CN105500859A - High-viscosity self-adhesive protection film and preparation method thereof - Google Patents
High-viscosity self-adhesive protection film and preparation method thereof Download PDFInfo
- Publication number
- CN105500859A CN105500859A CN201510362230.7A CN201510362230A CN105500859A CN 105500859 A CN105500859 A CN 105500859A CN 201510362230 A CN201510362230 A CN 201510362230A CN 105500859 A CN105500859 A CN 105500859A
- Authority
- CN
- China
- Prior art keywords
- self
- adhesive
- layer
- protecting film
- prepared
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2007/00—Flat articles, e.g. films or sheets
- B29L2007/002—Panels; Plates; Sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2009/00—Layered products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
- B32B2250/246—All polymers belonging to those covered by groups B32B27/32 and B32B27/30
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/51—Elastic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/552—Fatigue strength
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/712—Weather resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/10—Homopolymers or copolymers of propene
- C08J2423/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Laminated Bodies (AREA)
Abstract
The invention discloses a high-viscosity self-adhesive protection film and a preparation method thereof. The high-viscosity self-adhesive protection film successively comprises a self-adhesive layer, a middle layer and an anti-stick back layer from top to bottom, and the anti-stick back layer is an anti-stick back layer added with an anti-stick master batch. In the high-viscosity self-adhesive protection film, the viscosity of the self-adhesive layer is high, and the anti-sticking back layer effectively prevents the self-adhesive layer from being bonded with the back layer when reeling is performed and facilitates unreeling, wherein the self-adhesive layer is prepared from modified SEBS and linear low-density polyethylene. The middle layer is prepared from linear low-density polyethylene and low-density polyethylene. The anti-stick back layer is prepared by selecting linear low-density polyethylene, low-density polyethylene and the anti-stick master batch. The added anti-stick master batch prevents the self-adhesive layer from being bonded with the back layer when reeling is performed, facilitates unreeling, and also guarantees that the self-adhesive film does not deform. The high-viscosity self-adhesive protection film does not need additional gluing and is easy to unreel, and during production, the film does not adhere to a roller and does not generate wrinkles or foams.
Description
Technical field
The invention belongs to co-extrusion self-adhesive film field, be specifically related to a kind of high sticky adhesive protecting film and preparation method thereof.
Background technology
Diaphragm divides by character can be divided into coating glue film and self-adhesive film; self-adhesive film is the abbreviation of tack diaphragm; be used for protecting the plastic sheeting of surperficial rapid wear; comparatively coating glue film; self-adhesive film has more advantage; as without cull, adhesion strength is stable, cost is low and profit is high, self-adhesive film becomes the main flow in market in recent years.According to the size of self-adhesive film viscosity, viscosity is divided into low sticky, high sticky, extra-high sticky self-adhesive film by 0.45N/25mm (25 DEG C) to 1.5N/25mm (25 DEG C) to 3.6N/25mm (25 DEG C).
Self-adhesive film is generally produce in the mode of co-extrusion, in one-time formed co-extrusion self-adhesive film field, because the difficulty of technique and formula is all comparatively large, can only make low viscous co-extrusion product at present.There are some problems in high sticky product in the market, and such as uncoiling is difficult, uncoiling power is poor, produces bubble etc., the phenomenons such as in process of production, viscous layer also there will be roll banding, fold, rolling foaming.
Summary of the invention
For the deficiencies in the prior art, an object of the present invention is to provide a kind of high sticky adhesive protecting film, and this height glues the easy uncoiling of adhesive protecting film, and not roll banding in production process, does not produce fold, foaming phenomena.
For reaching this object, the present invention by the following technical solutions:
A kind of high sticky adhesive protecting film, comprise self-adhesive layer, intermediate layer and antiseized backing layer from top to bottom successively, described antiseized backing layer is the antiseized backing layer that with the addition of anti-adhesion master batch.
Wherein, described anti-adhesion master batch by weight percentage, is prepared from by 85% ~ 95% polypropylene and 5% ~ 15% synthetic silica.
Anti-adhesion master batch is the masterbatch that the mixture of polypropylene and synthetic silica is prepared into, and extrudes, dry, pelletizing makes anti-adhesion master batch with masterbatch carrier polypropylene after fully being mixed by synthetic silica through extruder; The low price of synthetic silica, specific area is large, the anti-adhesion master batch anti-adhesion effects that is prepared into polypropylene is splendid.
Wherein, described self-adhesive layer by weight percentage, is prepared from by the modified SEBS of 80% ~ 90% and the LLDPE of 10% ~ 20%; Described intermediate layer by weight percentage, is prepared from by 75% ~ 85% LLDPE and 15% ~ 25% low density polyethylene (LDPE); Described antiseized backing layer by weight percentage, is prepared from by 65% ~ 75% LLDPE, 10% ~ 20% low density polyethylene (LDPE), 10% ~ 20% anti-adhesion master batch.
SEBS take polystyrene as end segment, and the ethylene-butene copolymer obtained with polybutadiene hydrogenation is the linear three embedding copolymers of middle spring block.SEBS containing unsaturated double-bond, does not therefore have good stability and resistance to ag(e)ing.SEBS has excellent ageing-resistant performance, both there is plasticity, again there is high resiliency, can use be processed without the need to sulfuration, leftover pieces can heavily use, and are widely used in and produce high-grade elastomer, modifying plastics, adhesive, lubricant tackifier, the inserts of electric wire and protective cover material etc.SEBS has the mechanical property of good weatherability, heat resistance, compression resistant morphotropism and excellence.In addition, the fusing point of SEBS is higher, can have more stable molten condition at high operating temperatures, can improve self-adhesive layer melt strength at high operating temperatures, avoids self-adhesive layer to be destroyed.
Preferably, modified SEBS is by SEBS and tackifying resin, Hydrogenated SBS, PE blending and modifying, obtains through kneading, preparation.Utilize modified SEBS to be made into the self-adhesive layer of different viscosities as required, be then covered on sheet material through subsequent machining technology, such as baking, bending, punching press etc., design the adhesive protecting film of different performance.
Polyethylene (POLYETHYLENE, PE) is the polymer formed by vinyl polymerization, and production development is existing about 60 years history so far, and global polyethylene production occupies first of five large general resins.Polyethylene, according to the difference of polymerization, molecular weight height, chain structure, is divided into high density polyethylene (HDPE), low density polyethylene (LDPE) and LLDPE.
Low density polyethylene (LDPE) (LOWDENSITYPOLYETHYLENE, LDPE) is commonly called as polyethylene from high pressure process, and because density is lower, material is the softest, is mainly used in plastic bag, film for agricultural use etc.
High density polyethylene (HDPE) (HIGHDENSITYPOLYETHYLENE, HDPE) low-pressure polyethylene is commonly called as, compare with LDPE and LLDPE, there are higher heatproof, oil resistivity, resistance to vapour permeability and environmental stress crack resistance, in addition electrical insulating property and impact resistance and cold tolerance fine, be mainly used in the field such as blowing, injection moulding.
Linear low density polyethylene (LLDPE) (LINEARLOWDENSITYPOLYETHYLENE, LLDPE) is then the copolymer that ethene and a small amount of high alpha-olefin are polymerized in the presence of a catalyst.The advantages such as LLDPE outward appearance is similar to LDPE, and the transparency is more poor, and lustrous surface is good, has low-temperature flexibility, high-modulus, counter-bending and stress cracking resistance, and under low temperature impact strength is better.
Preferably, the thickness of described self-adhesive layer is 4 ~ 8 μm, and the thickness in described intermediate layer is 20 ~ 50 μm, and the thickness of described antiseized backing layer is 4 ~ 8 μm.
Two of object of the present invention is the preparation method providing a kind of high sticky adhesive protecting film, for reaching this object, the present invention by the following technical solutions:
A preparation method for high sticky adhesive protecting film, detailed process is the material of self-adhesive layer, intermediate layer and antiseized backing layer is put into extruder to be prepared into described height by co-extrusion processing technology and to glue adhesive protecting film.
Wherein, described co-extrusion processing technology is specially: the material of self-adhesive layer, intermediate layer and antiseized backing layer is put into extruder and is extruded into die head; mould bubble is formed through blower fan blowout; mould bubble is pressed from both sides flat by entering herringbone row after the steady bubble frame roller of release treatment by nip rolls; then split through cutting knife after traction nip rolls drawing-off process; film after segmentation, by wind-up roll rolling, obtains described height and glues adhesive protecting film.
Wherein, the release treatment of described steady bubble frame roller for applying F-C paint on steady bubble frame roller.
Wherein, described traction nip rolls is silicon rubber nip rolls.
Compared with prior art, beneficial effect of the present invention is: a kind of high sticky adhesive protecting film, and comprise self-adhesive layer, intermediate layer and antiseized backing layer from top to bottom successively, described antiseized backing layer is the antiseized backing layer that with the addition of anti-adhesion master batch; Height of the present invention glues in adhesive protecting film, the viscosity of self-adhesive layer is large, when antiseized backing layer effectively prevents rolling, self-adhesive layer is to the bonding of backing layer, facilitate uncoiling, wherein, select modified SEBS and LLDPE to be prepared from self-adhesive layer, with LLDPE material for main component, add and to make after modified SEBS diaphragm have good tack stability and resistance to ag(e)ing and good processing characteristics; Intermediate layer selects LLDPE and low density polyethylene (LDPE) to be prepared from; Low density polyethylene (LDPE), because density is low, material is soft, mainly plays the object of adjustment processability; Antiseized backing layer selects LLDPE, low density polyethylene (LDPE) and anti-adhesion master batch to be prepared from, and the self-adhesive layer that to add when preventing rolling of anti-adhesion master batch is beneficial to uncoiling to the bonding of backing layer, ensures that self-adhesive film is indeformable simultaneously.Height of the present invention glues adhesive protecting film need not gluing in addition, easy uncoiling, and not roll banding in production process, does not produce fold, foaming phenomena.
Accompanying drawing explanation
Fig. 1 is the structural representation of a kind of high sticky adhesive protecting film of the present invention;
Fig. 2 is the structural representation of the production equipment of a kind of high sticky adhesive protecting film of prior art.
Reference numeral is as follows:
1-self-adhesive layer; 2-intermediate layer; The antiseized backing layer of 3-, 4-extruder; 5-blower fan; 6-surely steeps frame roller; 7-herringbone is arranged; 8-nip rolls; 9-draws nip rolls; 10-cutting knife; 11-wind-up roll.
Detailed description of the invention
Technical scheme of the present invention is further illustrated below by the drawings and specific embodiments.
As no specific instructions, various raw material of the present invention all can commercially availablely be buied, or prepares according to the conventional method of this area.
As shown in Figure 1, a kind of high sticky adhesive protecting film of the present invention, comprises self-adhesive layer 1, intermediate layer 2 from top to bottom successively and with the addition of the antiseized backing layer 3 of anti-adhesion master batch.
As shown in Figure 2; when producing high sticky self-adhesive film; the material of self-adhesive layer as above, intermediate layer, antiseized backing layer is put into extruder 4 and is extruded into die head; blow out through blower fan 5 and form mould bubble; mould bubble by the steady bubble frame roller 6 of release treatment through herringbone row 7 pressed from both sides by nip rolls 8 flat after after traction nip rolls 9 drawing-off process after cutting knife 10 is split by wind-up roll 11 rolling, obtain described height and glue adhesive protecting film.Wherein, steady bubble frame roller 6 applies the release treatment that F-C paint does steady bubble frame roller, and the anti-adhesion effects of F-C paint is good, can reduce the viscous force of self-adhesive film, avoid mould to steep shake and film wrinkling.Traction nip rolls 9 is silicon rubber nip rolls, and silicon rubber nip rolls can prevent the self-adhesive layer of self-adhesive film and the bonding of nip rolls, reduces tractive resistance, avoids the problem producing bubble, surface wrinkling.Technical scheme of the present invention is further illustrated below in conjunction with embodiment.
Embodiment 1
A kind of high sticky adhesive protecting film, comprise self-adhesive layer 1, intermediate layer 2 and antiseized backing layer 3 from top to bottom successively, antiseized backing layer 3 for the addition of the antiseized backing layer of anti-adhesion master batch, wherein, self-adhesive layer 1 by weight percentage, is prepared from by the modified SEBS of 85% and the LLDPE of 15%; 2 layers, centre by weight percentage, is prepared from by 80% LLDPE and 20% low density polyethylene (LDPE); Antiseized backing layer 3 by weight percentage, be prepared from by 70% LLDPE, 15% low density polyethylene (LDPE), 15% anti-adhesion master batch, anti-adhesion master batch by weight percentage, be prepared from by 85% polypropylene and 15% synthetic silica, the thickness of self-adhesive layer 1 is 4um, the thickness in intermediate layer 2 is 20um, and the thickness of antiseized backing layer 3 is 4um.
Embodiment 2
A kind of high sticky adhesive protecting film, comprise self-adhesive layer 1, intermediate layer 2 and antiseized backing layer 3 from top to bottom successively, antiseized backing layer 3 for the addition of the antiseized backing layer of anti-adhesion master batch, wherein, self-adhesive layer 1 by weight percentage, is prepared from by the modified SEBS of 90% and the LLDPE of 10%; Intermediate layer 2 by weight percentage, is prepared from by 85% LLDPE and 15% low density polyethylene (LDPE); Antiseized backing layer 3 by weight percentage, be prepared from by 65% LLDPE, 20% low density polyethylene (LDPE), 15% anti-adhesion master batch, anti-adhesion master batch by weight percentage, be prepared from by 90% polypropylene and 10% synthetic silica, the thickness of self-adhesive layer 1 is 6um, the thickness in intermediate layer 2 is 35um, and the thickness of antiseized backing layer 3 is 6um.
Embodiment 3
A kind of high sticky adhesive protecting film, comprise self-adhesive layer 1, intermediate layer 2 and antiseized backing layer 3 from top to bottom successively, antiseized backing layer 3 for the addition of the antiseized backing layer of anti-adhesion master batch, wherein, self-adhesive layer 1 by weight percentage, is prepared from by the modified SEBS of 80% and the LLDPE of 20%; Intermediate layer 2 by weight percentage, is prepared from by 75% LLDPE and 25% low density polyethylene (LDPE); Antiseized backing layer 3 by weight percentage, be prepared from by 75% LLDPE, 10% low density polyethylene (LDPE), 15% anti-adhesion master batch, anti-adhesion master batch by weight percentage, be prepared from by 90% polypropylene and 10% synthetic silica, the thickness of self-adhesive layer 1 is 8um, the thickness in intermediate layer 2 is 50um, and the thickness of antiseized backing layer 3 is 8um.
The present invention is by improving the formula of high sticky self-adhesive film, modified SEBS is with the addition of in self-adhesive film, anti-adhesion master batch is with the addition of in antiseized backing layer, the height of production is made to glue self-adhesive film not roll banding, facilitate uncoiling, do not produce the problem that fold bubbles in production process, in addition, the preparation method of the sticky self-adhesive film of this height is simple, is beneficial to operation.
Applicant states, the present invention illustrates detailed process equipment and process flow process of the present invention by above-described embodiment, but the present invention is not limited to above-mentioned detailed process equipment and process flow process, namely do not mean that the present invention must rely on above-mentioned detailed process equipment and process flow process and could implement.Person of ordinary skill in the field should understand, any improvement in the present invention, to equivalence replacement and the interpolation of auxiliary element, the concrete way choice etc. of each raw material of product of the present invention, all drops within protection scope of the present invention and open scope.
Claims (9)
1. one kind high sticky adhesive protecting film; it is characterized in that; comprise self-adhesive layer (1), intermediate layer (2) and antiseized backing layer (3) from top to bottom successively, described antiseized backing layer (3) is for the addition of the antiseized backing layer of anti-adhesion master batch.
2. a kind of high sticky adhesive protecting film according to claim 1, it is characterized in that, described anti-adhesion master batch by weight percentage, is prepared from by 85% ~ 95% polypropylene and 5% ~ 15% synthetic silica.
3. a kind of high sticky adhesive protecting film according to claim 1, it is characterized in that, described self-adhesive layer (1) by weight percentage, is prepared from by the modified SEBS of 80% ~ 90% and the LLDPE of 10% ~ 20%;
Described intermediate layer (2) by weight percentage, is prepared from by 75% ~ 85% LLDPE and 15% ~ 25% low density polyethylene (LDPE);
Described antiseized backing layer (3) by weight percentage, is prepared from by 65% ~ 75% LLDPE, 10% ~ 20% low density polyethylene (LDPE), 10% ~ 20% anti-adhesion master batch.
4. a kind of high sticky adhesive protecting film according to claim 1, is characterized in that, described modified SEBS is that SEBS and tackifying resin, Hydrogenated SBS, PE blending and modifying obtain.
5. a kind of high sticky adhesive protecting film according to claim 1; it is characterized in that; the thickness of described self-adhesive layer (1) is 4 ~ 8 μm, and the thickness of described intermediate layer (2) is 20 ~ 50 μm, and the thickness of described antiseized backing layer (3) is 4 ~ 8 μm.
6. one kind is glued the preparation method of adhesive protecting film as the height in Claims 1 to 5 as described in any one; it is characterized in that, the material of self-adhesive layer (1), intermediate layer (2) and antiseized backing layer (3) is put into extruder (4) and be prepared into described height by co-extrusion processing technology and glue adhesive protecting film.
7. the preparation method of a kind of high sticky adhesive protecting film according to claim 6, it is characterized in that, described co-extrusion processing technology is specially: by self-adhesive layer (1), the material of intermediate layer (2) and antiseized backing layer (3) is put into extruder (4) and is extruded into die head, mould bubble is formed through blower fan (5) blowout, mould bubble is by after the steady bubble frame roller (6) of release treatment, entering herringbone row (7) is pressed from both sides flat by nip rolls (8), then split through cutting knife (10) after traction nip rolls (9) drawing-off process, film after segmentation is by wind-up roll (11) rolling, obtain described height and glue adhesive protecting film.
8. the preparation method of a kind of high sticky adhesive protecting film according to claim 7, is characterized in that, the release treatment of described steady bubble frame roller (6) for applying F-C paint on steady bubble frame roller (6).
9. the preparation method of a kind of high sticky adhesive protecting film according to claim 7, is characterized in that, described traction nip rolls (9) is silicon rubber nip rolls.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510362230.7A CN105500859A (en) | 2015-06-26 | 2015-06-26 | High-viscosity self-adhesive protection film and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510362230.7A CN105500859A (en) | 2015-06-26 | 2015-06-26 | High-viscosity self-adhesive protection film and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105500859A true CN105500859A (en) | 2016-04-20 |
Family
ID=55709333
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510362230.7A Pending CN105500859A (en) | 2015-06-26 | 2015-06-26 | High-viscosity self-adhesive protection film and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105500859A (en) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106010328A (en) * | 2016-05-05 | 2016-10-12 | 佛山市顺元塑胶制品有限公司 | Deep stamping oil-resistant multilayer co-extrusion type protective film |
| CN106432868A (en) * | 2016-09-19 | 2017-02-22 | 无锡市速达电讯材料有限公司 | Self-adhesive film formula and preparation technology |
| CN107418486A (en) * | 2017-08-07 | 2017-12-01 | 无锡市三力胶带有限公司 | Adhesive protecting film and preparation method thereof |
| CN109054670A (en) * | 2018-09-05 | 2018-12-21 | 安徽新恒辉反光材料有限公司 | A kind of reflectorized material surface protection film and its manufacturing process |
| CN109228287A (en) * | 2018-10-12 | 2019-01-18 | 佛山市运通晨塑料助剂有限公司 | The environmentally protective not trace PE adhesive protecting film masterbatch of one kind and its production method |
| CN109401002A (en) * | 2018-09-26 | 2019-03-01 | 天津泽恒包装制品有限公司 | A kind of PE high glues the preparation method of protective film masterbatch |
| CN109605886A (en) * | 2018-11-15 | 2019-04-12 | 永新股份（黄山）包装有限公司 | A kind of high-temperature resistant nano grade tack optical protection layer and its production method |
| CN110229630A (en) * | 2019-06-17 | 2019-09-13 | 湖北慧狮塑业股份有限公司 | It is a kind of for thin plate and the heatproof adhesive protecting film of sheet material |
| CN110964452A (en) * | 2019-11-21 | 2020-04-07 | 佛山市顺元塑胶制品有限公司 | Deep-drawing-resistant PE self-adhesion stainless steel protective film |
| CN111253879A (en) * | 2020-02-17 | 2020-06-09 | 佛山市顺元塑胶制品有限公司 | Low-unwinding-force polyethylene low-viscosity protective film and preparation method thereof |
| CN111284099A (en) * | 2020-03-24 | 2020-06-16 | 佛山市顺元塑胶制品有限公司 | PE self-adhesive protective film for elevator and preparation method thereof |
| CN111361120A (en) * | 2017-12-22 | 2020-07-03 | 福建恒安家庭生活用品有限公司 | Preparation method of soft base film based on SBS elastomer |
| CN111925738A (en) * | 2020-08-12 | 2020-11-13 | 佛山(华南)新材料研究院 | Easy-to-unwind self-adhesive protective film and preparation method thereof |
| CN112430436A (en) * | 2020-10-21 | 2021-03-02 | 永生运佳(宣城)薄膜科技有限公司 | High-viscosity easy-to-unwind self-adhesive protective film |
| CN115491146A (en) * | 2022-02-21 | 2022-12-20 | 广东东立新材料科技股份有限公司 | Ultrahigh temperature-resistant plastic suction forming protective film and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101679816A (en) * | 2007-05-31 | 2010-03-24 | 出光统一科技株式会社 | Surface protective film |
| JP2011231335A (en) * | 2004-12-07 | 2011-11-17 | Mitsui Chemicals Tohcello Inc | Adhesive film |
| CN103865421A (en) * | 2010-03-31 | 2014-06-18 | 东丽薄膜先端加工股份有限公司 | Surface protection film |
| CN104118118A (en) * | 2014-07-07 | 2014-10-29 | 武汉新中德塑机股份有限公司 | High-viscosity self-adhesive film production device |
| CN104140768A (en) * | 2013-05-10 | 2014-11-12 | 鸿威光电股份有限公司 | Protection film |
| CN104220548A (en) * | 2012-04-10 | 2014-12-17 | 东洋纺株式会社 | Self-adhesive surface protection film |
| CN104685017A (en) * | 2012-10-05 | 2015-06-03 | 东洋纺株式会社 | Self-adhesive surface protection film |
| CN204820560U (en) * | 2015-06-26 | 2015-12-02 | 宝丽菲姆保护膜（苏州）有限公司 | Height glues self -adhesion protection film |
-
2015
- 2015-06-26 CN CN201510362230.7A patent/CN105500859A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011231335A (en) * | 2004-12-07 | 2011-11-17 | Mitsui Chemicals Tohcello Inc | Adhesive film |
| CN101679816A (en) * | 2007-05-31 | 2010-03-24 | 出光统一科技株式会社 | Surface protective film |
| CN103865421A (en) * | 2010-03-31 | 2014-06-18 | 东丽薄膜先端加工股份有限公司 | Surface protection film |
| CN104220548A (en) * | 2012-04-10 | 2014-12-17 | 东洋纺株式会社 | Self-adhesive surface protection film |
| CN104685017A (en) * | 2012-10-05 | 2015-06-03 | 东洋纺株式会社 | Self-adhesive surface protection film |
| CN104140768A (en) * | 2013-05-10 | 2014-11-12 | 鸿威光电股份有限公司 | Protection film |
| CN104118118A (en) * | 2014-07-07 | 2014-10-29 | 武汉新中德塑机股份有限公司 | High-viscosity self-adhesive film production device |
| CN204820560U (en) * | 2015-06-26 | 2015-12-02 | 宝丽菲姆保护膜（苏州）有限公司 | Height glues self -adhesion protection film |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106010328A (en) * | 2016-05-05 | 2016-10-12 | 佛山市顺元塑胶制品有限公司 | Deep stamping oil-resistant multilayer co-extrusion type protective film |
| CN106432868A (en) * | 2016-09-19 | 2017-02-22 | 无锡市速达电讯材料有限公司 | Self-adhesive film formula and preparation technology |
| CN107418486A (en) * | 2017-08-07 | 2017-12-01 | 无锡市三力胶带有限公司 | Adhesive protecting film and preparation method thereof |
| CN111361119A (en) * | 2017-12-22 | 2020-07-03 | 福建恒安家庭生活用品有限公司 | Preparation method of soft base membrane based on SEBS (styrene-ethylene-butadiene-styrene) elastomer |
| CN111361122A (en) * | 2017-12-22 | 2020-07-03 | 福建恒安家庭生活用品有限公司 | Preparation method of soft base membrane based on SIS elastomer |
| CN111361120A (en) * | 2017-12-22 | 2020-07-03 | 福建恒安家庭生活用品有限公司 | Preparation method of soft base film based on SBS elastomer |
| CN109054670A (en) * | 2018-09-05 | 2018-12-21 | 安徽新恒辉反光材料有限公司 | A kind of reflectorized material surface protection film and its manufacturing process |
| CN109401002A (en) * | 2018-09-26 | 2019-03-01 | 天津泽恒包装制品有限公司 | A kind of PE high glues the preparation method of protective film masterbatch |
| CN109228287A (en) * | 2018-10-12 | 2019-01-18 | 佛山市运通晨塑料助剂有限公司 | The environmentally protective not trace PE adhesive protecting film masterbatch of one kind and its production method |
| CN109605886A (en) * | 2018-11-15 | 2019-04-12 | 永新股份（黄山）包装有限公司 | A kind of high-temperature resistant nano grade tack optical protection layer and its production method |
| CN110229630A (en) * | 2019-06-17 | 2019-09-13 | 湖北慧狮塑业股份有限公司 | It is a kind of for thin plate and the heatproof adhesive protecting film of sheet material |
| CN110964452A (en) * | 2019-11-21 | 2020-04-07 | 佛山市顺元塑胶制品有限公司 | Deep-drawing-resistant PE self-adhesion stainless steel protective film |
| CN110964452B (en) * | 2019-11-21 | 2021-12-10 | 佛山市顺元塑胶制品有限公司 | Deep-drawing-resistant PE self-adhesion stainless steel protective film |
| CN111253879A (en) * | 2020-02-17 | 2020-06-09 | 佛山市顺元塑胶制品有限公司 | Low-unwinding-force polyethylene low-viscosity protective film and preparation method thereof |
| CN111253879B (en) * | 2020-02-17 | 2022-02-11 | 佛山市顺元塑胶制品有限公司 | Low-unwinding-force polyethylene low-viscosity protective film and preparation method thereof |
| CN111284099A (en) * | 2020-03-24 | 2020-06-16 | 佛山市顺元塑胶制品有限公司 | PE self-adhesive protective film for elevator and preparation method thereof |
| CN111925738A (en) * | 2020-08-12 | 2020-11-13 | 佛山(华南)新材料研究院 | Easy-to-unwind self-adhesive protective film and preparation method thereof |
| CN111925738B (en) * | 2020-08-12 | 2022-04-29 | 佛山(华南)新材料研究院 | Easy-to-unwind self-adhesive protective film and preparation method thereof |
| CN112430436A (en) * | 2020-10-21 | 2021-03-02 | 永生运佳(宣城)薄膜科技有限公司 | High-viscosity easy-to-unwind self-adhesive protective film |
| CN115491146A (en) * | 2022-02-21 | 2022-12-20 | 广东东立新材料科技股份有限公司 | Ultrahigh temperature-resistant plastic suction forming protective film and preparation method thereof |
| CN115491146B (en) * | 2022-02-21 | 2023-12-12 | 广东东立新材料科技股份有限公司 | Ultrahigh temperature-resistant plastic-suction forming protective film and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105500859A (en) | High-viscosity self-adhesive protection film and preparation method thereof | |
| CN104354414B (en) | A kind of high-temperature resisting clean type self-adhesion protective film and preparation method thereof | |
| CA2975863C (en) | Hydrogenated block copolymer | |
| CN106827751B (en) | A kind of environment-friendly type automobile inner decoration composite material and preparation method | |
| CN104497900B (en) | A kind of adhesive protecting film and the application in bonding protection bright finish PC plate thereof | |
| CN104039877B (en) | Foamed polyolefin resin sheet material, its manufacture method, and application thereof | |
| JP3154931B2 (en) | Embossed sheet, laminate using the same, and method of manufacturing the same | |
| CN108481855B (en) | Low-heat-seal-strength polyethylene film and preparation method thereof | |
| CN103568386B (en) | Multilayer film for flexible package | |
| CN205024142U (en) | High temperature resistant self -adhesion protection film | |
| CN108638614A (en) | The manufacturing method of laminated glass | |
| CN108473638A (en) | Hydrogenated copolymer, composition and formed body | |
| CN102051018A (en) | Thermoplastic elastomer for being subjected to secondary injection adhesion with PBT (polybutylene terephthalate) material and composite molding product using same | |
| CN106393750A (en) | Integrated forming technology of macromolecular sheet production and gluing | |
| CN107531034B (en) | Multilayer film and preparation method thereof | |
| CN102470652B (en) | Surface protection film | |
| CN106827746A (en) | A kind of multi-layer co-extruded compound mould release membrance | |
| JP2017105171A (en) | Laminate foam sheet and thermal molded body | |
| CN107201187A (en) | A kind of macromolecule water-proof sheet material production technology | |
| CN110964452B (en) | Deep-drawing-resistant PE self-adhesion stainless steel protective film | |
| US5540983A (en) | Conveyor belts derived from compositions comprising vinyl aromatic-conjugated diene block copolymers | |
| CN204820560U (en) | Height glues self -adhesion protection film | |
| CN201587630U (en) | Extinction blocking five-layer coextruded composite film | |
| CN104062698A (en) | Production method for high-intensity reflective films | |
| CN104140768A (en) | Protection film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160420 |