CN105507015A - Artificial leather for carbon nano tube reinforced adsorption type environment-friendly automotive upholstery and preparation method thereof - Google Patents
Artificial leather for carbon nano tube reinforced adsorption type environment-friendly automotive upholstery and preparation method thereof Download PDFInfo
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- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
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- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
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- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
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- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0004—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using ultra-fine two-component fibres, e.g. island/sea, or ultra-fine one component fibres (< 1 denier)
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- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0011—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
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- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0034—Polyamide fibres
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- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/26—Vehicles, transportation
- D06N2211/263—Cars
Abstract
The invention discloses artificial leather for carbon nano tube reinforced adsorption type environment-friendly automotive upholstery. The artificial leather is prepared from, by weight, 75-77 parts of polyamide-6, 25-26 parts of alkali-soluble polyester chips, an appropriate amount of a sodium hydroxide solution with the concentration of 20%, 50-53 parts of waterborne polyurethane, 5-6 parts of nano magnesium hydroxide, 3-4 parts of ammonium polyphosphate, 5-6 parts of sodium dodecyl benzene sulfonate, 3-4 parts of rutile titanium white color paste, an appropriate amount of water, 0.7-0.8 part of pregelatinized starch, 2-3 parts of liquid silica gel, 0.7-0.8 part of beta-cyclodextrin, 4-5 parts of carbon nano tubes, 4-5 parts of concentrated sulfuric acid, 0.8-1 part of cocoanut fatty acid diethanolamide and 1-1.2 parts of lignin. The artificial leather utilizes strong acid to conduct surface oxidation on the carbon nano tubes, can strengthen the interface combination effect and compatibility of the carbon nano tubes and polyurethane and improve the strength of a produced product, also has a good adsorption effect and can improve an automotive interior environment after being made into the automotive upholstery.
Description
Technical field
The present invention relates to synthetic leather field of material technology, particularly relate to a kind of CNT and strengthen absorbent-type environmentally friendly vehicle inside gadget artificial leather and preparation method thereof.
Background technology
Along with rapid development of economy, the living standard of people is more and more higher, also improves gradually the requirement of quality of life.The demand of leather and fur products is increasing, and class is also more and more higher.China's population multiple resource is few, corium limited source, is difficult to the demand meeting people.Nowadays interior leather for automobiles has been widely used in the inside gadget of riding vehicle, carrier.Along with growth in the living standard, people are also more and more higher to the quality requirement of interior leather for automobiles, environmental requirement, comfort requirement.Automotive trim is removed from office, and optimal selection is corium, but corium contaminated environment in himself production process is serious, and content of beary metal easily exceeds standard, and in inside gadget process, lumber recovery is lower, and its cost is high, is difficult to by low and middle-grade passenger car is accepted; And people pay attention to gradually to environmental protection, advocating today of environmental protection and energy saving, sustainable development, people also start to develop leather fabric to replace animal's leather, to avoid the injury to wild animal and the destruction to natural environment.
At present, the positions such as automobile door plate, face fabric for automobile seat, instrument board, compartment inwall, Roof of vehicle, steering wheel cover, the main material adopting non-weaving cloth etc. and the compound such as polyvinyl chloride, polyurethane.There is the defects such as Boardy Feeling, comfortableness are poor, loss of properties on aging, smell weight, the easy migration precipitation of plasticizer in common polyvinyl chloride dermatine, thus common PVC artificial leather at present in automotive trim gradually replace by polyurethane (PU) synthetic leather.And the production of Synthetic Leather adopts solvent type production system, the use of a large amount of organic solvent, not only contaminated environment, and the health seriously compromising people.Along with the reinforcement of environmental regulation and people's environmental consciousness, waterborne polyurethane synthetic leather technology becomes the study hotspot in this field.
Therefore, manufacture and a kind of with corium, there is same sense of touch, comfortable equally, and environmentally friendly, physical properties is identical with corium or exceed the research and development task that genuine imitation leather interior leather for automobiles becomes artificial leather production field.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, provides a kind of CNT to strengthen absorbent-type environmentally friendly vehicle inside gadget artificial leather and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of CNT strengthens absorbent-type environmentally friendly vehicle inside gadget artificial leather, is made up of the raw material of following weight portion: polyamide-675-77, alkali soluble polyester chip 25-26, concentration are that 20% sodium hydroxide solution is appropriate, aqueous polyurethane 50-53, nano-sized magnesium hydroxide 5-6, APP 3-4, neopelex 5-6, rutile titanium stock white 3-4, water are appropriate, pregelatinized starch 0.7-0.8, liquid silica gel 2-3, beta-schardinger dextrin-0.7-0.8, CNT 4-5, concentrated sulfuric acid 4-5, cocoanut fatty acid diethanolamide 0.8-1, lignin 1-1.2.
According to claims 1, a kind of CNT strengthens absorbent-type environmentally friendly vehicle inside gadget artificial leather, is prepared from by following concrete grammar:
(1) rear for polyamide-6 section and alkali soluble polyester chip are carried out drying respectively, control moisture and be less than 1%, enter fabric of island-in-sea type spinning pack respectively by respective singe screw spinning machine stirring melting and carry out spray silk, the tow obtained through drawing-off (at temperature is 75 DEG C drawing-off 3.5 times), oil, reel, dry (drying 5-10 minute for 55-65 DEG C), cut off (control fibre length is 50-55mm, and fiber number is 5-7dtex) and obtain composite superfine staple; After shredding cotton, adopted by composite superfine staple carding machine to be carded to single layer fibre net, then composite bed fiber web is formed through cross lapping machine, puncture on needing machine again, finally utilize bead cutter cutting neat, under the condition of 120-140 DEG C, carry out thermal contraction fixation, obtain superfine fiber synthetic leather base cloth;
(2) neopelex is dissolved in the water of 5 times amount, add nano-sized magnesium hydroxide, the aqueous polyurethane of rutile titanium stock white APP and half amount, be heated to 50 DEG C, after stirring 15 minutes with the speed of 500 revs/min, 10 minutes are stirred again with the speed of 1000 revs/min, obtain nano modified material emulsion, put it in dipping tank, then by above-mentioned superfine fiber synthetic leather base cloth dipping wherein, through roll pressed after abundant dipping, base cloth is taken out and puts into baking oven, fully dry at the temperature of 120-130 DEG C, obtain fire-retardant anti-solarization modified superfine fiber synthetic leather base cloth,
(3) above-mentioned fire-retardant anti-solarization modified superfine fiber synthetic leather base cloth being immersed concentration is in 20% sodium hydroxide solution, is heated to 60-70 DEG C, soaks 40 minutes, extracts alkali soluble polyester out and carries out fibrillation process, wash rear dried for standby;
(4) CNT is put into the reactor being equipped with condenser pipe, heater, slowly add the concentrated sulfuric acid, 100 DEG C are heated in oil bath, react and be cooled to room temperature after 1 hour, filtered by sintered glass funnel, be washed with water to neutrality, the powder obtained put into vacuum drying chamber dry, obtain the CNT of surface oxidation; Pregelatinized starch is added in the water of 10 times amount, be heated to dissolve completely, add the aqueous polyurethane of surplus, cocoanut fatty acid diethanolamide, liquid silica gel, the CNT of above-mentioned surface oxidation and all the other residual componentss, stir 20 minutes with the speed of 800 turns/part, obtain modified aqueous polyurethane slurry;
(5) Ji Bu that step (3) obtains is immersed in above-mentioned modified aqueous polyurethane slurry, through roll pressed after abundant dipping, base cloth is taken out and puts into baking oven, first with the temperature of 80 DEG C drying 5 minutes, its moisture is volatilized under controlled condition, then is warming up to dry 5 minutes of 100 DEG C of continuation, be finally warming up to 140 DEG C, make its complete crosslinking curing film forming of surface, make material of the present invention through operations such as sanding, dyeing, embossing, Final finishing afterwards.
Advantage of the present invention is: first the present invention adds the alkaline-resisting components matching aqueous polyurethane such as nano-sized magnesium hydroxide, rutile titanium stock white and carry out first time to the synthetic leather base cloth that polyamide-6, polyester mixed fiber are made and flood modification, in the surface making nano particle cover base cloth uniformly and gap, form good fire-retardant, sun-proof result; No longer adopt toluene afterwards but utilize NaOH to carry out fibrillation to modified Ji Bu, organic solvent residual can not be caused in the product while the surface forming how empty warp, to human body and Environmental security close friend.The present invention's twice maceration extract all adopts aqueous polyurethane, the solvent borne polyurethane of abandoning tradition, have nontoxicly not remain, do not fire, advantage free from environmental pollution, and remain that the good processability of solvent borne polyurethane, product mechanical strength are high, good springiness, wear-resisting premium properties.
The present invention utilizes strong acid to carry out surface oxidation to CNT, interface tuberculosis effect and the compatibility of CNT and polyurethane can be strengthened, can improve the intensity making product, also possess good suction-operated, making automotive upholstery can improve environment inside car.
Detailed description of the invention
A kind of CNT strengthens absorbent-type environmentally friendly vehicle inside gadget artificial leather, is made up of the raw material of following weight portion (kilogram): polyamide-675, alkali soluble polyester chip 25, concentration are that 20% sodium hydroxide solution is appropriate, aqueous polyurethane 50, nano-sized magnesium hydroxide 5, APP 3, neopelex 5, rutile titanium stock white 3, water are appropriate, pregelatinized starch 0.7, liquid silica gel 2, beta cyclodextrin 0.7, CNT 4, the concentrated sulfuric acid 4, cocoanut fatty acid diethanolamide 0.8, lignin 1.
According to claims 1, a kind of CNT strengthens absorbent-type environmentally friendly vehicle inside gadget artificial leather, is prepared from by following concrete grammar:
(1) rear for polyamide-6 section and alkali soluble polyester chip are carried out drying respectively, control moisture and be less than 1%, enter fabric of island-in-sea type spinning pack respectively by respective singe screw spinning machine stirring melting and carry out spray silk, the tow obtained through drawing-off (at temperature is 75 DEG C drawing-off 3.5 times), oil, reel, dry (drying 5 minutes for 55 DEG C), cut off (control fibre length is 50mm, and fiber number is 5dtex) and obtain composite superfine staple; After shredding cotton, adopted by composite superfine staple carding machine to be carded to single layer fibre net, then composite bed fiber web is formed through cross lapping machine, puncture on needing machine again, finally utilize bead cutter cutting neat, under the condition of 120 DEG C, carry out thermal contraction fixation, obtain superfine fiber synthetic leather base cloth;
(2) neopelex is dissolved in the water of 5 times amount, add nano-sized magnesium hydroxide, the aqueous polyurethane of rutile titanium stock white APP and half amount, be heated to 50 DEG C, after stirring 15 minutes with the speed of 500 revs/min, 10 minutes are stirred again with the speed of 1000 revs/min, obtain nano modified material emulsion, put it in dipping tank, then by above-mentioned superfine fiber synthetic leather base cloth dipping wherein, through roll pressed after abundant dipping, base cloth is taken out and puts into baking oven, fully dry at the temperature of 120 DEG C, obtain fire-retardant anti-solarization modified superfine fiber synthetic leather base cloth,
(3) above-mentioned fire-retardant anti-solarization modified superfine fiber synthetic leather base cloth being immersed concentration is in 20% sodium hydroxide solution, is heated to 60 DEG C, soaks 40 minutes, extracts alkali soluble polyester out and carries out fibrillation process, wash rear dried for standby;
(4) CNT is put into the reactor being equipped with condenser pipe, heater, slowly add the concentrated sulfuric acid, 100 DEG C are heated in oil bath, react and be cooled to room temperature after 1 hour, filtered by sintered glass funnel, be washed with water to neutrality, the powder obtained put into vacuum drying chamber dry, obtain the CNT of surface oxidation; Pregelatinized starch is added in the water of 10 times amount, be heated to dissolve completely, add the aqueous polyurethane of surplus, cocoanut fatty acid diethanolamide, liquid silica gel, the CNT of above-mentioned surface oxidation and all the other residual componentss, stir 20 minutes with the speed of 800 turns/part, obtain modified aqueous polyurethane slurry;
(5) Ji Bu that step (3) obtains is immersed in above-mentioned modified aqueous polyurethane slurry, through roll pressed after abundant dipping, base cloth is taken out and puts into baking oven, first with the temperature of 80 DEG C drying 5 minutes, its moisture is volatilized under controlled condition, then is warming up to dry 5 minutes of 100 DEG C of continuation, be finally warming up to 140 DEG C, make its complete crosslinking curing film forming of surface, make material of the present invention through operations such as sanding, dyeing, embossing, Final finishing afterwards.
The simulated leather material that the present invention obtains is through a series of detection, data are as follows: tear load and be greater than 80N, peel load is greater than 70(N/20mm), 23 DEG C of 100,000 folding fastness are Pyatyi,-10 DEG C of 40,000 folding fastness are Pyatyi, xerotripsis grade Pyatyi, wet rubbing grade level Four, soak in the NaOH of alkaline-resisting 10% when the peel strength after 24 hours to remain under more than 80%, 1000g loading conditions mill 500 times without damaged.
Claims (2)
1. a CNT strengthens absorbent-type environmentally friendly vehicle inside gadget artificial leather, it is characterized in that, be made up of the raw material of following weight portion: polyamide-675-77, alkali soluble polyester chip 25-26, concentration is that 20% sodium hydroxide solution is appropriate, aqueous polyurethane 50-53, nano-sized magnesium hydroxide 5-6, APP 3-4, neopelex 5-6, rutile titanium stock white 3-4, water is appropriate, pregelatinized starch 0.7-0.8, liquid silica gel 2-3, beta-schardinger dextrin-0.7-0.8, CNT 4-5, concentrated sulfuric acid 4-5, cocoanut fatty acid diethanolamide 0.8-1, lignin 1-1.2.
2. according to claims 1, a kind of CNT strengthens absorbent-type environmentally friendly vehicle inside gadget artificial leather, it is characterized in that, is prepared from by following concrete grammar:
(1) rear for polyamide-6 section and alkali soluble polyester chip are carried out drying respectively, control moisture and be less than 1%, enter fabric of island-in-sea type spinning pack respectively by respective singe screw spinning machine stirring melting and carry out spray silk, the tow obtained through drawing-off (at temperature is 75 DEG C drawing-off 3.5 times), oil, reel, dry (drying 5-10 minute for 55-65 DEG C), cut off (control fibre length is 50-55mm, and fiber number is 5-7dtex) and obtain composite superfine staple; After shredding cotton, adopted by composite superfine staple carding machine to be carded to single layer fibre net, then composite bed fiber web is formed through cross lapping machine, puncture on needing machine again, finally utilize bead cutter cutting neat, under the condition of 120-140 DEG C, carry out thermal contraction fixation, obtain superfine fiber synthetic leather base cloth;
(2) neopelex is dissolved in the water of 5 times amount, add nano-sized magnesium hydroxide, the aqueous polyurethane of rutile titanium stock white APP and half amount, be heated to 50 DEG C, after stirring 15 minutes with the speed of 500 revs/min, 10 minutes are stirred again with the speed of 1000 revs/min, obtain nano modified material emulsion, put it in dipping tank, then by above-mentioned superfine fiber synthetic leather base cloth dipping wherein, through roll pressed after abundant dipping, base cloth is taken out and puts into baking oven, fully dry at the temperature of 120-130 DEG C, obtain fire-retardant anti-solarization modified superfine fiber synthetic leather base cloth,
(3) above-mentioned fire-retardant anti-solarization modified superfine fiber synthetic leather base cloth being immersed concentration is in 20% sodium hydroxide solution, is heated to 60-70 DEG C, soaks 40 minutes, extracts alkali soluble polyester out and carries out fibrillation process, wash rear dried for standby;
(4) CNT is put into the reactor being equipped with condenser pipe, heater, slowly add the concentrated sulfuric acid, 100 DEG C are heated in oil bath, react and be cooled to room temperature after 1 hour, filtered by sintered glass funnel, be washed with water to neutrality, the powder obtained put into vacuum drying chamber dry, obtain the CNT of surface oxidation; Pregelatinized starch is added in the water of 10 times amount, be heated to dissolve completely, add the aqueous polyurethane of surplus, cocoanut fatty acid diethanolamide, liquid silica gel, the CNT of above-mentioned surface oxidation and all the other residual componentss, stir 20 minutes with the speed of 800 turns/part, obtain modified aqueous polyurethane slurry;
(5) Ji Bu that step (3) obtains is immersed in above-mentioned modified aqueous polyurethane slurry, through roll pressed after abundant dipping, base cloth is taken out and puts into baking oven, first with the temperature of 80 DEG C drying 5 minutes, its moisture is volatilized under controlled condition, then is warming up to dry 5 minutes of 100 DEG C of continuation, be finally warming up to 140 DEG C, make its complete crosslinking curing film forming of surface, make material of the present invention through operations such as sanding, dyeing, embossing, Final finishing afterwards.
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107460778A (en) * | 2017-08-29 | 2017-12-12 | 安徽乐踏鞋业有限公司 | A kind of processing method for improving imitation leather material wear ability |
| WO2018042310A3 (en) * | 2016-08-30 | 2018-06-07 | Prosetex S.P.A. | Fire-retarding mixture with carbonaceous component and process for the production thereof |
| CN109371702A (en) * | 2018-10-22 | 2019-02-22 | 江西泽晞新材料有限公司 | A kind of environment-friendly type aqueous synthetic leather dry technology for production |
| US10272836B2 (en) | 2017-06-28 | 2019-04-30 | Honda Motor Co., Ltd. | Smart functional leather for steering wheel and dash board |
| US10682952B2 (en) | 2017-06-28 | 2020-06-16 | Honda Motor Co., Ltd. | Embossed smart functional premium natural leather |
| US10742061B2 (en) | 2017-06-28 | 2020-08-11 | Honda Motor Co., Ltd. | Smart functional leather for recharging a portable electronic device |
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| US10682952B2 (en) | 2017-06-28 | 2020-06-16 | Honda Motor Co., Ltd. | Embossed smart functional premium natural leather |
| US10946797B2 (en) | 2017-06-28 | 2021-03-16 | Honda Motor Co., Ltd. | Smart functional leather for steering wheel and dash board |
| US10953793B2 (en) | 2017-06-28 | 2021-03-23 | Honda Motor Co., Ltd. | Haptic function leather component and method of making the same |
| US11027647B2 (en) | 2017-06-28 | 2021-06-08 | Honda Motor Co., Ltd. | Embossed smart functional premium natural leather |
| US11225191B2 (en) | 2017-06-28 | 2022-01-18 | Honda Motor Co., Ltd. | Smart leather with wireless power |
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| US11827143B2 (en) | 2017-06-28 | 2023-11-28 | Honda Motor Co., Ltd. | Embossed smart functional premium natural leather |
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| US11751337B2 (en) | 2019-04-26 | 2023-09-05 | Honda Motor Co., Ltd. | Wireless power of in-mold electronics and the application within a vehicle |
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