CN105540699A - Nanometer phosphorus-free water treatment material and preparation method thereof - Google Patents
Nanometer phosphorus-free water treatment material and preparation method thereof Download PDFInfo
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- CN105540699A CN105540699A CN201610052752.1A CN201610052752A CN105540699A CN 105540699 A CN105540699 A CN 105540699A CN 201610052752 A CN201610052752 A CN 201610052752A CN 105540699 A CN105540699 A CN 105540699A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
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- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Water Treatment By Sorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The invention discloses a nanometer phosphorus-free water treatment material and a preparation method thereof. The nanometer phosphorus-free water treatment material is prepared from, by weight, 55-60 parts of polymethyl acrylate, 25-30 parts of bentonite, 10-14 parts of trimethylolpropane triacrylate, 8-11 parts of wollastonite, 5-10 parts of montmorillonite, 4-6 parts of zinc tungstate, 3-6 parts of aluminum sulfate, 2-4 parts of zinc sulfate, 1-2 parts of aluminum potassium sulfate dodecahydrate and 1-2 parts of benzotriazole. The preparation method of the nanometer phosphorus-free water treatment material is further provided.
Description
Technical field
The invention belongs to technical field of water treatment, particularly without phosphorus material for water treatment of a kind of nanometer and preparation method thereof.
Background technology
Sewage disposal: the process reaching a certain water body of draining or the water quality requirement that reuses for making sewage it is purified.Sewage disposal is widely used in building, agricultural, and the every field such as traffic, the energy, petrochemical industry, environmental protection, urban look, medical treatment, food and drink, also come into the daily life of common people more and more.
Along with growth and the industrial expansion of population, water resources shortage, environmental pressure also constantly increases the weight of, the quality of water quality directly affects the healthy of environment and people, and especially organic pollutant, accelerates the growth and breeding of Measures of Algae in Water Body material, water body is worsened accelerate, problem of environmental pollution has become China's problem demanding prompt solution, and therefore, the effect of sewage disposal technology in production and life is also increasing.
Summary of the invention
For above-mentioned demand, invention especially provides without phosphorus material for water treatment of a kind of nanometer and preparation method thereof.
Object of the present invention can be achieved through the following technical solutions:
The without phosphorus material for water treatment of a kind of nanometer, be made up of the component comprising following weight part:
Polymethyl acrylate 55-60 part, wilkinite 25-30 part,
Viscoat 295 10-14 part, wollastonite 8-11 part,
Silicoaluminate magnesium 5-10 part, zinc tungstate 4-6 part, Tai-Ace S 150 3-6 part,
Zinc sulfate 2-4 part, 12 hydrazine aluminum sulfate potassium 1-2 parts,
Benzotriazole 1-2 part.
Described component also comprises gac 0-1 weight part.
Described component also comprises V-Brite B 0-1 weight part.
A preparation method for the without phosphorus material for water treatment of nanometer, the method comprises the following steps:
(1) take polymethyl acrylate 55-60 weight part, wilkinite 25-30 weight part, Viscoat 295 10-14 weight part, wollastonite 8-11 weight part, silicoaluminate magnesium 5-10 weight part, zinc tungstate 4-6 weight part, Tai-Ace S 150 3-6 weight part, zinc sulfate 2-4 weight part, 12 hydrazine aluminum sulfate potassium 1-2 weight parts, benzotriazole 1-2 weight part, gac 0-1 weight part and V-Brite B 0-1 weight part, add grinding in ball grinder 8-15 minute;
(2) add in high pressure homogenizer and mix 10-20 minute, be cooled to room temperature, obtain the without phosphorus material for water treatment of nanometer.
Mixing temperature in described high pressure homogenizer is 75-85 DEG C, and blend pressure is 22-25MPa.
Compared with prior art, its beneficial effect is in the present invention:
(1) the without phosphorus material for water treatment of nanometer of the present invention take polymethyl acrylate as main raw material, by adding wilkinite, Viscoat 295, wollastonite, silicoaluminate magnesium, zinc tungstate, Tai-Ace S 150, zinc sulfate, 12 hydrazine aluminum sulfate potassium and benzotriazoles, the without phosphorus material for water treatment of obtained nanometer has good water treatment efficiency and good adsorption and sedimentation performance.
(2) the without phosphorus material for water treatment stable performance of nanometer of the present invention, can be applicable to the sewage disposal of different PH, and have good anti-microbial effect.
(3) the without phosphorus material for water treatment of nanometer of the present invention, its preparation method is simple, is easy to suitability for industrialized production.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
(1) take polymethyl acrylate 55kg, wilkinite 25kg, Viscoat 295 10kg, wollastonite 8kg, silicoaluminate magnesium 5kg, zinc tungstate 4kg, Tai-Ace S 150 3kg, zinc sulfate 2kg, 12 hydrazine aluminum sulfate potassium 1kg and benzotriazole 1kg, add grinding in ball grinder 8 minutes;
(2) to add in high pressure homogenizer 75 DEG C, mixing 10 minutes under 22MPa condition, be cooled to room temperature, obtain the without phosphorus material for water treatment of nanometer.
The performance test results of the obtained without phosphorus material for water treatment of nanometer is as shown in table 1.
Embodiment 2
(1) take polymethyl acrylate 55kg, wilkinite 25kg, Viscoat 295 10kg, wollastonite 8kg, silicoaluminate magnesium 5kg, zinc tungstate 4kg, Tai-Ace S 150 3kg, zinc sulfate 2kg, 12 hydrazine aluminum sulfate potassium 1kg, benzotriazole 1kg, gac 1kg and V-Brite B 1kg, add grinding in ball grinder 8 minutes;
(2) to add in high pressure homogenizer 75 DEG C, mixing 10 minutes under 22MPa condition, be cooled to room temperature, obtain the without phosphorus material for water treatment of nanometer.
The performance test results of the obtained without phosphorus material for water treatment of nanometer is as shown in table 1.
Embodiment 3
(1) take polymethyl acrylate 60kg, wilkinite 30kg, Viscoat 295 14kg, wollastonite 11kg, silicoaluminate magnesium 10kg, zinc tungstate 6kg, Tai-Ace S 150 6kg, zinc sulfate 4kg, 12 hydrazine aluminum sulfate potassium 2kg, benzotriazole 2kg, gac 1kg and V-Brite B 1kg, add grinding in ball grinder 15 minutes;
(2) to add in high pressure homogenizer 85 DEG C, mixing 20 minutes under 25MPa condition, be cooled to room temperature, obtain the without phosphorus material for water treatment of nanometer.
The performance test results of the obtained without phosphorus material for water treatment of nanometer is as shown in table 1.
Embodiment 4
(1) take polymethyl acrylate 60kg, wilkinite 30kg, Viscoat 295 10kg, wollastonite 11kg, silicoaluminate magnesium 10kg, zinc tungstate 4kg, Tai-Ace S 150 6kg, zinc sulfate 4kg, 12 hydrazine aluminum sulfate potassium 2kg, benzotriazole 2kg, gac 1kg and V-Brite B 1kg, add grinding in ball grinder 15 minutes;
(2) to add in high pressure homogenizer 85 DEG C, mixing 20 minutes under 25MPa condition, be cooled to room temperature, obtain the without phosphorus material for water treatment of nanometer.
The performance test results of the obtained without phosphorus material for water treatment of nanometer is as shown in table 1.
Embodiment 5
(1) take polymethyl acrylate 58kg, wilkinite 28kg, Viscoat 295 12kg, wollastonite 10kg, silicoaluminate magnesium 8kg, zinc tungstate 5kg, Tai-Ace S 150 5kg, zinc sulfate 3kg, 12 hydrazine aluminum sulfate potassium 1.5kg, benzotriazole 1.5kg, gac 0.5kg and V-Brite B 0.5kg, add grinding in ball grinder 11 minutes;
(2) to add in high pressure homogenizer 80 DEG C, mixing 15 minutes under 23MPa condition, be cooled to room temperature, obtain the without phosphorus material for water treatment of nanometer.
The performance test results of the obtained without phosphorus material for water treatment of nanometer is as shown in table 1.
Comparative example 1
(1) take polymethyl acrylate 60kg, wilkinite 30kg, Viscoat 295 14kg, wollastonite 11kg, silicoaluminate magnesium 10kg, zinc tungstate 6kg, Tai-Ace S 150 6kg, zinc sulfate 4kg, gac 1kg and V-Brite B 1kg, add grinding in ball grinder 15 minutes;
(2) to add in high pressure homogenizer 85 DEG C, mixing 20 minutes under 25MPa condition, be cooled to room temperature, obtain the without phosphorus material for water treatment of nanometer.
The performance test results of the obtained without phosphorus material for water treatment of nanometer is as shown in table 1.
Comparative example 2
(1) take polymethyl acrylate 60kg, wilkinite 30kg, wollastonite 11kg, silicoaluminate magnesium 10kg, zinc tungstate 6kg, Tai-Ace S 150 6kg, zinc sulfate 4kg, 12 hydrazine aluminum sulfate potassium 2kg, benzotriazole 2kg, gac 1kg and V-Brite B 1kg, add grinding in ball grinder 15 minutes;
(2) to add in high pressure homogenizer 85 DEG C, mixing 20 minutes under 25MPa condition, be cooled to room temperature, obtain the without phosphorus material for water treatment of nanometer.
The performance test results of the obtained without phosphorus material for water treatment of nanometer is as shown in table 1.
Comparative example 3
(1) take polymethyl acrylate 60kg, wilkinite 30kg, Viscoat 295 14kg, wollastonite 11kg, silicoaluminate magnesium 10kg, Tai-Ace S 150 6kg, zinc sulfate 4kg, 12 hydrazine aluminum sulfate potassium 2kg, benzotriazole 2kg, gac 1kg and V-Brite B 1kg, add grinding in ball grinder 15 minutes;
(2) to add in high pressure homogenizer 85 DEG C, mixing 20 minutes under 25MPa condition, be cooled to room temperature, obtain the without phosphorus material for water treatment of nanometer.
The performance test results of the obtained without phosphorus material for water treatment of nanometer is as shown in table 1.
The sewage that without phosphorus for the nanometer of embodiment 1-5 and comparative example 1-3 material for water treatment is used for 1L is processed: the chemical oxygen demand (COD) (COD) of sewage is 650mg/L, the consumption of material for water treatment is the treatment effect that 0.4g/L can reach good, turbidity removal rate can reach more than 95%
Concrete outcome asks for an interview table 1.
Table 1
| Test event | COD(mg/L) | Removal of heavy metal ions rate (%) | Turbidity (NTU) clearance (%) |
| Embodiment 1 | 35 | 95 | 97 |
| Embodiment 2 | 33 | 96 | 98 |
| Embodiment 3 | 30 | 97 | 99 |
| Embodiment 4 | 32 | 97 | 98 |
| Embodiment 5 | 31 | 97 | 99 |
| Comparative example 1 | 98 | 56 | 68 |
| Comparative example 2 | 89 | 53 | 63 |
| Comparative example 3 | 86 | 45 | 60 |
The invention is not restricted to embodiment here, those skilled in the art, according to announcement of the present invention, do not depart from improvement that scope makes and amendment all should within protection scope of the present invention.
Claims (5)
1. the without phosphorus material for water treatment of nanometer, is characterized in that, is made up of the component comprising following weight part:
Polymethyl acrylate 55-60 part, wilkinite 25-30 part,
Viscoat 295 10-14 part, wollastonite 8-11 part,
Silicoaluminate magnesium 5-10 part, zinc tungstate 4-6 part, Tai-Ace S 150 3-6 part,
Zinc sulfate 2-4 part, 12 hydrazine aluminum sulfate potassium 1-2 parts,
Benzotriazole 1-2 part.
2. the without phosphorus material for water treatment of nanometer according to claim 1, it is characterized in that, described component also comprises gac 0-1 weight part.
3. the without phosphorus material for water treatment of nanometer according to claim 1, it is characterized in that, described component also comprises V-Brite B 0-1 weight part.
4. a preparation method for the without phosphorus material for water treatment of nanometer, it is characterized in that, the method comprises the following steps:
(1) take polymethyl acrylate 55-60 weight part, wilkinite 25-30 weight part, Viscoat 295 10-14 weight part, wollastonite 8-11 weight part, silicoaluminate magnesium 5-10 weight part, zinc tungstate 4-6 weight part, Tai-Ace S 150 3-6 weight part, zinc sulfate 2-4 weight part, 12 hydrazine aluminum sulfate potassium 1-2 weight parts, benzotriazole 1-2 weight part, gac 0-1 weight part and V-Brite B 0-1 weight part, add grinding in ball grinder 8-15 minute;
(2) add in high pressure homogenizer and mix 10-20 minute, be cooled to room temperature, obtain the without phosphorus material for water treatment of nanometer.
5. the preparation method of the without phosphorus material for water treatment of nanometer according to claim 4, it is characterized in that, the mixing temperature in described high pressure homogenizer is 75-85 DEG C, and blend pressure is 22-25MPa.
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| CN201610052752.1A CN105540699A (en) | 2016-01-26 | 2016-01-26 | Nanometer phosphorus-free water treatment material and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106277164A (en) * | 2016-08-24 | 2017-01-04 | 何晓东 | A kind of material for water treatment of phosphorus waste water and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101073764A (en) * | 2007-06-21 | 2007-11-21 | 广西大学 | Plastic-skeleton bentonite bentonite composite adsorbent and its production |
| CN101234800A (en) * | 2008-02-19 | 2008-08-06 | 武汉理工大学 | Composite material for treating azo dyes waste water and preparing method thereof |
| CN101327976A (en) * | 2008-07-15 | 2008-12-24 | 南通立源水处理技术有限公司 | Efficient water treatment flocculant |
| CN103521196A (en) * | 2013-09-10 | 2014-01-22 | 天津道俊包装制品销售有限公司 | Ferroferric oxide/polymer microsphere adsorption metal ions |
-
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- 2016-01-26 CN CN201610052752.1A patent/CN105540699A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101073764A (en) * | 2007-06-21 | 2007-11-21 | 广西大学 | Plastic-skeleton bentonite bentonite composite adsorbent and its production |
| CN101234800A (en) * | 2008-02-19 | 2008-08-06 | 武汉理工大学 | Composite material for treating azo dyes waste water and preparing method thereof |
| CN101327976A (en) * | 2008-07-15 | 2008-12-24 | 南通立源水处理技术有限公司 | Efficient water treatment flocculant |
| CN103521196A (en) * | 2013-09-10 | 2014-01-22 | 天津道俊包装制品销售有限公司 | Ferroferric oxide/polymer microsphere adsorption metal ions |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106277164A (en) * | 2016-08-24 | 2017-01-04 | 何晓东 | A kind of material for water treatment of phosphorus waste water and preparation method thereof |
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