CN103993482A - Flame-retardant waterborne polyurethane superfine fiber synthetic leather base cloth and manufacturing method thereof - Google Patents
Flame-retardant waterborne polyurethane superfine fiber synthetic leather base cloth and manufacturing method thereof Download PDFInfo
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- CN103993482A CN103993482A CN201410191080.3A CN201410191080A CN103993482A CN 103993482 A CN103993482 A CN 103993482A CN 201410191080 A CN201410191080 A CN 201410191080A CN 103993482 A CN103993482 A CN 103993482A
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Abstract
The invention relates to the technical field of superfine fiber composite materials, in particular to a flame-retardant waterborne polyurethane superfine fiber synthetic leather base cloth and a manufacturing method thereof. The flame-retardant waterborne polyurethane superfine fiber synthetic leather base cloth includes an orange segment type bi-component superfine fiber non-woven fabric base obtained by conducting impregnation by a phospholipid fatliquor with a mass concentration of 5-15% and a waterborne polyurethane flame-retardant slurry in order and then performing drying. The manufacturing method includes: taking the orange segment type bi-component superfine fiber non-woven fabric as the base material, adopting a twice impregnation combination technology to combine a variety of flame retardants with the base material together, thus obtaining the waterborne polyurethane superfine fiber synthetic leather base cloth with a flame-retardant function. The flame retardance of the base cloth can reach the FMVSS302 flame-retardant testing standards of American automobile materials, and the waterborne polyurethane superfine fiber synthetic leather base cloth is mainly used for manufacturing of home decoration superfine fiber synthetic leather and automobile interior decoration superfine fiber synthetic leather, thus developing a new application field for orange segment type bi-component superfine fiber non-woven fabric.
Description
Technical field
The present invention relates to superfine fibre technical field of composite materials, be specifically related to a kind of flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth and manufacture method thereof.
Background technology
Twentieth century forties can be traced back in the source of fiber fine research, and what utilize at first that synthetic fiber successfully make composite fibre industrialization is the E.I.Du Pont Company of the U.S..
The companies such as between 1962-1965, toray, clock spin, Supreme Being people, Kuraray utilize method separately successfully to produce the superfine fibre differing from one another.For example, the various composite fibres such as multi-core type, wood grain type, radial pattern, hollow radial pattern are developed.
Enter the eighties of last century later stage seventies, Dong Li company is therefrom subject to inspiration by analysis natural fabric and produces fibre technology very uniformly.After the eighties, the characteristic that superfine fibre is good is subject to consumer's favor, forms the Artificial Chamois Leather heat of today.
Arrived eighties of last century after the nineties, many companies release the fine denier filaments such as polyester, polyamide, polyacrylonitrile and polypropylene one after another in the world.Also there is the nouns such as " fine count fiber ", " microfibre ", " superfine fibre ", yet there is no in the world so far the unified definition of relevant fine count fiber simultaneously.In the last few years, Japanese chemical fibre industry was generally called superfine fibre by monofilament linear density lower than the fiber of 0.3dtex.
Superfine fibre is because it,, than traditional fiber finer, so have more fluffy, soft sense of touch than general fiber, and can overcome the air-locked shortcoming of easy wrinkle, artificial fibre of natural fabric.In addition, it also has warming, not mouldy, free from insect pests, light weight, waterproof many excellent specific properties that can not be substituted such as even absorb water.
The purposes of superfine fibre is more and more extensive, and is progressively applied in the aspects such as senior clad material, medical protective material, fine filtering material, senior polishing material.
Tangerine lobe type bi-component superfine fibre can adopt water thorn, needling process to produce non-weaving cloth.In China, tangerine lobe type bi-component micro staple fiber non-weaving cloth is mainly used in cleaning products at present, and the non-weaving cloth of high-grade tangerine lobe bicomponent filament procedure of fibre production, for leather base fabric, is produced clothes and glove leather etc.
Summary of the invention
The object of the present invention is to provide a kind of flame-retardant aqueous polyurethane superfine fiber chemical leather and manufacture method thereof with good flame-retardance energy and environmental protection, the Application Areas making new advances for tangerine lobe type bi-component not weaving fabric of superfine fiber exploitation.
For achieving the above object, the present invention is by the following technical solutions:
Flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth provided by the invention, comprises service property (quality) concentration is 5～15% successively phosphatide fatting agent and aqueous polyurethane flame-retardant slurry dipping dry tangerine lobe type bi-component not weaving fabric of superfine fiber base material; Described aqueous polyurethane flame-retardant slurry comprises: with weight of material umber, calculate 2～4 parts of 30～50 parts of aqueous polyurethanes, 3～5 parts, aluminium hydroxide, magnesium hydroxide 5～10 and APP.
The manufacture method of flame-retardant aqueous polyurethane superfine fiber chemical leather provided by the invention comprises the following steps: the tangerine lobe type bi-component not weaving fabric of superfine fiber of 1) take is base material, service property (quality) concentration is that 5～15% phosphatide fatting agent is to base material impregnation process, and to control pickup be 30～50% of base material weight, dry processing then;
2) by step 1) dried base material uses aqueous polyurethane flame-retardant slurry dipping, and to control pickup be 50～80% of base material weight, and then dry processing, obtains flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth;
Described aqueous polyurethane flame-retardant slurry comprises, in parts by weight, and 2～4 parts of 30～50 parts of aqueous polyurethanes, 3～5 parts, aluminium hydroxide, 5～10 parts of magnesium hydroxides and APP.
Further, soybean lecithin fatting agent or modified lecithin fatting agent that step 1) described phosphatide fatting agent is modification.
Further, described phosphatide fatting agent is phosphatide fatting agent LZ507.
Further, step 2) described aqueous polyurethane is aq. polyurethane, and solid content is 30%.
Further, step 2) described aluminium hydroxide and magnesium hydroxide fineness are greater than 400 orders.
Further, step 2) described APP is that the degree of polymerization is 1000～1500 APP.
Further, step 1) and 2) described dry temperature is 105～150 ℃.
Further, described in, be immersed in dipping tank and carry out.
Compared with prior art, product provided by the invention has following useful technique effect: by take tangerine lobe type bi-component not weaving fabric of superfine fiber, prepare flame retardant type synthetic leather as base material, for the Application Areas that the exploitation of tangerine lobe type bi-component not weaving fabric of superfine fiber makes new advances, the anti-flammability of product of the present invention can reach american car material FMVSS302 flame retardant test standard.And because product provided by the invention is used aqueous polyurethane flame-retardant slurry, flood, so there is good environment protecting, can be used for the manufacture of home decoration superfine fiber chemical leather and automotive trim superfine fiber chemical leather.
Compared with prior art, preparation method provided by the invention has following useful technique effect: one, step 1) dipping adopts phosphate fat-liquoring agent, can be at the coated one deck phosphatide fatting agent in the fiber outside of tangerine lobe type bi-component not weaving fabric of superfine fiber, can stop the bonding of aqueous polyurethane flame-retardant slurry and fiber on the one hand, thereby prevent base cloth hardening, phosphatide fatting agent is phosphorous fatting agent on the other hand, itself just has certain fire resistance, can give base cloth certain anti-flammability; Two, step 2) dipping adopts the aqueous polyurethane flame-retardant slurry being comprised of aqueous polyurethane, aluminium hydroxide, magnesium hydroxide and APP, wherein aqueous polyurethane is as adhesive, can be by the fixing base material of other material, and aluminium hydroxide, magnesium hydroxide and APP have good cooperative flame retardant effect.
The specific embodiment
A kind of flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth provided by the invention, comprises working concentration is 5～15% successively phosphatide fatting agent and aqueous polyurethane flame-retardant slurry dipping dry tangerine lobe type bi-component not weaving fabric of superfine fiber base material; Aqueous polyurethane flame-retardant slurry comprises: with weight of material umber, calculate 2～4 parts of 30～50 parts of aqueous polyurethanes, 3～5 parts, aluminium hydroxide, magnesium hydroxide 5～10 and APP.The anti-flammability of flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth can reach american car material FMVSS302 flame retardant test standard, is mainly used in the manufacture of home decoration superfine fiber chemical leather and automotive trim superfine fiber chemical leather.
The manufacture method of a kind of flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth provided by the invention, comprises the following steps:
1) take tangerine lobe type bi-component not weaving fabric of superfine fiber is base material, by the dipping tank that mass concentration is 5～15% phosphatide fatting agent is housed, fully, after dipping, by roll, controlling pickup is 30～50% of non-weaving cloth weight, and fully dry at the temperature of 105～150 ℃; Soybean lecithin fatting agent or modified lecithin fatting agent that wherein phosphatide fatting agent is modification, can adopt the phosphatide fatting agent LZ507 of Jiangmen city BEST Fine Chemical Works.
2) by step 1) dried base material fully floods by the dipping tank of aqueous polyurethane flame-retardant slurry is housed, by roll, controlling pickup is 50～80% of base material weight, then fully dry at the temperature of 105～150 ℃, obtain flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth; Aqueous polyurethane flame-retardant slurry is: in parts by weight, 30～50 parts of based polyurethanes of water intaking, 3～5 parts, aluminium hydroxide, 5～10 parts of magnesium hydroxides and 2～4 parts of even mixing of APP make.
Wherein aqueous polyurethane is aq. polyurethane, and solid content is 30%, the products such as the use for synthetic leather resin KTC710 of employing Ketian Chemical Co., Ltd., Hefei City, KTC711, KTC712.Aluminium hydroxide and magnesium hydroxide are industrial goods, and fineness is greater than 400 orders.APP is the APP of the degree of polymerization 1000～1500, adopts the APPII type high polymerization degree APP fire retardant of Fauna of Kunshan, Jiangsu Jin Yikun fire proofing Co., Ltd.Tangerine lobe type bi-component not weaving fabric of superfine fiber can adopt the tangerine lobe type bi-component not weaving fabric of superfine fiber that spins Singapore dollar non-woven material Co., Ltd in Langfang.
Below in conjunction with embodiment, the present invention is described further.
Embodiment 1
The manufacture method of a kind of flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth provided by the invention, comprises the following steps:
1) take tangerine lobe type bi-component not weaving fabric of superfine fiber is base material, and by the dipping tank that mass concentration is 5% phosphatide fatting agent is housed, fully, after dipping, by roll, controlling pickup is 30% of non-weaving cloth weight, and is fully dried at 105～150 ℃; Soybean lecithin fatting agent or modified lecithin fatting agent that wherein phosphatide fatting agent is modification, the phosphatide fatting agent LZ507 of employing Jiangmen city BEST Fine Chemical Works.
2) by step 1) dried base material fully floods by the dipping tank of aqueous polyurethane flame-retardant slurry is housed, by roll, controlling pickup is 50% of base material weight, then fully dry between 105～150 ℃, obtain flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth; Aqueous polyurethane flame-retardant slurry is: in parts by weight, 30 parts of based polyurethanes of water intaking, 3 parts, aluminium hydroxide, magnesium hydroxide 5 and APP 2 are evenly mixed and made.
Wherein aqueous polyurethane is aq. polyurethane, and solid content is 30%, adopts the use for synthetic leather resin KTC710 of Ketian Chemical Co., Ltd., Hefei City.Aluminium hydroxide and magnesium hydroxide are industrial goods, and fineness is greater than 400 orders.APP is the APP of the degree of polymerization 1000～1500, adopts the APPII type high polymerization degree APP fire retardant of Fauna of Kunshan, Jiangsu Jin Yikun fire proofing Co., Ltd.
Embodiment 2
The manufacture method of a kind of flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth provided by the invention, comprises the following steps:
1) take tangerine lobe type bi-component not weaving fabric of superfine fiber is base material, and by the dipping tank that mass concentration is 15% phosphatide fatting agent is housed, fully, after dipping, by roll, controlling pickup is 50% of non-weaving cloth weight, and is fully dried at 105～150 ℃; Soybean lecithin fatting agent or modified lecithin fatting agent that wherein phosphatide fatting agent is modification, the phosphatide fatting agent LZ507 of employing Jiangmen city BEST Fine Chemical Works.
2) by step 1) dried base material fully floods by the dipping tank of aqueous polyurethane flame-retardant slurry is housed, by roll, controlling pickup is 80% of base material weight, then fully dry between 105～150 ℃, obtain flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth; Aqueous polyurethane flame-retardant slurry is: in parts by weight, 50 parts of based polyurethanes of water intaking, 10 parts, aluminium hydroxide, 10 parts of magnesium hydroxides and 4 parts of even mixing of APP make.
Wherein aqueous polyurethane is aq. polyurethane, and solid content is 30%, adopts the use for synthetic leather resin KTC710 of Ketian Chemical Co., Ltd., Hefei City.Aluminium hydroxide and magnesium hydroxide are industrial goods, and fineness is greater than 400 orders.APP is the APP of the degree of polymerization 1000～1500, adopts the APPII type high polymerization degree APP fire retardant of Fauna of Kunshan, Jiangsu Jin Yikun fire proofing Co., Ltd.
Embodiment 3
The manufacture method of a kind of flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth provided by the invention, comprises the following steps:
1) take tangerine lobe type bi-component not weaving fabric of superfine fiber is base material, by the dipping tank that mass concentration is 8% phosphatide fatting agent is housed, fully, after dipping, by roll, controlling pickup is 35% of non-weaving cloth weight, and fully dry at the temperature of 105～150 ℃; Soybean lecithin fatting agent or modified lecithin fatting agent that wherein phosphatide fatting agent is modification, can adopt the phosphatide fatting agent LZ507 of Jiangmen city BEST Fine Chemical Works.
2) by step 1) dried base material fully floods by the dipping tank of aqueous polyurethane flame-retardant slurry is housed, by roll, controlling pickup is 80% of base material weight, then fully dry at the temperature of 105～150 ℃, obtain flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth; Aqueous polyurethane flame-retardant slurry is: in parts by weight, 40 parts of based polyurethanes of water intaking, 3 parts, aluminium hydroxide, 9 parts of magnesium hydroxides and APP 2 are evenly mixed and made.
Wherein aqueous polyurethane is aq. polyurethane, and solid content is 30%, the products such as the use for synthetic leather resin KTC710 of employing Ketian Chemical Co., Ltd., Hefei City, KTC711, KTC712.Aluminium hydroxide and magnesium hydroxide are industrial goods, and fineness is greater than 400 orders.APP is the APP of the degree of polymerization 1000～1500, adopts the APPII type high polymerization degree APP fire retardant of Fauna of Kunshan, Jiangsu Jin Yikun fire proofing Co., Ltd.Tangerine lobe type bi-component not weaving fabric of superfine fiber can adopt the tangerine lobe type bi-component not weaving fabric of superfine fiber that spins Singapore dollar non-woven material Co., Ltd in Langfang.
Embodiment 4
The manufacture method of a kind of flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth provided by the invention, comprises the following steps:
1) take tangerine lobe type bi-component not weaving fabric of superfine fiber is base material, by the dipping tank that mass concentration is 10% phosphatide fatting agent is housed, fully, after dipping, by roll, controlling pickup is 45% of non-weaving cloth weight, and fully dry at the temperature of 105～150 ℃; Soybean lecithin fatting agent or modified lecithin fatting agent that wherein phosphatide fatting agent is modification, can adopt the phosphatide fatting agent LZ507 of Jiangmen city BEST Fine Chemical Works.
2) by step 1) dried base material fully floods by the dipping tank of aqueous polyurethane flame-retardant slurry is housed, by roll, controlling pickup is 60% of base material weight, then fully dry at the temperature of 105～150 ℃, obtain flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth; Aqueous polyurethane flame-retardant slurry is: in parts by weight, 45 parts of based polyurethanes of water intaking, 5 parts, aluminium hydroxide, 5 parts of magnesium hydroxides and 3 parts of even mixing of APP make.
Wherein aqueous polyurethane is aq. polyurethane, and solid content is 30%, the products such as the use for synthetic leather resin KTC710 of employing Ketian Chemical Co., Ltd., Hefei City, KTC711, KTC712.Aluminium hydroxide and magnesium hydroxide are industrial goods, and fineness is greater than 400 orders.APP is the APP of the degree of polymerization 1000～1500, adopts the APPII type high polymerization degree APP fire retardant of Fauna of Kunshan, Jiangsu Jin Yikun fire proofing Co., Ltd.Tangerine lobe type bi-component not weaving fabric of superfine fiber can adopt the tangerine lobe type bi-component not weaving fabric of superfine fiber that spins Singapore dollar non-woven material Co., Ltd in Langfang.
Embodiment 5
The manufacture method of a kind of flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth provided by the invention, comprises the following steps:
1) take tangerine lobe type bi-component not weaving fabric of superfine fiber is base material, by the dipping tank that mass concentration is 13% phosphatide fatting agent is housed, fully, after dipping, by roll, controlling pickup is 40% of non-weaving cloth weight, and fully dry at the temperature of 105～150 ℃; Soybean lecithin fatting agent or modified lecithin fatting agent that wherein phosphatide fatting agent is modification, can adopt the phosphatide fatting agent LZ507 of Jiangmen city BEST Fine Chemical Works.
2) by step 1) dried base material fully floods by the dipping tank of aqueous polyurethane flame-retardant slurry is housed, by roll, controlling pickup is 70% of base material weight, then fully dry at the temperature of 105～150 ℃, obtain flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth; Aqueous polyurethane flame-retardant slurry is: in parts by weight, 35 parts of based polyurethanes of water intaking, 4 parts, aluminium hydroxide, 7 parts of magnesium hydroxides and 4 parts of even mixing of APP make.
Wherein aqueous polyurethane is aq. polyurethane, and solid content is 30%, the products such as the use for synthetic leather resin KTC710 of employing Ketian Chemical Co., Ltd., Hefei City, KTC711, KTC712.Aluminium hydroxide and magnesium hydroxide are industrial goods, and fineness is greater than 400 orders.APP is the APP of the degree of polymerization 1000～1500, adopts the APPII type high polymerization degree APP fire retardant of Fauna of Kunshan, Jiangsu Jin Yikun fire proofing Co., Ltd.Tangerine lobe type bi-component not weaving fabric of superfine fiber can adopt the tangerine lobe type bi-component not weaving fabric of superfine fiber that spins Singapore dollar non-woven material Co., Ltd in Langfang.
Embodiment 6
The manufacture method of a kind of flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth provided by the invention, comprises the following steps:
1) take tangerine lobe type bi-component not weaving fabric of superfine fiber is base material, by the dipping tank that mass concentration is 15% phosphatide fatting agent is housed, fully, after dipping, by roll, controlling pickup is 30% of non-weaving cloth weight, and fully dry at the temperature of 105～150 ℃; Soybean lecithin fatting agent or modified lecithin fatting agent that wherein phosphatide fatting agent is modification, can adopt the phosphatide fatting agent LZ507 of Jiangmen city BEST Fine Chemical Works.
2) by step 1) dried base material fully floods by the dipping tank of aqueous polyurethane flame-retardant slurry is housed, by roll, controlling pickup is 50% of base material weight, then fully dry at the temperature of 105～150 ℃, obtain flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth; Aqueous polyurethane flame-retardant slurry is: in parts by weight, 50 parts of based polyurethanes of water intaking, 3 parts, aluminium hydroxide, 10 parts of magnesium hydroxides and 3 parts of even mixing of APP make.
Wherein aqueous polyurethane is aq. polyurethane, and solid content is 30%, the products such as the use for synthetic leather resin KTC710 of employing Ketian Chemical Co., Ltd., Hefei City, KTC711, KTC712.Aluminium hydroxide and magnesium hydroxide are industrial goods, and fineness is greater than 400 orders.APP is the APP of the degree of polymerization 1000～1500, adopts the APPII type high polymerization degree APP fire retardant of Fauna of Kunshan, Jiangsu Jin Yikun fire proofing Co., Ltd.Tangerine lobe type bi-component not weaving fabric of superfine fiber can adopt the tangerine lobe type bi-component not weaving fabric of superfine fiber that spins Singapore dollar non-woven material Co., Ltd in Langfang.
Claims (9)
1. a flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth, is characterized in that, comprises service property (quality) concentration is 5～15% successively phosphatide fatting agent and aqueous polyurethane flame-retardant slurry dipping dry tangerine lobe type bi-component not weaving fabric of superfine fiber base material; Described aqueous polyurethane flame-retardant slurry comprises: with weight of material umber, calculate 2～4 parts of 30～50 parts of aqueous polyurethanes, 3～5 parts, aluminium hydroxide, magnesium hydroxide 5～10 and APP.
2. a manufacture method for flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth, is characterized in that, comprises the following steps:
1) take tangerine lobe type bi-component not weaving fabric of superfine fiber is base material, and the phosphatide fatting agent that service property (quality) concentration is 5～15% is to base material impregnation process, and to control pickup be 30～50% of base material weight, then dry processing;
2) by step 1) dried base material uses aqueous polyurethane flame-retardant slurry dipping, and to control pickup be 50～80% of base material weight, and then dry processing, obtains flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth;
Described aqueous polyurethane flame-retardant slurry comprises, in parts by weight, and 2～4 parts of 30～50 parts of aqueous polyurethanes, 3～5 parts, aluminium hydroxide, 5～10 parts of magnesium hydroxides and APP.
3. a kind of manufacture method of flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth according to claim 2, is characterized in that step 1) described phosphatide fatting agent be modification soybean lecithin fatting agent or modified lecithin fatting agent.
4. a kind of manufacture method of flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth according to claim 3, is characterized in that, described phosphatide fatting agent is phosphatide fatting agent LZ507.
5. a kind of manufacture method of flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth according to claim 2, is characterized in that step 2) described aqueous polyurethane is aq. polyurethane, solid content is 30%.
6. a kind of manufacture method of flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth according to claim 2, is characterized in that step 2) described aluminium hydroxide and magnesium hydroxide fineness be greater than 400 orders.
7. a kind of manufacture method of flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth according to claim 2, is characterized in that step 2) described APP is that the degree of polymerization is 1000～1500 APP.
8. a kind of manufacture method of flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth according to claim 2, is characterized in that step 1) and 2) described dry temperature is 105～150 ℃.
9. the manufacture method of a kind of flame-retardant aqueous polyurethane superfine fiber synthetic leather base cloth according to claim 2, is characterized in that, described in be immersed in dipping tank and carry out.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20040084329A (en) * | 2003-03-22 | 2004-10-06 | 최창용 | Flame retardant processing method on fibrous materials by natural mineral and aqueous flame retardant. |
| CN101929083A (en) * | 2009-06-19 | 2010-12-29 | 上海华峰超纤材料股份有限公司 | Superfine fiber polyurethane leather and base cloth as well as preparation method and application |
| CN102444026A (en) * | 2011-10-11 | 2012-05-09 | 福建可利得皮革纤维有限公司 | Method for producing high-performance suede superfine fiber synthetic leather for clothes |
| CN103451958A (en) * | 2013-08-27 | 2013-12-18 | 陕西科技大学 | After finishing method for improving compliance of superfine fiber synthetic leather |
-
2014
- 2014-05-07 CN CN201410191080.3A patent/CN103993482B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20040084329A (en) * | 2003-03-22 | 2004-10-06 | 최창용 | Flame retardant processing method on fibrous materials by natural mineral and aqueous flame retardant. |
| CN101929083A (en) * | 2009-06-19 | 2010-12-29 | 上海华峰超纤材料股份有限公司 | Superfine fiber polyurethane leather and base cloth as well as preparation method and application |
| CN102444026A (en) * | 2011-10-11 | 2012-05-09 | 福建可利得皮革纤维有限公司 | Method for producing high-performance suede superfine fiber synthetic leather for clothes |
| CN103451958A (en) * | 2013-08-27 | 2013-12-18 | 陕西科技大学 | After finishing method for improving compliance of superfine fiber synthetic leather |
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