CN105524408A - Electromagnetic shielding PEEK composite material and preparation method thereof - Google Patents
Electromagnetic shielding PEEK composite material and preparation method thereof Download PDFInfo
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- CN105524408A CN105524408A CN201510737506.5A CN201510737506A CN105524408A CN 105524408 A CN105524408 A CN 105524408A CN 201510737506 A CN201510737506 A CN 201510737506A CN 105524408 A CN105524408 A CN 105524408A
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Abstract
The invention discloses an electromagnetic shielding PEEK composite material. The composite material is prepared from 67 to 79 parts of PEEK, 8 to 12 parts of copper powder, 5 to 8 parts of nanometer digadolinium trioxide, 5 to 8 parts of nanometer zinc oxide and 3 to 5 parts of low-sulfonation PEEK, wherein the copper powder, nanometer digadolinium trioxide and nanometer zinc oxide have undergone surface treatment by high-sulfonation PEEK, the sulfonation degree of high-sulfonation PEEK is 70 to 80, and the sulfonation degree of low-sulfonation PEEK is 40 to 50. The invention also discloses a preparation method for the electromagnetic shielding PEEK composite material. According to the invention, the nanometer digadolinium trioxide, nanometer zinc oxide and copper powder are added into PEEK, so the electromagnetic protection performance of a PEEK material can be effectively improved, wear resistance of the PEEK material is enhanced, and the PEEK material can be used in an occasion needing electromagnetic shielding; the inorganic materials are treated with high-sulfonation PEEK at first, so surface activity of the inorganic materials is improved, dispersion of the inorganic materials in a PEEK matrix is facilitated, and agglomeration is reduced; and due to addition of low-sulfonation PEEK into a composite system, tighter bonding between inorganic substances and PEEK in the system is realized, falling of the inorganic materials in the process of friction is prevented and wear resistance and strength of the material are improved.
Description
Technical field
The present invention relates to electromagnetic shielding PEEK matrix material and preparation method thereof, belong to field of compound material.
Background technology
Polyether-ether-ketone (PEEK) is the linear aromatic race macromolecular compound containing chain link in molecular backbone chain, is a kind of high temperature resistant, high performance thermoplastic special engineering plastic.PEEK has the performance such as good mechanical property and chemicals-resistant, wear-resistant, hydrolysis; Light specific gravity, self-lubricating property is good, there is extraordinary processing characteristics, the high-tech industrial circles such as aviation, machinery, electronics, chemical industry, automobile can be applied to, especially the component of machine of the speed of being used in up to the high request on the High Speed Railway Trains of 350KM/h can be manufactured, as gear, bearing, piston ring, support ring, wear ring (letter), valve block, wear-resisting ring etc., there is the trend replacing traditional metal materials.Pure PEEK is electrical insulator, and hertzian wave can be straightway by PEEK material, when therefore PEEK material uses in the electrical apparatus, needs its modification, to make it have good electromagnetic shielding protection effect.
Summary of the invention
The object of this invention is to provide a kind of electromagnetic shielding PEEK matrix material, there is outstanding mechanical property and higher effectiveness.
For achieving the above object, the technical solution used in the present invention is: a kind of electromagnetic shielding PEEK matrix material, by 67-79 part PEEK, 8-12 part copper powder, 5-8 part nanometer Gadolinium trioxide, 5-8 part nano zine oxide, the low sulfonated PEEK of 3-5 part make, wherein said copper powder, nano oxidized gadolinium, nano zine oxide are all through too high sulfonation PEEK surface treatment, and the sulfonation degree of high sulfonation PEEK is 70-80, and the sulfonation degree of low sulfonated PEEK is 40-50.
Preferably, described nanometer Gadolinium trioxide particle diameter is 100nm.
Preferably, described Particle Size of Nanometer ZnO is 50nm.
Preferably, described copper powder size is 0.1-10um.
Present invention also offers the preparation method of above-mentioned electromagnetic shielding PEEK matrix material, its step comprises:
A, nanometer Gadolinium trioxide, nano zine oxide, copper powder carry out drying respectively, by soluble in water for the sulfonation PEEK of approrpiate wts, add nanometer Gadolinium trioxide, nano zine oxide, copper powder, ultrasonic agitation post-heating reacts, and temperature of reaction is 80 DEG C, reaction times 12h, then 50 DEG C of standing 36h, then suction filtration, dry, pulverizing, wherein the mass ratio of sulfonation PEEK and nanometer Gadolinium trioxide+nano zine oxide+copper powder is 1:50;
The powder that B, PEEK, low sulfonated PEEK and steps A obtain adds in high-speed mixer, fully stirs to make all material mix;
C, mixed material put into the hot pressing die die cavity of 395-400 DEG C, after melting, at 20Mpa forming under the pressure, cooling and demolding;
Material after D, the demoulding is at 250 DEG C of insulation 60min, and whole insulating process pressure is 4Mpa, obtains finished product.
The present invention adds nanometer Gadolinium trioxide, nano zine oxide, copper powder in PEEK, effectively can improve the electromagnetic protection performance of PEEK material, and improve its wear resistance, can use needing the occasion of electromagnetic shielding.Nanometer Gadolinium trioxide and nano zine oxide and copper powder have synergistic effect, and obtained material also has ray shield effect.Nanometer Gadolinium trioxide, nano zine oxide, copper powder are first with the PEEK process of high sulfonation, its surfactivity can be improved, contribute to its dispersion in PEEK matrix, reduce and reunite, in compound system, add low sulfonated PEEK contribute to inorganics and PEEK in system and more combine closely, stop the disengaging of inorganic materials in friction process, to raising material wear ability and intensity helpful.
Embodiment
Embodiment 1
The preparation method of this electromagnetic shielding PEEK matrix material, its step comprises:
A, nanometer Gadolinium trioxide, nano zine oxide, copper powder carry out drying respectively, by soluble in water for the sulfonation PEEK of approrpiate wts, add 5 parts of nanometer Gadolinium trioxides, 5 parts of nano zine oxides, 8 parts of copper powders, ultrasonic agitation post-heating reacts, and temperature of reaction is 80 DEG C, reaction times 12h, then 50 DEG C of standing 36h, then suction filtration, dry, pulverizing, wherein the mass ratio of sulfonation PEEK and nanometer Gadolinium trioxide+nano zine oxide+copper powder is 1:50;
The obtained powder of B, 79 parts of PEEK, 3 parts of low sulfonated PEEK and steps A adds in high-speed mixer, fully stirs to make all material mix;
C, mixed material put into the hot pressing die die cavity of 395-400 DEG C, after melting, at 20Mpa forming under the pressure, cooling and demolding;
Material after D, the demoulding is at 250 DEG C of insulation 60min, and whole insulating process pressure is 4Mpa, obtains finished product.
Carry out performance test to obtained electromagnetic shielding PEEK matrix material, test result is in table 1.
Embodiment 2
The preparation method of this electromagnetic shielding PEEK matrix material, its step comprises:
A, nanometer Gadolinium trioxide, nano zine oxide, copper powder carry out drying respectively, by soluble in water for the sulfonation PEEK of approrpiate wts, add 8 parts of nanometer Gadolinium trioxides, 8 parts of nano zine oxides, 12 parts of copper powders, ultrasonic agitation post-heating reacts, and temperature of reaction is 80 DEG C, reaction times 12h, then 50 DEG C of standing 36h, then suction filtration, dry, pulverizing, wherein the mass ratio of sulfonation PEEK and nanometer Gadolinium trioxide+nano zine oxide+copper powder is 1:50;
The obtained powder of B, 67 parts of PEEK, 5 parts of low sulfonated PEEK and steps A adds in high-speed mixer, fully stirs to make all material mix;
C, mixed material put into the hot pressing die die cavity of 395-400 DEG C, after melting, at 20Mpa forming under the pressure, cooling and demolding;
Material after D, the demoulding is at 250 DEG C of insulation 60min, and whole insulating process pressure is 4Mpa, obtains finished product.
Carry out performance test to obtained electromagnetic shielding PEEK matrix material, test result is in table 1.
Embodiment 3
The preparation method of this electromagnetic shielding PEEK matrix material, its step comprises:
A, nanometer Gadolinium trioxide, nano zine oxide, copper powder carry out drying respectively, by soluble in water for the sulfonation PEEK of approrpiate wts, add 6 parts of nanometer Gadolinium trioxides, 7 parts of nano zine oxides, 10 parts of copper powders, ultrasonic agitation post-heating reacts, and temperature of reaction is 80 DEG C, reaction times 12h, then 50 DEG C of standing 36h, then suction filtration, dry, pulverizing, wherein the mass ratio of sulfonation PEEK and nanometer Gadolinium trioxide+nano zine oxide+copper powder is 1:50;
The obtained powder of B, 73 parts of PEEK, 4 parts of low sulfonated PEEK and steps A adds in high-speed mixer, fully stirs to make all material mix;
C, mixed material put into the hot pressing die die cavity of 395-400 DEG C, after melting, at 20Mpa forming under the pressure, cooling and demolding;
Material after D, the demoulding is at 250 DEG C of insulation 60min, and whole insulating process pressure is 4Mpa, obtains finished product.
Carry out performance test to obtained electromagnetic shielding PEEK matrix material, test result is in table 1.
Remarks: friction-wear test condition: initial load 196N, rotating speed 200r/min, metal to-metal contact 2h.To emery wheel: 45 steel, 42-45HRC.
Claims (5)
1. an electromagnetic shielding PEEK matrix material, it is characterized in that: by 67-79 part PEEK, 8-12 part copper powder, 5-8 part nanometer Gadolinium trioxide, 5-8 part nano zine oxide, the low sulfonated PEEK of 3-5 part make, wherein said copper powder, nano oxidized gadolinium, nano zine oxide are all through too high sulfonation PEEK surface treatment, the sulfonation degree of high sulfonation PEEK is 70-80, and the sulfonation degree of low sulfonated PEEK is 40-50.
2. electromagnetic shielding PEEK matrix material according to claim 1, is characterized in that: described nanometer Gadolinium trioxide particle diameter is 100nm.
3. electromagnetic shielding PEEK matrix material according to claim 2, is characterized in that: described Particle Size of Nanometer ZnO is 50nm.
4. electromagnetic shielding PEEK matrix material according to claim 3, is characterized in that: described copper powder size is 0.1-10um.
5. the preparation method of the electromagnetic shielding PEEK matrix material according to any one of a claim 1-4, its step comprises:
A, nanometer Gadolinium trioxide, nano zine oxide, copper powder carry out drying respectively, by soluble in water for the sulfonation PEEK of approrpiate wts, add nanometer Gadolinium trioxide, nano zine oxide, copper powder, ultrasonic agitation post-heating reacts, and temperature of reaction is 80 DEG C, reaction times 12h, then 50 DEG C of standing 36h, then suction filtration, dry, pulverizing, wherein the mass ratio of sulfonation PEEK and nanometer Gadolinium trioxide+nano zine oxide+copper powder is 1:50;
The powder that B, PEEK, low sulfonated PEEK and steps A obtain adds in high-speed mixer, fully stirs to make all material mix;
C, mixed material put into the hot pressing die die cavity of 395-400 DEG C, after melting, at 20Mpa forming under the pressure, cooling and demolding;
Material after D, the demoulding is at 250 DEG C of insulation 60min, and whole insulating process pressure is 4Mpa, obtains finished product.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106633627A (en) * | 2017-01-05 | 2017-05-10 | 吉林大学 | Polyether-ether-ketone/nanometer zinc oxide/carbon fiber wear-resistant composite material and preparation method thereof, and application of composite material to mechanical polishing of retaining rings |
| CN106883551A (en) * | 2017-03-24 | 2017-06-23 | 合肥羿振电力设备有限公司 | A kind of power equipment electromagnetic shielding material and preparation method thereof |
| CN108250670A (en) * | 2017-12-05 | 2018-07-06 | 宜宾天原集团股份有限公司 | A kind of multiphase composite strengthening polyether-ether-ketone wear-resistant material and preparation method thereof |
| CN109233198A (en) * | 2018-08-28 | 2019-01-18 | 合肥卓汇新材料科技有限公司 | A kind of preparation method of polyether-ether-ketone electromagnetic shielding composite material |
| CN109320905A (en) * | 2018-09-17 | 2019-02-12 | 张万里 | A kind of electromagnetic shielding material of power equipment and preparation method thereof |
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| CN102775726A (en) * | 2012-08-29 | 2012-11-14 | 吉林大学 | Polyether-ether-ketone composite material containing gadolinium oxide and preparation method of composite material |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106633627A (en) * | 2017-01-05 | 2017-05-10 | 吉林大学 | Polyether-ether-ketone/nanometer zinc oxide/carbon fiber wear-resistant composite material and preparation method thereof, and application of composite material to mechanical polishing of retaining rings |
| CN106883551A (en) * | 2017-03-24 | 2017-06-23 | 合肥羿振电力设备有限公司 | A kind of power equipment electromagnetic shielding material and preparation method thereof |
| CN108250670A (en) * | 2017-12-05 | 2018-07-06 | 宜宾天原集团股份有限公司 | A kind of multiphase composite strengthening polyether-ether-ketone wear-resistant material and preparation method thereof |
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| CN109320905A (en) * | 2018-09-17 | 2019-02-12 | 张万里 | A kind of electromagnetic shielding material of power equipment and preparation method thereof |
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Address after: 211162 Jiangsu, Jiangning District, Binjiang Development Zone, No., Copper Road, No. 18 Applicant after: Nanjing Kent composites Limited by Share Ltd Applicant after: Nanjing CompTECH New Material Co., Ltd. Applicant after: NANJING JIAFA MACHINERY CO., LTD. Applicant after: NANJING RUNTE NEW MATERIAL CO., LTD. Address before: 211162 Nanjing City, Jiangning Province town, the town of copper, Copper Road, No. 18 Applicant before: Nanjing Kente Composite Material Co., Ltd. Applicant before: Nanjing CompTECH New Material Co., Ltd. Applicant before: NANJING JIAFA MACHINERY CO., LTD. Applicant before: NANJING RUNTE NEW MATERIAL CO., LTD. |
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Effective date of registration: 20170713 Address after: 211162 Jiangsu, Jiangning District, Binjiang Development Zone, No., Copper Road, No. 18 Applicant after: Nanjing Kent composites Limited by Share Ltd Applicant after: Nanjing CompTECH New Material Co., Ltd. Applicant after: NANJING RUNTE NEW MATERIAL CO., LTD. Address before: 211162 Jiangsu, Jiangning District, Binjiang Development Zone, No., Copper Road, No. 18 Applicant before: Nanjing Kent composites Limited by Share Ltd Applicant before: Nanjing CompTECH New Material Co., Ltd. Applicant before: NANJING JIAFA MACHINERY CO., LTD. Applicant before: NANJING RUNTE NEW MATERIAL CO., LTD. |
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Application publication date: 20160427 |