CN1055351A - Utilize filtrated sludge of cane sugar refinery to make the method for fertilizer - Google Patents

Utilize filtrated sludge of cane sugar refinery to make the method for fertilizer Download PDF

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Publication number
CN1055351A
CN1055351A CN91102320A CN91102320A CN1055351A CN 1055351 A CN1055351 A CN 1055351A CN 91102320 A CN91102320 A CN 91102320A CN 91102320 A CN91102320 A CN 91102320A CN 1055351 A CN1055351 A CN 1055351A
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China
Prior art keywords
wet filter
fertilizer
filter mud
parts
phosphate
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Pending
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CN91102320A
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Chinese (zh)
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叶薇英
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INST OF SCIENCE AND TECHNOLOGY OF CHEMICAL INDUSTRY FUJIAN PROV
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INST OF SCIENCE AND TECHNOLOGY OF CHEMICAL INDUSTRY FUJIAN PROV
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Priority to CN91102320A priority Critical patent/CN1055351A/en
Publication of CN1055351A publication Critical patent/CN1055351A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses

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  • Fertilizers (AREA)

Abstract

The present invention relates to the recovery and utilization technology of the wet filter mud of cane sugar factory refuse.Take in the wet filter mud that undried is handled, to add amendment, make through mixing reaction that physical behavior is splendid to be powdery or granular mixing fertilizer, and then add an amount of nitrogen, potassium, rare earth element, plant-growth regulator and make binary, the Nitrogen, Phosphorus and Potassium that contains rare earth element or plant-growth regulator.Thereby make the wet filter mud that is sposh shape stink change over the fertilizer that powdery or particulate state do not have stink, solved a large amount of wet problem of environment that filter mud causes, have very big economic benefit and social benefit.

Description

Utilize filtrated sludge of cane sugar refinery to make the method for fertilizer
The present invention relates to the recovery and utilization technology of the wet filter mud of cane sugar factory refuse, this technology is applicable to makes mixing fertilizer and composite fertilizer with filtrated sludge of cane sugar refinery.
Cane sugar factory (sulfurous method or carbonatation process) all will be discharged a large amount of wet filter mud waste materials, the output of its wet filter mud is about 3%~5% of sugarcane-squeezing amount, the sugar refinery of pressing 2000 tons of sugarcanes one day has 60~100 tons of wet filter muds to discharge every day approximately, and the whole nation has wet filter mud 200~3,000,000 tons every year approximately.Wet filter mud contains multiple element and a large amount of organic substances such as rich in protein and nitrogen, phosphorus, potassium, calcium, magnesium, sulphur, is a kind of good organic fertilizer.But because wet filter mud water content is bigger, is the sposh shape and volatilizes the extremely difficult smell of smelling, physical behavior is poor, brings very big inconvenience to utilization.So that domestic and international many cane sugar factories are the wet mud waste of major part, or water dashes and enter rivers, or dig large-area melt pit and bury, and if things go on like this, cause that BOD and the COD in the water body increases, and cause serious environmental to pollute.
For this reason, the object of the present invention is to provide and the wet filter mud of cane sugar factory handled to make physical behavior good, do not have difficult olfaction, and the organic and inorganic that is easy to use mixing is fertile and the production method of various composite fertilizers, fundamentally to solve the problem that wet filter mud pollutes.
The key of the technology of the present invention solution is: utilize wet filter mud composting material, just must solve because water content causes physical behavior poor greatly, and bad-smell problem.Major technology feature of the present invention in view of the above is:
One, direct adding can change one or more amendments of wet filter mud physical behavior in the wet filter mud of handling without super-dry, and control pH value is 6~7, through mixing reaction, the process stacking is handled or is handled without stacking, and promptly can be made into to be powdery or the good organic and inorganic mixing fertilizer of particulate state physical behavior.Described amendment is: calcium superphosphate, fused(calcium magnesium)phosphate, thomas phosphate, defluorinated phosphate, various fuel ash, bicarbonate of ammonia, ammonium sulfate, volatile salt, ammonium phosphate sulfate, ammonium phosphate, Calcium hydrogen carbonate, sugarcane chaff, lime carbonate, lime and precipitated superphosphate behind normal superphosphate, double superhosphate, double superphosphate, ammoniated superphosphate, the adding alkali works ammoniated mother sludge waste residue.
Owing to the adding of above-mentioned amendment reacts, the reaction heat that reaction generates raises temperature of charge, partly water evaporates effusion in the filter mud that will wet, and having partly in the reaction again, free-water generates corresponding crystal water, thereby reduced the moisture content existence, changed the physical behavior in the wet filter mud.In addition, along with the increase of pilling up time, above-mentioned reaction process is just complete more, makes the physical behavior of material better, and stink disappears so that finally obtain loose more, dry physical behavior is splendid, the powdery that can directly use or granular organic and inorganic mix fertile
They are two years old, system composite fertilizer: can mix at the organic and inorganic of above-mentioned gained as required and add the required trace element of an amount of nitrogen, phosphorus, potassium and some plants, rare earth element on the fertile basis, reach somatomedin, further make the various binary, the Nitrogen, Phosphorus and Potassium that contain trace element, rare earth element or somatomedin.
So far, because the realization of the technology of the present invention, the wet filter mud of a large amount of pollutents that cane sugar factory is discharged obtains handling, and organic and inorganic mixing fertilizer of being made and binary, Nitrogen, Phosphorus and Potassium have splendid physical behavior, not having the wet original stink of filter mud, is a kind of good organic-inorganic fertilizer.Again because the technology of the present invention is that the wet filter mud that undried is handled is directly handled, thereby a large amount of energy consumptions, fund, equipment have been saved, be a kind of less investment, method simple to operate, thereby solved wet filter mud and caused environmental pollution problems, turn waste into wealth, tangible economic benefit and social benefit are arranged.
Embodiment is as follows:
What example 1-example 14 was used is the wet filter mud of sulfurous method cane sugar factory.
6 parts of the wet filter muds of example 1., 3 parts of double superhosphate, fused(calcium magnesium)phosphate mix for 1 part, and placing becomes promptly after one day that to contain effect phosphorus be 17%, and pH is 6.5 mixing fertilizer.
1 part of 4 parts of the wet filter mud of example 2., 5 parts of ammoniated superphosphates, combustion ash mix to contain available phosphorus 8%, nitrogen 1~2%, pH value be 6 mixing fertilizer.
1 part of 4 parts of the wet filter mud of example 3., 5 parts of calcium superphosphate, fused(calcium magnesium)phosphate mix contain the mixing fertilizer of available phosphorus 10%.
0.3 part of 4 parts of the wet filter mud of example 4., 5 parts of calcium superphosphate, 0.7 part of volatile salt, combustion ash mix contain available phosphorus 10%, nitrogenous 2% composite fertilizer.
4 parts of the wet filter muds of example 5., add 6 parts of calcium superphosphate behind alkali works's ammoniated mother sludge waste residue mix contain the mixing fertilizer of available phosphorus 8%, nitrogen 1%.
4 parts of the wet filter muds of example 6., 5 parts of calcium superphosphate, bicarbonate of ammonia mix and place for 1 part and promptly got the mixing fertilizer that contains available phosphorus 10%, nitrogen 1.5% in one day.
After mixing, 1 part of 4 parts of the wet filter mud of example 7., 5 parts of calcium superphosphate, calcium phosphate promptly get the mixing fertilizer of available phosphorus 10%.
1 part of 3 parts of the wet filter mud of example 8., 6 parts of calcium superphosphate, lime mix to such an extent that to contain available phosphorus be 10% mixing fertilizer.
5 parts of the wet filter muds of example 9., 4 parts of double superhosphate, thomas phosphate mix for 1 part to be placed after half a day to such an extent that available phosphorus is 20% mixing fertilizer.
1 part of 5 parts of the wet filter mud of example 10., 4 parts of double superhosphate, defluorinated phosphate mix to such an extent that contain the mixing fertilizer of available phosphorus 20%.
5 parts of the wet filter muds of example 11., 4 parts in ammonium phosphate, fuel ash mix for 1 part promptly to get and contain that available phosphorus is 22%, the mixing fertilizer of nitrogen 4%.
The mixing fertilizer that must contain available phosphorus 12%, nitrogen 3% after 2 parts of 4 parts of the wet filter muds of example 12., 4 parts of ammonium phoaphate-sulfates, fuel ash mix.
1 part of 3 parts of the wet filter mud of example 13., 6 parts of calcium superphosphate, precipitated superphosphate mix to such an extent that contain the mixing fertilizer of available phosphorus 10%.
The mixing fertilizer that must contain available phosphorus 7% after 1 part of 4 parts of the wet filter mud of example 14., 4 parts in fused(calcium magnesium)phosphate, 1 part of fuel ash, sugarcane chaff mix.
What example 15-example 18 was used is the wet filter mud of carbonic acid law cane sugar factory.
The mixing fertilizer that must contain available phosphorus 8% after 5 parts of 5 parts of the wet filter muds of example 15., calcium superphosphate mix.
Must contain available phosphorus after 3 parts of 4 parts of the wet filter muds of example 16., 3 parts of calcium superphosphate, monoammonium phosphate mix and be 18%, the mixing fertilizer of nitrogen 3%.
1 part of 6 parts of the wet filter mud of example 17., 3 parts of double superhosphate, fuel ash mix the back and place that must to contain available phosphorus half a day be 15% mixing fertilizer.
4 parts of 6 parts of the wet filter muds of example 18., double superhosphate mix the back and place that must to contain available phosphorus in one day be 20% mixing fertilizer.
1 part of 7 parts of the wet filter mud of example 19., 2 parts of double superhosphate, fuel ash mix the back and place that must to contain available phosphorus in one day be 11% mixing fertilizer.
Example 20. is got by fertile 5 parts of 0.5 part in the bicarbonate of ammonia of adding of the mixing of example 3 gained, 3 parts in urea, Repone K and is mixed after select grain, oven dry, cooling promptly to get and contain available phosphorus 5% for 1.5 parts.Potassium oxide 9%, nitrogen 12%, total nutrient 25% contain organic Nitrogen, Phosphorus and Potassium.
Example 21. is got fertile 4 parts of the mixing of example 17 gained, adds after 1.5 parts of 4.5 parts of ammonium chlorides, Repone K mix, and promptly get nitrogenous 10%, available phosphorus 6%, potassium oxide 9%, total oxygen part through granulation, oven dry, cooling is 25% three no composite fertilizers that contain organic matter.
Example 22. is got fertile 5 parts of the mixing of example 10 gained, adds ammonium sulfate and mixes for 5 parts and make the organic binary compound fertilizer that contains available phosphorus 10%, nitrogen 10%.
Example 23. is got fertile 5 parts of the mixing of example 18 gained, add 2 parts of humic acid fertilizers, 1 part in bicarbonate of ammonia, urea mix for 2 parts make contain available phosphorus 10%, nitrogen 9%, humic acids 6% contain plant physiological regulator and organic binary compound fertilizer.
Example 24. adds the borate that contains 1% 3 nitrogenize, two boron respectively in the various composite fertilizers of above-mentioned example 20~example 23 gained, make various binary, the Nitrogen, Phosphorus and Potassium of boracic trace element.

Claims (2)

1, a kind ofly make the method for fertilizer, the invention is characterized in filtrated sludge of cane sugar refinery:
1.1 direct adding can change one or more amendments of wet filter mud physical behavior in the wet filter mud that undried was handled, and the control pH value is 6~7, through mixing reaction, handles or handles without stacking through stacking, promptly make and be powdery or granular organic--inorganic fertilizer
Described amendment is: calcium superphosphate, fused(calcium magnesium)phosphate, thomas phosphate, defluorinated phosphate, various fuel ash, bicarbonate of ammonia, ammonium sulfate, volatile salt, ammonium phosphate sulfate, ammonium phosphate, secondary calcium phosphate, sugarcane chaff, lime carbonate, lime and precipitated superphosphate behind normal superphosphate, double superhosphate, double superphosphate, ammoniated superphosphate, the adding alkali works ammoniated mother sludge waste residue
1.2 can in the organic and inorganic mixing fertilizer of above-mentioned gained, add an amount of required trace element, rare earth element and the somatomedin of nitrogen, phosphorus, potassium and some plants, further make the various binary, the Nitrogen, Phosphorus and Potassium that contain trace element, rare earth element or somatomedin.
2,, it is characterized in that the employed wet filter mud and the ratio of the consumption of amendment are 3~7: 7~3 according to the method for the described composting material of claim.
CN91102320A 1991-03-31 1991-03-31 Utilize filtrated sludge of cane sugar refinery to make the method for fertilizer Pending CN1055351A (en)

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CN91102320A CN1055351A (en) 1991-03-31 1991-03-31 Utilize filtrated sludge of cane sugar refinery to make the method for fertilizer

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Application Number Priority Date Filing Date Title
CN91102320A CN1055351A (en) 1991-03-31 1991-03-31 Utilize filtrated sludge of cane sugar refinery to make the method for fertilizer

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1102558C (en) * 1999-10-19 2003-03-05 李成义 Method for producing granular carbonic acid gas fertilizer from sugar refinery filter mud
CN101734966A (en) * 2008-11-13 2010-06-16 广东传丰复合肥厂有限公司 Active element compound (mixed) fertilizer
CN103288522A (en) * 2013-06-14 2013-09-11 云南中蔗农业科技有限责任公司 Special organic/inorganic compound fertilizer for sugarcane produced by use of filter mud from sugar factory
CN103992800A (en) * 2014-03-11 2014-08-20 高宝周 Method for producing acidification soil conditioner by using filtered mud alcohol waste liquid from carbonatation process sugaring
CN108484260A (en) * 2018-03-30 2018-09-04 广西壮族自治区农业科学院农业资源与环境研究所 The method for improving filter mud of sugarcane fertilizer backward production facilities using rotary drum prilling process
CN108484259A (en) * 2018-03-30 2018-09-04 广西壮族自治区农业科学院农业资源与环境研究所 The method for improving filter mud of sugarcane fertilizer backward production facilities using disc granulation technique

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1102558C (en) * 1999-10-19 2003-03-05 李成义 Method for producing granular carbonic acid gas fertilizer from sugar refinery filter mud
CN101734966A (en) * 2008-11-13 2010-06-16 广东传丰复合肥厂有限公司 Active element compound (mixed) fertilizer
CN103288522A (en) * 2013-06-14 2013-09-11 云南中蔗农业科技有限责任公司 Special organic/inorganic compound fertilizer for sugarcane produced by use of filter mud from sugar factory
CN103992800A (en) * 2014-03-11 2014-08-20 高宝周 Method for producing acidification soil conditioner by using filtered mud alcohol waste liquid from carbonatation process sugaring
CN103992800B (en) * 2014-03-11 2017-03-22 高宝周 Method for producing acidification soil conditioner by using filtered mud alcohol waste liquid from carbonatation process sugaring
CN108484260A (en) * 2018-03-30 2018-09-04 广西壮族自治区农业科学院农业资源与环境研究所 The method for improving filter mud of sugarcane fertilizer backward production facilities using rotary drum prilling process
CN108484259A (en) * 2018-03-30 2018-09-04 广西壮族自治区农业科学院农业资源与环境研究所 The method for improving filter mud of sugarcane fertilizer backward production facilities using disc granulation technique
CN108484259B (en) * 2018-03-30 2021-08-20 广西壮族自治区农业科学院农业资源与环境研究所 Method for improving laggard capacity of sugarcane mud filtering fertilizer by using disc granulation process
CN108484260B (en) * 2018-03-30 2021-08-20 广西壮族自治区农业科学院农业资源与环境研究所 Method for improving laggard capacity of sugarcane mud filtering fertilizer by using rotary drum granulation process

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