CN105496798B - A kind of powder filled hydrogel and its preparation and application - Google Patents
A kind of powder filled hydrogel and its preparation and application Download PDFInfo
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- CN105496798B CN105496798B CN201511002826.2A CN201511002826A CN105496798B CN 105496798 B CN105496798 B CN 105496798B CN 201511002826 A CN201511002826 A CN 201511002826A CN 105496798 B CN105496798 B CN 105496798B
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- 239000000843 powder Substances 0.000 title claims abstract description 203
- 239000000017 hydrogel Substances 0.000 title claims abstract description 111
- 238000002360 preparation method Methods 0.000 title claims description 7
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229920002125 Sokalan® Polymers 0.000 claims abstract description 17
- 239000000661 sodium alginate Substances 0.000 claims abstract description 17
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 17
- 229940005550 sodium alginate Drugs 0.000 claims abstract description 17
- 239000002904 solvent Substances 0.000 claims abstract description 17
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229960001631 carbomer Drugs 0.000 claims abstract description 13
- 239000002537 cosmetic Substances 0.000 claims abstract description 12
- 238000002156 mixing Methods 0.000 claims abstract description 10
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims abstract description 10
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims abstract description 10
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical group O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 38
- 239000008367 deionised water Substances 0.000 claims description 31
- 229910021641 deionized water Inorganic materials 0.000 claims description 31
- 238000003756 stirring Methods 0.000 claims description 16
- 239000000725 suspension Substances 0.000 claims description 16
- 241000220317 Rosa Species 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 241001116389 Aloe Species 0.000 claims description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 235000011399 aloe vera Nutrition 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 235000008599 Poria cocos Nutrition 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 7
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 150000001413 amino acids Chemical class 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 4
- 239000005543 nano-size silicon particle Substances 0.000 claims description 4
- 239000004584 polyacrylic acid Substances 0.000 claims description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- 239000003906 humectant Substances 0.000 claims description 3
- 239000008271 cosmetic emulsion Substances 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims 1
- 241001619444 Wolfiporia cocos Species 0.000 claims 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 abstract description 30
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 abstract description 6
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 abstract description 6
- 229920006243 acrylic copolymer Polymers 0.000 abstract description 2
- 239000000499 gel Substances 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 description 29
- 238000009472 formulation Methods 0.000 description 28
- 238000013112 stability test Methods 0.000 description 15
- 238000013019 agitation Methods 0.000 description 14
- 238000004140 cleaning Methods 0.000 description 14
- 238000013517 stratification Methods 0.000 description 14
- 239000003795 chemical substances by application Substances 0.000 description 12
- 241000213006 Angelica dahurica Species 0.000 description 8
- 244000197580 Poria cocos Species 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 7
- 241000196324 Embryophyta Species 0.000 description 6
- 230000001953 sensory effect Effects 0.000 description 6
- 239000002253 acid Substances 0.000 description 3
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 3
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 3
- 230000002087 whitening effect Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- -1 hydroxylmethyl Chemical group 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 210000003491 skin Anatomy 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- POJWUDADGALRAB-PVQJCKRUSA-N Allantoin Natural products NC(=O)N[C@@H]1NC(=O)NC1=O POJWUDADGALRAB-PVQJCKRUSA-N 0.000 description 1
- 201000004384 Alopecia Diseases 0.000 description 1
- 241000125175 Angelica Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 206010010904 Convulsion Diseases 0.000 description 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 235000001287 Guettarda speciosa Nutrition 0.000 description 1
- 208000003351 Melanosis Diseases 0.000 description 1
- 244000246386 Mentha pulegium Species 0.000 description 1
- 235000016257 Mentha pulegium Nutrition 0.000 description 1
- 235000004357 Mentha x piperita Nutrition 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 229930003268 Vitamin C Natural products 0.000 description 1
- 208000000260 Warts Diseases 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 229960000458 allantoin Drugs 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229930014669 anthocyanidin Natural products 0.000 description 1
- 150000001452 anthocyanidin derivatives Chemical class 0.000 description 1
- 235000008758 anthocyanidins Nutrition 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 230000019522 cellular metabolic process Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 230000036461 convulsion Effects 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 150000007946 flavonol Chemical class 0.000 description 1
- HVQAJTFOCKOKIN-UHFFFAOYSA-N flavonol Natural products O1C2=CC=CC=C2C(=O)C(O)=C1C1=CC=CC=C1 HVQAJTFOCKOKIN-UHFFFAOYSA-N 0.000 description 1
- 235000011957 flavonols Nutrition 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 208000024963 hair loss Diseases 0.000 description 1
- 230000003676 hair loss Effects 0.000 description 1
- 235000001050 hortel pimenta Nutrition 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000008338 local blood flow Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002398 materia medica Substances 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 210000004927 skin cell Anatomy 0.000 description 1
- 201000010153 skin papilloma Diseases 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/042—Gels
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/733—Alginic acid; Salts thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/98—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin
- A61K8/987—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin of species other than mammals or birds
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/10—General cosmetic use
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
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Abstract
The present invention discloses a kind of powder filled hydrogel, and the powder filled hydrogel is made of the raw material of following quality proportioning：0.5 part of powder, 0.05~0.5 part of gelator, 5~20 parts of solvent；The powder includes Plant Powder, pearl powder and inorganic particulate used for cosmetic used for cosmetic；The gelator is the mixing of one or both of Sodium Polyacrylate, sodium carboxymethylcellulose, sodium cellulose glycolate, acrylic copolymer, sodium alginate, carbomer or more；Gelator non-toxic and safe of the present invention, it is cheap and pollution-free, be conducive to the popularization and application of gel products of the present invention；Powder filled hydrogel stability of the present invention is good, not stratified, easy to maintain, easy to be absorbed, smears and feel, and cosmetic field can be widely used in.
Description
(1) technical field
The present invention relates to a kind of powder filled hydrogel, more particularly to a kind of powder filled hydrogel used for cosmetic and its system
It is standby with application.
(2) background technology
Pearl powder and natural vegetable powder possess excellent skin whitening effects, are increasingly welcome by consumer.
Modern research shows that pearl powder improve the immunity of the human body, slow down aging, freckle removing and whitening, supplement calcium etc. all have it is only
Special effect.《Pharmacopoeia of People's Republic of China》And《Dictionary of medicinal plant》Indicate：Pearl have calm the nerves arresting convulsion, shade removing,
Solve taking poison and growing muscle due and other effects.Can the natural vegetable powder of whitening have rose powder, aloe powder, angelica dahurica powder, Poria cocos powder etc..Rose powder is rich in people
Amino acid, protein, organic acid vitamin C etc. needed for body, and containing three big abundant rare elements:Natural anthocyanidin, natural class
Flavonol, natural total polyphenols.And aloe powder has treatment whelk and swollen wart, slows down aging, hair care prevents white hair and the work of hair loss
With.Angelica dahurica powder can improve local blood circulation, eliminate pigment excess accumulation in the tissue, promote skin cell metabolism, into
And have the function that beauty,《Compendium of Materia Medica》Call the root of Dahurain angelica " long skin, color of moistening, face fat can be made ".
At present about there are mainly two types of the application methods of pearl powder or Plant Powder：One, consumer is about to pearl powder or plant certainly
Object powder is used with water or Essence collocation；Two, by pearl powder or Plant Powder and water and EDTA-Na2, allantoin, glycerine, the third two
The auxiliary agents such as alcohol, peppermint, rose, amino acid humectant directly mix, and obtain the mixing paste solidifying body containing solid powder
Directly use.Method one cannot be satisfied consumer to product using simple and efficiently demand, paste prepared by method two solidify
Body usually have the shortcomings that bad stability, easy layering, it is not easy to maintain, be not easy to absorb, smear and feel bad.The present invention is directed to above-mentioned skill
Art problem has designed and developed a kind of preparation method of the novel powder filled hydrogel for cosmetic use.
(3) invention content
The invention aims to solve existing pearl powder or Plant Powder filling obtain paste solidifying body stability it is bad,
Easily layering, it is not easy to maintain, be not easy to absorb, smear the problems such as sense is bad, the present invention provides it is a kind of it is novel be used for it is used for cosmetic
The powder filled hydrogel on way and the preparation method and application thereof, can be widely applied to cosmetic field.
The technical solution adopted by the present invention is：
The present invention provides a kind of powder filled hydrogel, the powder filled hydrogel by following quality proportioning raw material group
At：0.5 part of powder, 0.05~0.5 part of gelator, 5~20 parts of solvent；
The powder includes Plant Powder, pearl powder and inorganic particulate used for cosmetic used for cosmetic；
The gelator is Sodium Polyacrylate, sodium carboxymethylcellulose, sodium cellulose glycolate, polyacrylic acid copolymerized
The mixing of one or both of object, sodium alginate, carbomer or more；
The solvent is deionized water or Essence；The Essence used for cosmetic that the Essence is known in the art, it is excellent
Quality group is selected to become：76.8 parts of deionized water, 6 parts of glycerine, 10 parts of propylene glycol, 3 parts of polyacrylic acid, 0.2 part of rose and ammonia
4 parts of base acid moisturizer.
Further, the diameter of particle is 2000~3000 mesh.
Further, the powder is pearl powder, rose powder, aloe powder, angelica dahurica powder, Poria cocos powder, nano-calcium carbonate or nanometer
One kind in silica.
Further, the gelator is one of following：Sodium Polyacrylate, sodium carboxymethylcellulose, hydroxymethyl cellulose
Sodium, acrylic copolymer, sodium alginate；The Sodium Polyacrylate molecular weight is 4,000,000-500 ten thousand, described polyacrylic acid copolymerized
Object molecular weight is 2,000,000-300 ten thousand.
Further, the gelator is one of following：(1) sodium alginate and carbomer mass ratio 2：1 mixing；(2)
Sodium alginate and carbomer mass ratio 2：1 mixing；(3) sodium alginate and Sodium Polyacrylate mass ratio 2：1 mixing.The card
Wave nurse is Acritamer 940.
Further, the powder filled hydrogel is made of the raw material of following quality proportioning：0.5 part of powder, gelator
0.1~0.3 part, 10 parts of solvent.
The present invention also provides a kind of preparation method of the powder filled hydrogel, the method is：By formula ratio, by powder
Suspension is made in the dissolving of body solvent, stirs evenly, and gelator is added, ultrasonic disperse is uniform, obtains powder filled hydrogel.
Further, the supersonic frequency is 40KHz, 10~30min of ultrasonic time.
The present invention also provides a kind of application of powder filled hydrogel in preparing cosmetic emulsion.
Pearl powder, rose powder, aloe powder, angelica dahurica powder, Poria cocos powder are all made of airflow pulverization method in powder of the present invention
It prepares.
Compared with prior art, the present invention has the advantages that：
1, gelator non-toxic and safe of the present invention, it is cheap and pollution-free, be conducive to gel production of the present invention
The popularization and application of product.
2, powder filled hydrogel stability of the present invention is good, not stratified, easy to maintain, easy absorbs, smears and feel, this hair
Bright powder filled hydrogel can be widely used in cosmetic field in 4000r/min centrifugations 10min without apparent lamination.
(4) specific implementation mode
With reference to specific embodiment, the present invention is described further, but protection scope of the present invention is not limited in
This：
Essence quality group described in the embodiment of the present invention becomes：76.8 parts of deionized water, 10 parts of propylene glycol, is gathered 6 parts of glycerine
4 parts of 3 parts of acrylic acid, 0.2 part of rose and amino acid humectant.
Stability test centrifugal rotational speed 4000r/min described in the embodiment of the present invention, system is not stratified, then has guarantee the quality within 1~2 year
Phase.
Embodiment 1：
(1) powder filled hydrogel formulation 1：Pearl powder 0.5g (2000~3000 mesh of grain size), sodium cellulose glycolate
0.3g, deionized water 10g.
(2) powder filled hydrogel formulation 2：Pearl powder 0.5g (2000~3000 mesh of grain size), sodium cellulose glycolate
0.3g, Essence 10g.
(3) prepared by powder filled hydrogel：According to formula ratio, use deionized water and Essence as molten pearl powder respectively
Agent configures pearl powder suspension, and formula ratio gelator sodium cellulose glycolate is added in magnetic agitation, and it is small to continue stirring 1
When.Then by hydrogel, (40KHz) is 20 minutes ultrasonic in sonic cleaning device, obtains powder filled hydrogel.
Stability test：Powder filled hydrogel is centrifuged on centrifuge, centrifuges 10min, rotating speed 4000r/min, is seen
Examine its degeee of stratification.
Embodiment 2：
(1) powder filled hydrogel formulation 1：Aloe powder 0.5g (2000~3000 mesh of grain size), sodium cellulose glycolate
0.3g, deionized water 10g.
(2) powder filled hydrogel formulation 2：Aloe powder 0.5g (2000~3000 mesh of grain size), sodium cellulose glycolate
0.3g, Essence 10g.
(3) prepared by powder filled hydrogel：According to formula ratio, use deionized water and Essence as molten aloe powder respectively
Agent configures aloe powder suspension, and formula ratio gelator sodium cellulose glycolate is added in magnetic agitation, and it is small to continue stirring 1
When.Then by hydrogel, (40KHz) is 20 minutes ultrasonic in sonic cleaning device, obtains powder filled hydrogel.
Stability test：Powder filled hydrogel is centrifuged on centrifuge, centrifuges 10min, rotating speed 4000r/min, is seen
Examine its degeee of stratification.
Embodiment 3：
(1) powder filled hydrogel formulation 1：Rose powder 0.5g (2000~3000 mesh of grain size), sodium cellulose glycolate
0.3g, deionized water 10g.
(2) powder filled hydrogel formulation 2：Rose powder 0.5g (2000~3000 mesh of grain size), sodium cellulose glycolate
0.3g, Essence 10g.
(3) prepared by powder filled hydrogel：According to formula ratio, use deionized water and Essence as molten in rose powder respectively
Agent configures rose powder suspension, and formula ratio gelator sodium cellulose glycolate is added in magnetic agitation, and it is small to continue stirring 1
When.Then by hydrogel, (40KHz) is 20 minutes ultrasonic in sonic cleaning device, obtains powder filled hydrogel.
Stability test：Powder filled hydrogel is centrifuged on centrifuge, centrifuges 10min, rotating speed 4000r/min, is seen
Examine its degeee of stratification.
Embodiment 4：
(1) powder filled hydrogel formulation 1：Angelica dahurica powder 0.5g (2000~3000 mesh of grain size), sodium cellulose glycolate
0.3g, deionized water 10g.
(2) powder filled hydrogel formulation 2：Angelica dahurica powder 0.5g (2000~3000 mesh of grain size), sodium cellulose glycolate
0.3g, Essence 10g.
(3) prepared by powder filled hydrogel：According to formula ratio, use deionized water and Essence as molten angelica dahurica powder respectively
Agent configures angelica dahurica powder suspension, and formula ratio gelator sodium cellulose glycolate is added in magnetic agitation, and it is small to continue stirring 1
When.Then by hydrogel, (40KHz) is 20 minutes ultrasonic in sonic cleaning device, obtains powder filled hydrogel.
Stability test：Powder filled hydrogel is centrifuged on centrifuge, centrifuges 10min, rotating speed 4000r/min, is seen
Examine its degeee of stratification.
Embodiment 5：
(1) powder filled hydrogel formulation 1：Poria cocos powder 0.5g (2000~3000 mesh of grain size), sodium cellulose glycolate
0.3g, deionized water 10g.
(2) powder filled hydrogel formulation 2：Poria cocos powder 0.5g (2000~3000 mesh of grain size), sodium cellulose glycolate
0.3g, Essence 10g.
(3) prepared by powder filled hydrogel：According to formula ratio, use deionized water and Essence as molten Poria cocos powder respectively
Agent configures Poria cocos powder suspension, and formula ratio gelator sodium cellulose glycolate is added in magnetic agitation, and it is small to continue stirring 1
When.Then by hydrogel, (40KHz) is 20 minutes ultrasonic in sonic cleaning device, obtains powder filled hydrogel.
Stability test：Powder filled hydrogel is centrifuged on centrifuge, centrifuges 10min, rotating speed 4000r/min, is seen
Examine its degeee of stratification.
Embodiment 6：
(1) powder filled hydrogel formulation 1：Nano-calcium carbonate 0.5g (2000~3000 mesh of grain size), hydroxymethyl cellulose
Sodium 0.3g, deionized water 10g.
(2) powder filled hydrogel formulation 2：Nano-calcium carbonate 0.5g (2000~3000 mesh of grain size), hydroxymethyl cellulose
Sodium 0.3g, Essence 10g.
(3) prepared by powder filled hydrogel：According to formula ratio, nano-calcium carbonate deionized water and Essence are made respectively
Nano calcium carbonate suspension is configured for solvent, formula ratio gelator sodium cellulose glycolate is added in magnetic agitation, is continued
Stirring 1 hour.Then by hydrogel, (40KHz) is 20 minutes ultrasonic in sonic cleaning device, obtains powder filled hydrogel.
Stability test：Powder filled hydrogel is centrifuged on centrifuge, centrifuges 10min, rotating speed 4000r/min, is seen
Examine its degeee of stratification.
Embodiment 7：
(1) powder filled hydrogel formulation 1：Nano silicon dioxide 0.5g (2000~3000 mesh of grain size), hydroxylmethyl cellulose
Plain sodium 0.3g, deionized water 10g.
(2) powder filled hydrogel formulation 2：Nano silicon dioxide 0.5g (2000~3000 mesh of grain size), hydroxylmethyl cellulose
Plain sodium 0.3g, Essence 10g.
(3) prepared by powder filled hydrogel：According to formula ratio, respectively by nano silicon dioxide deionized water and Essence
Nanometer titanium dioxide silicon suspension is configured as solvent, formula ratio gelator sodium cellulose glycolate is added in magnetic agitation,
Continue stirring 1 hour.Then by hydrogel, (40KHz) is 20 minutes ultrasonic in sonic cleaning device, obtains powder filled water-setting
Glue.
Stability test：Powder filled hydrogel is centrifuged on centrifuge, centrifuges 10min, rotating speed 4000r/min, is seen
Examine its degeee of stratification.
Embodiment 8：
(1) powder filled hydrogel formulation 1：Pearl powder 0.5g (2000~3000 mesh of grain size), carbomer 0.1g, deionization
Water 10g.
(2) powder filled hydrogel formulation 2：Pearl powder 0.5g (2000~3000 mesh of grain size), carbomer 0.1g, Essence
10g。
(3) prepared by powder filled hydrogel：According to formula ratio, use deionized water and Essence as molten pearl powder respectively
Agent configures pearl powder suspension, and formula ratio gelator carbomer is added in magnetic agitation, continues stirring 1 hour.Then will
Hydrogel (40kHz) ultrasound 20 minutes in sonic cleaning device, obtain powder filled hydrogel.
Stability test：Powder filled hydrogel is centrifuged on centrifuge, centrifuges 10min, rotating speed 4000r/min, is seen
Examine its degeee of stratification.
Embodiment 9：
(1) powder filled hydrogel formulation 1：Pearl powder 0.5g (2000~3000 mesh of grain size), Sodium Polyacrylate (molecular weight
For 4,000,000-500 ten thousand) 0.1g, deionized water 10g.
(2) powder filled hydrogel formulation 2：Pearl powder 0.5g (2000~3000 mesh of grain size), Sodium Polyacrylate (molecular weight
For 4,000,000-500 ten thousand) 0.1g, Essence 10g.
(3) prepared by powder filled hydrogel：According to formula ratio, use deionized water and Essence as molten pearl powder respectively
Agent configures pearl powder suspension, and formula ratio gelator Sodium Polyacrylate is added in magnetic agitation, continues stirring 1 hour.So
By hydrogel, (40kHz) is 20 minutes ultrasonic in sonic cleaning device afterwards, obtains powder filled hydrogel.
Stability test：Powder filled hydrogel is centrifuged on centrifuge, centrifuges 10min, rotating speed 4000r/min, is seen
Examine its degeee of stratification.
Embodiment 10：
(1) powder filled hydrogel formulation 1：Pearl powder 0.5g (2000~3000 mesh of grain size), sodium carboxymethylcellulose
0.3g, deionized water 10g.
(2) powder filled hydrogel formulation 2：Pearl powder 0.5g (2000~3000 mesh of grain size), sodium carboxymethylcellulose
0.3g, Essence 10g.
(3) prepared by powder filled hydrogel：According to formula ratio, use deionized water and Essence as molten pearl powder respectively
Agent configures pearl powder suspension, and formula ratio gelator sodium carboxymethylcellulose is added in magnetic agitation, and it is small to continue stirring 1
When.Then by hydrogel, (40kHz) is 20 minutes ultrasonic in sonic cleaning device, obtains powder filled hydrogel.
Stability test：Powder filled hydrogel is centrifuged on centrifuge, centrifuges 10min, rotating speed 4000r/min, is seen
Examine its degeee of stratification.
Embodiment 11：
(1) powder filled hydrogel formulation 1：Pearl powder 0.5g (2000~3000 mesh of grain size), sodium alginate 0.3g, go from
Sub- water 10g.
(2) powder filled hydrogel formulation 2：Pearl powder 0.5g (2000~3000 mesh of grain size), sodium alginate 0.3g, essence
Liquid 10g.
(3) prepared by powder filled hydrogel：According to formula ratio, use deionized water and Essence as molten pearl powder respectively
Agent configures pearl powder suspension, and formula ratio gelator sodium alginate is added in magnetic agitation, continues stirring 1 hour.Then
By hydrogel, (40kHz) is 20 minutes ultrasonic in sonic cleaning device, obtains powder filled hydrogel.
Stability test：Powder filled hydrogel is centrifuged on centrifuge, centrifuges 10min, rotating speed 4000r/min, is seen
Examine its degeee of stratification.
Embodiment 12：
(1) powder filled hydrogel formulation 1：Pearl powder 0.5g (2000~3000 mesh of grain size), sodium alginate 0.1g, card wave
Nurse 0.05g, deionized water 10g.
(2) powder filled hydrogel formulation 2：Pearl powder 0.5g (2000~3000 mesh of grain size), sodium alginate 0.1g, card wave
Nurse 0.05g, Essence 10g.
(3) prepared by powder filled hydrogel：According to formula ratio, use deionized water and Essence as molten pearl powder respectively
Agent configures pearl powder suspension, and formula ratio gelator sodium alginate and carbomer are added in magnetic agitation, and it is small to continue stirring 1
When.Then by hydrogel, (40kHz) is 20 minutes ultrasonic in sonic cleaning device, obtains powder filled hydrogel.
Stability test：Powder filled hydrogel is centrifuged on centrifuge, centrifuges 10min, rotating speed 4000r/min, is seen
Examine its degeee of stratification.
Embodiment 13：
(1) powder filled hydrogel formulation 1：Pearl powder 0.5g (2000~3000 mesh of grain size), sodium cellulose glycolate
0.1g, carbomer 0.05g, deionized water 10g.
(2) powder filled hydrogel formulation 2：Pearl powder 0.5g (2000~3000 mesh of grain size), sodium cellulose glycolate
0.1g, carbomer 0.05g, Essence 10g.
(3) prepared by powder filled hydrogel：According to formula ratio, use deionized water and Essence as molten pearl powder respectively
Agent configures pearl powder suspension, and formula ratio gelator sodium cellulose glycolate and carbomer are added in magnetic agitation, continues
Stirring 1 hour.Then by hydrogel, (40kHz) is 20 minutes ultrasonic in sonic cleaning device, obtains powder filled hydrogel.
Stability test：Powder filled hydrogel is centrifuged on centrifuge, centrifuges 10min, rotating speed 4000r/min, is seen
Examine its degeee of stratification.
Embodiment 14：
(1) powder filled hydrogel formulation 1：Pearl powder 0.5g (2000~3000 mesh of grain size), sodium alginate 0.1g, poly- third
Olefin(e) acid sodium (molecular weight 4,000,000-500 ten thousand) 0.05g, deionized water 10g.
(2) powder filled hydrogel formulation 2：Pearl powder 0.5g (2000~3000 mesh of grain size), sodium alginate 0.1g, poly- third
Olefin(e) acid sodium (molecular weight 4,000,000-500 ten thousand) 0.05g, Essence 10g.
(3) prepared by powder filled hydrogel：According to formula ratio, use deionized water and Essence as molten pearl powder respectively
Agent configures pearl powder suspension, and formula ratio gelator sodium alginate and Sodium Polyacrylate are added in magnetic agitation, continues to stir
It mixes 1 hour.Then by hydrogel, (40kHz) is 20 minutes ultrasonic in sonic cleaning device, obtains powder filled hydrogel.
Stability test：Powder filled hydrogel is centrifuged into 10min in 4000r/min, its degeee of stratification is observed, as a result shows
Show, the powder filled hydrogel of example 1~14 is without apparent lamination.
1~14 powder filled hydrogel of example is carried out below to smear sense evaluation, comprehensive granular sensation glues hand degree, skids
Degree and powder absorbing state evaluate level of comfort.Comprehensive point is 0,1,2,3,4,5 from low to high, and 0 point is and uncomfortable, 5 points
For the most comfortable.Valuation officer 5,3 female of valuation officer, 2 man.
(solvent is 1 gelator sodium cellulose glycolate of table for sensory evaluation in different powders (Examples 1 to 7 formula 1)
Water)
The sensory evaluation in pearl powder (embodiment 1, the formula of embodiment 8~11 1) of 2 gelator of table (solvent is water)
The sensory evaluation in pearl powder (formula of embodiment 12~14 1) of 3 gelator of table compounding (solvent is water)
(solvent is 4 gelator sodium cellulose glycolate of table for sensory evaluation in different powders (Examples 1 to 7 formula 2)
Essence)
The sensory evaluation in pearl powder (embodiment 1, the formula of embodiment 8~11 2) of 5 gelator of table (solvent is Essence)
The sensory evaluation in pearl powder (formula of embodiment 12~14 2) of 6 gelator of table compounding (solvent is Essence)
Above example is only the more representational example of the present invention.Obviously, technical scheme of the present invention is not limited to
Embodiment is stated, acceptable there are many variations.Those skilled in the art become from present disclosure is directly derived
Change, is considered as protection scope of the present invention.
Claims (7)
1. a kind of powder filled hydrogel, it is characterised in that the powder filled hydrogel by following quality proportioning raw material group
At：0.5 part of powder, 0.05 ~ 0.5 part of gelator, 5 ~ 20 parts of solvent；
The powder is one kind in pearl powder, rose powder, aloe powder, Poria cocos powder, nano-calcium carbonate or nano silicon dioxide；
The gelator is one kind in following mixing：Sodium alginate and carbomer mass ratio 2：1 mixing, carboxymethyl cellulose
Plain sodium and carbomer mass ratio 2：1 mixing or sodium alginate and Sodium Polyacrylate mass ratio 2：1 mixing；
The solvent is deionized water or Essence used for cosmetic.
2. powder filled hydrogel as described in claim 1, it is characterised in that the diameter of particle is 2000 ~ 3000 mesh.
3. powder filled hydrogel as described in claim 1, it is characterised in that the powder filled hydrogel is matched by following quality
The raw material of ratio forms：0.5 part of powder, 0.1 ~ 0.3 part of gelator, 10 parts of solvent.
4. powder filled hydrogel as described in claim 1, it is characterised in that the Essence quality group becomes：Deionized water
4 parts of 76.8 parts, 6 parts of glycerine, 10 parts of propylene glycol, 3 parts of polyacrylic acid, 0.2 part of rose and amino acid humectant.
5. the preparation method of powder filled hydrogel described in a kind of claim 1, it is characterised in that the method is：By formula
The dissolving of powder solvent is made suspension, stirs evenly, gelator is added by amount, and ultrasonic disperse is uniform, obtains powder filled
Hydrogel.
6. preparation method as claimed in claim 5, it is characterised in that the supersonic frequency be 40KHz, ultrasonic time 10 ~
30min。
7. application of the powder filled hydrogel in preparing cosmetic emulsion described in a kind of claim 1.
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| CN117942269A (en) * | 2024-01-19 | 2024-04-30 | 义乌市东方仙子化妆品有限公司 | Cosmetic powder and preparation process thereof |
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| CN101757035A (en) * | 2009-11-20 | 2010-06-30 | 天津兆阳纳米科技有限公司 | Preparation method of stable nanometer pearl dispersion liquid |
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| KR101130993B1 (en) * | 2009-07-22 | 2012-03-28 | (주) 제이티 | Phase change hidrogel including pulp |
| MX2016008961A (en) * | 2014-01-31 | 2016-10-04 | Avent Inc | Hydrogel matrix having a non-uniform distribution of oxygen containing cells. |
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| CN102670415A (en) * | 2012-04-20 | 2012-09-19 | 费兰克·K·高 | Nano fiber paper mask |
| CN103405374A (en) * | 2013-07-16 | 2013-11-27 | 福建农林大学 | Freckle-removing and skin-whitening type gulcomannan particle facial mask and preparation method thereof |
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