CN105505077A - Indoor coating with sound absorption function and preparation method of indoor coating - Google Patents

Indoor coating with sound absorption function and preparation method of indoor coating Download PDF

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Publication number
CN105505077A
CN105505077A CN201610041338.0A CN201610041338A CN105505077A CN 105505077 A CN105505077 A CN 105505077A CN 201610041338 A CN201610041338 A CN 201610041338A CN 105505077 A CN105505077 A CN 105505077A
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parts
sound absorption
absorption function
indoor coating
indoor
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CN201610041338.0A
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CN105505077B (en
Inventor
袁志祥
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Hebei Chenyang Industry and Trade Group Co Ltd
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SHANGHAI XINLAI BUILDING DECORATION DESIGN CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/32Radiation-absorbing paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses an indoor coating with a sound absorption function and a preparation method of the indoor coating. The indoor coating is prepared from the following raw materials in parts by weight: 30-50 parts of silicon acrylic emulsion, 15-30 parts of aluminum silicate fiber, 10-18 parts of perlite, 8-15 parts of titanium dioxide, 2-6 parts of sodium alginate, 1-4 parts of lauryl sodium sulfate, 0.5-2 parts of propylene glycol methyl ether acetate, 0.8-2 parts of dimethyl silicone oil, 0.3-1.2 parts of potassium stearate, 0.1-1.0 part of an antibacterial agent and 0.1-1.0 part of an ultraviolet absorber. According to the indoor coating with the sound absorption function and the preparation method, by optimizing the types and the consumption of the ultraviolet absorber and the antibacterial agent suitable for the indoor coating by virtue of a reasonable proportion, the illumination aging resistance is improved, and furthermore, the indoor coating has good antibacterial performance.

Description

A kind of indoor paint with sound absorption function and preparation method thereof
Technical field
The present invention relates to coating technology Material Field, particularly relate to a kind of indoor paint with sound absorption function and preparation method thereof.
Background technology
Paint finishing can bond very well with body material in body surface and form the material of complete and tough and tensile protective membrane, is called coating.Coating and paint are identical concepts.Paint is people's custom titles used for a long time, after introducing China, just utilizes in building trade always.The effect of coating may be summarized to be three aspects: provide protection, decoration function, specific function effect.The general composition of coating: comprise filmogen, color stuffing, solvent, auxiliary agent.
Building coating has decoration functions, defencive function and livability and improves function.Proportion shared by various function is not quite similar because application target is different.Decoration functions is the function of beautifying the appearance value improving it by buildings.Mainly comprise the design design of plane color, pattern and gloss aspect and the design design of three-dimensional pattern.But to match with the size and shape of the moulding of buildings itself and base material itself, just can fully play out.
Defencive function refers to architecture protection thing not by the impact of environment and the function of destruction.The content that different types of protected body requires defencive function is also different.As just very large in the indoor index difference with reaching required by outdoor application.Some buildingss to mildew-resistant, fire prevention, heat insulating, corrosion-resistant etc. have particular requirement.
Livability improves function mainly for indoor application, contributes to the function improving living environment exactly, as effect and classification, the antisweat etc. of sound-proofing, sound absorbing coating.
Coating act as decoration and protection, protects by the surface being coated with jewelry, prevents the erosion of the light, oxygen, chemical substance, solvent etc. from the external world, improve the work-ing life of coated thing; Paint finishing material surface, changes its color, decorative pattern, gloss, texture etc., improves the aesthetic value of object.
Organosilicon crylic acid latex is that the organosilane monomer containing unsaturated link(age) and acrylic monomer are added suitable auxiliary agent, the emulsion be polymerized by the coated polymerization technique of nucleocapsid.Combine organosilicon fire-resistant, weathering resistance, chemical-resistant, high tint retention, snappiness, the tack of the low not v ulnerability of hydrophobic, surface energy and acrylic resin.A kind of high durable, high water-fast, resistant to pollution environment-friendly type building emulsion and coating.
The invention provides a kind of indoor paint with sound absorption function, there is excellent illumination aging resisting, anti-microbial property.
Summary of the invention
For above shortcomings in prior art, one of technical problem to be solved by this invention is to provide a kind of indoor paint with sound absorption function.
Two of technical problem to be solved by this invention is to provide a kind of preparation method with the indoor paint of sound absorption function.
The present invention seeks to be achieved through the following technical solutions:
There is an indoor paint for sound absorption function, be prepared from by the raw material of following weight parts:
Organosilicon crylic acid latex 30 ~ 50 parts, aluminum silicate fiber 15 ~ 30 parts, perlite 10 ~ 18 parts, titanium dioxide 8 ~ 15 parts, sodium alginate 2 ~ 6 parts, sodium lauryl sulphate 1 ~ 4 part, 1-Methoxy-2-propyl acetate 0.5 ~ 2 part, dimethyl silicone oil 0.8 ~ 2 part, potassium stearate 0.3 ~ 1.2 part, antiseptic-germicide 0.1 ~ 1.0 part, ultraviolet absorbers 0.1 ~ 1.0 part.
Preferably, described antiseptic-germicide is mixed by iodo-5, the 5-dimethyl hydantion of 40-60wt%1,3-bis-and bromo-5, the 5-dimethyl hydantion of 40-60wt%3-.
Preferably, described ultraviolet absorbers is mixed by 40-60wt%2,2'-dihydroxyl-4,4'-dimethoxy-benzophenone-5,5'-disulfonic acid and 40-60wt%2,2'-dihydroxyl-4-methoxy benzophenone.
Present invention also offers the above-mentioned preparation method with the indoor paint of sound absorption function, organosilicon crylic acid latex, aluminum silicate fiber, perlite, titanium dioxide, sodium alginate, sodium lauryl sulphate, dimethyl silicone oil, potassium stearate, antiseptic-germicide, ultraviolet absorbers are mixed, sand milling, then add 1-Methoxy-2-propyl acetate and mix.
A kind of indoor paint with sound absorption function of the present invention and preparation method thereof, by rational proportioning, optimizes applicable indoor paint ultraviolet absorbers, the kind of antiseptic-germicide and consumption, improves illumination aging resisting performance, and have good antimicrobial property.
Embodiment
Below in conjunction with embodiment, the present invention is described further, the following stated, only to preferred embodiment of the present invention, not do other forms of restriction to the present invention, any those skilled in the art may utilize the technology contents of above-mentioned announcement to be changed to the Equivalent embodiments of equal change.Everyly do not depart from the present invention program's content, any simple modification done following examples according to technical spirit of the present invention or equivalent variations, all drop in protection scope of the present invention.
Each raw material introduction in embodiment:
Organosilicon crylic acid latex, with reference to number of patent application: the method preparation of embodiment 1 in 201510031949.2.
Aluminum silicate fiber, No. CAS: 12141-46-7, adopt the aluminum silicate fiber that Shandong Hai Xin Refractory Co., ltd produces.
Perlite, No. CAS: 93763-70-3, adopt the perlite that Xinyang Correspondent Industrial Co., Ltd. produces.
Titanium dioxide, No. CAS: 1317-80-2, particle diameter is 15-25nm.
Sodium alginate, No. CAS: 31581-02-9, adopt the sodium alginate that Guangdong Chen Yuan Fine Chemical Co., Ltd produces.
Sodium lauryl sulphate, No. CAS: 151-21-3.
1-Methoxy-2-propyl acetate, No. CAS: 108-65-6.
Dimethyl silicone oil, No. CAS: 63148-62-9.
Potassium stearate, No. CAS: 593-29-3.
Iodo-5, the 5-dimethyl hydantion of 1,3-bis-, No. CAS: 2232-12-4.
Bromo-5, the 5-dimethyl hydantion of 3-, No. CAS: 58402-65-6.
2,2'-dihydroxyl-4,4'-dimethoxy-benzophenone-5,5'-disulfonic acid, No. CAS: 1843-03-4.
2,2'-dihydroxyl-4-methoxy benzophenone, No. CAS: 181314-48-7.
Embodiment 1
Take each raw material (weight part): organosilicon crylic acid latex 40 parts, aluminum silicate fiber 20 parts, perlite 12 parts, titanium dioxide 10 parts, sodium alginate 4 parts, sodium lauryl sulphate 2.5 parts, 1-Methoxy-2-propyl acetate 1 part, dimethyl silicone oil 1 part, potassium stearate 0.7 part, antiseptic-germicide 0.5 part, ultraviolet absorbers 0.5 part.
Described ultraviolet absorbers is mixed by 0.25 part of 2,2'-dihydroxyl-4,4'-dimethoxy-benzophenone-5,5'-disulfonic acid and 0.25 part of 2,2'-dihydroxyl-4-methoxy benzophenone and obtains.
Described antiseptic-germicide is mixed by 0.25 part of 1,3-bis-iodo-5,5-dimethyl hydantion and 0.25 part of bromo-5,5-dimethyl hydantion of 3-and obtains.
There is the indoor paint preparation of sound absorption function:
Organosilicon crylic acid latex, aluminum silicate fiber, perlite, titanium dioxide, sodium alginate, sodium lauryl sulphate, dimethyl silicone oil, potassium stearate, antiseptic-germicide, ultraviolet absorbers are added in high speed dispersor and mixes; Again through sand mill sand milling to fineness be 25-35 μm; Add 1-Methoxy-2-propyl acetate again to mix, namely obtain the indoor paint with sound absorption function of the present invention.
Embodiment 2
Have the indoor paint of sound absorption function by the proportioning raw materials of embodiment 1 and method preparation, difference is only: described antiseptic-germicide is 0.5 part of 1,3-bis-iodo-5,5-dimethyl hydantion.Obtain the indoor paint with sound absorption function of embodiment 2.
Embodiment 3
Have the indoor paint of sound absorption function by the proportioning raw materials of embodiment 1 and method preparation, difference is only: described antiseptic-germicide is 0.5 part of bromo-5,5-dimethyl hydantion of 3-.Obtain the indoor paint with sound absorption function of embodiment 3.
Embodiment 4
Have the indoor paint of sound absorption function by the proportioning raw materials of embodiment 1 and method preparation, difference is only: described ultraviolet absorbers is 0.5 part of 2,2'-dihydroxyl-4,4'-dimethoxy-benzophenone-5,5'-disulfonic acid.Obtain the indoor paint with sound absorption function of embodiment 4.
Embodiment 5
Have the indoor paint of sound absorption function by the proportioning raw materials of embodiment 1 and method preparation, difference is only: described ultraviolet absorbers is that 0.5 part of 2,2'-dihydroxyl-4-methoxy benzophenone mixes and obtain.Obtain the indoor paint with sound absorption function of embodiment 5.
Test case 1
The anti-microbial property with the indoor paint of sound absorption function that embodiment 1-5 prepares is tested, anti-microbial property presses GB/T21866-2008 antibiotic paint anti-microbial property measuring method and antibacterial effect, HG/T3980-2007 antibiotic paint measure, and test item is antibacterial test and fungus-proof test.
Antibacterial test: intestinal bacteria ATYCC25922, streptococcus aureus ATCC6538.
Concrete test result is in table 1:
Table 1: the indoor paint anti-microbial property test data with sound absorption function
Comparing embodiment 1 and embodiment 2-3, when antiseptic-germicide add total amount identical, embodiment 1 (1,3-bis-iodo-5,5-dimethyl hydantion and bromo-5, the 5-dimethyl hydantion of 3-composite) anti-microbial property with the indoor paint of sound absorption function is obviously better than embodiment 2-3 (1,3-bis-iodo-5, single raw material in 5-dimethyl hydantion and bromo-5, the 5-dimethyl hydantion of 3-).
Test case 2
Carry out yellowing resistance test to the indoor paint with sound absorption function that embodiment 1-5 prepares, yellowing resistance presses IOS11507:1997 test.Concrete test result is in table 2:
Table 2: the indoor paint anti-yellowing property test data with sound absorption function
Comparing embodiment 1 and embodiment 4-5, when ultraviolet absorbers add total amount identical, embodiment 1 (2,2'-dihydroxyl-4,4'-dimethoxy-benzophenone-5,5'-disulfonic acid and 2,2'-dihydroxyl-4-methoxy benzophenone is composite) anti-yellowing property with the indoor paint of sound absorption function is obviously better than embodiment 4-5 (2,2'-dihydroxyl-4,4'-dimethoxy-benzophenone-5, single raw material in 5'-disulfonic acid and 2,2'-dihydroxyl-4-methoxy benzophenone).

Claims (4)

1. one kind has the indoor paint of sound absorption function, it is characterized in that, be prepared from by the raw material of following weight parts: organosilicon crylic acid latex 30 ~ 50 parts, aluminum silicate fiber 15 ~ 30 parts, perlite 10 ~ 18 parts, titanium dioxide 8 ~ 15 parts, sodium alginate 2 ~ 6 parts, sodium lauryl sulphate 1 ~ 4 part, 1-Methoxy-2-propyl acetate 0.5 ~ 2 part, dimethyl silicone oil 0.8 ~ 2 part, potassium stearate 0.3 ~ 1.2 part, antiseptic-germicide 0.1 ~ 1.0 part, ultraviolet absorbers 0.1 ~ 1.0 part.
2. have the indoor paint of sound absorption function as claimed in claim 1, it is characterized in that, described antiseptic-germicide is mixed by iodo-5, the 5-dimethyl hydantion of 40-60wt%1,3-bis-and bromo-5, the 5-dimethyl hydantion of 40-60wt%3-.
3. have the indoor paint of sound absorption function as claimed in claim 1 or 2, it is characterized in that, described ultraviolet absorbers is by 40-60wt%2,2'-dihydroxyl-4,4'-dimethoxy-benzophenone-5,5'-disulfonic acid and 40-60wt%2,2'-dihydroxyl-4-methoxy benzophenone mix.
4. the preparation method with the indoor paint of sound absorption function as described in any one of claim 1-3, it is characterized in that, organosilicon crylic acid latex, aluminum silicate fiber, perlite, titanium dioxide, sodium alginate, sodium lauryl sulphate, dimethyl silicone oil, potassium stearate, antiseptic-germicide, ultraviolet absorbers are mixed, sand milling, then add 1-Methoxy-2-propyl acetate and mix.
CN201610041338.0A 2016-01-21 2016-01-21 A kind of indoor coating and preparation method thereof with sound absorption function Active CN105505077B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1425720A (en) * 2003-01-10 2003-06-25 梅派 Sound absorptive environment protection paint
CN101270239A (en) * 2007-03-19 2008-09-24 吴尉文 Environment friendly acoustical absorption anacoustic interior decoration paint
CN102140279A (en) * 2010-11-19 2011-08-03 吴江龙泾红贝家装有限公司 Interior wall sound-absorbing material
CN102220057A (en) * 2011-04-28 2011-10-19 上海绿山实业有限公司 Sound-absorbing paint and preparation method thereof
CN105153853A (en) * 2015-09-02 2015-12-16 太仓顺如成建筑材料有限公司 Indoor coating with sound absorption function

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1425720A (en) * 2003-01-10 2003-06-25 梅派 Sound absorptive environment protection paint
CN101270239A (en) * 2007-03-19 2008-09-24 吴尉文 Environment friendly acoustical absorption anacoustic interior decoration paint
CN102140279A (en) * 2010-11-19 2011-08-03 吴江龙泾红贝家装有限公司 Interior wall sound-absorbing material
CN102220057A (en) * 2011-04-28 2011-10-19 上海绿山实业有限公司 Sound-absorbing paint and preparation method thereof
CN105153853A (en) * 2015-09-02 2015-12-16 太仓顺如成建筑材料有限公司 Indoor coating with sound absorption function

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
张光华: "《水处理化学品制备与应用指南》", 31 October 2003 *
汪盛藻: "《丙烯酸涂料生产实用技术问答》", 31 March 2007 *
陈昌杰: "《塑料功能性包装薄膜》", 28 February 2010 *

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