
Wood-plastic material adopts xylon or vegetable fibre to fill, strengthens, and through hot pressing compound, the modified thermoplastic material that different processing mode makes such as to melt extrude.In recent years increasingly exhausted with global resources, social environment consciousness is day by day surging, proposes requirements at the higher level to timber and petroleum chemicals application.In this context, this advantage that can play each component in material of wood plastic composite, the use limitation that overcome because strength of wood is low, the large and organic materials Young's modulus of variability is low etc. causes, can make full use of again discarded timber and plastics, reduce environmental pollution.At present, Wood-plastic material, compared to wood materials, has fire-retardant, waterproof, the excellent properties such as antibacterial, wear-resisting, can substitute the use such as log and plastics in a lot of field.
Summary of the invention
The object of the present invention is to provide a kind of fire-resistant waterproof antibiosis wood plastic material, to realize the fire-resistant waterproof antibacterial of Wood-plastic material better.
To achieve these goals, technical scheme of the present invention is as follows.
A kind of fire-resistant waterproof antibiosis wood plastic material, be made up of the component of following mass fraction: straw powder 186 ~ 190 parts, powdered rice hulls 188 ~ 192 parts, wood powder 184 ~ 188 parts, lead sulfate tribasic 14 ~ 18 parts, polyethylene wax 10 ~ 14 parts, 14 ~ 18 parts, aluminium hydroxide, maleic anhydride 10 ~ 14 parts, polytetrafluoroethylene fiber 16 ~ 20 parts, nano imvite 10 ~ 14 parts, nano titanium oxide 14 ~ 18 parts, chlorinatedpolyethylene 10 ~ 14 parts, maleic anhydride inoculated polypropylene 14 ~ 18 parts, m-tetrachlorophthalodinitrile 10 ~ 14 parts, distearyl dimethyl ammonium chloride 14 ~ 18 parts, cresyl diphenyl phosphate 10 ~ 14 parts, camphor 14 ~ 18 parts, Leyden blue 10 ~ 14 parts, sodium lauryl sulphate 14 ~ 18 parts, tripoly phosphate sodium STPP 10 ~ 14 parts.
Further, above-mentioned fire-resistant waterproof antibiosis wood plastic material, be made up of the component of following mass fraction: straw powder 186 parts, powdered rice hulls 188 parts, wood powder 184 parts, lead sulfate tribasic 14 parts, polyethylene wax 10 parts, 14 parts, aluminium hydroxide, maleic anhydride 10 parts, polytetrafluoroethylene fiber 16 parts, nano imvite 10 parts, nano titanium oxide 14 parts, chlorinatedpolyethylene 10 parts, maleic anhydride inoculated polypropylene 14 parts, m-tetrachlorophthalodinitrile 10 parts, distearyl dimethyl ammonium chloride 14 parts, cresyl diphenyl phosphate 10 parts, camphor 14 parts, Leyden blue 10 parts, sodium lauryl sulphate 14 parts, tripoly phosphate sodium STPP 10 parts.
Further, above-mentioned fire-resistant waterproof antibiosis wood plastic material, be made up of the component of following mass fraction: straw powder 188 parts, powdered rice hulls 190 parts, wood powder 186 parts, lead sulfate tribasic 16 parts, polyethylene wax 12 parts, 16 parts, aluminium hydroxide, maleic anhydride 12 parts, polytetrafluoroethylene fiber 18 parts, nano imvite 12 parts, nano titanium oxide 16 parts, chlorinatedpolyethylene 12 parts, maleic anhydride inoculated polypropylene 16 parts, m-tetrachlorophthalodinitrile 12 parts, distearyl dimethyl ammonium chloride 16 parts, cresyl diphenyl phosphate 12 parts, camphor 16 parts, Leyden blue 12 parts, sodium lauryl sulphate 16 parts, tripoly phosphate sodium STPP 12 parts.
Further, above-mentioned fire-resistant waterproof antibiosis wood plastic material, be made up of the component of following mass fraction: straw powder 190 parts, powdered rice hulls 192 parts, wood powder 188 parts, lead sulfate tribasic 18 parts, polyethylene wax 14 parts, 18 parts, aluminium hydroxide, maleic anhydride 14 parts, polytetrafluoroethylene fiber 20 parts, nano imvite 14 parts, nano titanium oxide 18 parts, chlorinatedpolyethylene 14 parts, maleic anhydride inoculated polypropylene 18 parts, m-tetrachlorophthalodinitrile 14 parts, distearyl dimethyl ammonium chloride 18 parts, cresyl diphenyl phosphate 14 parts, camphor 18 parts, Leyden blue 14 parts, sodium lauryl sulphate 18 parts, tripoly phosphate sodium STPP 14 parts.
Further, above-mentioned fire-resistant waterproof antibiosis wood plastic material preparation method step is as follows:
(1) straw powder of described mass fraction, powdered rice hulls, wood powder, lead sulfate tribasic, polyethylene wax, aluminium hydroxide, maleic anhydride, polytetrafluoroethylene fiber, chlorinatedpolyethylene, maleic anhydride inoculated polypropylene, m-tetrachlorophthalodinitrile, distearyl dimethyl ammonium chloride, cresyl diphenyl phosphate, camphor, Leyden blue, sodium lauryl sulphate, tripoly phosphate sodium STPP are mixed, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 40KHz, rate of dispersion 5000 ~ 5400r/min, jitter time is 30 ~ 60min;
(2) add the nano imvite of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 35KHz, rate of dispersion 4800 ~ 5200r/min, and jitter time is 30 ~ 50min;
(3) add the nano titanium oxide of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 30KHz, rate of dispersion 4600 ~ 4800r/min, and jitter time is 20 ~ 40min; Mix rear obtained this product.
This beneficial effect of the invention is: this fire-resistant waterproof antibiosis wood plastic material preparation process method is simple, and prepared product has comparatively superior fire-retardant, acid and alkali-resistance, water-proof antibiotic performance, is adapted at multiple fields and uses, improve product performance.
Embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is described, better to understand the present invention.
Embodiment 1
Fire-resistant waterproof antibiosis wood plastic material in the present embodiment, be made up of the component of following mass fraction: straw powder 186 parts, powdered rice hulls 188 parts, wood powder 184 parts, lead sulfate tribasic 14 parts, polyethylene wax 10 parts, 14 parts, aluminium hydroxide, maleic anhydride 10 parts, polytetrafluoroethylene fiber 16 parts, nano imvite 10 parts, nano titanium oxide 14 parts, chlorinatedpolyethylene 10 parts, maleic anhydride inoculated polypropylene 14 parts, m-tetrachlorophthalodinitrile 10 parts, distearyl dimethyl ammonium chloride 14 parts, cresyl diphenyl phosphate 10 parts, camphor 14 parts, Leyden blue 10 parts, sodium lauryl sulphate 14 parts, tripoly phosphate sodium STPP 10 parts.
Above-mentioned fire-resistant waterproof antibiosis wood plastic material preparation method step is as follows:
(1) straw powder of described mass fraction, powdered rice hulls, wood powder, lead sulfate tribasic, polyethylene wax, aluminium hydroxide, maleic anhydride, polytetrafluoroethylene fiber, chlorinatedpolyethylene, maleic anhydride inoculated polypropylene, m-tetrachlorophthalodinitrile, distearyl dimethyl ammonium chloride, cresyl diphenyl phosphate, camphor, Leyden blue, sodium lauryl sulphate, tripoly phosphate sodium STPP are mixed, ultrasonic high speed dispersion, ultrasonic frequency is 20kHz, rate of dispersion 5400r/min, jitter time is 60min;
(2) add the nano imvite of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20kHz, rate of dispersion 5200r/min, and jitter time is 50min;
(3) add the nano titanium oxide of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20kHz, rate of dispersion 4800r/min, and jitter time is 40min; Mix rear obtained this product.
Embodiment 2
Fire-resistant waterproof antibiosis wood plastic material in the present embodiment, be made up of the component of following mass fraction: straw powder 188 parts, powdered rice hulls 190 parts, wood powder 186 parts, lead sulfate tribasic 16 parts, polyethylene wax 12 parts, 16 parts, aluminium hydroxide, maleic anhydride 12 parts, polytetrafluoroethylene fiber 18 parts, nano imvite 12 parts, nano titanium oxide 16 parts, chlorinatedpolyethylene 12 parts, maleic anhydride inoculated polypropylene 16 parts, m-tetrachlorophthalodinitrile 12 parts, distearyl dimethyl ammonium chloride 16 parts, cresyl diphenyl phosphate 12 parts, camphor 16 parts, Leyden blue 12 parts, sodium lauryl sulphate 16 parts, tripoly phosphate sodium STPP 12 parts.
Above-mentioned fire-resistant waterproof antibiosis wood plastic material preparation method step is as follows:
(1) straw powder of described mass fraction, powdered rice hulls, wood powder, lead sulfate tribasic, polyethylene wax, aluminium hydroxide, maleic anhydride, polytetrafluoroethylene fiber, chlorinatedpolyethylene, maleic anhydride inoculated polypropylene, m-tetrachlorophthalodinitrile, distearyl dimethyl ammonium chloride, cresyl diphenyl phosphate, camphor, Leyden blue, sodium lauryl sulphate, tripoly phosphate sodium STPP are mixed, ultrasonic high speed dispersion, ultrasonic frequency is 30kHz, rate of dispersion 5200r/min, jitter time is 45min;
(2) add the nano imvite of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 27kHz, rate of dispersion 5000r/min, and jitter time is 40min;
(3) add the nano titanium oxide of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 25kHz, rate of dispersion 4700r/min, and jitter time is 30min; Mix rear obtained this product.
Embodiment 3
Fire-resistant waterproof antibiosis wood plastic material in the present embodiment, be made up of the component of following mass fraction: straw powder 190 parts, powdered rice hulls 192 parts, wood powder 188 parts, lead sulfate tribasic 18 parts, polyethylene wax 14 parts, 18 parts, aluminium hydroxide, maleic anhydride 14 parts, polytetrafluoroethylene fiber 20 parts, nano imvite 14 parts, nano titanium oxide 18 parts, chlorinatedpolyethylene 14 parts, maleic anhydride inoculated polypropylene 18 parts, m-tetrachlorophthalodinitrile 14 parts, distearyl dimethyl ammonium chloride 18 parts, cresyl diphenyl phosphate 14 parts, camphor 18 parts, Leyden blue 14 parts, sodium lauryl sulphate 18 parts, tripoly phosphate sodium STPP 14 parts.
Above-mentioned fire-resistant waterproof antibiosis wood plastic material preparation method step is as follows:
(1) straw powder of described mass fraction, powdered rice hulls, wood powder, lead sulfate tribasic, polyethylene wax, aluminium hydroxide, maleic anhydride, polytetrafluoroethylene fiber, chlorinatedpolyethylene, maleic anhydride inoculated polypropylene, m-tetrachlorophthalodinitrile, distearyl dimethyl ammonium chloride, cresyl diphenyl phosphate, camphor, Leyden blue, sodium lauryl sulphate, tripoly phosphate sodium STPP are mixed, ultrasonic high speed dispersion, ultrasonic frequency is 40kHz, rate of dispersion 5000r/min, jitter time is 30min;
(2) add the nano imvite of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 35kHz, rate of dispersion 4800r/min, and jitter time is 30min;
(3) add the nano titanium oxide of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 30kHz, rate of dispersion 4600r/min, and jitter time is 20min; Mix rear obtained this product.
Carry out performance measurement for the product in embodiment 1, embodiment 2 and embodiment 3 and certain commercially available prod, measured data are as shown in table 1.Fire protection flame retarding level estimate adopts UL94 standard.
Table 1 the performance test results
Visible, product of the present invention has good acid and alkali-resistance, fire protection flame retarding, waterproof, anti-microbial property.
The above is the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications are also considered as protection scope of the present invention.
Claims (5)
1. a fire-resistant waterproof antibiosis wood plastic material, it is characterized in that: be made up of the component of following mass fraction: straw powder 186 ~ 190 parts, powdered rice hulls 188 ~ 192 parts, wood powder 184 ~ 188 parts, lead sulfate tribasic 14 ~ 18 parts, polyethylene wax 10 ~ 14 parts, 14 ~ 18 parts, aluminium hydroxide, maleic anhydride 10 ~ 14 parts, polytetrafluoroethylene fiber 16 ~ 20 parts, nano imvite 10 ~ 14 parts, nano titanium oxide 14 ~ 18 parts, chlorinatedpolyethylene 10 ~ 14 parts, maleic anhydride inoculated polypropylene 14 ~ 18 parts, m-tetrachlorophthalodinitrile 10 ~ 14 parts, distearyl dimethyl ammonium chloride 14 ~ 18 parts, cresyl diphenyl phosphate 10 ~ 14 parts, camphor 14 ~ 18 parts, Leyden blue 10 ~ 14 parts, sodium lauryl sulphate 14 ~ 18 parts, tripoly phosphate sodium STPP 10 ~ 14 parts.
2. fire-resistant waterproof antibiosis wood plastic material according to claim 1, it is characterized in that: described fire-resistant waterproof antibiosis wood plastic material is made up of the component of following mass fraction: straw powder 186 parts, powdered rice hulls 188 parts, wood powder 184 parts, lead sulfate tribasic 14 parts, polyethylene wax 10 parts, 14 parts, aluminium hydroxide, maleic anhydride 10 parts, polytetrafluoroethylene fiber 16 parts, nano imvite 10 parts, nano titanium oxide 14 parts, chlorinatedpolyethylene 10 parts, maleic anhydride inoculated polypropylene 14 parts, m-tetrachlorophthalodinitrile 10 parts, distearyl dimethyl ammonium chloride 14 parts, cresyl diphenyl phosphate 10 parts, camphor 14 parts, Leyden blue 10 parts, sodium lauryl sulphate 14 parts, tripoly phosphate sodium STPP 10 parts.
3. fire-resistant waterproof antibiosis wood plastic material according to claim 1, it is characterized in that: described fire-resistant waterproof antibiosis wood plastic material is made up of the component of following mass fraction: straw powder 188 parts, powdered rice hulls 190 parts, wood powder 186 parts, lead sulfate tribasic 16 parts, polyethylene wax 12 parts, 16 parts, aluminium hydroxide, maleic anhydride 12 parts, polytetrafluoroethylene fiber 18 parts, nano imvite 12 parts, nano titanium oxide 16 parts, chlorinatedpolyethylene 12 parts, maleic anhydride inoculated polypropylene 16 parts, m-tetrachlorophthalodinitrile 12 parts, distearyl dimethyl ammonium chloride 16 parts, cresyl diphenyl phosphate 12 parts, camphor 16 parts, Leyden blue 12 parts, sodium lauryl sulphate 16 parts, tripoly phosphate sodium STPP 12 parts.
4. fire-resistant waterproof antibiosis wood plastic material according to claim 1, it is characterized in that: described fire-resistant waterproof antibiosis wood plastic material is made up of the component of following mass fraction: straw powder 190 parts, powdered rice hulls 192 parts, wood powder 188 parts, lead sulfate tribasic 18 parts, polyethylene wax 14 parts, 18 parts, aluminium hydroxide, maleic anhydride 14 parts, polytetrafluoroethylene fiber 20 parts, nano imvite 14 parts, nano titanium oxide 18 parts, chlorinatedpolyethylene 14 parts, maleic anhydride inoculated polypropylene 18 parts, m-tetrachlorophthalodinitrile 14 parts, distearyl dimethyl ammonium chloride 18 parts, cresyl diphenyl phosphate 14 parts, camphor 18 parts, Leyden blue 14 parts, sodium lauryl sulphate 18 parts, tripoly phosphate sodium STPP 14 parts.
5. fire-resistant waterproof antibiosis wood plastic material according to claim 1, is characterized in that: described fire-resistant waterproof antibiosis wood plastic material preparation method step is as follows:
(1) straw powder of described mass fraction, powdered rice hulls, wood powder, lead sulfate tribasic, polyethylene wax, aluminium hydroxide, maleic anhydride, polytetrafluoroethylene fiber, chlorinatedpolyethylene, maleic anhydride inoculated polypropylene, m-tetrachlorophthalodinitrile, distearyl dimethyl ammonium chloride, cresyl diphenyl phosphate, camphor, Leyden blue, sodium lauryl sulphate, tripoly phosphate sodium STPP are mixed, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 40KHz, rate of dispersion 5000 ~ 5400r/min, jitter time is 30 ~ 60min;
(2) add the nano imvite of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 35KHz, rate of dispersion 4800 ~ 5200r/min, and jitter time is 30 ~ 50min;
(3) add the nano titanium oxide of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 30KHz, rate of dispersion 4600 ~ 4800r/min, and jitter time is 20 ~ 40min; Mix rear obtained this product.
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| CN201610036751.8A CN105542499A (en) | 2016-01-19 | 2016-01-19 | Flame-resistant waterproof antibacterial wood-plastic material |
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| CN201610036751.8A CN105542499A (en) | 2016-01-19 | 2016-01-19 | Flame-resistant waterproof antibacterial wood-plastic material |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105925191A (en) * | 2016-05-27 | 2016-09-07 | 安庆越球建筑防水材料有限公司 | Waterproof asphalt material |
| CN106188886A (en) * | 2016-07-21 | 2016-12-07 | 芜湖昊轩环保新材料有限公司 | A kind of aging resistance corrosion resistant wood plastic composite board and preparation method thereof |
| CN106522030A (en) * | 2016-11-11 | 2017-03-22 | 广州市极合技术咨询有限公司 | Wear-resistant packing paper with high structure strength, and production method thereof |
| CN109181078A (en) * | 2018-09-26 | 2019-01-11 | 安徽继宏环保科技有限公司 | A kind of straw fiber board |
| CN109880390A (en) * | 2019-01-23 | 2019-06-14 | 深圳市骏丰木链网科技股份有限公司 | A kind of mould proof water proof fire retardant plate and preparation method thereof |
| CN110791112A (en) * | 2019-09-25 | 2020-02-14 | 湖南波比工艺品制造有限公司 | Environment-friendly wood-plastic material and preparation method and application thereof |
| CN113059646A (en) * | 2021-03-19 | 2021-07-02 | 何增明 | Bio-based bamboo fiber building board preparation machine equipment and preparation method |
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| CN102618052A (en) * | 2012-03-30 | 2012-08-01 | 常熟市常福有机复合肥有限公司 | Environmental-protection high-performance wood-plastic composite |
| CN105038283A (en) * | 2015-08-13 | 2015-11-11 | 许超群 | High-performance wood-plastic composite material and preparation method thereof |
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| CN102516788A (en) * | 2011-11-30 | 2012-06-27 | 南京康标新型材料有限公司 | Material for wood-plastic furniture capable of being coated |
| CN102618052A (en) * | 2012-03-30 | 2012-08-01 | 常熟市常福有机复合肥有限公司 | Environmental-protection high-performance wood-plastic composite |
| CN105038283A (en) * | 2015-08-13 | 2015-11-11 | 许超群 | High-performance wood-plastic composite material and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105925191A (en) * | 2016-05-27 | 2016-09-07 | 安庆越球建筑防水材料有限公司 | Waterproof asphalt material |
| CN106188886A (en) * | 2016-07-21 | 2016-12-07 | 芜湖昊轩环保新材料有限公司 | A kind of aging resistance corrosion resistant wood plastic composite board and preparation method thereof |
| CN106522030A (en) * | 2016-11-11 | 2017-03-22 | 广州市极合技术咨询有限公司 | Wear-resistant packing paper with high structure strength, and production method thereof |
| CN109181078A (en) * | 2018-09-26 | 2019-01-11 | 安徽继宏环保科技有限公司 | A kind of straw fiber board |
| CN109880390A (en) * | 2019-01-23 | 2019-06-14 | 深圳市骏丰木链网科技股份有限公司 | A kind of mould proof water proof fire retardant plate and preparation method thereof |
| CN110791112A (en) * | 2019-09-25 | 2020-02-14 | 湖南波比工艺品制造有限公司 | Environment-friendly wood-plastic material and preparation method and application thereof |
| CN113059646A (en) * | 2021-03-19 | 2021-07-02 | 何增明 | Bio-based bamboo fiber building board preparation machine equipment and preparation method |
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Application publication date: 20160504 |