CN104312444A - Water glass-based multiple-effect wood adhesive and preparation method thereof - Google Patents
Water glass-based multiple-effect wood adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN104312444A CN104312444A CN201410535934.5A CN201410535934A CN104312444A CN 104312444 A CN104312444 A CN 104312444A CN 201410535934 A CN201410535934 A CN 201410535934A CN 104312444 A CN104312444 A CN 104312444A
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- parts
- water glass
- preparation
- rotating speed
- ammonium polyphosphate
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- NTHWMYGWWRZVTN-UHFFFAOYSA-N Sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 235000019353 potassium silicate Nutrition 0.000 title claims abstract description 23
- 239000002023 wood Substances 0.000 title claims abstract description 17
- 239000000853 adhesive Substances 0.000 title claims abstract description 15
- 230000001070 adhesive Effects 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 34
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229920001276 Ammonium polyphosphate Polymers 0.000 claims abstract description 19
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 19
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 17
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N Ammonium phosphates Chemical compound [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 16
- 230000000694 effects Effects 0.000 claims abstract description 14
- -1 ammonium salt modified acrylate Chemical class 0.000 claims abstract description 11
- 210000003135 Vibrissae Anatomy 0.000 claims abstract description 10
- 239000000839 emulsion Substances 0.000 claims abstract description 10
- 229920001285 xanthan gum Polymers 0.000 claims abstract description 10
- 239000000230 xanthan gum Substances 0.000 claims abstract description 10
- 229940082509 xanthan gum Drugs 0.000 claims abstract description 10
- 235000010493 xanthan gum Nutrition 0.000 claims abstract description 10
- 239000011787 zinc oxide Substances 0.000 claims abstract description 10
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims abstract description 9
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- YZSHYAWHUYHGGZ-UHFFFAOYSA-N magnesium;tetradecanoic acid Chemical compound [Mg].CCCCCCCCCCCCCC(O)=O YZSHYAWHUYHGGZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000011863 silicon-based powder Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 238000010521 absorption reaction Methods 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 2
- 239000000779 smoke Substances 0.000 abstract description 2
- 235000012239 silicon dioxide Nutrition 0.000 abstract 2
- 241000894006 Bacteria Species 0.000 abstract 1
- 229940105112 MAGNESIUM MYRISTATE Drugs 0.000 abstract 1
- 231100000614 Poison Toxicity 0.000 abstract 1
- 238000005536 corrosion prevention Methods 0.000 abstract 1
- DMRBHZWQMKSQGR-UHFFFAOYSA-L magnesium;tetradecanoate Chemical compound [Mg+2].CCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCC([O-])=O DMRBHZWQMKSQGR-UHFFFAOYSA-L 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 230000000979 retarding Effects 0.000 abstract 1
- 230000001629 suppression Effects 0.000 abstract 1
- 238000004078 waterproofing Methods 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 238000004513 sizing Methods 0.000 description 7
- 230000000844 anti-bacterial Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 235000019504 cigarettes Nutrition 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- 210000002381 Plasma Anatomy 0.000 description 1
- 230000003712 anti-aging Effects 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000002708 enhancing Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 230000003000 nontoxic Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 230000002195 synergetic Effects 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Abstract
The invention discloses a water glass-based multiple-effect wood adhesive and a preparation method thereof. The water glass-based multiple-effect wood adhesive comprises the following materials by weight parts: 100 parts of water glass, 10-20 parts of ammonium salt modified acrylate emulsion, 4-8 parts of magnesium myristate, 1-2 parts of a silane coupling agent, 5-10 parts of tetrapod-like zinc oxide whiskers, 1-3 parts of xanthan gum, 3-8 parts of silicon dioxide coated ammonium polyphosphate, 3-5 parts of molybdenum oxide, 10-30 parts of water, and 6-12 parts of silica micro-powder. The preparation method comprises the two steps: preparation of silicon dioxide coated ammonium polyphosphate and preparation of the water glass-based adhesive. The water glass-based multiple-effect wood adhesive has environment-friendly and non-poisonous effects, and has the functions of inflaming retarding, smoke suppression, bacteria prevention, sound absorption, corrosion prevention, water proofing and the like; the preparation method is simple and convenient, and is easy in industrialization.
Description
Technical field
The present invention relates to based Wood Adhesives field, be specially a kind of water glass Quito effect based Wood Adhesives and preparation method thereof.
Background technology
Traditional timber sizing agent only has binding function usually, and cause the preparation of functionalization composite wooden material often to need first to carry out the multi task process such as fire-retardant, anticorrosion to timber, technique is loaded down with trivial details, low effort.Modern the growing of wood-based panel industry makes it more and more higher to the requirement of sizing agent, and except having high adhesion energy, the multiple-effect wood sizing agent had without aldehyde, the performance such as fire-retardant, antibacterial, anticorrosion is just receiving more concern.
Summary of the invention
Technical problem solved by the invention is to provide a kind of water glass Quito to imitate based Wood Adhesives, to solve the shortcoming in above-mentioned background technology.
Technical problem solved by the invention realizes by the following technical solutions:
A kind of water glass Quito effect based Wood Adhesives, comprises the raw material of following weight part:
Water glass: 100 parts;
Ammonium salt modified acrylate emulsion: 10-20 part;
Myristic acid magnesium: 4-8 part;
Silane coupling agent: 1-2 part;
Four acicular type zinc oxide crystal whisker: 5-10 part;
Xanthan gum: 1-3 part;
Coated with silica ammonium polyphosphate: 3-8 part;
Molybdenum oxide: 3-5 part;
Water: 10-30 part;
Silicon powder: 6-12 part;
Its concrete preparation method's step is:
1) first prepare coated with silica ammonium polyphosphate: ammonium polyphosphate powder is immersed 24h in silicon sol, then mixture is dry, pulverize, levigate, just obtain described coated with silica ammonium polyphosphate.
2) slowly join in 100 parts of water glass by 10-20 part ammonium salt modified acrylate emulsion, hand operated mixing makes the two mix.Then 4-8 part myristic acid magnesium, 1-2 part silane coupling agent, 5-10 part four acicular type zinc oxide crystal whisker is added successively, after stirring under rotating speed is 800r/min rotating speed, add 1-3 part xanthan gum, 3-8 part coated with silica ammonium polyphosphate, 3-5 part molybdenum oxide and 10-30 part water again, dispersed with stirring 30-60min under rotating speed is 800r/min rotating speed.Finally add 6-12 part silicon powder, stir.
Know-why of the present invention is: ammonium salt modified acrylate emulsion has the advantages that snappiness is high, sticking power is good, it is mixed with water glass, can realize reducing the fragility of water glass adhesive and strengthening the object of splicing power; Four acicular type zinc oxide crystal whisker has wear-resisting, enhancing, noise reduction, suction ripple, the outstanding properties such as antistatic, antibacterial, anti-aging; Silicon powder has fire-resistant, anticorrosion, waterproof, the function such as impervious; Molybdenum oxide and coated with silica ammonium polyphosphate have smoke-inhibiting flame retardant effect, and coated with silica ammonium polyphosphate can prevent fire retardant in use to run off, and plays permanent flame retardant effect; Myristic acid magnesium is a kind of higher fatty acid salt, can capture the sodium ion in water glass, plays the effect strengthening sizing agent water resistance; Meanwhile, between silicon, magnesium, phosphorus, molybdenum, zinc plasma, can synergistic effect be produced, improve the fire-retardant fireproof performance of sizing agent further; Xanthan gum has emulsification, thickening, stable effect, contributes to the infiltration of system and stablizes.Thus, above combined system can obtain having environment friendly aldehyde-free, fire-retardant, press down cigarette, antibacterial, sound absorption, many effects such as anticorrosion, water-fast in the based Wood Adhesives of one.
Beneficial effect: all abundance, excellent property, nontoxic such as the present invention's main ingredient used water glass, acrylic ester emulsion, silicon powder, four acicular type zinc oxide crystal whisker, myristic acid magnesium, xanthan gum, ensure that high-performance and the environment friendly aldehyde-free of sizing agent.In the present invention based Wood Adhesives have concurrently environmental protection, fire-retardant, press down cigarette, antibacterial, sound absorption, the effect such as anticorrosion, water-fast, and preparation technology is simple, easy industrialization, cleanliness without any pollution.Use multiple-effect wood sizing agent of the present invention a step can realize having multi-functional all kinds of wood-based panel product manufacture.
Embodiment
The technique means realized to make the present invention, creation characteristic, reaching object and effect is easy to understand, below in conjunction with specific embodiment, setting forth the present invention further.
Embodiment 1
First prepare coated with silica ammonium polyphosphate: ammonium polyphosphate powder is immersed 24h in silicon sol, then mixture is dry, pulverize, levigate, just obtain coated with silica ammonium polyphosphate.
Slowly joined by 10 parts of ammonium salt modified acrylate emulsions in 100 parts of water glass, hand operated mixing makes the two mix.Then 4 parts of myristic acid magnesium, 1 part of silane coupling agent, 5 parts of four acicular type zinc oxide crystal whiskers are added successively, after stirring under rotating speed is 800r/min rotating speed, add 1 part of xanthan gum, 3 parts of coated with silica ammonium polyphosphates, 3 parts of molybdenum oxides and 10 parts of water again, dispersed with stirring 30min under rotating speed is 800r/min rotating speed.Finally add 6 parts of silicon powders, stir.
Embodiment 2
Slowly joined by 15 parts of ammonium salt modified acrylate emulsions in 100 parts of water glass, hand operated mixing makes the two mix.Then 6 parts of myristic acid magnesium, 1.5 parts of silane coupling agents, 7.5 parts of four acicular type zinc oxide crystal whiskers are added successively, after stirring under rotating speed is 800r/min rotating speed, add 2 parts of xanthan gum, 5.5 parts of coated with silica ammonium polyphosphates, 4 parts of molybdenum oxides and 20 parts of water again, dispersed with stirring 45min under rotating speed is 800r/min rotating speed.Finally add 9 parts of silicon powders, stir.
Embodiment 3
Slowly joined by 20 parts of ammonium salt modified acrylate emulsions in 100 parts of water glass, hand operated mixing makes the two mix.Then 8 parts of myristic acid magnesium, 2 parts of silane coupling agents, 10 parts of four acicular type zinc oxide crystal whiskers are added successively, after stirring under rotating speed is 800r/min rotating speed, add 3 parts of xanthan gum, 8 parts of coated with silica ammonium polyphosphates, 5 parts of molybdenum oxides and 30 parts of water again, dispersed with stirring 60min under rotating speed is 800r/min rotating speed.Finally add 12 parts of silicon powders, stir.
More than show and describe ultimate principle of the present invention and principal character and advantage of the present invention; the technician of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and specification sheets just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications; these changes and improvements all fall in the claimed scope of the invention, and application claims protection domain is defined by appending claims and equivalent thereof.
Claims (2)
1. water glass Quito effect based Wood Adhesives, is characterized in that, comprise the component of following weight part:
Water glass: 100 parts;
Ammonium salt modified acrylate emulsion: 10-20 part;
Myristic acid magnesium: 4-8 part;
Silane coupling agent: 1-2 part;
Four acicular type zinc oxide crystal whisker: 5-10 part;
Xanthan gum: 1-3 part;
Coated with silica ammonium polyphosphate: 3-8 part;
Molybdenum oxide: 3-5 part;
Water: 10-30 part;
Silicon powder: 6-12 part.
2., for the preparation of the preparation method of above-mentioned water glass Quito effect based Wood Adhesives, it is characterized in that, comprise the following steps:
1) first ammonium polyphosphate powder is immersed 24h in silicon sol, then by dry for mixture, pulverize, levigate, just obtain described coated with silica ammonium polyphosphate;
2) slowly join in 100 parts of water glass by 10-20 part ammonium salt modified acrylate emulsion, hand operated mixing makes the two mix; Then 4-8 part myristic acid magnesium, 1-2 part silane coupling agent, 5-10 part four acicular type zinc oxide crystal whisker is added successively, after stirring under rotating speed is 800r/min rotating speed, add 1-3 part xanthan gum, 3-8 part coated with silica ammonium polyphosphate, 3-5 part molybdenum oxide and 10-30 part water again, dispersed with stirring 30-60min under rotating speed is 800r/min rotating speed; Finally add 6-12 part silicon powder, stir.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410535934.5A CN104312444B (en) | 2014-10-13 | 2014-10-13 | A kind of waterglass Quito effect based Wood Adhesives and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410535934.5A CN104312444B (en) | 2014-10-13 | 2014-10-13 | A kind of waterglass Quito effect based Wood Adhesives and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104312444A true CN104312444A (en) | 2015-01-28 |
| CN104312444B CN104312444B (en) | 2016-06-15 |
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| CN201410535934.5A Expired - Fee Related CN104312444B (en) | 2014-10-13 | 2014-10-13 | A kind of waterglass Quito effect based Wood Adhesives and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108485535A (en) * | 2018-03-09 | 2018-09-04 | 中南林业科技大学 | A kind of inorganic adhesive of short-cycle hot-pressing and its preparation method and application |
| CN110540806A (en) * | 2019-10-21 | 2019-12-06 | 山东鲁阳节能材料股份有限公司 | High-temperature-resistant sealant, and preparation method and application thereof |
| CN110845978A (en) * | 2019-11-28 | 2020-02-28 | 新沂市金达木业有限公司 | High-strength adhesive for composite board and preparation method thereof |
| US11453200B2 (en) * | 2016-07-13 | 2022-09-27 | Knauf Gips Kg | Non-flammable panel with real wood veneer and method of manufacture |
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|---|---|---|---|---|
| US6482876B1 (en) * | 1997-07-17 | 2002-11-19 | Henkel Kommanditgesellschaft Auf Aktien | Agglomerates for the production of an aqueous binder system |
| CN101760049A (en) * | 2009-12-09 | 2010-06-30 | 衢州卫凯化工有限公司 | Method for preparing core-shell silicon dioxide-coated ammonium polyphosphate (APP) |
| CN102863906A (en) * | 2012-10-17 | 2013-01-09 | 中南林业科技大学 | Low-cost environment-friendly water glass wood adhesive and preparation method thereof |
-
2014
- 2014-10-13 CN CN201410535934.5A patent/CN104312444B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6482876B1 (en) * | 1997-07-17 | 2002-11-19 | Henkel Kommanditgesellschaft Auf Aktien | Agglomerates for the production of an aqueous binder system |
| CN101760049A (en) * | 2009-12-09 | 2010-06-30 | 衢州卫凯化工有限公司 | Method for preparing core-shell silicon dioxide-coated ammonium polyphosphate (APP) |
| CN102863906A (en) * | 2012-10-17 | 2013-01-09 | 中南林业科技大学 | Low-cost environment-friendly water glass wood adhesive and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11453200B2 (en) * | 2016-07-13 | 2022-09-27 | Knauf Gips Kg | Non-flammable panel with real wood veneer and method of manufacture |
| CN108485535A (en) * | 2018-03-09 | 2018-09-04 | 中南林业科技大学 | A kind of inorganic adhesive of short-cycle hot-pressing and its preparation method and application |
| CN108485535B (en) * | 2018-03-09 | 2020-12-29 | 中南林业科技大学 | Short-period hot-pressing inorganic adhesive and preparation method and application thereof |
| CN110540806A (en) * | 2019-10-21 | 2019-12-06 | 山东鲁阳节能材料股份有限公司 | High-temperature-resistant sealant, and preparation method and application thereof |
| CN110540806B (en) * | 2019-10-21 | 2021-09-14 | 山东鲁阳节能材料股份有限公司 | High-temperature-resistant sealant, and preparation method and application thereof |
| CN110845978A (en) * | 2019-11-28 | 2020-02-28 | 新沂市金达木业有限公司 | High-strength adhesive for composite board and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN104312444B (en) | 2016-06-15 |
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Address after: 515834 Guangdong City, Chenghai Province, east of the town of Huai Huai Industrial Zone Co-patentee after: Central South University of Forestry and Technology Patentee after: Yihua life Polytron Technologies Inc Address before: 515000 Chenghai District, Shantou City, Guangdong, Huai Dong Industrial District, Lian Xia Town, Chenghai District Co-patentee before: Central South University of Forestry and Technology Patentee before: Guangdong Province Yihua Timber Industry Co., Ltd. |
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Granted publication date: 20160615 Termination date: 20191013 |