CN105538788A - Flame-retardant five-layer co-extrusion totally-coated inorganic board - Google Patents
Flame-retardant five-layer co-extrusion totally-coated inorganic board Download PDFInfo
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- CN105538788A CN105538788A CN201610089308.7A CN201610089308A CN105538788A CN 105538788 A CN105538788 A CN 105538788A CN 201610089308 A CN201610089308 A CN 201610089308A CN 105538788 A CN105538788 A CN 105538788A
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- retardant
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 95
- 238000001125 extrusion Methods 0.000 title claims abstract description 58
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 47
- 239000010410 layer Substances 0.000 claims abstract description 119
- 239000000463 material Substances 0.000 claims abstract description 109
- 239000002131 composite material Substances 0.000 claims abstract description 75
- 239000012790 adhesive layer Substances 0.000 claims abstract description 46
- 229910010272 inorganic material Inorganic materials 0.000 claims abstract description 40
- 239000011147 inorganic material Substances 0.000 claims abstract description 40
- 238000000034 method Methods 0.000 claims description 26
- 230000008569 process Effects 0.000 claims description 20
- 229920000642 polymer Polymers 0.000 claims description 13
- 229920000098 polyolefin Polymers 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 7
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- 239000011246 composite particle Substances 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 6
- 239000004814 polyurethane Substances 0.000 claims description 6
- 239000000853 adhesive Substances 0.000 claims description 5
- 230000001070 adhesive effect Effects 0.000 claims description 5
- 238000002485 combustion reaction Methods 0.000 claims description 5
- 239000003112 inhibitor Substances 0.000 claims description 5
- 238000005453 pelletization Methods 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 4
- 239000011368 organic material Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- -1 polyethylene Polymers 0.000 claims description 4
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 229920002396 Polyurea Polymers 0.000 claims description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 3
- 229920001587 Wood-plastic composite Polymers 0.000 claims description 3
- 150000004645 aluminates Chemical class 0.000 claims description 3
- 229910052796 boron Inorganic materials 0.000 claims description 3
- 239000004917 carbon fiber Substances 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 230000002708 enhancing effect Effects 0.000 claims description 3
- 239000003822 epoxy resin Substances 0.000 claims description 3
- 150000004820 halides Chemical class 0.000 claims description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- 239000000395 magnesium oxide Substances 0.000 claims description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 3
- 150000004767 nitrides Chemical class 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 229920000647 polyepoxide Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- 230000011218 segmentation Effects 0.000 claims description 3
- 229910021332 silicide Inorganic materials 0.000 claims description 3
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 claims description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 3
- 230000003019 stabilising effect Effects 0.000 claims description 3
- 239000011155 wood-plastic composite Substances 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims 1
- 238000012545 processing Methods 0.000 abstract description 15
- 239000011248 coating agent Substances 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- 230000000694 effects Effects 0.000 description 13
- 238000013461 design Methods 0.000 description 8
- 239000002023 wood Substances 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000007493 shaping process Methods 0.000 description 6
- 239000004566 building material Substances 0.000 description 4
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- 230000007812 deficiency Effects 0.000 description 3
- 230000001788 irregular Effects 0.000 description 3
- 238000003754 machining Methods 0.000 description 3
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- 235000019504 cigarettes Nutrition 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
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- 238000010168 coupling process Methods 0.000 description 1
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- 238000005520 cutting process Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/12—Articles with an irregular circumference when viewed in cross-section, e.g. window profiles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
- B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/016—Flame-proofing or flame-retarding additives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/103—Metal fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/106—Carbon fibres, e.g. graphite fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/14—Mixture of at least two fibres made of different materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2419/00—Buildings or parts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Special Wing (AREA)
Abstract
The invention discloses a flame-retardant five-layer co-extrusion totally-coated inorganic board. The flame-retardant five-layer co-extrusion totally-coated inorganic board comprises a co-extrusion flame-retardant layer, an outer adhesive layer, an inorganic material layer, an inner adhesive layer, a composite material layer and multiple hollow cavities. The sections of the flame-retardant co-extrusion totally-coated inorganic board comprise the L-shaped section and the plane section which are surrounded by the composite material layer to form the hollower cavities, and the outer side of the composite material layer is fixedly bound with the inorganic material layer through the inner adhesive layer; the inorganic material layer is arranged by surrounding the composite material layer in a totally coating or a sectionally coating mode; the periphery of the inorganic material layer or the periphery of the composite material layer is fixedly bound with the co-extrusion flame-retardant layer through the outer adhesive layer. According to the flame-retardant five-layer co-extrusion totally-coated inorganic board, the co-extrusion mode is adopted, the material cost is reduced, the subsequent processing cost is reduced through one-time forming, the whole flame-retardant property of the product is high and reaches the flame retardance of A level, by means of the hollow cavity or special-shaped cavity structure, the material consumption can be reduced by 50% or above, the product weight is reduced, and the lightweight building and carrying requirements are met.
Description
Technical field
The present invention relates to a kind of co-extrusion inorganic plate technical equipment field, particularly the full coated inorganic sheet material of the fire-retardant five-layer co-squeezing of one.
Background technology
Along with the minimizing of the forest reserves, global wood supply quantity not sufficient, high-quality timber particularly lacks, and needs import about the half of annual timber industry wood raw material; And the propelling of urbanization and the raising of people's living standard, building trade and a large amount of structure material of furniture industry demand, a large amount of fast growing wood and alternative aptitude source, there is the deficiency that intensity is low, defect is many, poor dimensional stability, utilization rate are low, therefore, research and development board, slows down the pressure of import external high-quality timber, reduces pressure to domestic wildwood timber resources demand, significant.
Sheet material is the material that current purposes is maximum, and purposes widely, as decorative panel, clad plate, building slab etc.In packaging plate field, due to the raising of people's living standard, commodity tremendous expansion, and also its external packing plate is had higher requirement due to the change of commodity nature.Except the mechanical property of excellence comprises except intensity, toughness, elasticity etc., market demands have difference in functionality sexual demand to sheet material, as barrier, water proofing property, anti-flammability, antibiotic property etc., provide better protection as inner package.Except functional, also propose new requirement to the environmental-protecting performance of sheet material, plastic plate, due to the alternative of its structure, can be arranged in pairs or groups out and have the high performance sheet material of various difference, but plastics non-degradable, a large amount of waste and the white pollution of resource will be caused.
Deficiency of the prior art is: door or door pocket sheet material use that solid wood, Stainless Steel, gypsum line, stone material, mosaic, glass, wood composite, wood are moulded usually, acrylic etc.; By the material of so many kind, make there is certain style, when meeting the door of aesthetical standard or door pocket pattern, need repeatedly complicated processing shaping, the consumable quantity in manufacture process can be very high; The anti-flammability of door or door pocket comes into one's own gradually, the door that particularly A level is fire-retardant and door pocket, some inorganic anti-flaming materials adopted prepare corresponding door or door pocket, although can reach the A level flame-retarding characteristic of needs, the processing in later stage can increase suitable cost; Because structural member is many, cause the installation exercise of door and door pocket complicated.
Summary of the invention
For solving the problems of the technologies described above, the invention provides the full coated inorganic sheet material of a kind of fire-retardant five-layer co-squeezing, for deficiency of the prior art, design the full coated inorganic sheet material of fire-retardant co-extrusion, from outside to inside successively by co-extrusion flame-retardant layer, outer adhesive layer, inorganic material layer, interior adhesive layer and composite layer coextrusion sheet material, manufacture door and door pocket by sheet material; Adopt the processing mode of co-extrusion, machine-shaping structure is simple, and waste of material is few, and hollow molded cavity structure effectively saves material cost; Co-extrusion one-shot forming reduces subsequent machining cost, adopts inorganic material and in macromolecular material, add certain fire retardant to do different subjects material, can improve the flame-retarding characteristic of corresponding product entirety; The one-time formed door of co-extrusion and door pocket greatly reduce the component difficulty of installment work.
For achieving the above object, technical scheme of the present invention is as follows: the full coated inorganic sheet material of a kind of fire-retardant five-layer co-squeezing, comprise co-extrusion flame-retardant layer, outer adhesive layer, inorganic material layer, interior adhesive layer, composite layer, hollow die cavity A, hollow die cavity B, hollow die cavity C, it is characterized in that:
The shape of cross section of the full coated inorganic sheet material of described fire-retardant co-extrusion is L shape section and plane section, in described L shape section and plane section by composite layer around forming multiple hollow die cavity, described hollow die cavity comprises hollow die cavity A, hollow die cavity B and hollow die cavity C; Be adhesively fixed by interior adhesive layer and inorganic material layer outside described composite layer; Described inorganic material layer to distribute around described composite layer in the mode that coated or segmentation is entirely coated, and to be arranged at described composite layer outside; The L shape section that described inorganic material layer and composite layer are formed and plane section periphery are adhesively fixed by outer adhesive layer and co-extrusion flame-retardant layer; Described hollow type cavity shape is the incorporating aspects shape of a kind of in circle, rectangle, polygon, ellipse or more than two kinds, and the position of described hollow die cavity can not affect installing and using of rear Qimen or door pocket; The quantitative range that hollow die cavity in described L shape section is arranged is 2 to 5, and the quantitative range that the hollow die cavity in described plane section is arranged is 5 to 20.。
Described co-extrusion flame-retardant layer adopts polyolefin-based composite high-molecular material and fire retardant, and preferably, described polyolefin-based composite high-molecular material is mixed by the one in polyethylene, polyvinyl chloride or two kinds; The proportion of described polyolefin-based composite high-molecular material is between 10%-30%; Described fire retardant is one in inorganic combustion inhibitor, expansion type flame retardant or two kinds of mixed high-efficient flame-retardant systems; The adding proportion scope of described fire retardant is between 50%-90%.
Described interior adhesive layer and outer adhesive layer mix for one or more have close-burning macromolecular material, and described interior adhesive layer and outer adhesive layer comprise PUR, epoxy resin, polyurethane adhesive; In the macromolecular material molecular structure of described interior adhesive layer and outer adhesive layer, there is lipophilic group and hydrophilic radical simultaneously.
Described inorganic material layer is by silicate, aluminate, borate, phosphate, germanate and magnesia, one in any one or more than two kinds in the stabilising system raw material that magnesium chloride is mixed and/or oxide, nitride, carbide, boride, sulfide, silicide, halide or more than two kinds raw materials, and the macromolecular material mixture of 5%-30% forms; Described inorganic material layer itself can not be lighted, and after burning, residual quantity scope is more than 50%-90%.
Described composite layer is the heterogeneous material that two or more the material in organic material, inorganic material, macromolecular material is prepared through combination process; Described heterogeneous material is polymer composite; Wherein polymer composite is one or more mixtures in the polyolefin-based composite material of wood plastic composite, glass dimension, carbon fiber, boron fibre, silicon carbide fibre enhancing.
Polymer composite addition scope in described composite layer is between 30%-60%, and the addition scope of the native cellulose in described polymer composite is between 10%-60%.
The technical process of described composite layer is as follows: according to certain formula system, prepare composite particles, and described composite particles adopts flat two extruder extruding pelletization, and its expressing technique temperature range is between 140 DEG C-200 DEG C.
The technical process of described co-extrusion flame-retardant layer is as follows: according to certain formula system, prepares flame-proof composite material particle, and prepare flame-proof composite material particle and adopt flat two extruder extruding pelletization, its expressing technique temperature range is between 140 DEG C-200 DEG C.
The technical process of described fire-retardant co-extrusion full coated inorganic sheet material is as follows: use co-extrusion modling mode to process, the coextrusion used is: main frame is the two extruder of cone, subsidiary engine is single screw extrusion machine, and the Process temperature ranges of coextrusion controls between 140 DEG C-200 DEG C.
The flame retardant rating of described fire-retardant co-extrusion full coated inorganic sheet material can reach the A level flame retardant rating in national building materials flame retardant rating standard; The full coated inorganic sheet material of described fire-retardant co-extrusion adopts the machine-shaping of co-extrusion processing mode, and its consumptive material reduces by more than 50%, and cost reduces by more than 50%.
Replacement scheme of the present invention is: by the one-time formed processing mode of coextrusion, can carry out the sheet material design of various structures according to actual needs, as the shape of solid construction, hollow-core construction, polymorphic structure, polygonized structure, enrich the kind of this series products; By hollow die cavity or irregular cavity structure, material usage more than 50% can be reduced.
Operation principle of the present invention is: 1, the processing mode of complete coated co-extrusion is adopted to process, combine inorganic anti-flaming material and organic fire-resisting material, during after reducing inorganic material, Qimen or door pocket manufacture, need the repeatedly cutting (inorganic fire-retarded sheet material) carried out according to difformity, bonding, the expense that compacting waits processing to produce, style and the diversification of color wood grain, built-in hollow die cavity, its consumptive material reduces by more than 50%, cost reduces by more than 50%, solving inorganic anti-flaming material self can not extrusion molding, can not disposable making special-shaped product, and high-molecular organic material is easily made as abnormity, but but do not reach the difficult problem that A level is fire-retardant, the standard that in national building materials flame retardant rating standard, A level difficulty is fired or do not fired can be reached, 2, adopt and there is certain anti-flammability or do skin by the polymer composite that formula Design obtains, fire-retardant and keep the shape of product, comprise abnormity.Internal layer utilizes the cooling effect of different inorganic combustion inhibitor, dilution effect, partition effect, press down cigarette effect etc. and expansion type flame retardant reaches efficient flame retardant effect; 3, the macromolecular material simultaneously in strand with lipophilic group and hydrophilic radical is adopted, by composite layer together with inorganic material layer bonding; Composite layer itself is the macromolecular material containing lipophilic group, and inorganic material itself is hydrophilic, and the tack coat adopted has this two kinds of characteristics simultaneously, plays the effect of coupling; 4, the composite layer macromolecular material adopted, extrudes processing through equipment, prepares and meets arbitrarily attractive in appearance and style that is demand, can be hollow and foaming, not only can improve the whole structure of product, can also reduce costs the weight with product greatly.
Pass through technique scheme, the beneficial effect of technical solution of the present invention is: design the full coated inorganic sheet material of fire-retardant co-extrusion, from outside to inside successively by co-extrusion flame-retardant layer, outer adhesive layer, inorganic material layer, interior adhesive layer and composite layer coextrusion sheet material, manufacture door and door pocket by sheet material; Adopt the processing mode of co-extrusion, machine-shaping structure is simple, and waste of material is few, and hollow molded cavity structure effectively saves material cost; Co-extrusion one-shot forming reduces subsequent machining cost, adopts inorganic material and in macromolecular material, add certain fire retardant to do multilayer material of main part, can improve the flame-retarding characteristic of corresponding product entirety; The one-time formed door of co-extrusion and door pocket greatly reduce the component difficulty of installment work; Coextrusion one-shot forming can design the sheet material of plurality of specifications and shape, is designed to hollow die cavity or irregular cavity structure can reduce material consumption more than 50%; Fundamentally avoid the adhesive that uses containing formaldehyde to the harm of environment and people, its flame retardant effect can reach the fire-retardant requirement of A level.
Accompanying drawing explanation
In order to be illustrated more clearly in the technical scheme of the embodiment of the present invention, be briefly described to the accompanying drawing used required in embodiment or description of the prior art below, apparently, accompanying drawing in the following describes is only some embodiments of the present invention, for those of ordinary skill in the art, under the prerequisite not paying creative work, other accompanying drawing can also be obtained according to these accompanying drawings.
Fig. 1 is the fire-retardant five-layer co-squeezing of the one disclosed in the embodiment of the present invention full coated inorganic sheet material embodiment 1 cross sectional representation;
Fig. 2 is the fire-retardant five-layer co-squeezing of the one disclosed in the embodiment of the present invention full coated inorganic sheet material embodiment 2 cross sectional representation;
Fig. 3 is A place enlarged drawing in the fire-retardant five-layer co-squeezing of the one disclosed in the embodiment of the present invention full coated inorganic sheet material embodiment 1;
Fig. 4 is the fire-retardant five-layer co-squeezing of the one disclosed in the embodiment of the present invention full coated inorganic sheet material embodiment 3 cross sectional representation;
Fig. 5 is Q place enlarged drawing in the fire-retardant five-layer co-squeezing of the one disclosed in the embodiment of the present invention full coated inorganic sheet material embodiment 3.
Numeral and the corresponding component title represented by letter in figure:
1. adhesive layer in co-extrusion flame-retardant layer 2. outer adhesive layer 3. inorganic material layer 4.
5. the hollow die cavity C of composite layer 6. hollow die cavity A7. hollow die cavity B8.
Detailed description of the invention
Below in conjunction with embodiment of the present invention accompanying drawing, be described the technical scheme in the embodiment of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
According to Fig. 1, Fig. 2, Fig. 3, Fig. 4 and Fig. 5, the invention provides the full coated inorganic sheet material of a kind of fire-retardant five-layer co-squeezing, comprise co-extrusion flame-retardant layer 1, outer adhesive layer 2, inorganic material layer 3, interior adhesive layer 4, composite layer 5, hollow die cavity A6, hollow die cavity B7, hollow die cavity C8
The shape of cross section of the full coated inorganic sheet material of described fire-retardant co-extrusion is L shape section and plane section, in described L shape section and plane section by composite layer 5 around forming multiple hollow die cavity, described hollow die cavity comprises hollow die cavity A6, hollow die cavity B7 and hollow die cavity C8; Be adhesively fixed with inorganic material layer 3 by interior adhesive layer 4 outside described composite layer 5; Described inorganic material layer 3 to distribute around described composite layer 5 in the mode that coated or segmentation is entirely coated, and to be arranged at described composite layer 5 outside; The L shape section that described inorganic material layer 3 and composite layer 5 are formed and plane section periphery are adhesively fixed with co-extrusion flame-retardant layer 1 by outer adhesive layer 2; Described hollow type cavity shape is the incorporating aspects shape of a kind of in circle, rectangle, polygon, ellipse or more than two kinds, and the position of described hollow die cavity can not affect installing and using of rear Qimen or door pocket; The quantitative range that hollow die cavity in described L shape section is arranged is 2 to 5, and the quantitative range that the hollow die cavity in plane section is arranged is 5 to 20, depends on the width of plate.
Described co-extrusion flame-retardant layer 1 adopts polyolefin-based composite high-molecular material and fire retardant, and preferably, described polyolefin-based composite high-molecular material is mixed by the one in polyethylene, polyvinyl chloride or two kinds; The proportion of described polyolefin-based composite high-molecular material is between 10%-30%; Described fire retardant is one in inorganic combustion inhibitor, expansion type flame retardant or two kinds of mixed high-efficient flame-retardant systems; The adding proportion scope of described fire retardant is between 50%-90%.
Described interior adhesive layer 4 and outer adhesive layer 2 mix for one or more have close-burning macromolecular material, and described interior adhesive layer 4 and outer adhesive layer 2 comprise PUR, epoxy resin, polyurethane adhesive; In the macromolecular material molecular structure of described interior adhesive layer 4 and outer adhesive layer 2, there is lipophilic group and hydrophilic radical simultaneously.
Described inorganic material layer 3 is by silicate, aluminate, borate, phosphate, germanate and magnesia, one in any one or more than two kinds in the stabilising system raw material that magnesium chloride is mixed and/or oxide, nitride, carbide, boride, sulfide, silicide, halide or more than two kinds raw materials, and the macromolecular material mixture of 5%-30% forms; Described inorganic material layer 3 itself can not be lighted, and after burning, residual quantity scope is more than 50%-90%.
Described composite layer 5 is the heterogeneous material that two or more the material in organic material, inorganic material, macromolecular material is prepared through combination process; Described heterogeneous material is polymer composite; Wherein polymer composite is one or more mixtures in the polyolefin-based composite material of wood plastic composite, glass dimension, carbon fiber, boron fibre, silicon carbide fibre enhancing.
Polymer composite addition scope in described composite layer 5 is between 30%-60%, and the addition scope of the native cellulose in described polymer composite is between 10%-60%.
The technical process of described composite layer 5 is as follows: according to certain formula system, prepare composite particles, and described composite particles adopts flat two extruder extruding pelletization, and its expressing technique temperature range is between 140 DEG C-200 DEG C.
The technical process of described co-extrusion flame-retardant layer 1 is as follows: use co-extrusion modling mode to process, the coextrusion used is: inorganic material layer and composite layer main frame are two conical double screw extruders, co-extrusion flame-retardant layer, interior adhesive layer and outer adhesive layer adopt two single screw extrusion machines, and the Process temperature ranges of coextrusion controls between 140 DEG C-200 DEG C.
The flame retardant rating of described fire-retardant co-extrusion full coated inorganic sheet material can reach the A level flame retardant rating in national building materials flame retardant rating standard; The full coated inorganic sheet material of described fire-retardant co-extrusion adopts the machine-shaping of co-extrusion processing mode, and its consumptive material reduces by more than 50%, and cost reduces by more than 50%, and weight reduces by more than 30%.
Specific embodiment of the invention operating procedure is: 1, adopt the processing mode of complete coated co-extrusion to process, reduce in rear Qimen or door pocket manufacture, need the expense of repeatedly processing generation of carrying out according to difformity, style, color and texture diversification, built-in hollow die cavity, its consumptive material reduces by more than 50%, and cost reduces by more than 50%; 2, adopt the inorganic material with certain anti-flammability and by the flame-retardant high-molecular composite that formula Design obtains, the difficult standard of firing or not firing in national building materials flame retardant rating standard can be reached; Utilize the cooling effect of different inorganic combustion inhibitor, dilution effect, partition effect, press down cigarette effect etc. and expansion type flame retardant reaches efficient flame retardant effect; 3, the macromolecular material simultaneously in strand with lipophilic group and hydrophilic radical is adopted, together with being bondd with inorganic material layer 3 by composite layer 5; Composite layer 5 itself is the macromolecular material containing lipophilic group, and inorganic material 3 itself is hydrophilic, and the tack coat adopted has this two kinds of characteristics simultaneously, plays bridge beam action; 4, composite layer 5 macromolecular material adopted, extrudes processing through equipment, prepares and meets arbitrarily attractive in appearance and style that is demand, not only can improve the whole structure of product, can also reduce costs greatly.
By above-mentioned specific embodiment, the invention has the beneficial effects as follows: design the full coated inorganic sheet material of fire-retardant co-extrusion, from outside to inside successively by co-extrusion flame-retardant layer, outer adhesive layer, inorganic material layer, interior adhesive layer and composite layer coextrusion sheet material, manufacture door and door pocket by sheet material; Adopt the processing mode of co-extrusion, machine-shaping structure is simple, and waste of material is few, and saving material cost effectively falls in hollow molded cavity structure; Co-extrusion one-shot forming reduces subsequent machining cost, adopts inorganic material or in macromolecular material, add certain fire retardant to do material of main part, can improve the flame-retarding characteristic of corresponding product entirety; The one-time formed door of co-extrusion and door pocket greatly reduce the component difficulty of installment work; Coextrusion one-shot forming can design the sheet material of plurality of specifications and shape, is designed to hollow die cavity or irregular cavity structure can reduce material consumption more than 50%; Fundamentally avoid the adhesive that uses containing formaldehyde to the harm of environment and people, its flame retardant effect can reach the fire-retardant requirement of A level.
To the above-mentioned explanation of the disclosed embodiments, professional and technical personnel in the field are realized or uses the present invention.To be apparent to the multiple amendment of these embodiments concerning those skilled in the art, General Principle as defined herein can without departing from the spirit or scope of the present invention, realize in other embodiments.Therefore, the present invention can not be restricted to these embodiments shown in this article, but will meet the widest scope consistent with principle disclosed herein and features of novelty.
Claims (9)
1. the full coated inorganic sheet material of fire-retardant five-layer co-squeezing, is characterized in that, once extrude all layer materials, comprises co-extrusion flame-retardant layer, outer adhesive layer, inorganic material layer, interior adhesive layer, composite layer, hollow die cavity A, hollow die cavity B, hollow die cavity C; The shape of cross section of the full coated inorganic sheet material of described fire-retardant co-extrusion is L shape section and plane section, L shape section and plate shaped section can be door pocket and door-plate, in described L shape section and plane section by composite layer around forming multiple hollow die cavity, described hollow die cavity comprises hollow die cavity A, hollow die cavity B and hollow die cavity C; Be adhesively fixed by interior adhesive layer and inorganic material layer outside described composite layer; Described inorganic material layer to distribute around described composite layer in the mode that coated or segmentation is entirely coated, and to be arranged at described composite layer outside; The L shape section that described inorganic material layer and composite layer are formed and plane section periphery are adhesively fixed by outer adhesive layer and co-extrusion flame-retardant layer; Described hollow type cavity shape is the incorporating aspects shape of a kind of in circle, rectangle, polygon, ellipse or more than two kinds; The quantitative range that hollow die cavity in described L shape section and plane section is arranged is 2 to 5, and the quantitative range that the hollow die cavity in described plate shaped section is arranged is 5 to 20.
2. the full coated inorganic sheet material of the fire-retardant five-layer co-squeezing of one according to claim 1, it is characterized in that, described co-extrusion flame-retardant layer adopts polyolefin-based composite high-molecular material and fire retardant, preferably, described polyolefin-based composite high-molecular material is mixed by the one in polyethylene, polyvinyl chloride or two kinds; The proportion of described polyolefin-based composite high-molecular material is between 10%-30%; Described fire retardant is one in inorganic combustion inhibitor, expansion type flame retardant or two kinds of mixed high-efficient flame-retardant systems; The adding proportion scope of described fire retardant is between 50%-90%.
3. the full coated inorganic sheet material of the fire-retardant five-layer co-squeezing of one according to claim 1, it is characterized in that, described interior adhesive layer and outer adhesive layer mix for one or more have close-burning macromolecular material, and described interior adhesive layer and outer adhesive layer comprise PUR, epoxy resin, polyurethane adhesive; In the macromolecular material molecular structure of described interior adhesive layer and outer adhesive layer, there is lipophilic group and hydrophilic radical simultaneously.
4. the full coated inorganic sheet material of the fire-retardant five-layer co-squeezing of one according to claim 1, it is characterized in that, described inorganic material layer is by silicate, aluminate, borate, phosphate, germanate and magnesia, one in any one or more than two kinds in the stabilising system raw material that magnesium chloride is mixed and/or oxide, nitride, carbide, boride, sulfide, silicide, halide or more than two kinds raw materials, and the macromolecular material mixture of 5%-30% forms; Described inorganic material layer itself can not be lighted, and after burning, residual quantity scope is more than 50%-90%.
5. the full coated inorganic sheet material of the fire-retardant five-layer co-squeezing of one according to claim 1, it is characterized in that, described composite layer is the heterogeneous material that two or more the material in organic material, inorganic material, macromolecular material is prepared through combination process; Described heterogeneous material is polymer composite; Wherein polymer composite is one or more mixtures in the polyolefin-based composite material of wood plastic composite, glass dimension, carbon fiber, boron fibre, silicon carbide fibre enhancing.
6. the full coated inorganic sheet material of the fire-retardant five-layer co-squeezing of one according to claim 1, it is characterized in that, polymer composite addition scope in described composite layer is between 30%-60%, and the addition scope of the native cellulose in described polymer composite is between 10%-60%.
7. the full coated inorganic sheet material of the fire-retardant five-layer co-squeezing of one according to claim 1, it is characterized in that, the technical process of described composite layer is as follows: according to certain formula system, prepare composite particles, described composite particles adopts flat two extruder extruding pelletization, and its expressing technique temperature range is between 140 DEG C-200 DEG C.
8. the full coated inorganic sheet material of the fire-retardant five-layer co-squeezing of one according to claim 1, it is characterized in that, the technical process of described co-extrusion flame-retardant layer is as follows: according to certain formula system, prepare flame-proof composite material particle, prepare flame-proof composite material particle and adopt flat two extruder extruding pelletization, its expressing technique temperature range is between 140 DEG C-200 DEG C.
9. the full coated inorganic sheet material of the fire-retardant five-layer co-squeezing of one according to claim 1, it is characterized in that, the technical process of described fire-retardant co-extrusion full coated inorganic sheet material is as follows: use five-layer co-squeezing to go out molding mode and process, the coextrusion used is: inorganic material layer and composite layer main frame are two conical double screw extruders, co-extrusion flame-retardant layer, interior adhesive layer and outer adhesive layer adopt two single screw extrusion machines, and the Process temperature ranges of coextrusion controls between 140 DEG C-200 DEG C.
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Cited By (1)
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