CN105503062B - A kind of cement products of anti-sand holes - Google Patents
A kind of cement products of anti-sand holes Download PDFInfo
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- CN105503062B CN105503062B CN201511025631.XA CN201511025631A CN105503062B CN 105503062 B CN105503062 B CN 105503062B CN 201511025631 A CN201511025631 A CN 201511025631A CN 105503062 B CN105503062 B CN 105503062B
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- cement
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/30—Water reducers, plasticisers, air-entrainers, flow improvers
- C04B2103/302—Water reducers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/44—Thickening, gelling or viscosity increasing agents
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/46—Water-loss or fluid-loss reducers, hygroscopic or hydrophilic agents, water retention agents
- C04B2103/465—Water-sorbing agents, hygroscopic or hydrophilic agents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a kind of cement products of anti-sand holes, count in parts by weight, and the cement products includes following material composition:20 50 parts of cement, 10 30 parts of flyash, 10 20 parts of glass fibre, 30 70 parts of water, 25 parts of adjustable solidification agent, 26 parts of composite modifier.The cement products of the present invention, formula is reasonable, easy to use.The compound action of composite modifier and flocculant and other dispensings, prepares that surface is smooth, and durability is good, freeze proof impervious plate.The cement products flat appearance, durability is good, and surface does not have sand holes and stomata.The preparation method of cement products of the present invention is simple, easy to operate, is easy to grasp.
Description
Technical field
The present invention relates to building material field, more particularly to a kind of cement products of anti-sand holes.
Background technology
At present, the defects of traditional plate surface is due in formula and manufacture craft, the small trachoma of generally existing and stomata,
Its appearance is not only influenced, but also influences it using function, has the plate of trachoma when spray painting is related in the later stage, spray painting can be in sand
Eye place generates recess, if increasing spray painting amount, not only influences appearance, but also paints that the time dried is different, influence engineering into
Degree, has the water imbibition that bladdery plate can influence plate, plate surface easily cracks, and durability is poor, freeze proof, impermeability
Difference.
The information for being disclosed in the background section is merely intended to increase the understanding of the general background to the present invention, without answering
When being considered as recognizing or imply that the information structure has been the prior art well known to persons skilled in the art in any form.
The content of the invention
It is an object of the invention to provide a kind of cement products of anti-sand holes, and the cement products flat appearance, durability is good,
Surface does not have sand holes and stomata.
Another object of the present invention is to provide a kind of preparation method of the cement products of anti-sand holes.
To achieve the above object, the present invention provides a kind of cement products of anti-sand holes, count in parts by weight, the cement
Product includes following material composition:20-50 parts of cement, 10-30 parts of flyash, 10-20 parts of glass fibre, 30-70 parts of water are adjusted solidifying
2-5 parts of agent, 2-6 parts of composite modifier.
Preferably, in above-mentioned technical proposal, the composite modifier includes following substance component:Super finely ground slag, water-reducing agent,
Water-retaining agent, thickener.
Preferably, in above-mentioned technical proposal, count in parts by weight, the composite modifier includes following substance component:It is super
5-10 parts of mineral fine, 1-5 parts of water-reducing agent, 0.5-1 parts of water-retaining agent, 0.5-1 parts of thickener.
Preferably, in above-mentioned technical proposal, the super finely ground slag is the calcium carbonate superfine powder of 180-200 mesh.
Preferably, in above-mentioned technical proposal, the water-reducing agent be sulfamic acid, nano-zirconium carbide, propylene glycol, pyrophosphoric acid
Sodium, ethylene diamine tetra methylene phosphonic acid sodium, the one or more in barium metaborate.
Preferably, in above-mentioned technical proposal, the water-retaining agent be ferrous sulfate, sodium metasilicate, talcum powder, cross-linked polysaccharides acetic acid
One or more in ester.
Preferably, in above-mentioned technical proposal, the thickener is selected from bentonite, oxidized sodium alginate, two benzal sorboses
Alcohol, N hydroxymethyl acrylamide, the one or more in dibutyl phthalate.
Preferably, in above-mentioned technical proposal, the adjustable solidification agent is counted in parts by weight including following components:Amino tea sulfoacid calcium
10-20 parts, 5-10 parts of calcium nitrate, 2-4 parts of sodium citrate, 2-4 parts of sodium gluconate, 1-5 parts of anhydrous sodium pyrophosphate and hydroxypropyl
1-3 parts of methyl cellulose ether.
A kind of preparation method of the cement products of anti-sand holes, comprises the following steps:
(1) first by 20-50 parts of cement, 10-30 parts of flyash, 10-20 parts of glass fibre, which is added in 30-70 parts of water, stirs 2-
10min;
(2) 2-6 parts of stirring 1min of composite modifier are added in, stand 5-10min;
(3) 2-5 parts of adjustable solidification agent is added in, stirs 1-2min, feeding rolls out line workshop, production is rolled out into template is filling
Wet panel is sent into the maintenance of maintenance workshop after cutting.
Compared with prior art, the present invention has the advantages that:The cement products of the present invention, formula is reasonable, uses
It is convenient.The compound action of composite modifier and flocculant and other dispensings, prepares that surface is smooth, and durability is good, freeze proof impervious
Plate.The cement products flat appearance, durability is good, and surface does not have sand holes and stomata.The preparation side of cement products of the present invention
Method is simple, easy to operate, is easy to grasp.
Specific embodiment
With reference to specific embodiment, the specific embodiment of the present invention is described in detail, it is to be understood that this hair
Bright protection domain is not restricted by specific implementation.
Embodiment 1
A kind of preparation method of the cement products of anti-sand holes, comprises the following steps:
(1) prepare the raw material needed for production, count in parts by weight, including:20 parts of cement, 10 parts of flyash, glass fibre
10 parts, 30 parts of water, 2 parts of adjustable solidification agent, 2 parts of composite modifier.
The composite modifier is counted in parts by weight including following substance component:5 parts of the calcium carbonate superfine powder of 180-200 mesh,
1 part of water-reducing agent, 0.5 part of water-retaining agent, 0.5 part of thickener.
The water-reducing agent is sulfamic acid, nano-zirconium carbide, propylene glycol, the mixture of sodium pyrophosphate and barium metaborate;Ammonia
The mass ratio of base sulfonic acid, nano-zirconium carbide, propylene glycol, sodium pyrophosphate and barium metaborate is 1:1:1:1:1.
The water-retaining agent be ferrous sulfate, talcum powder, the mixture of cross-linked polysaccharides acetate;Ferrous sulfate, talcum powder are handed over
The mass ratio for joining polysaccharide acetate is 1:2:1.
The thickener is selected from bentonite, oxidized sodium alginate, benzylidene sorbitol, N hydroxymethyl acrylamide, neighbour
The mixture of dibatyl phithalate;Bentonite, oxidized sodium alginate, benzylidene sorbitol, N hydroxymethyl acrylamide are adjacent
The mass ratio of dibatyl phithalate is 1:0.5:1:0.3:1.
The adjustable solidification agent is counted in parts by weight including following components:10 parts of amino tea sulfoacid calcium, 5 parts of calcium nitrate, citric acid
1 part of 2 parts of sodium, 2 parts of sodium gluconate, 1 part of anhydrous sodium pyrophosphate and hydroxypropyl methyl cellulose ether.
(2) first by cement, flyash, glass fibre adds in 30 parts of water and stirs 7min.
(3) 2 parts of stirring 1min of composite modifier are added in, stand 8min.
(4) 2 parts of adjustable solidification agent is added in, stirs 2min, feeding rolls out line workshop, production wet plate is rolled out into template is filling
Material is sent into the maintenance of maintenance workshop after cutting.
Embodiment 2
The present embodiment and the difference of embodiment 1 are that the raw material for producing the cement products of anti-sand holes is different.
The raw material needed for anti-sand holes cement products is produced, is counted in parts by weight, including:50 parts of cement, 30 parts of flyash, glass
20 parts of glass fiber, 70 parts of water, 5 parts of adjustable solidification agent, 6 parts of composite modifier;
It counts in parts by weight, the composite modifier includes following substance component:The calcium carbonate superfine powder 10 of 180-200 mesh
Part, 5 parts of water-reducing agent, 1 part of water-retaining agent, 1 part of thickener.
The water-reducing agent be sulfamic acid, nano-zirconium carbide, propylene glycol, sodium pyrophosphate, ethylene diamine tetra methylene phosphonic acid sodium
Mixture;Sulfamic acid, nano-zirconium carbide, propylene glycol, sodium pyrophosphate, the mass ratio of ethylene diamine tetra methylene phosphonic acid sodium is 1:2:1:
1。
The water-retaining agent be ferrous sulfate, sodium metasilicate, the mixture of talcum powder;Ferrous sulfate, sodium metasilicate, the matter of talcum powder
Amount is than being 1:1:1.
The thickener is selected from bentonite, N hydroxymethyl acrylamide, the mixture of dibutyl phthalate;Swelling
Soil, N hydroxymethyl acrylamide, the mass ratio of dibutyl phthalate is 1:1:1.
The adjustable solidification agent is counted in parts by weight including following components:20 parts of amino tea sulfoacid calcium, 10 parts of calcium nitrate, citric acid
3 parts of 4 parts of sodium, 4 parts of sodium gluconate, 5 parts of anhydrous sodium pyrophosphate and hydroxypropyl methyl cellulose ether.
Embodiment 3
The present embodiment and the difference of embodiment 1 are that the raw material for producing the cement products of anti-sand holes is different.
The raw material needed for anti-sand holes cement products is produced, is counted in parts by weight, including:40 parts of cement, 16 parts of flyash, glass
16 parts of glass fiber, 55 parts of water, 3 parts of adjustable solidification agent, 4 parts of composite modifier;
It counts in parts by weight, the composite modifier includes following substance component:The calcium carbonate superfine powder 5-10 of 180-200 mesh
Part, 3 parts of water-reducing agent, 0.8 part of water-retaining agent, 0.7 part of thickener.
The water-reducing agent be sulfamic acid, nano-zirconium carbide, sodium pyrophosphate, ethylene diamine tetra methylene phosphonic acid sodium, barium metaborate
Mixture;Sulfamic acid, nano-zirconium carbide, sodium pyrophosphate, ethylene diamine tetra methylene phosphonic acid sodium, the mass ratio of barium metaborate is 1:
1:1:1:1.
The water-retaining agent be ferrous sulfate, talcum powder, the mixture of cross-linked polysaccharides acetate;Ferrous sulfate, talcum powder are handed over
The mass ratio for joining polysaccharide acetate is 1:1:1.
The thickener is mixed selected from bentonite, oxidized sodium alginate, benzylidene sorbitol, N hydroxymethyl acrylamide
Close object;Bentonite, oxidized sodium alginate, benzylidene sorbitol, the mass ratio of N hydroxymethyl acrylamide is 1:0.5:1:1.
The adjustable solidification agent is counted in parts by weight including following components:15 parts of amino tea sulfoacid calcium, 8 parts of calcium nitrate, citric acid
2 parts of 3 parts of sodium, 3 parts of sodium gluconate, 4 parts of anhydrous sodium pyrophosphate and hydroxypropyl methyl cellulose ether.
Comparative example 1
The present embodiment and the difference of embodiment 1 are that the raw material for producing the cement products of anti-sand holes is different.
The raw material needed for anti-sand holes cement products is produced, is counted in parts by weight, including:40 parts of cement, 16 parts of flyash, glass
16 parts of glass fiber, 55 parts of water, 3 parts of adjustable solidification agent;
The adjustable solidification agent is counted in parts by weight including following components:15 parts of amino tea sulfoacid calcium, 8 parts of calcium nitrate, citric acid
2 parts of 3 parts of sodium, 3 parts of sodium gluconate, 4 parts of anhydrous sodium pyrophosphate and hydroxypropyl methyl cellulose ether.
By the crack resistence agent of embodiment and comparative example for making cement fibrolite plate, and then detect the items of cement fibrolite plate
Index.As shown in table 1.
Table 1 is the testing result of anti-sand holes cement products water resistance and strength character made from the present embodiment
As shown in table 1, the cement products impermeability pressure for being doped with composite modifier has reached 0.9MPa, and is not added with compound
The cement products impermeability pressure of modifying agent only has 0.6MPa.Therefore, composite modifier is added in cement products so that cement system
Product have certain densification, while improve the compression strength of cement products.And cement products surface is without sand holes and stomata.
The description of the foregoing specific exemplary embodiment to the present invention is in order to illustrate and illustration purpose.These descriptions
It is not wishing to limit the invention to disclosed precise forms, and it will be apparent that according to the above instruction, can much be changed
And variation.The purpose of selecting and describing the exemplary embodiment is that explain that the certain principles of the present invention and its reality should
With so that those skilled in the art can realize and utilize the present invention a variety of exemplary implementation schemes and
Various chooses and changes.The scope of the present invention is intended to be limited by claims and its equivalents.
Claims (5)
1. a kind of cement products of anti-sand holes, which is characterized in that count in parts by weight, the cement products includes following substance group
Point:20-50 parts of cement, 10-30 parts of flyash, 10-20 parts of glass fibre, 30-70 parts of water, 2-5 parts of adjustable solidification agent, composite modifier
2-6 parts;
It counts in parts by weight, the composite modifier includes following substance component:5-10 parts of super finely ground slag, 1-5 parts of water-reducing agent are protected
0.5-1 parts of aqua, 0.5-1 parts of thickener;
The water-reducing agent is:The water-reducing agent is sulfamic acid, nano-zirconium carbide, propylene glycol, sodium pyrophosphate and barium metaborate
Mixture;The mass ratio of sulfamic acid, nano-zirconium carbide, propylene glycol, sodium pyrophosphate and barium metaborate is 1:1:1:1:1;
The water-retaining agent be ferrous sulfate, talcum powder, the mixture of cross-linked polysaccharides acetate;Ferrous sulfate, talcum powder, crosslinking are more
The mass ratio of sweet and sour acid esters is 1:2:1;
The adjustable solidification agent is counted in parts by weight including following components:10-20 parts of amino tea sulfoacid calcium, 5-10 parts of calcium nitrate, lemon
Sour sodium 2-4 parts, 2-4 parts of sodium gluconate, 1-3 parts of 1-5 parts of anhydrous sodium pyrophosphate and hydroxypropyl methyl cellulose ether;
The thickener is selected from bentonite, oxidized sodium alginate, benzylidene sorbitol, N hydroxymethyl acrylamide, adjacent benzene two
The mixture of formic acid dibutyl ester;Bentonite, oxidized sodium alginate, benzylidene sorbitol, N hydroxymethyl acrylamide, adjacent benzene two
The mass ratio of formic acid dibutyl ester is 1:0.5:1:0.3:1.
2. a kind of cement products of anti-sand holes, which is characterized in that count in parts by weight, the cement products includes following substance group
Point:20-50 parts of cement, 10-30 parts of flyash, 10-20 parts of glass fibre, 30-70 parts of water, 2-5 parts of adjustable solidification agent, composite modifier
2-6 parts;
It counts in parts by weight, the composite modifier includes following substance component:5-10 parts of super finely ground slag, 1-5 parts of water-reducing agent are protected
0.5-1 parts of aqua, 0.5-1 parts of thickener;
The water-reducing agent be sulfamic acid, nano-zirconium carbide, propylene glycol, sodium pyrophosphate, the mixing of ethylene diamine tetra methylene phosphonic acid sodium
Object;Sulfamic acid, nano-zirconium carbide, propylene glycol, sodium pyrophosphate, the mass ratio of ethylene diamine tetra methylene phosphonic acid sodium is 1:2:1:1;
The water-retaining agent be ferrous sulfate, sodium metasilicate, the mixture of talcum powder;Ferrous sulfate, sodium metasilicate, the mass ratio of talcum powder
For 1:1:1;
The adjustable solidification agent is counted in parts by weight including following components:10-20 parts of amino tea sulfoacid calcium, 5-10 parts of calcium nitrate, lemon
Sour sodium 2-4 parts, 2-4 parts of sodium gluconate, 1-3 parts of 1-5 parts of anhydrous sodium pyrophosphate and hydroxypropyl methyl cellulose ether;
The thickener is selected from bentonite, N hydroxymethyl acrylamide, the mixture of dibutyl phthalate;Bentonite, N-
Hydroxymethyl acrylamide, the mass ratio of dibutyl phthalate is 1:1:1.
3. a kind of cement products of anti-sand holes, which is characterized in that count in parts by weight, the cement products includes following substance group
Point:20-50 parts of cement, 10-30 parts of flyash, 10-20 parts of glass fibre, 30-70 parts of water, 2-5 parts of adjustable solidification agent, composite modifier
2-6 parts;
It counts in parts by weight, the composite modifier includes following substance component:5-10 parts of super finely ground slag, 1-5 parts of water-reducing agent are protected
0.5-1 parts of aqua, 0.5-1 parts of thickener;
The water-reducing agent is sulfamic acid, nano-zirconium carbide, sodium pyrophosphate, ethylene diamine tetra methylene phosphonic acid sodium, barium metaborate it is mixed
Close object;Sulfamic acid, nano-zirconium carbide, sodium pyrophosphate, ethylene diamine tetra methylene phosphonic acid sodium, the mass ratio of barium metaborate is 1:1:1:
1:1;
The water-retaining agent be ferrous sulfate, talcum powder, the mixture of cross-linked polysaccharides acetate;Ferrous sulfate, talcum powder, crosslinking are more
The mass ratio of sweet and sour acid esters is 1:1:1;
The adjustable solidification agent is counted in parts by weight including following components:10-20 parts of amino tea sulfoacid calcium, 5-10 parts of calcium nitrate, lemon
Sour sodium 2-4 parts, 2-4 parts of sodium gluconate, 1-3 parts of 1-5 parts of anhydrous sodium pyrophosphate and hydroxypropyl methyl cellulose ether;
The thickener is selected from bentonite, oxidized sodium alginate, benzylidene sorbitol, the mixing of N hydroxymethyl acrylamide
Object;Bentonite, oxidized sodium alginate, benzylidene sorbitol, the mass ratio of N hydroxymethyl acrylamide is 1:0.5:1:1.
4. according to the cement products of any anti-sand holes in claim 1-3, which is characterized in that the super finely ground slag is
The calcium carbonate superfine powder of 180-200 mesh.
5. a kind of preparation method of the cement products of anti-sand holes as described in any in 1-3 such as claim, which is characterized in that including with
Lower step:
(1) first by 20-50 parts of cement, 10-30 parts of flyash, 10-20 parts of glass fibre, which is added in 30-70 parts of water, stirs 2-
10min;
(2) 2-6 parts of stirring 1min of composite modifier are added in, stand 5-10min;
(3) 2-5 parts of adjustable solidification agent is added in, stirs 1-2min, feeding rolls out line workshop, production wet plate is rolled out into template is filling
Material is sent into the maintenance of maintenance workshop after cutting.
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CN106116364B (en) * | 2016-06-28 | 2018-09-28 | 王青 | A kind of fibre reinforced concrete and preparation method thereof |
CN108285290A (en) * | 2018-04-27 | 2018-07-17 | 江苏百瑞吉新材料有限公司 | A kind of concrete water-retaining agent |
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CN103255888A (en) * | 2013-04-18 | 2013-08-21 | 深圳市爱思宝科技发展有限公司 | Full-body dry hanging plate and manufacturing method thereof |
CN103253909A (en) * | 2013-04-18 | 2013-08-21 | 深圳市爱思宝科技发展有限公司 | Glaze material and preparation method of glaze material plate |
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