CN105524498A - Graphene ferric oxide base far infrared heating coating and preparation method thereof - Google Patents
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Abstract
The invention discloses a graphene ferric oxide base far infrared heating coating and a preparation method thereof. Graphene oxide, nanometer ferric oxide, cerium oxide, tremolite, nanometer silver-ferrum dioxide core-shell structures, obsidian, alipite, ophiolite, medical stone, chlorite, aluminum oxide sol, eucalyptus oil, white alundum, silicone-acrylic emulsion and defoaming agents are used as raw materials; the environment-friendly and healthy graphene ferric oxide base far infrared heating coating with high far infrared heating capability is prepared through a plasma spraying coating process.
Description
Technical field
The invention belongs to far infrared heating coatings art, particularly iron oxide based far infrared heating coating of a kind of Graphene and preparation method thereof.
Background technology
Far infrared rays has stronger seepage force and radial force, has significant temperature control effect and resonance effect, and it is easily absorbed by object and is converted into energy in object.After far infrared rays is absorbed by the body, water molecules in body can be made to produce resonance, make water molecule activation, strengthen its intermolecular bonding force, thus the biomacromolecules such as activation of protein, make biological cell be in the highest vibrational level.Because biomass cells produces resonance effect, far infrared heat energy can be delivered to the subcutaneous darker part of human body, following deep layer temperature rises, and the warm of generation is distributed from inside to outside.This action intensity, makes telangiectasis, stimulates circulation, and strengthens the metabolism between each tissue, increases the regenerative power of tissue, improves the immunological competence of body, regulates the exaltation state of spirit, thus plays the effect of health care.Also there is a lot of far infrared heating material now, as Far-infrared self heating waist support, Far-infrared self heating waist support, also known as Tourmaline self-heating waist support, under the exciting of human body temperature, by shifting the effect of catalyst, thermoinduction material reacts releasing heat in time, and under the amplification of heat energy, far-infrared negative-ion penetrates to the skin depths, the objectionable impuritiess such as peroxynitrite decomposition lipid, and get rid of external by urine and sweat, vasodilation, stimulates circulation, active cells, regulates neural.Far-infrared radiation material absorbed effective conversion of other energy and the molecular vibration of heated material, and reach the objects such as heating, drying, it have energy-conservation, heat temperature raising is fast, pollution-free, thermo-efficiency high, can be widely used in the aspects such as weaving, printing and dyeing, electromechanics, printing, glass annealing, food-processing and health care, civilian cooker, heating installation.
Graphene (Graphene) is the two dimensional crystal only having one deck atomic thickness being stripped out from graphite material, being made up of carbon atom.Graphene oxide (grapheneoxide) is the oxide compound of Graphene, and its color is brown color, and product common on the market has Powdered, sheet and solution shape.Because of after oxidation, it on oxygen-containing functional group increase and make character comparatively Graphene more vivaciously, nature can be improved via various with the reaction of oxygen-containing functional group.It has stronger electroconductibility and thermal conductivity.Graphene has been widely used in a lot of field, but still quite few about the research of graphene-based far infrared heating coating.
Summary of the invention
The object of the invention is for the problems referred to above, develop a kind of environmental protection, health, the iron oxide based far infrared heating coating of Graphene that far infrared heating ability is strong and preparation method thereof.
The iron oxide based far infrared heating coating of a kind of Graphene, this coating comprises the raw material of following weight part:
Graphene oxide 26-36 part;
Nano-sized iron oxide 26-36 part;
Cerium oxide 10-13 part;
Tremolite 10-13 part;
Nanometer silver-ferrous oxide nucleocapsid structure 1-6 part;
Obsidian 1-6 part;
Green magnesium nickel stone 1-6 part;
Serpentine 1-6 part;
Medical stone 1-6 part;
Chlorite 1-6 part;
Alumina sol 1-6 part;
Eucalyptus oil 1-6 part;
White fused alumina 1-6 part;
Organosilicon crylic acid latex 1-6 part;
Defoamer 1-6 part;
Described graphene oxide is obtained by following preparation method:
Get 2 weight part flaky graphites and 1 parts by weight of potassium nitrate is added in the 90 weight part vitriol oils, the mixture obtained is placed in a reservoir and cools in ice-water bath, keep violent stirring simultaneously, continue the potassium permanganate slowly adding 5 weight parts, obtain the suspension of brown; Add the hydrogen peroxide solution of the 2wt% of 5 weight parts subsequently again, obtain jonquilleous suspension; Then wash suspension respectively with deionized water and ethanol, subsequently graphene oxide is dispersed in the extracting solution of aloe, at 82 DEG C, be uniformly mixed 3h, obtain the graphene oxide that extract solution from aloe is modified.
As preferably, this coating comprises the raw material of following weight part:
Graphene oxide 26 parts;
Nano-sized iron oxide 26 parts;
Cerium oxide 12 parts;
The tremolite 12 parts;
Nanometer silver-ferrous oxide nucleocapsid structure 3 parts;
Obsidian 3 parts;
Green 3 parts, magnesium nickel stone;
3 parts, serpentine;
Medical stone 3 parts;
3 parts, chlorite;
Alumina sol 3 parts;
Eucalyptus oil 3 parts;
White fused alumina 3 parts;
Organosilicon crylic acid latex 3 parts;
Defoamer 3 parts.
As preferably, described defoamer is polydimethylsiloxane.
Prepare a method for the iron oxide based far infrared heating coating of above-mentioned Graphene, comprise the steps:
(1) prepare burden according to the iron oxide based far infrared heating coating material composition of Graphene; By raw material mixing wet ball-milling 12 hours, solvent was distilled water, and abrading-ball is ferric oxide abrading-ball, dries, obtain standby material after ball milling at 44 DEG C;
(2) by substrate pre-treatment according to demand; Be applied in pretreated substrate by standby material plasma spray subsequently, can obtain the iron oxide based far infrared heating coating of Graphene, the thickness of coating is 1-26mm.
Beneficial effect of the present invention:
(1) the present invention adopts graphene oxide, nano-sized iron oxide, cerium oxide, the tremolite, nanometer silver-ferrous oxide nucleocapsid structure, obsidian, green magnesium nickel stone, serpentine, medical stone, chlorite, alumina sol, eucalyptus oil, white fused alumina, organosilicon crylic acid latex and defoamer to be raw material, main component is wherein graphene oxide and nano-sized iron oxide, graphene oxide is the graphene oxide that extract solution from aloe is modified, this Graphene is except the function with far infrared heating, also there is effect of health environment-friendly, useful for human body; And the compound use of graphene oxide and nano-sized iron oxide, the two collaborative far infrared heating effect that strengthens;
(2) in order to optimize the performance of far infrared heating further, have selected cerium oxide, the tremolite, nanometer silver-ferrous oxide nucleocapsid structure, obsidian, green magnesium nickel stone, serpentine, medical stone, chlorite, alumina sol, eucalyptus oil, white fused alumina, organosilicon crylic acid latex and defoamer is ancillary component, these auxiliary materials and graphene oxide, together with nano-sized iron oxide, work in coordination with the far infrared heating performance strengthening coating.For example the component such as nanometer silver-silicon dixoide nucleocapsid structure also has the effect of sterilization and disinfection; The infrared emittance of coating prepared by the present invention has exceeded 99.1%.
(4) the iron oxide based far infrared heating preparation technology of coating of this Graphene is simple, is easy to industrialization, and raw material sources are extensive, are applicable to very much being applied to production.
Embodiment
Below in conjunction with specific embodiment, and comparable data describes in further detail the present invention.Should be understood that these embodiments just in order to demonstrate the invention, but not limit the scope of the invention by any way.
Embodiment 1:
The iron oxide based far infrared heating coating of a kind of Graphene, this coating comprises the raw material of following weight part:
Graphene oxide 26 parts;
Nano-sized iron oxide 26 parts;
Cerium oxide 12 parts;
The tremolite 12 parts;
Nanometer silver-ferrous oxide nucleocapsid structure 3 parts;
Obsidian 3 parts;
Green 3 parts, magnesium nickel stone;
3 parts, serpentine;
Medical stone 3 parts;
3 parts, chlorite;
Alumina sol 3 parts;
Eucalyptus oil 3 parts;
White fused alumina 3 parts;
Organosilicon crylic acid latex 3 parts;
Defoamer 3 parts;
Described graphene oxide is obtained by following preparation method:
Get 2 weight part flaky graphites and 1 parts by weight of potassium nitrate is added in the 90 weight part vitriol oils, the mixture obtained is placed in a reservoir and cools in ice-water bath, keep violent stirring simultaneously, continue the potassium permanganate slowly adding 5 weight parts, obtain the suspension of brown; Add the hydrogen peroxide solution of the 2wt% of 5 weight parts subsequently again, obtain jonquilleous suspension; Then wash suspension respectively with deionized water and ethanol, subsequently graphene oxide is dispersed in the extracting solution of aloe, at 82 DEG C, be uniformly mixed 3h, obtain the graphene oxide that extract solution from aloe is modified.
Described defoamer is polydimethylsiloxane.
Prepare a method for the iron oxide based far infrared heating coating of above-mentioned Graphene, comprise the steps:
(1) prepare burden according to the iron oxide based far infrared heating coating material composition of Graphene; By raw material mixing wet ball-milling 12 hours, solvent was distilled water, and abrading-ball is ferric oxide abrading-ball, dries, obtain standby material after ball milling at 44 DEG C;
(2) by substrate pre-treatment according to demand; Be applied in pretreated substrate by standby material plasma spray subsequently, can obtain the iron oxide based far infrared heating coating of Graphene, the thickness of coating is 10mm.The far infrared transmissivity of this coating is 99.2%.
Embodiment 2:
The iron oxide based far infrared heating coating of a kind of Graphene, this coating comprises the raw material of following weight part:
Graphene oxide 26 parts;
Nano-sized iron oxide 26 parts;
Cerium oxide 13 parts;
The tremolite 13 parts;
Nanometer silver-ferrous oxide nucleocapsid structure 1 part;
Obsidian 1 part;
Green 1 part, magnesium nickel stone;
1 part, serpentine;
Medical stone 1 part;
1 part, chlorite;
Alumina sol 1 part;
Eucalyptus oil 1 part;
White fused alumina 1 part;
Organosilicon crylic acid latex 1 part;
Defoamer 1 part;
Described graphene oxide is obtained by following preparation method:
Get 2 weight part flaky graphites and 1 parts by weight of potassium nitrate is added in the 90 weight part vitriol oils, the mixture obtained is placed in a reservoir and cools in ice-water bath, keep violent stirring simultaneously, continue the potassium permanganate slowly adding 5 weight parts, obtain the suspension of brown; Add the hydrogen peroxide solution of the 2wt% of 5 weight parts subsequently again, obtain jonquilleous suspension; Then wash suspension respectively with deionized water and ethanol, subsequently graphene oxide is dispersed in the extracting solution of aloe, at 82 DEG C, be uniformly mixed 3h, obtain the graphene oxide that extract solution from aloe is modified.
Described defoamer is polydimethylsiloxane.
Prepare a method for the iron oxide based far infrared heating coating of above-mentioned Graphene, comprise the steps:
(1) prepare burden according to the iron oxide based far infrared heating coating material composition of Graphene; By raw material mixing wet ball-milling 12 hours, solvent was distilled water, and abrading-ball is ferric oxide abrading-ball, dries, obtain standby material after ball milling at 44 DEG C;
(2) by substrate pre-treatment according to demand; Be applied in pretreated substrate by standby material plasma spray subsequently, can obtain the iron oxide based far infrared heating coating of Graphene, the thickness of coating is 15mm.The far infrared transmissivity of this coating is 99.5%.
Embodiment 3:
The iron oxide based far infrared heating coating of a kind of Graphene, this coating comprises the raw material of following weight part:
Graphene oxide 26 parts;
Nano-sized iron oxide 26 parts;
Cerium oxide 13 parts;
The tremolite 13 parts;
Nanometer silver-ferrous oxide nucleocapsid structure 2 parts;
Obsidian 2 parts;
Green 2 parts, magnesium nickel stone;
2 parts, serpentine;
Medical stone 2 parts;
2 parts, chlorite;
Alumina sol 2 parts;
Eucalyptus oil 2 parts;
White fused alumina 2 parts;
Organosilicon crylic acid latex 2 parts;
Defoamer 2 parts;
Described graphene oxide is obtained by following preparation method:
Get 2 weight part flaky graphites and 1 parts by weight of potassium nitrate is added in the 90 weight part vitriol oils, the mixture obtained is placed in a reservoir and cools in ice-water bath, keep violent stirring simultaneously, continue the potassium permanganate slowly adding 5 weight parts, obtain the suspension of brown; Add the hydrogen peroxide solution of the 2wt% of 5 weight parts subsequently again, obtain jonquilleous suspension; Then wash suspension respectively with deionized water and ethanol, subsequently graphene oxide is dispersed in the extracting solution of aloe, at 82 DEG C, be uniformly mixed 3h, obtain the graphene oxide that extract solution from aloe is modified.
Described defoamer is polydimethylsiloxane.
Prepare a method for the iron oxide based far infrared heating coating of above-mentioned Graphene, comprise the steps:
(1) prepare burden according to the iron oxide based far infrared heating coating material composition of Graphene; By raw material mixing wet ball-milling 12 hours, solvent was distilled water, and abrading-ball is ferric oxide abrading-ball, dries, obtain standby material after ball milling at 44 DEG C;
(2) by substrate pre-treatment according to demand; Be applied in pretreated substrate by standby material plasma spray subsequently, can obtain the iron oxide based far infrared heating coating of Graphene, the thickness of coating is 12mm.The far infrared transmissivity of this coating is 99.6%.
Embodiment 4:
The iron oxide based far infrared heating coating of a kind of Graphene, this coating comprises the raw material of following weight part:
Graphene oxide 36 parts;
Nano-sized iron oxide 36 parts;
Cerium oxide 10 parts;
The tremolite 10 parts;
Nanometer silver-ferrous oxide nucleocapsid structure 3 parts;
Obsidian 2 parts;
Green 2 parts, magnesium nickel stone;
3 parts, serpentine;
Medical stone 2 parts;
2 parts, chlorite;
Alumina sol 2 parts;
Eucalyptus oil 2 parts;
White fused alumina 3 parts;
Organosilicon crylic acid latex 2 parts;
Defoamer 3 parts;
Described graphene oxide is obtained by following preparation method:
Get 2 weight part flaky graphites and 1 parts by weight of potassium nitrate is added in the 90 weight part vitriol oils, the mixture obtained is placed in a reservoir and cools in ice-water bath, keep violent stirring simultaneously, continue the potassium permanganate slowly adding 5 weight parts, obtain the suspension of brown; Add the hydrogen peroxide solution of the 2wt% of 5 weight parts subsequently again, obtain jonquilleous suspension; Then wash suspension respectively with deionized water and ethanol, subsequently graphene oxide is dispersed in the extracting solution of aloe, at 82 DEG C, be uniformly mixed 3h, obtain the graphene oxide that extract solution from aloe is modified.
Described defoamer is polydimethylsiloxane.
Prepare a method for the iron oxide based far infrared heating coating of above-mentioned Graphene, comprise the steps:
(1) prepare burden according to the iron oxide based far infrared heating coating material composition of Graphene; By raw material mixing wet ball-milling 12 hours, solvent was distilled water, and abrading-ball is ferric oxide abrading-ball, dries, obtain standby material after ball milling at 44 DEG C;
(2) by substrate pre-treatment according to demand; Be applied in pretreated substrate by standby material plasma spray subsequently, can obtain the iron oxide based far infrared heating coating of Graphene, the thickness of coating is 16mm.The far infrared transmissivity of this coating is 99.6%.
To those skilled in the art, obviously the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit of the present invention or essential characteristic, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.
In addition, be to be understood that, although this specification sheets is described according to embodiment, but not each embodiment only comprises an independently technical scheme, this narrating mode of specification sheets is only for clarity sake, those skilled in the art should by specification sheets integrally, and the technical scheme in each embodiment also through appropriately combined, can form other embodiments that it will be appreciated by those skilled in the art that.
Claims (4)
1. the iron oxide based far infrared heating coating of Graphene, is characterized in that: this coating comprises the raw material of following weight part:
Graphene oxide 26-36 part;
Nano-sized iron oxide 26-36 part;
Cerium oxide 10-13 part;
Tremolite 10-13 part;
Nanometer silver-ferrous oxide nucleocapsid structure 1-6 part;
Obsidian 1-6 part;
Green magnesium nickel stone 1-6 part;
Serpentine 1-6 part;
Medical stone 1-6 part;
Chlorite 1-6 part;
Alumina sol 1-6 part;
Eucalyptus oil 1-6 part;
White fused alumina 1-6 part;
Organosilicon crylic acid latex 1-6 part;
Defoamer 1-6 part;
Described graphene oxide is obtained by following preparation method:
Get 2 weight part flaky graphites and 1 parts by weight of potassium nitrate is added in the 90 weight part vitriol oils, the mixture obtained is placed in a reservoir and cools in ice-water bath, keep violent stirring simultaneously, continue the potassium permanganate slowly adding 5 weight parts, obtain the suspension of brown; Add the hydrogen peroxide solution of the 2wt% of 5 weight parts subsequently again, obtain jonquilleous suspension; Then wash suspension respectively with deionized water and ethanol, subsequently graphene oxide is dispersed in the extracting solution of aloe, at 82 DEG C, be uniformly mixed 3h, obtain the graphene oxide that extract solution from aloe is modified.
2. the iron oxide based far infrared heating coating of Graphene as claimed in claim 2, is characterized in that:
This coating comprises the raw material of following weight part:
Graphene oxide 26 parts;
Nano-sized iron oxide 26 parts;
Cerium oxide 12 parts;
The tremolite 12 parts;
Nanometer silver-ferrous oxide nucleocapsid structure 3 parts;
Obsidian 3 parts;
Green 3 parts, magnesium nickel stone;
3 parts, serpentine;
Medical stone 3 parts;
3 parts, chlorite;
Alumina sol 3 parts;
Eucalyptus oil 3 parts;
White fused alumina 3 parts;
Organosilicon crylic acid latex 3 parts;
Defoamer 3 parts.
3. the iron oxide based far infrared heating coating of Graphene as claimed in claim 1 or 2, is characterized in that: described defoamer is polydimethylsiloxane.
4. prepare a method for the iron oxide based far infrared heating coating of Graphene as claimed in claim 1, it is characterized in that: comprise the steps:
(1) prepare burden according to the iron oxide based far infrared heating coating material composition of Graphene; By raw material mixing wet ball-milling 12 hours, solvent was distilled water, and abrading-ball is ferric oxide abrading-ball, dries, obtain standby material after ball milling at 44 DEG C;
(2) by substrate pre-treatment according to demand; Be applied in pretreated substrate by standby material plasma spray subsequently, can obtain the iron oxide based far infrared heating coating of Graphene, the thickness of coating is 1-26mm.
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CN107780203A (en) * | 2017-11-14 | 2018-03-09 | 惠州市丰圣实业有限公司 | A kind of fabric for discharging anion, far infrared and biological magnetic energy composite energy |
CN107901515A (en) * | 2017-11-14 | 2018-04-13 | 惠州市丰圣实业有限公司 | A kind of releasing far infrared fabric |
CN108882412A (en) * | 2018-08-06 | 2018-11-23 | 山东贝子坊电子商务有限公司 | A kind of interior warm quilt of graphene anion fever |
CN111662579A (en) * | 2020-05-22 | 2020-09-15 | 广东日禾电器有限公司 | Heating coating material for ceramic substrate and preparation method thereof |
CN111892830A (en) * | 2020-08-28 | 2020-11-06 | 湖州思源颜料有限公司 | Preparation method of iron oxide black pigment with strong acid resistance |
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CN101333100A (en) * | 2008-08-05 | 2008-12-31 | 浙江大学 | Bamboo charcoal-based far infrared composite material and method for preparing same |
CN103432994A (en) * | 2013-09-09 | 2013-12-11 | 中国科学院新疆理化技术研究所 | Preparation method of magnetic graphene based oil absorption foam material |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107780203A (en) * | 2017-11-14 | 2018-03-09 | 惠州市丰圣实业有限公司 | A kind of fabric for discharging anion, far infrared and biological magnetic energy composite energy |
CN107901515A (en) * | 2017-11-14 | 2018-04-13 | 惠州市丰圣实业有限公司 | A kind of releasing far infrared fabric |
CN108882412A (en) * | 2018-08-06 | 2018-11-23 | 山东贝子坊电子商务有限公司 | A kind of interior warm quilt of graphene anion fever |
CN108882412B (en) * | 2018-08-06 | 2021-04-09 | 山东贝子坊电子商务有限公司 | Graphene negative ion heating internal heating quilt |
CN111662579A (en) * | 2020-05-22 | 2020-09-15 | 广东日禾电器有限公司 | Heating coating material for ceramic substrate and preparation method thereof |
CN111892830A (en) * | 2020-08-28 | 2020-11-06 | 湖州思源颜料有限公司 | Preparation method of iron oxide black pigment with strong acid resistance |
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