CN105507103B - Light-duty high-strength water-permeable brick with photocatalysis effect - Google Patents
Light-duty high-strength water-permeable brick with photocatalysis effect Download PDFInfo
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- CN105507103B CN105507103B CN201610098216.5A CN201610098216A CN105507103B CN 105507103 B CN105507103 B CN 105507103B CN 201610098216 A CN201610098216 A CN 201610098216A CN 105507103 B CN105507103 B CN 105507103B
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- haydite
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- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C11/00—Details of pavings
- E01C11/22—Gutters; Kerbs ; Surface drainage of streets, roads or like traffic areas
- E01C11/224—Surface drainage of streets
- E01C11/225—Paving specially adapted for through-the-surfacing drainage, e.g. perforated, porous; Preformed paving elements comprising, or adapted to form, passageways for carrying off drainage
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/06—Aluminous cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
- C04B28/26—Silicates of the alkali metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
- C04B2111/00508—Cement paints
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00612—Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2038—Resistance against physical degradation
- C04B2111/2061—Materials containing photocatalysts, e.g. TiO2, for avoiding staining by air pollutants or the like
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C2201/00—Paving elements
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Abstract
The invention discloses a kind of light-duty high-strength water-permeable bricks with photocatalysis effect, including reverse osmosis permeable layers, pervious bed and the photocatalysis layer being sequentially distributed from bottom to top, the photocatalysis layer uses the cement-based material with photocatalysis performance to spray, the pervious bed uses the regeneration lightweight aggregate concrete doped with haydite to pour into a mould, and the reverse osmosis permeable layers are also poured into a mould using the regeneration lightweight aggregate concrete doped with haydite;It is divided into three-decker from top to bottom, it is photocatalysis layer, pervious bed and reverse osmosis permeable layers respectively, photocatalysis layer can be effectively treated motor-vehicle tail-gas, and three layers have certain porosity, pervious bed can effective draining, reverse osmosis permeable layers can effectively reduce influence of the tropical island effect to environment.
Description
Technical field
The present invention relates to building material technical field more particularly to a kind of light-duty high-strength with photocatalysis effect are permeable
Brick.
Background technology
With the development of China's construction industry and popularizing for automobile, a large amount of construction of the concrete road surface in city are right
In the city that drainage infrastructure is poor, urban waterlogging is easily caused in rainy season, is brought seriously to the life of city dweller
Influence.Tropical island effect is easily generated when summer temperature is high.Still further aspect, concrete or bituminous paving color list
Adjust, for drive or pedestrian be easy to generate visual fatigue.And being on the increase with motor vehicles such as automobiles, generation have
Evil tail gas is more and more, and motor-vehicle tail-gas is the main reason for causing city haze, and still, traditional concrete is for being harmful to gas
Body, helpless.
Although pervious concrete, pervious asphalt concrete and water-permeable brick on the market can discharge water at present,
Effect unobvious for the Tail Gas that automobile generates, can not be effectively treated, and cannot efficiently use building waste
Deng the material to environmental danger, while existing water-permeable brick density is big, transport trouble, and energy consumption is larger.
Invention content
The technical problems to be solved by the invention are to provide a kind of light-duty high-strength water-permeable brick with photocatalysis effect, from
It is divided into three-decker under above, is photocatalysis layer, pervious bed and reverse osmosis permeable layers respectively, motor-vehicle tail-gas can effectively be located
Reason, three layers have certain porosity, can effective draining, reduce the influence of the environment of tropical island effect.
In order to solve the above technical problems, the technical solution used in the present invention is:It is a kind of light-duty with photocatalysis effect
High-strength water-permeable brick, including reverse osmosis permeable layers, pervious bed and the photocatalysis layer being sequentially distributed from bottom to top, the photocatalysis layer is using tool
The cement-based material for having photocatalysis performance is poured into a mould, and the pervious bed and reverse osmosis permeable layers are using the regeneration lightweight aggregate doped with haydite
Concrete is poured into a mould.
Photocatalysis layer thickness is 0.5cm-0.8cm, porosity 20%-25%, catalysis material and face not soluble in water
Material is uniformly distributed, and catalysis material 4-6g/m2 is sprayed after catalysis material is mixed with high abrasion cement and sodium metasilicate
Fixed, the ratio of mud 0.28, water-reducing agent volume is the 0.7%-0.9% of cementitious material weight, catalysis material for bismuth oxychloride or
Person's rare earth mixing with nano titanium dioxide.
The permeable layer thickness is 3cm-7cm, porosity 30%-50%, adds water including the following material of parts by weight
It mixes, wherein:10-15 parts of High Strength Cement-Based Materials, wherein 4-6 parts of the building waste based on brickbat, grain size are 5-
10mm's accounts for 2-3 parts, and grain size accounts for 3-4.5 parts for 10-15mm's, further includes 3-5 parts of haydite, the High Strength Cement-Based Materials are served as reasons
The material of following parts by weight mixes, wherein Portland cement 60-80 parts, 14-16 parts of silicon ash, 2-3 parts of water-reducing agent,
10-12 parts of 2-3 parts of sulphate aluminium cement and fiber.
The reverse osmosis layer thickness is 1cm-2cm, porosity 15%-20%, is added including the following material of parts by weight
Water mixes, wherein:2-3 parts of High Strength Cement-Based Materials, the building waste based on brickbat that grain size is 5-10mm is 2-4
Part, haydite is 3-5 parts, and the High Strength Cement-Based Materials is are mixed by the material of following parts by weight, wherein common silicic acid
10-12 parts of 60-80 parts of salt cement, 14-16 parts of silicon ash, 2-3 parts of water-reducing agent, 2-3 parts of sulphate aluminium cement and fiber.
The haydite is lytag or coal gangue haydite, and the grain size of haydite is 3mm-7mm.
It is using advantageous effect caused by above-mentioned technical proposal:It is divided into three-decker from top to bottom, is light respectively
Catalytic Layer, pervious bed and reverse osmosis permeable layers, photocatalysis layer have good photocatalysis effect, motor-vehicle tail-gas can be carried out effective
Processing, pervious bed have larger porosity, facilitate draining, difference is respectively adopted in three-decker using lightweight aggregate concrete is regenerated
Porosity, when water is big, can effective draining, in temperature height, when more arid, water-permeable brick can be discharged and held in itself
The water received, adjusting air humidity reduce influence of the tropical island effect to environment, still further aspect, pervious bed in the present invention and anti-
Permeable formation is using regeneration lightweight aggregate concrete, while effectively building waste is reused, moreover it is possible to a certain extent
Mitigate water-permeable brick density itself, reduce dead weight, be readily transported.
Description of the drawings
Fig. 1 is the structure diagram of the present invention;
In the accompanying drawings:1st, photocatalysis layer;2nd, pervious bed;3rd, reverse osmosis permeable layers.
Specific embodiment
With reference to the attached drawing in the embodiment of the present invention, the technical solution in the embodiment of the present invention is carried out clear, complete
Ground describes, it is clear that described embodiment is only the part of the embodiment of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, those of ordinary skill in the art are obtained every other without making creative work
Embodiment shall fall within the protection scope of the present invention.
Many details are elaborated in the following description to facilitate a thorough understanding of the present invention, still the present invention can be with
Implemented using other different from other manner described here, those skilled in the art can be without prejudice to intension of the present invention
In the case of do similar popularization, therefore the present invention is not limited by following public specific embodiment.
As shown in Figure 1, the invention discloses a kind of light-duty high-strength water-permeable brick with photocatalysis effect, including from bottom to top
Reverse osmosis permeable layers 3, pervious bed 2 and the photocatalysis layer 1 being sequentially distributed, the photocatalysis layer 1 is using the cement with photocatalysis performance
Sill sprays, and the pervious bed 2 and reverse osmosis permeable layers 3 are poured into a mould using the regeneration lightweight aggregate concrete doped with haydite;It is described
3 bottom surface of reverse osmosis permeable layers be equipped with decorative pattern, 3 thickness of reverse osmosis permeable layers be 1-2cm, porosity 15%-20%, the thickness of the pervious bed 2
It spends for 3-7cm, porosity 30%-35%, the thickness of the photocatalysis layer 1 is 0.5-0.8cm, porosity 20%-25%;
The grain size of haydite adulterated in the pervious bed 2 is 3-7mm, and the grain size of the building waste based on brickbat is 5-10mm.
During concrete application, the photocatalysis layer thickness in the present invention is 0.5cm-0.8cm, porosity 20%-
25%, catalysis material is uniformly distributed with pigment not soluble in water in this layer, and it is about 4-6g/m2 that light, which urges material, by photocatalysis
The cement-based material with photocatalysis performance that material is formed after being mixed with high abrasion cement and sodium metasilicate carries out spraying fixation, water
Gray scale 0.28 or so, water-reducing agent volume are the 0.7%-0.9% of cementitious material quality, and the catalysis material that may be used includes chlorine
Bismuth oxide or rare earth mixing with nano titanium dioxide can also use other catalysis materials with visible light catalytic performance.
Permeable layer thickness be 3cm-7cm, porosity 30%-35%, predominantly lytag, building based on brickbat
Building refuse and high strength cement sill composition, the grain size of haydite are 3mm-7mm, the grain of the building waste particle based on brickbat
Diameter has two kinds of 5-10mm and 10-15mm, and two kinds are pressed 2:3 are mixed, and the component of High Strength Cement-Based Materials is normal silicate water
Mud 60-80 parts (parts by weight), silicon ash 14-16 parts (parts by weight), water-reducing agent 2-3 parts (parts by weight), sulphate aluminium cement
2-3 parts (parts by weight) and fiber 10-12 parts (parts by weight).
When High Strength Cement-Based Materials mix, first High Strength Cement-Based Materials are mixed, add in the mixing water of half, stirring 60
Second, the building waste particle based on brickbat mixed in proportion is added, is stirred 120 seconds, then remaining mixing water is added
Enter, stir 60 seconds, water-cement ratio is controlled 0.3 or so.
The High Strength Cement-Based Materials of pervious bed account for 10-15 parts (parts by weight), are left as aggregate.As aggregate with brickbat
Based on building waste particle there are two types of, wherein grain size is that 5-10mm being accounted for 2-3 part (parts by weight), and grain size is 10-15mm's
It accounts for 3-4.5 parts (parts by weight), haydite accounts for 3-5 parts (parts by weight).
The thickness of reverse osmosis permeable layers is 1cm-2cm, porosity 15%-20%, and certain decorative pattern is made in its bottom surface, with increase
Friction, the key component of reverse osmosis permeable layers is identical with pervious bed, and the High Strength Cement-Based Materials in reverse osmosis permeable layers account for 2-3 parts of (parts by weight
Number), it is left as aggregate, the grain size of the building waste particle based on brickbat is 5-10mm, the building waste based on brickbat
Grain accounts for 2-4 parts (parts by weight), haydite 3-5 parts (parts by weight), and haydite uses lytag, can also use other kinds
Haydite.
Water-permeable brick according to the present invention is divided into three layers, prepares reverse osmosis permeable layers first, when the cement-based material of reverse osmosis permeable layers
Slurry prepares pervious bed when reaching initial set, when the cement base slurry of pervious bed reaches initial set, prepares photocatalysis layer,
Fixed catalysis material is sprayed, the color and pattern that customization needs as needed.
In order to ensure the performance of the present invention, the present embodiment is tested for the property by preparing platy structure, specific mistake
Journey is as follows:
Due to test block be multilayered structure, using respectively weigh, stir respectively, the method that specific resistance to compression mould once pressurizes into
Type, briquetting pressure are 4MPa or so.
With covered rearing with plastic film mold and test specimen after molding, test specimen is demoulded after 12 hours, shady place disposed within,
With covered rearing with plastic film, watering is primary daily, implements nourishment.High-temperature steam curing can also be used.
Main performance test:
1. the test specimen in experiment uses two kinds of sizes, the test specimen of 200mm*100mm*60mm is strong for compression strength, anti-folding
Degree experiment measures.The test specimen of 100mm*100mm*100mm, for measuring the water permeability of permeable concrete and anti-freezing property,
Freeze method test using slow.
Flexural strength can reach 7MPa within 28 days.
Compression strength can reach 45MPa within 28 days.
28 days water permeabilities:Coefficient of permeability is 6.76cm/s.
By 35 Frozen-thawed cycleds, mass loss rate 0.5%, compression strength loss rate is less than 25%.
2. photocatalysis effect, using rare earth mixing with nano titanium dioxide.And it is prepared into the plate of 60mm × 100mm × 200mm
Type test specimen.After form removal, after conserving template test specimen 7d, the nano-titanium dioxide solution spraying prepared to template surface of test piece,
Solution titanium dioxide concentration is 9g/L.The volume of spray solution is 100mL.Then Photocatalytic Degradation of Methyl Orange experiment is carried out.
Photocatalysis performance is tested:Test specimen is first cut into 30mm × 50mm × 100mm small samples, using the fluorescent lamp of 20W
Catalysis light source is done, is survey absorbance at 443nm in wavelength using spectrophotometer using methyl orange as catalytic degradation object, and
According to standard curve conversion methyl orange solution concentration, so as to obtain the degradation rate of methyl orange, light-catalysed effect quality, warp are evaluated
40 hours are spent, methyl orange has been degraded.
In short, the present invention is divided into three-decker from top to bottom, it is that photocatalysis layer, pervious bed and reverse osmosis permeable layers, light are urged respectively
Changing layer has good photocatalysis effect, and motor-vehicle tail-gas can be effectively treated, and pervious bed utilization regenerates lightweight aggregate and mixes
Solidifying soil, has larger porosity, facilitates draining, different porositys is respectively adopted in three-decker, can be effective when water is big
Draining in temperature height, when more arid, can discharge the water that water-permeable brick accommodates in itself, adjusting air humidity reduces heat island
Imitate response environment influence, still further aspect, the present invention in pervious bed and reverse osmosis permeable layers using regeneration lightweight aggregate concrete,
While effectively building waste is reused, moreover it is possible to mitigate water-permeable brick density itself to a certain extent, reduce dead weight, just
In transport.
Claims (2)
1. a kind of light-duty high-strength water-permeable brick with photocatalysis effect, it is characterised in that:It is anti-including what is be sequentially distributed from bottom to top
Permeable formation (3), pervious bed (2) and photocatalysis layer (1), the photocatalysis layer (1) is using the cement matrix with photocatalysis performance
Material cast, the pervious bed (2) and reverse osmosis permeable layers (3) are poured into a mould using the regeneration lightweight aggregate concrete doped with haydite;Light is urged
Change layer (1) thickness is 0.5cm-0.8cm, porosity 20%-25%, and catalysis material uniformly divides with pigment not soluble in water
Cloth, catalysis material 4-6g/m2 carry out spraying fixation, water after catalysis material is mixed with high abrasion cement and sodium metasilicate
Gray scale 0.28, water-reducing agent volume are the 0.7%-0.9% of cementitious material weight, and catalysis material is mixed for bismuth oxychloride or rare earth
Miscellaneous nano-titanium dioxide;Pervious bed (2) thickness is 3cm-7cm, porosity 30%-50%, as follows including parts by weight
Material water is added to mix, wherein:10-15 parts of High Strength Cement-Based Materials, 4-6 parts of the building waste based on brickbat, wherein
Grain size accounts for 2-3 parts for 5-10mm's, and grain size accounts for 3-4.5 parts for 10-15mm's, further includes 3-5 parts of haydite, the high-strength cement base
Material is is mixed by the material of following parts by weight, wherein Portland cement 60-80 parts, 14-16 parts of silicon ash, diminishing
10-12 parts of 2-3 parts of agent, 2-3 parts of sulphate aluminium cement and fiber;Reverse osmosis permeable layers (3) thickness is 1cm-2cm, and porosity is
15%-20% adds water to mix including the following material of parts by weight, wherein:2-3 parts of High Strength Cement-Based Materials, grain size are
For the building waste based on brickbat of 5-10mm as 2-4 parts, haydite is 3-5 parts, and the High Strength Cement-Based Materials are by weighing as follows
The material of amount number mixes, wherein Portland cement 60-80 parts, 14-16 parts of silicon ash, 2-3 parts of water-reducing agent, sulphur aluminic acid
10-12 parts of 2-3 parts of salt cement and fiber, the bottom surface of the reverse osmosis permeable layers are equipped with the decorative pattern for increasing friction.
2. the light-duty high-strength water-permeable brick according to claim 1 with photocatalysis effect, it is characterised in that:The haydite is
Lytag or coal gangue haydite, the grain size of haydite is 3mm-7mm.
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CN105507103B true CN105507103B (en) | 2018-06-15 |
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CN106007499B (en) * | 2016-05-17 | 2018-04-13 | 广州世正环保科技发展有限公司 | A kind of water-retaining lightweight grass-planting brick and preparation method thereof |
CN106220085B (en) * | 2016-07-12 | 2018-02-13 | 绍兴职业技术学院 | A kind of high intensity high water-permeability pavior brick and preparation method thereof |
CN106938199A (en) * | 2017-02-27 | 2017-07-11 | 河海大学 | A kind of visible light-responded photocatalysis porous brick |
CN107352971A (en) * | 2017-03-02 | 2017-11-17 | 潘映昆 | A kind of method and water-permeable brick for making water-permeable brick |
CN107226662B (en) * | 2017-06-02 | 2020-05-01 | 中国一冶集团有限公司 | Large-doping blast furnace heavy slag composite sand-based water permeable brick and efficient preparation method thereof |
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CN108191331B (en) * | 2017-12-22 | 2020-11-24 | 天津市建筑科学研究院有限公司 | Hollow kerb capable of cleaning and permeating water and bearing runoff |
CN108505498B (en) * | 2018-04-04 | 2019-12-13 | 河海大学 | photocatalytic and biological purification integrated ecological revetment block and preparation method thereof |
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CN110681215B (en) * | 2019-10-17 | 2021-10-15 | 河海大学 | Photocatalytic composite filter disc with water quality purification function and preparation method thereof |
CN111518441B (en) * | 2020-05-21 | 2022-04-01 | 中冶南方城市建设工程技术有限公司 | Visible light catalysis water permeable brick and manufacturing method and application thereof |
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