CN105531028B - 第9族过渡金属催化剂及其使用方法 - Google Patents

第9族过渡金属催化剂及其使用方法 Download PDF

Info

Publication number
CN105531028B
CN105531028B CN201380077684.9A CN201380077684A CN105531028B CN 105531028 B CN105531028 B CN 105531028B CN 201380077684 A CN201380077684 A CN 201380077684A CN 105531028 B CN105531028 B CN 105531028B
Authority
CN
China
Prior art keywords
group
catalyst
alkyl
reaction
azide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201380077684.9A
Other languages
English (en)
Chinese (zh)
Other versions
CN105531028A (zh
Inventor
弗朗西斯·沃尔特·科列捏斯·沃波特
赫里巴托·迪亚兹贝拉斯克斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangming Innovation (wuhan) Co Ltd
Original Assignee
Guangming Innovation (wuhan) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangming Innovation (wuhan) Co Ltd filed Critical Guangming Innovation (wuhan) Co Ltd
Publication of CN105531028A publication Critical patent/CN105531028A/zh
Application granted granted Critical
Publication of CN105531028B publication Critical patent/CN105531028B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2269—Heterocyclic carbenes
    • B01J31/2273—Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/04—1,2,3-Triazoles; Hydrogenated 1,2,3-triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/04—1,2,3-Triazoles; Hydrogenated 1,2,3-triazoles
    • C07D249/06—1,2,3-Triazoles; Hydrogenated 1,2,3-triazoles with aryl radicals directly attached to ring atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14—Other (co) polymerisation, e.g. of lactides, epoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/324—Cyclisations via conversion of C-C multiple to single or less multiple bonds, e.g. cycloadditions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201380077684.9A 2013-04-26 2013-04-26 第9族过渡金属催化剂及其使用方法 Active CN105531028B (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2013/074755 WO2014172885A1 (fr) 2013-04-26 2013-04-26 Catalyseurs à métal de transition du groupe 9 et procédé d'utilisation de ceux-ci

Publications (2)

Publication Number Publication Date
CN105531028A CN105531028A (zh) 2016-04-27
CN105531028B true CN105531028B (zh) 2019-06-25

Family

ID=51791010

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380077684.9A Active CN105531028B (zh) 2013-04-26 2013-04-26 第9族过渡金属催化剂及其使用方法

Country Status (2)

Country Link
CN (1) CN105531028B (fr)
WO (1) WO2014172885A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6564369B2 (ja) 2013-12-09 2019-08-21 デュレクト コーポレイション 薬学的活性剤複合体、ポリマー複合体、ならびにこれらを伴う組成物及び方法
CN105153051B (zh) * 2015-08-31 2018-06-22 河南师范大学 羧甲基纤维素/纳米铜催化合成1,2,3-三氮唑类化合物的方法
CN105061340B (zh) * 2015-08-31 2018-03-20 河南师范大学 活性炭负载纳米铜催化剂催化合成1,2,3‑三氮唑类化合物的方法
CN113559924B (zh) * 2021-07-28 2023-10-03 绍兴七轩新材料科技有限公司 一种离子液体催化剂及其制备方法和应用

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101402644A (zh) * 2008-10-31 2009-04-08 浙江大学 金属氮杂环卡宾配合物的制备方法
TW200950884A (en) * 2008-06-11 2009-12-16 Henkel Corp (N-heterocyclic carbene) copper salt complex as latent click catalyst
CN101824052A (zh) * 2010-05-19 2010-09-08 中国科学院上海有机化学研究所 一种氮杂环卡宾金属络合物催化合成膦化合物的方法
WO2011094580A2 (fr) * 2010-01-28 2011-08-04 Alnylam Pharmaceuticals, Inc. Cuivre chélaté à utiliser dans la préparation d'oligonucléotides conjugués
WO2012025195A1 (fr) * 2010-08-25 2012-03-01 Universität Heidelberg Catalyseurs moléculaires à base de complexes de cuivre à au moins deux noyaux

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW200950884A (en) * 2008-06-11 2009-12-16 Henkel Corp (N-heterocyclic carbene) copper salt complex as latent click catalyst
CN101402644A (zh) * 2008-10-31 2009-04-08 浙江大学 金属氮杂环卡宾配合物的制备方法
WO2011094580A2 (fr) * 2010-01-28 2011-08-04 Alnylam Pharmaceuticals, Inc. Cuivre chélaté à utiliser dans la préparation d'oligonucléotides conjugués
CN101824052A (zh) * 2010-05-19 2010-09-08 中国科学院上海有机化学研究所 一种氮杂环卡宾金属络合物催化合成膦化合物的方法
WO2012025195A1 (fr) * 2010-08-25 2012-03-01 Universität Heidelberg Catalyseurs moléculaires à base de complexes de cuivre à au moins deux noyaux

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Multicomponent Synthesis of 1,2,3-Triazoles in Water Catalyzed by Silica-Immobilized NHC-Cu(I);Wan Li等;《Catal. Lett.》;20120728;第142卷;第1134-1140页
SiO2-NHC-Cu(I): an efficient and reusable catalyst for [3+2] cycloaddition of organic azides and terminal alkynes under solvent-free reaction conditions at room temperature;Li Pinhua 等;《Tetrahedron》;20080917;第10825-10830页

Also Published As

Publication number Publication date
CN105531028A (zh) 2016-04-27
WO2014172885A1 (fr) 2014-10-30

Similar Documents

Publication Publication Date Title
Zhou et al. Alkyne activation by a porous silver coordination polymer for heterogeneous catalysis of carbon dioxide cycloaddition
Preston et al. Controlled formation of heteroleptic [Pd2 (La) 2 (Lb) 2] 4+ cages
Lu et al. Highly stable copper (I)-based metal–organic framework assembled with resorcin [4] arene and polyoxometalate for efficient heterogeneous catalysis of azide–alkyne “click” reaction
Hoshimoto et al. One-Pot, Single-Step, and Gram-Scale Synthesis of Mononuclear [(η6-arene) Ni (N-heterocyclic carbene)] Complexes: Useful Precursors of the Ni0–NHC Unit
Xiang et al. Synthesis, Structure, and Reactivity of Organo-Iron (II) Complexes with N-Heterocyclic Carbene Ligation
Jaros et al. Aliphatic dicarboxylate directed assembly of silver (I) 1, 3, 5-triaza-7-phosphaadamantane coordination networks: Topological versatility and antimicrobial activity
Ray et al. Shorter argentophilic interaction than aurophilic interaction in a pair of dimeric {(NHC) MCl} 2 (M= Ag, Au) complexes supported over a N/O-functionalized N-heterocyclic carbene (NHC) ligand
Hase et al. Mechanistic aspects of the carboxylative cyclization of propargylamines and carbon dioxide catalyzed by gold (I) complexes bearing an N-heterocyclic carbene ligand
Lee et al. Chiral metallocycles: rational synthesis and novel applications
Mendoza-Espinosa et al. Phenoxy-linked mesoionic triazol-5-ylidenes as platforms for multinuclear transition metal complexes
Monfared et al. Cycloaddition of atmospheric CO 2 to epoxides under solvent-free conditions: a straightforward route to carbonates by green chemistry metrics
Gao et al. Designed synthesis of metal cluster-centered pseudo-rotaxane supramolecular architectures
Lazreg et al. Heteroleptic bis (N-heterocyclic carbene) copper (I) complexes: Highly efficient systems for the [3+ 2] cycloaddition of azides and alkynes
CN105531028B (zh) 第9族过渡金属催化剂及其使用方法
Liu et al. Carbene transfer reactivities of nickel (II)–N-heterocyclic carbene complexes and their applications in the synthesis of metal–NHC complexes
Sameni et al. Calix [4] arene daisychains
Ning et al. Self-assembly and host− guest interaction of metallomacrocycles using fluorescent dipyrazole linker with dimetallic clips
Sortais et al. Cyclometalation of primary benzyl amines by Ruthenium (II), Rhodium (III), and Iridium (III) complexes
García-Álvarez et al. Pd (II)-catalyzed cycloisomerisation of γ-alkynoic acids and one-pot tandem cycloisomerisation/CuAAC reactions in water
Donnelly et al. Adaptive N-mesoionic ligands anchored to a triazolylidene for ruthenium-mediated (de) hydrogenation catalysis
Gonell et al. Main‐chain organometallic microporous polymers bearing triphenylene–tris (N‐heterocyclic carbene)–gold species: catalytic properties
Reiner et al. Zirconium metal–organic frameworks assembled from Pd and Pt PNNNP pincer complexes: Synthesis, postsynthetic modification, and Lewis acid catalysis
Naik et al. Novel Trisphosphine Ligand Containing 1, 3, 5-Triazine Core,[2, 4, 6-C3N3 {C6H4PPh2-p} 3]: Synthesis and Transition Metal Chemistry
ACA Bayrakdar et al. Dinuclear gold (I) complexes bearing alkyl-bridged bis (N-heterocyclic carbene) ligands as catalysts for carboxylative cyclization of propargylamine: Synthesis, structure, and kinetic and mechanistic comparison to the mononuclear complex [Au (IPr) Cl]
Collins et al. Use of Ring-Expanded Diamino-and Diamidocarbene Ligands in Copper Catalyzed Azide–Alkyne “Click” Reactions

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant