CN105502639A - Method for co-processing hard-degraded animal bones in rural kitchen garbage and domestic sewage - Google Patents

Method for co-processing hard-degraded animal bones in rural kitchen garbage and domestic sewage Download PDF

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Publication number
CN105502639A
CN105502639A CN201610055014.2A CN201610055014A CN105502639A CN 105502639 A CN105502639 A CN 105502639A CN 201610055014 A CN201610055014 A CN 201610055014A CN 105502639 A CN105502639 A CN 105502639A
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rural
domestic sewage
sewage
animal bone
animal bones
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CN105502639B (en
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赵由才
曾超
夏发发
杨宁
王周
牛冬杰
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Tongji University
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Tongji University
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/10Packings; Fillings; Grids
    • C02F3/104Granular carriers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/40Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/80Destroying solid waste or transforming solid waste into something useful or harmless involving an extraction step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/105Phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Microbiology (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention relates to a method for co-processing hard-degraded animal bones in rural kitchen garbage and domestic sewage, and belongs to the technical field of solid waste resource utilization and sewage treatment. The method comprises the steps that cleaned animal bones in the rural kitchen garbage are soaked in a NaOH solution, cleaned through tap water and dried; the animal bones are moved into a muffle furnace for firing, cooled, crushed to be appropriate particle sizes and cleaned to obtain carrier packing used for microorganism attachment; an up-flow biological filter bed reactor is filled with the prepared packing, country life sewage treatment is conducted after inoculation membrane formation is conducted through activated sludge, and co-processing of the animal bones and domestic sewage is achieved. According to the method for co-processing the hard-degraded animal bones in the rural kitchen garbage and the domestic sewage, the technology is simple, under the condition of short hydraulic retention time of 6-10 h, the effluent quality is stable, and concentration of pollutants of COD<Cr> and NH<3->N is lower than the primary standard threshold value of Discharge Standard of Pollutants for Municipal Wastewater Treatment Plant (GB 18918-2002); meanwhile, a good removing effect on TP is achieved, and a wide prospect for applying the method to rural domestic sewage treatment is achieved.

Description

In the rubbish from cooking of a kind of rural area, difficult degradation animal bone and sanitary sewage coexist the method for putting
Technical field
The present invention relates to difficult degradation animal bone and sanitary sewage in the rubbish from cooking of a kind of rural area to coexist the method for putting.Belong to solid waste resource recovery to utilize and technical field of sewage.
Background technology
China's domestic sewage in rural areas existence discharge is wide, discharge point disperses, quantity discharged increases soon, organic concentration is high, discharge the features such as uneven, is difficult to focus on.Therefore, current China rural domestic sewage treatment rate is also very low, according to statistics village wastewater treatment rate only 7%.In various technology for treating domestic sewage in rural area, biomembrance process is low with its investment cost, management maintenance convenient, processing efficiency is high, little without floor space, effluent quality is good and be more and more subject to people's attention without advantages such as sludge bulking problems.Biomembrance process comprises the process forms such as biological filter, blodisc, biological contact oxidation pond, BAF and biological fluidized bed, its common feature is that attached growth of microorganisms is at filling surface, form microbial film, after sewage and biofilm contact, pollutent is transformed by microorganism adsorption, and sewage is purified.Filler, as microorganism carrier in biofilm reactor, affects microbial growth, breeds and come off, thus have very important impact to the operating performance of reactor.At present in biomembrance process sewage disposal conventional haydite, gac, zeolite and polymer carrier etc. as biofilm carrier, but these hand-stuff are for high expensive rural area or economically underdeveloped area.
Since nearly 30 years, rural economy is fast-developing, and urban residents' standard of living improves constantly, and the generation of residents in rural community and accumulating amount are all improving year by year.Because peasant household lives scattered in vast rural areas, the generation density of residents in rural community is low, and the logistics cost causing it to focus on is significantly higher than city, is difficult to focus on, cause the present situation not processing or deal with improperly, thus have a strong impact on Ecological Environment.Residents in rural community original-source by classification is collected can reduce rubbish generation from source, improve waste utilization rate, reduce transportation cost, reduce end disposes difficulty.Therefore, original-source by classification collects the trend of necessarily administering residents in rural community problem from now on.Generally speaking, domestic refuse can be divided into rubbish from cooking, recyclable rubbish (having valency waste product), and not recyclable rubbish and poisonous and harmful rubbish etc., also can be divided into dry rubbish and wet refuse etc.In screening residents in rural community, the dry refuse preparation of difficult degradation is applicable to the carrier filler of microorganic adhesion on the spot for rural domestic sewage treatment, and for Domestic Waste Minimization, innoxious and resource utilization is significant.
The preparation that much research all reports different biological filtering material for waste water treatments and the method for disposing of sewage thereof.But generally speaking, although these methods can obtain good effect, what it used on the one hand is mostly Nonrenewable resources, not only consume resource, and may damage environment, on the other hand, its high expensive, is not suitable for applying in rural area decentralized type sewage process engineering.At present, utilize the dry refuse of difficult degradation in residents in rural community to prepare filler and also rarely have report for the research of rural domestic sewage treatment, especially the animal bone in rubbish from cooking is smashed to reduce the pressure to environment because the feature of its difficult degradation generally needs first to sort out, thus causes much inconvenience.Although, difficult degradation animal bone in the rubbish from cooking of rural area and sanitary sewage are coexisted and puts, animal bone difficult degradation characteristic is utilized to be prepared into the carrier being easy to microorganic adhesion, as the filler for the treatment of domestic sewage in rural areas, not only can solve the process handling problems of carrying out animal bone after residents in rural community original-source by classification from now on, and be conducive to the Financial cost of saving rural domestic sewage treatment, but nobody did so far.
Summary of the invention
The object of the invention is day by day to increase the present situation low with sanitary sewage disposal rate for residents in rural community amount, provide difficult degradation animal bone and sanitary sewage in the rubbish from cooking of a kind of rural area to coexist the method for putting.The method is based on the thought of " treatment of wastes with processes of wastes against one another ", and utilize the feature with sewage disposal technology with combining solid waste resource recovery, the coexistence achieving dry refuse and domestic sewage in rural areas in residents in rural community is put.This is not only conducive to residents in rural community minimizing, innoxious and resource utilization, and makes domestic sewage in rural areas obtain treatment in situ and qualified discharge, has important practical value.Present method cost is low, cheaper starting materials is easy to get, and treatment process is simple, is convenient to Artificial Control and management.
In order to achieve the above object, the animal bone in residents in rural community sorts out and removes its surface impurity by the present invention; Animal bone sodium hydroxide solution is soaked to remove top layer grease and to come unstuck, then cleans up with tap water, dry to remove moisture; Animal bone after drying is moved into retort furnace calcination, the animal bone after roasting is crushed to suitable particle diameter, cleans the carrier filler namely obtained for microorganic adhesion; Load this filler to upflowing bio-filter bed reactor reactor, after utilizing active sludge to carry out inoculation membrane formation, pending domestic sewage in rural areas flows into from reactor lower part, flows out after processing from reactor top.Under shorter hydraulic detention time condition, principal pollutant COD crand NH 3-N concentration is lower than " urban wastewater treatment firm pollutant emission standard (GB18918-2002) " primary standard threshold value.Meanwhile, the TP in sewage also has good removal effect.
Concrete steps are as follows:
A, sorts out the animal bone in the rubbish from cooking of rural area and removes its surface impurity, clean with tap water;
B, the animal bone 24-72h obtained with the NaOH solution soaking step A that concentration is 0.3 ~ 1% mass percent, remove top layer grease and come unstuck, and then cleans with tap water, dry at 60 ~ 80 DEG C, remove moisture;
C, the animal bone obtained by step B moves into retort furnace, under certain temperature rise rate is 5 ~ 10 DEG C/min, retort furnace is warming up to 300 ~ 500 DEG C, and insulation 30 ~ 60min, shifts out retort furnace by animal bone after its naturally cooling;
D, the animal bone obtained by step C is crushed to the irregularly shaped particles that particle diameter is 0.6 ~ 2cm, with tap water to neutral, namely obtains the microbe carrier stuffing of rural domestic sewage treatment;
E, be that the sludge sewage of 5000mg/L ~ 6500mg/L is seeded to the bio-filter bed reactor that the microbe carrier stuffing that step D obtains is housed by mixed genetic-neural network MLSS, pass into pending domestic sewage in rural areas and microbial nutrition is provided, gas blower aeration provides oxygen, and acclimated microorganism also makes it be attached to carrier filler biofilm; Wherein, active sludge: the volume ratio of pending domestic sewage in rural areas is (1 ~ 2): 1; Gas blower aeration provides oxygen to reach 2 ~ 4mg/L with the dissolved oxygen in water outlet and is as the criterion, and after 72 hours, carrier filler surface or Internal biological film are formed;
F, passes into pending domestic sewage in rural areas in bio-filter bed reactor, and sewage is flowed between filler particles, carries out sewage disposal, and sewage hydraulic detention time is in the reactor 6 ~ 10h, COD in the water outlet of detection reaction device crand NH 3-N concentration is lower than " urban wastewater treatment firm pollutant emission standard (GB18918-2002) " primary standard threshold value, and meanwhile, TP also has good removal effect;
Animal bone in described steps A is one or more arbitrary ratio things of Os Sus domestica, Os Bovis seu Bubali, Fishbone and sheep bone etc.
The main pollutant consistence of the pending domestic sewage in rural areas in described step F is respectively: COD cr200 ~ 400mg/L, NH 3-N20 ~ 40mg/L, TP3 ~ 13mg/L.
Feature of the present invention is:
1, present invention achieves the dry refuse of residents in rural community (animal bone in rubbish from cooking) and the coexistence of domestic sewage in rural areas is put, not only solve harmless treatment and the recycling problem of animal bone in the rubbish from cooking of rural area, and achieve the low cost of domestic sewage in rural areas, efficient treatment in situ, there is important practical value.
2, cheaper starting materials is easy to get, product safety is harmless and the advantage of easy to be filmed to utilize filler that in the rubbish from cooking of rural area, difficult degradation animal bone produces to have in the present invention.
3, utilize difficult degradation animal bone process domestic sewage in rural areas in the rubbish from cooking of rural area, technique is simple, and stable effluent quality, is convenient to Artificial Control and management.
Accompanying drawing explanation
Fig. 1 is present invention process schematic flow sheet.
Inlet and outlet water COD when Fig. 2 is embodiment 1 hydraulic detention time 8h crchange and removal effect.
Inlet and outlet water NH when Fig. 3 is embodiment 1 hydraulic detention time 8h 3-N change and removal effect.
When Fig. 4 is embodiment 1 hydraulic detention time 8h, Inlet and outlet water TP changes and removal effect.
Embodiment
Below in conjunction with embodiment and accompanying drawing, the present invention is described in further detail, but embodiments of the present invention are not limited thereto.
Embodiment 1
A, removes top layer kindred and impurity by the Os Sus domestica in the residents in rural community swill collected, then clean with tap water;
B, is that the animal bone of steps A is soaked 48h by the NaOH solution of 0.5% with mass percent concentration, removes top layer grease and come unstuck, and then cleans with tap water and repeatedly rinses repeatedly, dry, remove moisture at 80 DEG C;
C, the animal bone obtained by step B moves into retort furnace, is incubated 60min, then after its naturally cooling, shifts out retort furnace with the temperature rise rate of 5 DEG C/min under 400 DEG C of temperature condition;
D, it is 0.6 ~ 2cm particle diameter that the animal bone obtained by step C is crushed to scope, with tap water to neutral, namely obtains the microbe carrier stuffing of rural domestic sewage treatment;
E, use preferred to upflow type aerating biological filter reactor, the filler prepared by step D loads biological filter reactor cell body; The active sludge (mixed genetic-neural network MLSS is 5290mg/L) getting sewage treatment plants second pond is above-mentionedly equipped with in the biological filter reactor of the microbe carrier stuffing of step D, in active sludge to being equipped with: pending domestic sewage in rural areas=2:1 volume ratio ratio adds pending domestic sewage in rural areas (Pollutant levels COD cr: 244 ~ 398mg/L, NH 3-N:32 ~ 35mg/L, TP:3 ~ 10mg/L) originate as microbial nutrition, gas blower aeration is utilized to provide dissolved oxygen for microorganism, clear water zone, reactor top dissolved oxygen is kept to be 2 ~ 4mg/L, change the clear water in reactor every the pending domestic sewage in rural areas of 24h equivalent, start after 72h to enter pending domestic sewage in rural areas continuously;
F, passes into pending domestic sewage in rural areas in reactor, makes sewage continuous flow between filler particles, utilizes gas blower aeration to provide dissolved oxygen for microorganism, keeps reactor water outlet dissolved oxygen to be 2 ~ 4mg/L.Under hydraulic detention time 8h condition, carry out analyzing and testing to Inlet and outlet water water quality, result shows water outlet COD crconcentration is 31 ~ 50mg/L, water outlet NH 3-N concentration is 0.2 ~ 4mg/L, water outlet COD and NH 3-N concentration is all lower than " urban wastewater treatment firm pollutant emission standard (GB18918-2002) " one-level A level threshold value.Water outlet TP concentration is 1.7 ~ 2.0mg/L, lower than " urban wastewater treatment firm pollutant emission standard (GB18918-2002) " secondary standard threshold value.Inlet and outlet water COD cr, NH 3the concentration of-N and TP and removal effect thereof are respectively as shown in Figure 2, Figure 3 and Figure 4.
Embodiment 2
A, removes top layer kindred and impurity by the Os Sus domestica in the residents in rural community swill collected, then clean with tap water;
B, is that the animal bone of steps A is soaked 24h by the NaOH solution of 1% with mass percent concentration, removes top layer grease and come unstuck, and then cleans with tap water and repeatedly rinses repeatedly, dry, remove moisture at 60 DEG C;
C, the animal bone obtained by step B moves into retort furnace, is incubated 45min, then after its naturally cooling, shifts out retort furnace with the temperature rise rate of 5 DEG C/min under 500 DEG C of temperature condition;
D, it is 1 ~ 2cm particle diameter that the animal bone obtained by step C is crushed to scope, with tap water to neutral, namely obtains the microbe carrier stuffing of rural domestic sewage treatment;
E, use preferred to upflow type aerating biological filter reactor, the active sludge (MLSS is 6100mg/L) getting sewage treatment plants second pond is passed in the biological filter reactor of the microbe carrier stuffing that above-mentioned steps D is housed, in active sludge: pending domestic sewage in rural areas=2:1 volume ratio ratio adds pending domestic sewage in rural areas (Pollutant levels COD cr: 234 ~ 347mg/L, NH 3-N:32 ~ 35mg/L, TP:3 ~ 13mg/L) originate as microbial nutrition, gas blower aeration is utilized to provide dissolved oxygen for microorganism, clear water zone, reactor top dissolved oxygen is kept to be 2 ~ 4mg/L, change the clear water in reactor every the domestic sewage in rural areas of 24h equivalent, after 72h, start continuum micromeehanics;
F, passes into pending domestic sewage in rural areas in reactor, makes sewage continuous flow between filler particles, utilizes gas blower aeration to provide dissolved oxygen for microorganism, keeps reactor water outlet dissolved oxygen to be 2 ~ 4mg/L.Under hydraulic detention time 6h condition, carry out analyzing and testing to Inlet and outlet water water quality, result shows water outlet COD crconcentration is 21 ~ 51mg/L, water outlet NH 3-N concentration is 3 ~ 8mg/L, water outlet COD and NH 3-N concentration is all lower than " urban wastewater treatment firm pollutant emission standard (GB18918-2002) " one-level B standard threshold value.Water outlet TP concentration is 1.2 ~ 1.9mg/L, lower than " urban wastewater treatment firm pollutant emission standard (GB18918-2002) " secondary standard threshold value.

Claims (1)

1. in the rubbish from cooking of rural area, difficult degradation animal bone and sanitary sewage coexist a method of putting, and it is characterized in that:
A, sorts out the animal bone in the rubbish from cooking of rural area and removes its surface impurity, clean with tap water;
B, the animal bone 24 ~ 72h obtained with the NaOH solution soaking step A that concentration is 0.3 ~ 1% mass percent, remove top layer grease and come unstuck, and then cleans with tap water, dry at 60 ~ 80 DEG C, remove moisture;
C, the animal bone obtained by step B moves into retort furnace, under temperature rise rate is 5 ~ 10 DEG C/min, retort furnace is warming up to 300 ~ 500 DEG C, and insulation 30 ~ 60min, shifts out retort furnace by animal bone after its naturally cooling;
D, the animal bone obtained by step C is crushed to the irregularly shaped particles that particle diameter is 0.6 ~ 2cm, with tap water to neutral, namely obtains the microbe carrier stuffing of rural domestic sewage treatment;
E, be that the sludge sewage of 5000mg/L ~ 6500mg/L is seeded to the bio-filter bed reactor that the microbe carrier stuffing that step D obtains is housed by mixed genetic-neural network MLSS, pass into pending domestic sewage in rural areas and microbial nutrition is provided, gas blower aeration provides oxygen, and acclimated microorganism also makes it be attached to carrier filler biofilm; Wherein, active sludge: the volume ratio of pending domestic sewage in rural areas is (1 ~ 2): 1; Gas blower aeration provides oxygen to reach 2 ~ 4mg/L with the dissolved oxygen in water outlet and is as the criterion, and after 72 hours, carrier filler surface or Internal biological film are formed gradually;
F, passes into pending domestic sewage in rural areas in bio-filter bed reactor, and sewage is flowed between filler particles, carries out sewage disposal, and sewage hydraulic detention time is in the reactor 6 ~ 10h, COD in the water outlet of detection reaction device crand NH 3-N concentration is lower than " urban wastewater treatment firm pollutant emission standard GB18918-2002 " primary standard threshold value, and meanwhile, TP also has good removal effect;
Animal bone in described steps A is one or more arbitrary ratio things of Os Sus domestica, Os Bovis seu Bubali, Fishbone and sheep bone etc.;
The main pollutant consistence of domestic sewage in rural areas pending in described step F is respectively: COD cr200 ~ 400mg/L, NH 3-N20 ~ 40mg/L, TP3 ~ 13mg/L.
CN201610055014.2A 2016-01-27 2016-01-27 A kind of method that difficult degradation animal bone is put with sanitary sewage coexistence in rural area rubbish from cooking Expired - Fee Related CN105502639B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107626709A (en) * 2017-09-22 2018-01-26 南京律智诚专利技术开发有限公司 A kind of solar power generation mineralized waste packed bed
CN112158943A (en) * 2020-09-11 2021-01-01 同济大学 Biological drip device based on living source dry garbage filler and application thereof
CN117534217A (en) * 2023-12-07 2024-02-09 知和环保科技有限公司 Water body restoration method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1224623A (en) * 1998-12-21 1999-08-04 冶金工业部钢铁研究总院 Compounding method of bone morphogenesis protein to calcined bone
JP2005161135A (en) * 2003-11-28 2005-06-23 Best Tech:Kk Apparatus and method for advanced treatment of wastewater
CN101229946A (en) * 2007-12-29 2008-07-30 兰州大学 Biological aerated filter filtering material for treating sewage and preparation method thereof
CN103172168A (en) * 2013-02-04 2013-06-26 合肥工业大学 Biological aerated filter filler preparation method capable of simultaneously removing phosphorus and nitrogen, and application thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1224623A (en) * 1998-12-21 1999-08-04 冶金工业部钢铁研究总院 Compounding method of bone morphogenesis protein to calcined bone
JP2005161135A (en) * 2003-11-28 2005-06-23 Best Tech:Kk Apparatus and method for advanced treatment of wastewater
CN101229946A (en) * 2007-12-29 2008-07-30 兰州大学 Biological aerated filter filtering material for treating sewage and preparation method thereof
CN103172168A (en) * 2013-02-04 2013-06-26 合肥工业大学 Biological aerated filter filler preparation method capable of simultaneously removing phosphorus and nitrogen, and application thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107626709A (en) * 2017-09-22 2018-01-26 南京律智诚专利技术开发有限公司 A kind of solar power generation mineralized waste packed bed
CN112158943A (en) * 2020-09-11 2021-01-01 同济大学 Biological drip device based on living source dry garbage filler and application thereof
CN112158943B (en) * 2020-09-11 2022-07-19 同济大学 Biological trickling device based on living source dry garbage filler and application thereof
CN117534217A (en) * 2023-12-07 2024-02-09 知和环保科技有限公司 Water body restoration method

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