CN105540773A - Environmental-protection water-treatment antibacterial agent and preparation method thereof - Google Patents
Environmental-protection water-treatment antibacterial agent and preparation method thereof Download PDFInfo
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- CN105540773A CN105540773A CN201610052648.2A CN201610052648A CN105540773A CN 105540773 A CN105540773 A CN 105540773A CN 201610052648 A CN201610052648 A CN 201610052648A CN 105540773 A CN105540773 A CN 105540773A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
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- Environmental & Geological Engineering (AREA)
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an environmental-protection water-treatment antibacterial agent and a preparation method thereof. The environmental-protection water-treatment antibacterial agent is prepared from, by weight, 20-30 parts of polymeric ferric sulfate, 20-30 parts of trimethyol propane triacytate, 15-18 parts of poly aluminum siloxane, 10-15 parts of aluminum sulfate, 10-14 parts of bentonite, 5-8 parts of starch phosphomonoester, 3-6 parts of bis(phenyl dimethyl siloxane)methyl silanol, 2-3 parts of n-pentadecane, 1-2 parts of 4',5,7-trihydroxy flavone, 0.8-1 part of dictamnine and 0.5-1.2 parts of ammonium oxalate. The invention further provides the preparation method of the environmental-protection water-treatment antibacterial agent.
Description
Technical field
The invention belongs to technical field of water treatment, particularly a kind of environment-protective water process antiseptic-germicide and preparation method thereof.
Background technology
Along with growth and the industrial expansion of population, water resources shortage, environmental pressure also constantly increases the weight of, the quality of water quality directly affects the healthy of environment and people, and especially organic pollutant, accelerates the growth and breeding of Measures of Algae in Water Body material, water body is worsened accelerate, problem of environmental pollution has become China's problem demanding prompt solution, and therefore, the effect of sewage disposal technology in production and life is also increasing.
Antiseptic-germicide for water treatment can be divided into organic system antiseptic-germicide, inorganic series antibacterial agent and natural antibacterial agent, known inorganic series antibacterial agent has the material of the germ resistance metals such as phosphatic rock, zeolite, glass, zirconium phosphate, silica gel even load silver or copper, but inorganic series antibacterial agent is generally Powdered antiseptic-germicide, easily there is the problem of water muddiness, and not easily reclaim.
Summary of the invention
For above-mentioned demand, invention especially provides a kind of environment-protective water process antiseptic-germicide and preparation method thereof.
Object of the present invention can be achieved through the following technical solutions:
A kind of environment-protective water process antiseptic-germicide, be made up of the component comprising following weight part:
Bodied ferric sulfate: 20-30 part, Viscoat 295: 20-30 part,
Polyaluminosiloxane: 15-18 part, Tai-Ace S 150: 10-15 part, wilkinite: 10-14 part,
Starch phosphate monoester: 5-8 part,
Two-(phenyldimethicones) methyl silanol: 3-6 part, Pentadecane: 2-3 part,
4', 5,7-trihydroxyflavone: 1-2 part, dictamine: 0.8-1 part,
Ammonium oxalate: 0.5-1.2 part.
Described component also comprises methyl triacetoxysilane 0-1 weight part.
Described component also comprises Sodium Silicofluoride 0-1 weight part.
A preparation method for environment-protective water process antiseptic-germicide, the method comprises the following steps:
(1) bodied ferric sulfate 20-30 weight part is taken, Viscoat 295 20-30 weight part, polyaluminosiloxane 15-18 weight part, Tai-Ace S 150 10-15 weight part, wilkinite 10-14 weight part, starch phosphate monoester 5-8 weight part, two-(phenyldimethicones) methyl silanol 3-6 weight part, Pentadecane 2-3 weight part, 4', 5, 7-trihydroxyflavone 1-2 weight part, dictamine 0.8-1 weight part, ammonium oxalate 0.5-1.2 weight part, methyl triacetoxysilane 0-1 weight part and Sodium Silicofluoride 0-1 weight part, fine grinding 10-20 minute is pulverized at 100-120 DEG C,
(2) add in high pressure homogenizer and mix 10-20 minute, be cooled to room temperature, obtain environment-protective water process antiseptic-germicide.
Mixing temperature in described high pressure homogenizer is 80-100 DEG C, and blend pressure is 22-25MPa.
Compared with prior art, its beneficial effect is in the present invention:
(1) environment-protective water process antiseptic-germicide of the present invention with bodied ferric sulfate and Viscoat 295 for main raw material, by adding polyaluminosiloxane, Tai-Ace S 150, wilkinite, starch phosphate monoester, two-(phenyldimethicones) methyl silanol, Pentadecane, 4', 5,7-trihydroxyflavone, dictamine and ammonium oxalate, obtained environment-protective water process antiseptic-germicide has good mechanical strength and large specific surface area, and has good anti-microbial effect.
(2) environment-protective water process antiseptic-germicide of the present invention has good wastewater purifying efficiency, and stable performance, the sewage disposal of different PH can be applicable to.
(3) environment-protective water process antiseptic-germicide of the present invention, its preparation method is simple, is easy to suitability for industrialized production.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
(1) bodied ferric sulfate 20kg, Viscoat 295 20kg, polyaluminosiloxane 15kg, Tai-Ace S 150 10kg, wilkinite 10kg, starch phosphate monoester 5kg, two-(phenyldimethicones) methyl silanol 3kg, Pentadecane 2kg, 4' is taken, 5,7-trihydroxyflavone 1kg, dictamine 0.8kg and ammonium oxalate 0.5kg, pulverize fine grinding 10 minutes at 100 DEG C;
(2) to add in high pressure homogenizer 80 DEG C, mixing 10 minutes under 22MPa, be cooled to room temperature, obtain environment-protective water process antiseptic-germicide.
The performance test results of obtained environment-protective water process antiseptic-germicide is as shown in table 1.
Embodiment 2
(1) bodied ferric sulfate 20kg, Viscoat 295 20kg, polyaluminosiloxane 15kg, Tai-Ace S 150 10kg, wilkinite 10kg, starch phosphate monoester 5kg, two-(phenyldimethicones) methyl silanol 3kg, Pentadecane 2kg, 4' is taken, 5,7-trihydroxyflavone 1kg, dictamine 0.8kg, ammonium oxalate 0.5kg, methyl triacetoxysilane 1kg and Sodium Silicofluoride 1kg, pulverize fine grinding 10 minutes at 100 DEG C;
(2) to add in high pressure homogenizer 80 DEG C, mixing 10 minutes under 22MPa, be cooled to room temperature, obtain environment-protective water process antiseptic-germicide.
The performance test results of obtained environment-protective water process antiseptic-germicide is as shown in table 1.
Embodiment 3
(1) bodied ferric sulfate 30kg, Viscoat 295 30kg, polyaluminosiloxane 18kg, Tai-Ace S 150 15kg, wilkinite 14kg, starch phosphate monoester 8kg, two-(phenyldimethicones) methyl silanol 6kg, Pentadecane 3kg, 4' is taken, 5,7-trihydroxyflavone 2kg, dictamine 1kg, ammonium oxalate 1.2kg, methyl triacetoxysilane 1kg and Sodium Silicofluoride 1kg, pulverize fine grinding 20 minutes at 120 DEG C;
(2) to add in high pressure homogenizer 100 DEG C, mixing 20 minutes under 25MPa, be cooled to room temperature, obtain environment-protective water process antiseptic-germicide.
The performance test results of obtained environment-protective water process antiseptic-germicide is as shown in table 1.
Embodiment 4
(1) bodied ferric sulfate 30kg, Viscoat 295 30kg, polyaluminosiloxane 18kg, Tai-Ace S 150 15kg, wilkinite 14kg, starch phosphate monoester 8kg, two-(phenyldimethicones) methyl silanol 6kg, Pentadecane 2kg, 4' is taken, 5,7-trihydroxyflavone 2kg, dictamine 0.8kg, ammonium oxalate 0.5kg, methyl triacetoxysilane 1kg and Sodium Silicofluoride 1kg, pulverize fine grinding 20 minutes at 120 DEG C;
(2) to add in high pressure homogenizer 100 DEG C, mixing 20 minutes under 25MPa, be cooled to room temperature, obtain environment-protective water process antiseptic-germicide.
The performance test results of obtained environment-protective water process antiseptic-germicide is as shown in table 1.
Embodiment 5
(1) bodied ferric sulfate 25kg, Viscoat 295 25kg, polyaluminosiloxane 17kg, Tai-Ace S 150 12kg, wilkinite 12kg, starch phosphate monoester 6kg, two-(phenyldimethicones) methyl silanol 4kg, Pentadecane 2.5kg, 4' is taken, 5,7-trihydroxyflavone 1.5kg, dictamine 0.9kg, ammonium oxalate 1kg, methyl triacetoxysilane 0.5kg and Sodium Silicofluoride 0.5kg, pulverize fine grinding 15 minutes at 110 DEG C;
(2) to add in high pressure homogenizer 90 DEG C, mixing 15 minutes under 23MPa, be cooled to room temperature, obtain environment-protective water process antiseptic-germicide.
The performance test results of obtained environment-protective water process antiseptic-germicide is as shown in table 1.
Comparative example 1
(1) bodied ferric sulfate 30kg, Viscoat 295 30kg, polyaluminosiloxane 18kg, Tai-Ace S 150 15kg, wilkinite 14kg, starch phosphate monoester 8kg, 4' is taken, 5,7-trihydroxyflavone 2kg, dictamine 1kg, ammonium oxalate 1.2kg, methyl triacetoxysilane 1kg and Sodium Silicofluoride 1kg, pulverize fine grinding 20 minutes at 120 DEG C;
(2) to add in high pressure homogenizer 100 DEG C, mixing 20 minutes under 25MPa, be cooled to room temperature, obtain environment-protective water process antiseptic-germicide.
The performance test results of obtained environment-protective water process antiseptic-germicide is as shown in table 1.
Comparative example 2
(1) take bodied ferric sulfate 30kg, Viscoat 295 30kg, polyaluminosiloxane 18kg, Tai-Ace S 150 15kg, wilkinite 14kg, starch phosphate monoester 8kg, two-(phenyldimethicones) methyl silanol 6kg, Pentadecane 3kg, dictamine 1kg, ammonium oxalate 1.2kg, methyl triacetoxysilane 1kg and Sodium Silicofluoride 1kg, at 120 DEG C, pulverize fine grinding 20 minutes;
(2) to add in high pressure homogenizer 100 DEG C, mixing 20 minutes under 25MPa, be cooled to room temperature, obtain environment-protective water process antiseptic-germicide.
The performance test results of obtained environment-protective water process antiseptic-germicide is as shown in table 1.
Comparative example 3
(1) bodied ferric sulfate 30kg, Viscoat 295 30kg, polyaluminosiloxane 18kg, Tai-Ace S 150 15kg, wilkinite 14kg, starch phosphate monoester 8kg, two-(phenyldimethicones) methyl silanol 6kg, Pentadecane 3kg, 4' is taken, 5,7-trihydroxyflavone 2kg, methyl triacetoxysilane 1kg and Sodium Silicofluoride 1kg, pulverize fine grinding 20 minutes at 120 DEG C;
(2) to add in high pressure homogenizer 100 DEG C, mixing 20 minutes under 25MPa, be cooled to room temperature, obtain environment-protective water process antiseptic-germicide.
The performance test results of obtained environment-protective water process antiseptic-germicide is as shown in table 1.
The environment-protective water process antiseptic-germicide of embodiment 1-5 and comparative example 1-3 is used for sewage disposal: the chemical oxygen demand COD of sewage is 500mg/L, and the consumption of antiseptic-germicide is the treatment effect that 0.4g/L can reach good, and concrete outcome asks for an interview table 1.
Table 1
| Test event | Sterilization rate (%) | Removal of heavy metal ions rate (%) | Chemical oxygen demand (COD) (mg/L) |
| Embodiment 1 | 98 | 97 | 32 |
| Embodiment 2 | 99 | 98 | 30 |
| Embodiment 3 | 99 | 98 | 26 |
| Embodiment 4 | 99 | 98 | 27 |
| Embodiment 5 | 99 | 99 | 20 |
| Comparative example 1 | 65 | 65 | 107 |
| Comparative example 2 | 63 | 63 | 90 |
| Comparative example 3 | 69 | 65 | 99 |
The invention is not restricted to embodiment here, those skilled in the art, according to announcement of the present invention, do not depart from improvement that scope makes and amendment all should within protection scope of the present invention.
Claims (5)
1. an environment-protective water process antiseptic-germicide, is characterized in that, is made up of the component comprising following weight part:
Bodied ferric sulfate: 20-30 part, Viscoat 295: 20-30 part,
Polyaluminosiloxane: 15-18 part, Tai-Ace S 150: 10-15 part, wilkinite: 10-14 part,
Starch phosphate monoester: 5-8 part,
Two-(phenyldimethicones) methyl silanol: 3-6 part, Pentadecane: 2-3 part,
4', 5,7-trihydroxyflavone: 1-2 part, dictamine: 0.8-1 part,
Ammonium oxalate: 0.5-1.2 part.
2. environment-protective water process antiseptic-germicide according to claim 1, it is characterized in that, described component also comprises methyl triacetoxysilane 0-1 weight part.
3. environment-protective water process antiseptic-germicide according to claim 1, it is characterized in that, described component also comprises Sodium Silicofluoride 0-1 weight part.
4. a preparation method for environment-protective water process antiseptic-germicide, is characterized in that, the method comprises the following steps:
(1) bodied ferric sulfate 20-30 weight part is taken, Viscoat 295 20-30 weight part, polyaluminosiloxane 15-18 weight part, Tai-Ace S 150 10-15 weight part, wilkinite 10-14 weight part, starch phosphate monoester 5-8 weight part, two-(phenyldimethicones) methyl silanol 3-6 weight part, Pentadecane 2-3 weight part, 4', 5, 7-trihydroxyflavone 1-2 weight part, dictamine 0.8-1 weight part, ammonium oxalate 0.5-1.2 weight part, methyl triacetoxysilane 0-1 weight part and Sodium Silicofluoride 0-1 weight part, fine grinding 10-20 minute is pulverized at 100-120 DEG C,
(2) add in high pressure homogenizer and mix 10-20 minute, be cooled to room temperature, obtain environment-protective water process antiseptic-germicide.
5. the preparation method of environment-protective water process antiseptic-germicide according to claim 4, it is characterized in that, the mixing temperature in described high pressure homogenizer is 80-100 DEG C, and blend pressure is 22-25MPa.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106376611A (en) * | 2016-09-18 | 2017-02-08 | 肇庆市高新区创客科技有限公司 | Environment-friendly water treatment antibacterial agent and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106376611A (en) * | 2016-09-18 | 2017-02-08 | 肇庆市高新区创客科技有限公司 | Environment-friendly water treatment antibacterial agent and preparation method thereof |
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Application publication date: 20160504 |