CN105542340A - Antiskid damping sole material and preparation method thereof - Google Patents
Antiskid damping sole material and preparation method thereof Download PDFInfo
- Publication number
- CN105542340A CN105542340A CN201610037818.XA CN201610037818A CN105542340A CN 105542340 A CN105542340 A CN 105542340A CN 201610037818 A CN201610037818 A CN 201610037818A CN 105542340 A CN105542340 A CN 105542340A
- Authority
- CN
- China
- Prior art keywords
- parts
- antiskid
- sole material
- shock
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses an antiskid damping PVC sole material. The antiskid damping PVC sole material comprises the following components in parts by weight: 30-60 parts of PVC resin, 10-15 parts of rare-earth butadiene rubber, 5-12 parts of natural rubber, 3-6 parts of wollastonite, 2-5 parts of zinc stearate, 1-2 parts of hollow glass bead, 1-2 parts of a foaming agent, 2-3 parts of an activating agent, 0.5-1 part of an accelerant and 0.5-1.5 parts of a vulcanizing agent. The invention also discloses a preparation method of the antiskid damping sole material. The sole material has good antiskid performance, high elasticity, a certain damping capability and excellent shock resistance, resists heat and wear and is soft and comfortable; the preparation method of the sole material is simple and is easy to operate.
Description
Technical field:
The present invention relates to polymer composite, be specifically related to a kind of antiskid, shock-absorbing material for sole of shoe.
Background technology:
Footwear are one of requisites of people's daily life.Footwear on market are various in style, and appearance style is elegant in appearance.People are pursuing on basis elegant in appearance, especially pay close attention to comfortableness, work-ing life etc. the i.e. high-elastic damping performance of sole of footwear, non-skid property.Due to one of the important component part of footwear during sole, the comfortableness of the footwear that the mechanical property of sole directly determines and work-ing life.
Walking is modal motion in people's daily life, and in the process of walking because the conditions such as pavement behavior, shoes that pedestrian wears are different, often there is the phenomenon of even falling down of skidding, thus make people injured, and the Hui Shi foot of walking of long period is uncomfortable, therefore, the sole preparing a kind of antiskid, shock-absorbing is the necessary demand ensureing HUMAN HEALTH.
Summary of the invention:
The object of this invention is to provide a kind of antiskid, shock-absorbing PVC sole material, its non-skid property is good, and elasticity is large, has certain cushioning ability, excellent shock resistance, heat-resisting, wear-resisting, soft comfortable.
Another object of the present invention is to provide the preparation method of this antiskid, shock-absorbing PVC sole material.
For achieving the above object, the present invention is by the following technical solutions:
A kind of antiskid, shock-absorbing PVC sole material, with parts by weight, comprises following component:
Polyvinyl chloride resin 30-60 part, rare earth polybutadiene rubber 10-15 part,
Natural rubber 5-12 part, wollastonite 3-6 part,
Zinic stearas 2-5 part, hollow glass micropearl 1-2 part,
Whipping agent 1-2 part, promoting agent 2-3 part,
Promotor 0.5-1 part, vulcanizing agent 0.5-1.5 part.
Preferred as technique scheme, a kind of antiskid, shock-absorbing PVC sole material, with parts by weight, comprises following component:
Polyvinyl chloride resin 45 parts, rare earth polybutadiene rubber 13 parts,
Natural rubber 10 parts, wollastonite 5 parts,
Zinic stearas 3.5 parts, hollow glass micropearl 2 parts,
Whipping agent 1.5 parts, coupling agent 2 parts,
Promotor 0.8 part, vulcanizing agent 1 part.
Preferred as technique scheme, described rare earth polybutadiene rubber is neodymium system rare earth polybutadiene rubber.
Preferred as technique scheme, the size of described wollastonite is 30-80nm.
Preferred as technique scheme, the size of described hollow glass micropearl is 1-2 μm, and density is 0.1-0.5g/cm
3.
Preferred as technique scheme, described whipping agent is that one or more in fatty alcohol-ether sodium sulfate, sodium lauryl sulphate, Sodium dodecylbenzene sulfonate mix.
Preferred as technique scheme, described coupling agent is one or more mixing in two-(3-triethoxyl silane propyl group)-disulphide, 3-aminopropyl triethoxysilane, N, N-dimethylaminoethanol.
Preferred as technique scheme, described promotor is one or more mixing in Good-Rite Nix, zinc isopropyl xanthate, zinc n butylxanthate, nabam.
Preferred as technique scheme, described vulcanizing agent is one or more mixing in isocyanic ester, urethanum, benzoyl peroxide.
A preparation method for antiskid, shock-absorbing PVC sole material, comprises the following steps:
Polyvinyl chloride resin, rare earth polybutadiene rubber, natural rubber, whipping agent, coupling agent to be joined in mill mixing 2-5min at 80-100 DEG C, add wollastonite, Zinic stearas, hollow glass micropearl, promotor and vulcanizing agent, be warming up to 100-120 DEG C, continue mixing 5-10min, mixing evenly after slice, after room temperature places 12-24h, carry out molded vulcanization on vulcanizing press shaping, obtains antiskid, shock-absorbing PVC sole material.
The present invention has following beneficial effect:
Add olefin block copolymers, in its molecular chain, " hard section ", " soft section " are alternately arranged, and length can control, thus effectively can improve toughness and the elasticity of material for sole of shoe, reach the object of damping;
Material for sole of shoe non-skid property provided by the invention is good, and elasticity is large, has certain cushioning ability, excellent shock resistance, heat-resisting, wear-resisting, soft comfortable.
Embodiment:
For a better understanding of the present invention, below by embodiment, the present invention is further described, and embodiment, only for explaining the present invention, can not form any restriction to the present invention.
Embodiment 1
A kind of antiskid, shock-absorbing PVC sole material, with parts by weight, comprises following component:
Polyvinyl chloride resin 30 parts, rare earth polybutadiene rubber 10 parts,
Natural rubber 5 parts, wollastonite 3 parts,
Zinic stearas 2 parts, hollow glass micropearl 1 part,
Whipping agent 1 part, promoting agent 2 parts,
Promotor 0.5 part, vulcanizing agent 0.5 part.
Its preparation method comprises the following steps:
Polyvinyl chloride resin, rare earth polybutadiene rubber, natural rubber, whipping agent, coupling agent to be joined in mill mixing 2min at 80 DEG C, add wollastonite, Zinic stearas, hollow glass micropearl, promotor and vulcanizing agent, be warming up to 100 DEG C, continue mixing 5min, mixing evenly after slice, after room temperature places 12h, carry out molded vulcanization on vulcanizing press shaping, obtains antiskid, shock-absorbing PVC sole material.
Embodiment 2
A kind of antiskid, shock-absorbing PVC sole material, with parts by weight, comprises following component:
Polyvinyl chloride resin 60 parts, rare earth polybutadiene rubber 15 parts,
Natural rubber 12 parts, wollastonite 6 parts,
Zinic stearas 5 parts, hollow glass micropearl 2 parts,
Whipping agent 2 parts, promoting agent 3 parts,
Promotor 1 part, vulcanizing agent 1.5 parts.
Its preparation method comprises the following steps:
Polyvinyl chloride resin, rare earth polybutadiene rubber, natural rubber, whipping agent, coupling agent to be joined in mill mixing 5min at 100 DEG C, add wollastonite, Zinic stearas, hollow glass micropearl, promotor and vulcanizing agent, be warming up to 120 DEG C, continue mixing 10min, mixing evenly after slice, after room temperature places 24h, carry out molded vulcanization on vulcanizing press shaping, obtains antiskid, shock-absorbing PVC sole material.
Embodiment 3
A kind of antiskid, shock-absorbing PVC sole material, with parts by weight, comprises following component:
Polyvinyl chloride resin 35 parts, rare earth polybutadiene rubber 11 parts,
Natural rubber 7 parts, wollastonite 4 parts,
Zinic stearas 3 parts, hollow glass micropearl 1.2 parts,
Whipping agent 1.2 parts, promoting agent 2.2 parts,
Promotor 0.6 part, vulcanizing agent 0.7 part.
Its preparation method comprises the following steps:
Polyvinyl chloride resin, rare earth polybutadiene rubber, natural rubber, whipping agent, coupling agent to be joined in mill mixing 3min at 85 DEG C, add wollastonite, Zinic stearas, hollow glass micropearl, promotor and vulcanizing agent, be warming up to 105 DEG C, continue mixing 6min, mixing evenly after slice, after room temperature places 14h, carry out molded vulcanization on vulcanizing press shaping, obtains antiskid, shock-absorbing PVC sole material.
Embodiment 4
A kind of antiskid, shock-absorbing PVC sole material, with parts by weight, comprises following component:
Polyvinyl chloride resin 40 parts, rare earth polybutadiene rubber 12 parts,
Natural rubber 9 parts, wollastonite 4.5 parts,
Zinic stearas 4 parts, hollow glass micropearl 1.4 parts,
Whipping agent 1.4 parts, promoting agent 2.4 parts,
Promotor 0.7 part, vulcanizing agent 0.9 part.
Its preparation method comprises the following steps:
Polyvinyl chloride resin, rare earth polybutadiene rubber, natural rubber, whipping agent, coupling agent to be joined in mill mixing 3min at 90 DEG C, add wollastonite, Zinic stearas, hollow glass micropearl, promotor and vulcanizing agent, be warming up to 110 DEG C, continue mixing 7min, mixing evenly after slice, after room temperature places 16h, carry out molded vulcanization on vulcanizing press shaping, obtains antiskid, shock-absorbing PVC sole material.
Embodiment 5
A kind of antiskid, shock-absorbing PVC sole material, with parts by weight, comprises following component:
Polyvinyl chloride resin 45 parts, rare earth polybutadiene rubber 13 parts,
Natural rubber 10 parts, wollastonite 5 parts,
Zinic stearas 4 parts, hollow glass micropearl 1.6 parts,
Whipping agent 1.6 parts, promoting agent 2.6 parts,
Promotor 0.8 part, vulcanizing agent 1.1 parts.
Its preparation method comprises the following steps:
Polyvinyl chloride resin, rare earth polybutadiene rubber, natural rubber, whipping agent, coupling agent to be joined in mill mixing 4min at 95 DEG C, add wollastonite, Zinic stearas, hollow glass micropearl, promotor and vulcanizing agent, be warming up to 115 DEG C, continue mixing 8min, mixing evenly after slice, after room temperature places 18h, carry out molded vulcanization on vulcanizing press shaping, obtains antiskid, shock-absorbing PVC sole material.
Embodiment 6
A kind of antiskid, shock-absorbing PVC sole material, with parts by weight, comprises following component:
Polyvinyl chloride resin 50 parts, rare earth polybutadiene rubber 14 parts,
Natural rubber 11 parts, wollastonite 5.5 parts,
Zinic stearas 4.5 parts, hollow glass micropearl 1.8 parts,
Whipping agent 1.8 parts, promoting agent 2.8 parts,
Promotor 0.9 part, vulcanizing agent 1.3 parts.
Its preparation method comprises the following steps:
Polyvinyl chloride resin, rare earth polybutadiene rubber, natural rubber, whipping agent, coupling agent to be joined in mill mixing 4min at 98 DEG C, add wollastonite, Zinic stearas, hollow glass micropearl, promotor and vulcanizing agent, be warming up to 118 DEG C, continue mixing 9min, mixing evenly after slice, after room temperature places 20h, carry out molded vulcanization on vulcanizing press shaping, obtains antiskid, shock-absorbing PVC sole material.
Carry out performance test to antiskid, shock-absorbing material for sole of shoe provided by the invention below, test result is as shown in table 1:
Table 1
From table 1, material for sole of shoe prepared by the present invention, excellent in mechanical performance, antiskid, shock-absorbing is effective.
Claims (10)
1. an antiskid, shock-absorbing PVC sole material, is characterized in that, with parts by weight, comprises following component:
Polyvinyl chloride resin 30-60 part, rare earth polybutadiene rubber 10-15 part,
Natural rubber 5-12 part, wollastonite 3-6 part,
Zinic stearas 2-5 part, hollow glass micropearl 1-2 part,
Whipping agent 1-2 part, promoting agent 2-3 part,
Promotor 0.5-1 part, vulcanizing agent 0.5-1.5 part.
2. a kind of antiskid, shock-absorbing PVC sole material as claimed in claim 1, is characterized in that, with parts by weight, comprise following component:
Polyvinyl chloride resin 45 parts, rare earth polybutadiene rubber 13 parts,
Natural rubber 10 parts, wollastonite 5 parts,
Zinic stearas 3.5 parts, hollow glass micropearl 2 parts,
Whipping agent 1.5 parts, coupling agent 2 parts,
Promotor 0.8 part, vulcanizing agent 1 part.
3. a kind of antiskid, shock-absorbing PVC sole material as claimed in claim 1, is characterized in that, described rare earth polybutadiene rubber is neodymium system rare earth polybutadiene rubber.
4. a kind of antiskid, shock-absorbing PVC sole material as claimed in claim 1, is characterized in that, the size of described wollastonite is 30-80nm.
5. a kind of antiskid, shock-absorbing PVC sole material as claimed in claim 1, is characterized in that, the size of described hollow glass micropearl is 1-2 μm, and density is 0.1-0.5g/cm
3.
6. a kind of antiskid, shock-absorbing PVC sole material as claimed in claim 1, is characterized in that, described whipping agent is that one or more in fatty alcohol-ether sodium sulfate, sodium lauryl sulphate, Sodium dodecylbenzene sulfonate mix.
7. a kind of antiskid, shock-absorbing PVC sole material as claimed in claim 1, it is characterized in that, described coupling agent is one or more mixing in two-(3-triethoxyl silane propyl group)-disulphide, 3-aminopropyl triethoxysilane, N, N-dimethylaminoethanol.
8. a kind of antiskid, shock-absorbing PVC sole material as claimed in claim 1, is characterized in that, described promotor is one or more mixing in Good-Rite Nix, zinc isopropyl xanthate, zinc n butylxanthate, nabam.
9. a kind of antiskid, shock-absorbing PVC sole material as claimed in claim 1, is characterized in that, described vulcanizing agent is one or more mixing in isocyanic ester, urethanum, benzoyl peroxide.
10. the preparation method of a kind of antiskid, shock-absorbing PVC sole material as described in as arbitrary in claim 1 to 9, is characterized in that, comprise the following steps:
Polyvinyl chloride resin, rare earth polybutadiene rubber, natural rubber, whipping agent, coupling agent to be joined in mill mixing 2-5min at 80-100 DEG C, add wollastonite, Zinic stearas, hollow glass micropearl, promotor and vulcanizing agent, be warming up to 100-120 DEG C, continue mixing 5-10min, mixing evenly after slice, after room temperature places 12-24h, carry out molded vulcanization on vulcanizing press shaping, obtains antiskid, shock-absorbing PVC sole material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610037818.XA CN105542340A (en) | 2016-01-20 | 2016-01-20 | Antiskid damping sole material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610037818.XA CN105542340A (en) | 2016-01-20 | 2016-01-20 | Antiskid damping sole material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105542340A true CN105542340A (en) | 2016-05-04 |
Family
ID=55821921
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610037818.XA Pending CN105542340A (en) | 2016-01-20 | 2016-01-20 | Antiskid damping sole material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105542340A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105968479A (en) * | 2016-05-17 | 2016-09-28 | 高永涛 | High-viscosity elastic material and preparation method thereof |
| CN107964141A (en) * | 2017-12-12 | 2018-04-27 | 温州市小林鞋材有限公司 | A kind of tear-proof sole and preparation method thereof |
| CN108299690A (en) * | 2017-12-26 | 2018-07-20 | 温州市巨伦鞋业有限公司 | Polyurethane shoe-sole and preparation method thereof |
| CN108359146A (en) * | 2017-12-26 | 2018-08-03 | 温州市巨伦鞋业有限公司 | A kind of sole and its manufacturing method of Labor protection shoes |
| CN108752652A (en) * | 2018-05-24 | 2018-11-06 | 际华三五七橡胶制品有限公司 | Caliga rubber outsole is made in a kind of lightweight |
| CN111218041A (en) * | 2020-03-14 | 2020-06-02 | 温州市瓯海凯欣鞋业有限公司 | Wear-resistant sole material and manufacturing method thereof |
| CN112477325A (en) * | 2020-12-31 | 2021-03-12 | 际华三五一五皮革皮鞋有限公司 | One-step formed light-weight cushioning composite outsole and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1154296A (en) * | 1995-10-25 | 1997-07-16 | 株式会社东星化学 | Method for manufacturing outsoles of shoes |
| CN1159460A (en) * | 1996-03-12 | 1997-09-17 | 韩国鞋和皮革研究所 | Thermoplastic PVC foam composition |
| CN101885865A (en) * | 2010-08-09 | 2010-11-17 | 中国皮革和制鞋工业研究院 | High shock-resistant, wear-resistant sport shoe sole material and manufacturing method thereof |
| CN103304919A (en) * | 2013-05-31 | 2013-09-18 | 苏州市景荣科技有限公司 | Fold resisting PVC (Polyvinyl Chloride) foaming sole material |
| CN104109266A (en) * | 2014-06-27 | 2014-10-22 | 安徽宁国尚鼎橡塑制品有限公司 | Wear-resistant and shock-reducing rubber material |
| CN104844852A (en) * | 2014-02-14 | 2015-08-19 | 江苏曜彰体育用品有限公司 | Tennis shoe sole |
-
2016
- 2016-01-20 CN CN201610037818.XA patent/CN105542340A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1154296A (en) * | 1995-10-25 | 1997-07-16 | 株式会社东星化学 | Method for manufacturing outsoles of shoes |
| CN1159460A (en) * | 1996-03-12 | 1997-09-17 | 韩国鞋和皮革研究所 | Thermoplastic PVC foam composition |
| CN101885865A (en) * | 2010-08-09 | 2010-11-17 | 中国皮革和制鞋工业研究院 | High shock-resistant, wear-resistant sport shoe sole material and manufacturing method thereof |
| CN103304919A (en) * | 2013-05-31 | 2013-09-18 | 苏州市景荣科技有限公司 | Fold resisting PVC (Polyvinyl Chloride) foaming sole material |
| CN104844852A (en) * | 2014-02-14 | 2015-08-19 | 江苏曜彰体育用品有限公司 | Tennis shoe sole |
| CN104109266A (en) * | 2014-06-27 | 2014-10-22 | 安徽宁国尚鼎橡塑制品有限公司 | Wear-resistant and shock-reducing rubber material |
Non-Patent Citations (1)
| Title |
|---|
| 汪多仁等: "《现代高分子材料生产及应用手册》", 31 May 2002 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105968479A (en) * | 2016-05-17 | 2016-09-28 | 高永涛 | High-viscosity elastic material and preparation method thereof |
| CN107964141A (en) * | 2017-12-12 | 2018-04-27 | 温州市小林鞋材有限公司 | A kind of tear-proof sole and preparation method thereof |
| CN107964141B (en) * | 2017-12-12 | 2020-09-08 | 温州市小林鞋材有限公司 | Anti-tearing sole and preparation method thereof |
| CN108299690A (en) * | 2017-12-26 | 2018-07-20 | 温州市巨伦鞋业有限公司 | Polyurethane shoe-sole and preparation method thereof |
| CN108359146A (en) * | 2017-12-26 | 2018-08-03 | 温州市巨伦鞋业有限公司 | A kind of sole and its manufacturing method of Labor protection shoes |
| CN108752652A (en) * | 2018-05-24 | 2018-11-06 | 际华三五七橡胶制品有限公司 | Caliga rubber outsole is made in a kind of lightweight |
| CN111218041A (en) * | 2020-03-14 | 2020-06-02 | 温州市瓯海凯欣鞋业有限公司 | Wear-resistant sole material and manufacturing method thereof |
| CN112477325A (en) * | 2020-12-31 | 2021-03-12 | 际华三五一五皮革皮鞋有限公司 | One-step formed light-weight cushioning composite outsole and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105542340A (en) | Antiskid damping sole material and preparation method thereof | |
| CN103788439B (en) | Wide temperature range height shock-absorbing sport shoes sole rubber material and preparation method thereof | |
| US20090289394A1 (en) | Method for manufacturing shoe sole using natural latex | |
| CN103497370A (en) | Shoe sole rubber composition | |
| CN104693564A (en) | Light damping and slipping preventing rubber and plastic foamed sole material and preparing method thereof | |
| CN101824134A (en) | Polyurethane for sports shoe sole and preparation method thereof | |
| CN103497377A (en) | Shoe sole rubber composition | |
| CN104610563A (en) | Preparation method of olefin block copolymer material foam, and application of foam | |
| CN107446191A (en) | A kind of sole rubber foams and its application | |
| CN108976523A (en) | A kind of sponge rubber and preparation method thereof of cold resistance microcellular structure | |
| CN104059258A (en) | Wear resistant and antiskid rubber | |
| CN105237719A (en) | Polyurethane insole and preparation method thereof | |
| CN110615994A (en) | Elastic damping sports shoe sole and preparation process thereof | |
| CN106147106A (en) | A kind of styrene-ethylene-ethylene-propylene-based block copolymer modified foaming body and preparation method and application | |
| US20130203924A1 (en) | Slip prevention pad and method of manufacturing the same | |
| CN103497413A (en) | Lightweight anti-skid high-wear-resistant rubber material for soles, and preparation method thereof | |
| CN202800282U (en) | Warm keeping boots | |
| CN206062290U (en) | A kind of electric insulation sole of bipeltate | |
| CN105542341A (en) | Deodorant anti-microbial PVC sole material and preparation method thereof | |
| CN110483882A (en) | A kind of transparent wear sole composition and preparation method thereof | |
| KR20130021174A (en) | Superadsorbent resin composition for shoes inner pad and the shoes inner pad which was produced using it | |
| CN106589508A (en) | Environment-friendly reclaimed rubber shoe sole | |
| CN203087733U (en) | Novel shoe outsole | |
| CN108859204A (en) | A kind of preparation process of channel rubber TPU foamed shoe sole | |
| CN106118027A (en) | A kind of preparation method of the outdoor activity material for sole of shoe of Wear-resistant puncture-resistant |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160504 |
|
| RJ01 | Rejection of invention patent application after publication |