CN105507047A - Resin consolidated abrasive diamond wire and production process thereof - Google Patents

Resin consolidated abrasive diamond wire and production process thereof Download PDF

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Publication number
CN105507047A
CN105507047A CN201610013725.3A CN201610013725A CN105507047A CN 105507047 A CN105507047 A CN 105507047A CN 201610013725 A CN201610013725 A CN 201610013725A CN 105507047 A CN105507047 A CN 105507047A
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CN
China
Prior art keywords
resin
wire
rope
diamond
diamond wire
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610013725.3A
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Chinese (zh)
Inventor
张年春
徐斌
盛荣生
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Sheng Li (china) New Material Technology Co Ltd
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Sheng Li (china) New Material Technology Co Ltd
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Application filed by Sheng Li (china) New Material Technology Co Ltd filed Critical Sheng Li (china) New Material Technology Co Ltd
Priority to CN201610013725.3A priority Critical patent/CN105507047A/en
Publication of CN105507047A publication Critical patent/CN105507047A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B1/00Constructional features of ropes or cables
    • D07B1/06Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core
    • D07B1/0693Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core having a strand configuration
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B5/00Making ropes or cables from special materials or of particular form
    • D07B5/005Making ropes or cables from special materials or of particular form characterised by their outer shape or surface properties
    • D07B5/006Making ropes or cables from special materials or of particular form characterised by their outer shape or surface properties by the properties of an outer surface polymeric coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28DWORKING STONE OR STONE-LIKE MATERIALS
    • B28D5/00Fine working of gems, jewels, crystals, e.g. of semiconductor material; apparatus or devices therefor
    • B28D5/04Fine working of gems, jewels, crystals, e.g. of semiconductor material; apparatus or devices therefor by tools other than rotary type, e.g. reciprocating tools
    • B28D5/045Fine working of gems, jewels, crystals, e.g. of semiconductor material; apparatus or devices therefor by tools other than rotary type, e.g. reciprocating tools by cutting with wires or closed-loop blades
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2201/00Ropes or cables
    • D07B2201/20Rope or cable components
    • D07B2201/2015Strands
    • D07B2201/2038Strands characterised by the number of wires or filaments
    • D07B2201/2039Strands characterised by the number of wires or filaments three to eight wires or filaments respectively forming a single layer
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2201/00Ropes or cables
    • D07B2201/20Rope or cable components
    • D07B2201/2015Strands
    • D07B2201/2042Strands characterised by a coating
    • D07B2201/2043Strands characterised by a coating comprising metals
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2205/00Rope or cable materials
    • D07B2205/20Organic high polymers
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2205/00Rope or cable materials
    • D07B2205/20Organic high polymers
    • D07B2205/2057Phenol resins
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2205/00Rope or cable materials
    • D07B2205/20Organic high polymers
    • D07B2205/206Epoxy resins
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2205/00Rope or cable materials
    • D07B2205/30Inorganic materials
    • DTEXTILES; PAPER
    • D07ROPES; CABLES OTHER THAN ELECTRIC
    • D07BROPES OR CABLES IN GENERAL
    • D07B2205/00Rope or cable materials
    • D07B2205/30Inorganic materials
    • D07B2205/3021Metals
    • D07B2205/3085Alloys, i.e. non ferrous
    • D07B2205/3089Brass, i.e. copper (Cu) and zinc (Zn) alloys

Abstract

The invention relates to the technical field of diamond wires, in particular to a resin consolidated abrasive diamond wire. The resin consolidated abrasive diamond wire comprises a core wire formed by twisting a plurality of steel wire strands, a brass bottom plated layer is plated on the outer side of the core wire, a consolidated resin layer is cured at the outer side of the brass bottom plated layer, and diamond micro-powder granules are distributed in the consolidated resin layer. The invention also discloses a resin consolidated abrasive diamond wire production process. The production process comprises the following steps: manufacture of the core wire; surface pretreatment; plating of the core wire bottom plated layer; resin paste coating; and resin diamond wire curing. Compared with an electroplated diamond wire, the resin diamond wire produced by the process has the advantages that corrosion caused by a solution accumulated in the space of a wire core part can be avoided due to no contact with a water-phase electrolyte solution during production of the resin combined diamond wire. Compared with a metal combination layer of the electroplated wire, the resin layer is low in rigidity, so that the thickness of an effected layer of a cut surface of a processed workpiece is lower than that of the electroplated wire, and the stress of a section is small. Resin coating and curing can be finished in two stages, thereby realizing high-speed production and reducing production cost greatly.

Description

A kind of resin bonded abrasive material diamond rope and production technology thereof
Technical field
The present invention relates to diamond rope technical field, particularly a kind of resin bonded abrasive material diamond rope and production technology thereof.
Background technology
After current diamond rope is twisted into rope primarily of circular section steel wire, the upper diadust of plating is made, compared with the diamond wire by circular section steel wire Direct Electroplating diadust, have many good qualities, when such as cutting (sapphire, crystal silicon), because the helical form of surperficial self-assembling formation of restricting caves in, be conducive to holding bits chip removal, improve cutting efficiency.The rope be twisted into by circular section steel wire, space is there is between steel wire and steel wire, soda acid or plating solution can be closed in electroplating process, core steel wire is caused to corrode gradually, if can not dispose, the rupture pull force of plating diamond rope can be reduced, in this external diamond rope use procedure, by alternating bending in high-tension situation, because the corrosion hole of inner surface or spot can reduce endurance life to affect cutting effect.
Summary of the invention
The technical issues that need to address of the present invention are to provide a kind of easy chip removal and the large resin bonded abrasive material diamond rope of rupture pull force and production technology thereof.
For solving above-mentioned technical problem, a kind of resin bonded abrasive material diamond rope of the present invention, comprise by the stranded core rope made of steel wire strand, brass prime coat is coated with outside described core rope, be solidified with uncured resin layer outside described brass prime coat, in described uncured resin layer, be distributed with diadust particle.
Further, the particle diameter of diadust particle is 5-50 μm.
Further, described core rope is made by the high tensile steel wire of 3 gangs of diameter 0.08mm-0.50mm is stranded.
The present invention also comprises a kind of resin bonded abrasive material diamond rope production technology, comprises the following steps,
Core rope makes: make core rope by multiply high tensile steel wire is stranded;
Surface preparation: by institute's coremaking rope through actinobacillus wheel unwrapping wire, successively through alkaline defatting agent solution, washing water, acid solution and washing water, then carry out drying and processing, obtains the core rope of surface cleaning;
Core rope prime coat plating: at core rope outer surface plating brass prime coat;
Resin slurry applies: the resin slurry being added with diadust particle is applied brass prime coat on the surface uniformly, obtains resin diamond wire;
Resin diamond rope is solidified: the resin diamond wire of above-mentioned gained is obtained sold resin diamond wire through being heating and curing.
Further, successively through 60 ± 5 DEG C of alkaline defatting agent solution, washing water, 10% sulfuric acid solution of 40 ± 5 DEG C and washing water in described step surface preparation, carry out drying and processing in 100 ± 5 DEG C, obtain the core rope of surface cleaning.
Further, be placed in mould by the resin slurry being added with particle diameter 5-50 μm bortz powder in described step resin slurry coating, be arranged on by core rope on line sending axle, core rope passes mould, with the continuous cabling of the speed of 0.5m/s-1.5m/s.
Further, described step resin diamond rope solidification is specifically further comprising the steps of,
Resin diamond wire initial solidification: by the resin diamond wire of above-mentioned gained through curing oven rapid primary solidification 20s at 550 DEG C-750 DEG C, obtain the resin diamond wire of semi-solid preparation;
Resin diamond wire slaking: above-mentioned gained semi-solid preparation resin diamond wire is placed on baking and curing in 150-400 DEG C of thermostatic drying chamber, finally obtains sold resin diamond wire.
Further, thermostatic drying chamber heating mode described in the slaking of described step resin diamond wire is intensification per hour 20 ± 5 DEG C, continuous warming 10 hours, and temperature retention time is 3 ± 0.5 hours, then Temperature fall to room temperature gets product resin diamond rope.
Further, adopt the mixed acid of 100-200g/l to carry out pickling in described step surface preparation, described mixed acid comprises sulfuric acid 30%, oxalic acid 10%, hydrochloric acid 15%, phosphatase 11 0%, and thiocarbamide 0.5%, BTA 0.5%, all the other are water.
Further, in the coating of described step resin slurry, resin slurry is that one or more in phenolic resins, epoxy resin, polyimide resin mix.
Adopt the resin diamond rope that above-mentioned technique is made, compared with plating diamond rope, aqueous phase electrolyte solution can not be contacted in the production process of resin-bonded diamond rope, avoid wire rope core portion space product corrosion.Relative to plating rope metal bonding layer, resin bed rigidity is low, institute process work piece cut surface damage layer thickness lower than plating line, cut into slices stress little.Resin-coating can complete in two stages with solidification, thus can realize high-speed production, thus significantly reduce production cost.
Accompanying drawing explanation
Below in conjunction with the drawings and specific embodiments, the present invention is further detailed explanation.
Fig. 1 is the structural representation of a kind of resin bonded abrasive material of the present invention diamond rope.
In figure: 1 is core rope, 2 is brass prime coat, and 3 is diadust particle, and 4 is the diadust particle wrapped up by resin, and 5 is uncured resin layer
Detailed description of the invention
As described in Figure 1, a kind of resin bonded abrasive material diamond rope of the present invention, comprise by 3 strands of stranded core ropes 1 made of steel wire, brass prime coat 2 is coated with outside described core rope 1, be solidified with uncured resin layer 5 outside described brass prime coat 2, be distributed with diadust particle 3 in described uncured resin layer 5 and form the diadust particle 4 wrapped up by resin.Compared with plating diamond rope, aqueous phase electrolyte solution can not be contacted in the production process of resin-bonded diamond rope, avoid wire rope core portion space product corrosion.Relative to plating rope metal bonding layer, resin bed rigidity is low, institute process work piece cut surface damage layer thickness lower than plating line, cut into slices stress little.Resin-coating can complete in two stages with solidification, thus can realize high-speed production, thus significantly reduce production cost.In addition, brass prime coat 2 further can prevent corrosion.
Resin bonded abrasive material diamond rope of the present invention is obtained by following production technology:
Embodiment one:
(1) core rope makes: make core rope by 3 strands of φ 0.08mm high tensile steel wires are stranded;
(2) surface preparation: by above-mentioned obtained core rope through actinobacillus wheel unwrapping wire, respectively through 60 ± 5 DEG C of alkaline defatting agent solution, washing water, 10% sulfuric acid solution of 40 ± 5 DEG C and washing water, carry out drying and processing in 110 ± 5 DEG C, obtain the core rope of surface cleaning;
(3) core rope plating prime coat: at core rope outer surface plating brass prime coat;
(4) resin slurry coating: the phenolic resins slurry being added with particle diameter 20 μm of bortz powders is coated on core rope on the surface uniformly, obtain resin diamond wire, the method wherein applying core rope is arranged on line sending axle by core rope, core rope passes mould, with the continuous cabling of the speed of 0.5m/s-1m/s;
(5) initial solidification of resin diamond rope: by the resin diamond rope of above-mentioned gained through curing oven rapid initial solidification 20s at 700 ± 50 DEG C, obtain the resin diamond wire of semi-solid preparation;
(6) slaking of resin diamond rope: above-mentioned gained semi-solid preparation resin diamond rope is placed on baking and curing in 150-400 DEG C of thermostatic drying chamber, finally obtain sold resin diamond rope, temperature drying device heating mode is: intensification per hour 20 ± 5 DEG C, continuous warming 10 hours, temperature retention time is 3 ± 0.5 hours, then Temperature fall to room temperature gets product resin diamond rope.
Embodiment two:
Difference from Example 1 is, described step (1) core rope makes SMIS rope for by 3 strands of φ 0.09mm steel wire stranded institute coremaking ropes.Step (2) surface preparation adopts the mixed acid of 100-200g/l to carry out pickling, and described mixed acid comprises sulfuric acid 30%, oxalic acid 10%, hydrochloric acid 15%, phosphatase 11 0%, and thiocarbamide 0.5%, BTA 0.5%, all the other are water.In the coating of step (4) resin slurry, diadust grain diameter is 30 μm, and step (5) (6) are with embodiment 1.
Embodiment three:
Be with embodiment 1 difference, described step (2) surface preparation adopts the mixed acid of 100-200g/l to carry out pickling, described mixed acid comprises sulfuric acid 30%, oxalic acid 10%, hydrochloric acid 15%, phosphatase 11 0%, and thiocarbamide 0.5%, BTA 0.5%, all the other are water.In the coating of step (4) resin slurry, Trace speed is 1.0m/s-1.5m/s, and resin used is phenolic resins and epoxy resin 4:1 mixing in mass ratio.In the initial solidification of step (5) resin diamond rope at temperature is 600 ± 50 DEG C rapid primary solidification 20s.In 8 hours, be warmed up to 200 DEG C in the slaking of step (6) resin diamond rope, grade per hour temperature rise, then be incubated 5 hours, be then naturally down to room temperature.
Certainly, resin slurry of the present invention also can adopt polyimide resin or itself and phenolic resins, epoxy resin to mix.
Although the foregoing describe the specific embodiment of the present invention; but those skilled in the art are to be understood that; these only illustrate; various changes or modifications can be made to present embodiment; and not deviating from principle of the present invention and essence, protection scope of the present invention is only defined by the appended claims.

Claims (10)

1. a resin bonded abrasive material diamond rope, it is characterized in that: comprise by the stranded core rope made of steel wire strand, be coated with brass prime coat outside described core rope, outside described brass prime coat, be solidified with uncured resin layer, in described uncured resin layer, be distributed with diadust particle.
2. according to a kind of resin bonded abrasive material diamond rope according to claim 1, it is characterized in that: the particle diameter of diadust particle is 5-50 μm.
3., according to a kind of resin bonded abrasive material diamond rope according to claim 1, it is characterized in that: described core rope is made by the high tensile steel wire of 3 gangs of diameter 0.08mm-0.50mm is stranded.
4. a resin bonded abrasive material diamond rope production technology, is characterized in that, comprise the following steps,
Core rope makes: make core rope by multiply high tensile steel wire is stranded;
Surface preparation: by institute's coremaking rope through actinobacillus wheel unwrapping wire, successively through alkaline defatting agent solution, washing water, acid solution and washing water, then carry out drying and processing, obtains the core rope of surface cleaning;
Core rope prime coat plating: at core rope outer surface plating brass prime coat;
Resin slurry applies: the resin slurry being added with diadust particle is applied brass prime coat on the surface uniformly, obtains resin diamond wire;
Resin diamond rope is solidified: the resin diamond wire of above-mentioned gained is obtained sold resin diamond wire through being heating and curing.
5. according to a kind of resin bonded abrasive material diamond rope production technology according to claim 4, it is characterized in that: successively through 60 ± 5 DEG C of alkaline defatting agent solution, washing water, 10% sulfuric acid solution of 40 ± 5 DEG C and washing water in described step surface preparation, carry out drying and processing in 100 ± 5 DEG C, obtain the core rope of surface cleaning.
6. according to a kind of resin bonded abrasive material diamond rope production technology according to claim 4, it is characterized in that: in described step resin slurry coating, the resin slurry being added with particle diameter 5-50 μm bortz powder is placed in mould, core rope is arranged on line sending axle, core rope passes mould, with the continuous cabling of the speed of 0.5m/s-1.5m/s.
7. according to a kind of resin bonded abrasive material diamond rope production technology according to claim 4, it is characterized in that, described step resin diamond rope solidification is specifically further comprising the steps of,
Resin diamond wire initial solidification: by the resin diamond wire of above-mentioned gained through curing oven rapid primary solidification 20s at 550 DEG C-750 DEG C, obtain the resin diamond wire of semi-solid preparation;
Resin diamond wire slaking: above-mentioned gained semi-solid preparation resin diamond wire is placed on baking and curing in 150-400 DEG C of thermostatic drying chamber, finally obtains sold resin diamond wire.
8. according to a kind of resin bonded abrasive material diamond rope production technology described in claim 7, it is characterized in that: thermostatic drying chamber heating mode described in the slaking of described step resin diamond wire is intensification per hour 20 ± 5 DEG C, continuous warming 10 hours, temperature retention time is 3 ± 0.5 hours, then Temperature fall to room temperature gets product resin diamond rope.
9. according to a kind of resin bonded abrasive material diamond rope production technology according to claim 4, it is characterized in that: in described step surface preparation, adopt the mixed acid of 100-200g/l to carry out pickling, described mixed acid comprises sulfuric acid 30%, oxalic acid 10%, hydrochloric acid 15%, phosphatase 11 0%, and thiocarbamide 0.5%, BTA 0.5%, all the other are water.
10. according to a kind of resin bonded abrasive material diamond rope production technology according to claim 4, it is characterized in that: in the coating of described step resin slurry, resin slurry is that one or more in phenolic resins, epoxy resin, polyimide resin mix.
CN201610013725.3A 2016-01-10 2016-01-10 Resin consolidated abrasive diamond wire and production process thereof Pending CN105507047A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107142759A (en) * 2017-05-20 2017-09-08 苏州霍姆特传感技术有限公司 A kind of elevator balanced compensated cable
CN107199522A (en) * 2017-06-27 2017-09-26 盛利维尔(中国)新材料技术股份有限公司 A kind of modified composition metal concretion abrasive diamond rope and its production technology
CN107234739A (en) * 2017-06-27 2017-10-10 盛利维尔(中国)新材料技术股份有限公司 A kind of antifriction resin diamond rope and its production method
CN107364022A (en) * 2017-06-27 2017-11-21 盛利维尔(中国)新材料技术股份有限公司 A kind of strong carrier fluid antifriction cutting steel wire and its production method
CN112589697A (en) * 2021-01-06 2021-04-02 李乔 Novel stranding device for composite metal consolidation abrasive diamond rope
CN113385612A (en) * 2021-05-06 2021-09-14 杨爱梅 Novel composite metal concreties abrasive material buddha's warrior attendant rope transposition equipment

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CN203125731U (en) * 2013-04-03 2013-08-14 盛利维尔(中国)新材料技术有限公司 Spiral diamond rope
CN103753721A (en) * 2014-01-21 2014-04-30 开封恒锐新金刚石制品有限公司 Method for producing resin diamond wire through metal powder doped with resin sizing agent
CN203636998U (en) * 2013-12-16 2014-06-11 盛利维尔(中国)新材料技术有限公司 Diamond cutting rope saw with steel wire stranded ropes and composite diamond abrasive materials
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CN104070614A (en) * 2013-03-26 2014-10-01 蒙特集团(香港)有限公司 Fixed abrasive wire saw and preparation method thereof
CN204054379U (en) * 2014-08-12 2014-12-31 盛利维尔(中国)新材料技术有限公司 A kind of with reservoir stranded form composite diamond steel wire
CN205818201U (en) * 2016-01-10 2016-12-21 盛利维尔(中国)新材料技术有限公司 A kind of resin bonded abrasive material diamond rope

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Publication number Priority date Publication date Assignee Title
JP2002036091A (en) * 2000-05-15 2002-02-05 Allied Material Corp Super-abrasive grain wire saw and manufacturing method
CN102658606A (en) * 2012-05-11 2012-09-12 香港雅诚国际有限公司 Manufacturing method of resin diamond wire
CN104070610A (en) * 2013-03-26 2014-10-01 蒙特集团(香港)有限公司 High-efficiency cutting wire saw with abrasive
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CN203125731U (en) * 2013-04-03 2013-08-14 盛利维尔(中国)新材料技术有限公司 Spiral diamond rope
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107142759A (en) * 2017-05-20 2017-09-08 苏州霍姆特传感技术有限公司 A kind of elevator balanced compensated cable
CN107199522A (en) * 2017-06-27 2017-09-26 盛利维尔(中国)新材料技术股份有限公司 A kind of modified composition metal concretion abrasive diamond rope and its production technology
CN107234739A (en) * 2017-06-27 2017-10-10 盛利维尔(中国)新材料技术股份有限公司 A kind of antifriction resin diamond rope and its production method
CN107364022A (en) * 2017-06-27 2017-11-21 盛利维尔(中国)新材料技术股份有限公司 A kind of strong carrier fluid antifriction cutting steel wire and its production method
CN112589697A (en) * 2021-01-06 2021-04-02 李乔 Novel stranding device for composite metal consolidation abrasive diamond rope
CN112589697B (en) * 2021-01-06 2021-07-09 李乔 Novel stranding device for composite metal consolidation abrasive diamond rope
CN113385612A (en) * 2021-05-06 2021-09-14 杨爱梅 Novel composite metal concreties abrasive material buddha's warrior attendant rope transposition equipment

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Address after: Jintan district two South Road 213200 Jiangsu city of Changzhou province No. 268

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Application publication date: 20160420