CN105482782A - Pitting-prevention engine liquid coolant - Google Patents

Pitting-prevention engine liquid coolant Download PDF

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Publication number
CN105482782A
CN105482782A CN201510840872.3A CN201510840872A CN105482782A CN 105482782 A CN105482782 A CN 105482782A CN 201510840872 A CN201510840872 A CN 201510840872A CN 105482782 A CN105482782 A CN 105482782A
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CN
China
Prior art keywords
parts
pitting
liquid coolant
engine coolant
spot corrosion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510840872.3A
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Chinese (zh)
Inventor
闫海玲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bengbu Haiming Die Casting Machine Co Ltd
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Bengbu Haiming Die Casting Machine Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bengbu Haiming Die Casting Machine Co Ltd filed Critical Bengbu Haiming Die Casting Machine Co Ltd
Priority to CN201510840872.3A priority Critical patent/CN105482782A/en
Publication of CN105482782A publication Critical patent/CN105482782A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/20Antifreeze additives therefor, e.g. for radiator liquids

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

The invention discloses a pitting-prevention engine liquid coolant. The pitting-prevention engine liquid coolant is prepared from a propylene glycol-ethylene glycol mixture, citric acid, dimethicone, tricarboxylic acid, nanometer alumina, guar gum, pentaerythritol and glycerin. The pitting-prevention engine liquid coolant has good cooling effects. Through tricarboxylic acid-triethanolamine-nanometer alumina-guar gum mixing pretreatment, liquid coolant structure properties are improved, engine coolant-caused engine cooling system pitting is greatly reduced and pitting corrosion inhibition protection performances are improved. The pitting-prevention engine liquid coolant has good antifreezing effects and no corrosivity and does not pollute a cooling pipe.

Description

A kind of anti-spot corrosion engine coolant
Technical field
The present invention relates to cooling fluid technical field, particularly relate to a kind of anti-spot corrosion engine coolant.
Background technology
Cooling fluid is a kind of complicated multicomponent system, and excellent cooling fluid should have heat radiation, protection against corrosion, antifreeze, the function such as high boiling point, scale-deposit-preventing and prevention foaming.Major part frostproofer is eliminated in succession due to a variety of causes, and as methyl alcohol, ethyl alcohol boiling point are low, vapor pressure is large and inflammable; Saline mixture easily gets rusty and produces crystalline deposit; Glycerine viscosity is higher, and freeze-proof is poor, incompatible with rubber; Diethylene Glycol low temperature viscosity is large, antirust ability difference etc., and engine coolant can not get solving to engine-cooling system pitting problem always, many tentative solution effects are not good, the effect of the cooling fluid control spot corrosion of single utilization ternary poly carboxylic acid does not reach desirable, can not meet the demand of many occasions.
Summary of the invention
The object of this invention is to provide a kind of anti-spot corrosion engine coolant.
The present invention is achieved through the following technical solutions:
A kind of anti-spot corrosion engine coolant, be made up of following composition by weight, propylene glycol and ethylene glycol blend 145 parts, citric acid 6 parts, dimethyl silicone oil 12 parts, ternary poly carboxylic acid 15 parts, nano aluminium oxide 8 parts, guar gum 14 parts, tetramethylolmethane 8 parts, glycerine 12 parts.
Further, described propylene glycol and ethylene glycol blend are after propylene glycol mixes in 1:3 ratio with ethylene glycol at 35-40 DEG C, and uniform stirring 30 minutes, stirring velocity is 300r/min.
Further, the granularity of described nano aluminium oxide is 10-12nm.
Further, ternary poly carboxylic acid is through pre-treatment: mixed at 25-30 DEG C with trolamine by ternary poly carboxylic acid, continues after 30 minutes, adds nano aluminium oxide and guar gum, uniform stirring 10 minutes.
Further, described dimethyl silicone oil is through pre-treatment: be that the oligoethylene glycol methyl glycidyl ether of 1 part mixes with dimethyl silicone oil with the mixture of octamethylcyclotetrasiloxane by total weight parts, at temperature is 60 DEG C, and reaction 1-2 hour; Described polyoxyethylene glycol methyl glycidyl ether mixes in 1:1 ratio with octamethylcyclotetrasiloxane.
The invention has the beneficial effects as follows, compared with prior art:
Cooling fluid of the present invention; cooling is good; what to coordinate nano aluminium oxide and guar gum with trolamine by ternary poly carboxylic acid mixes pre-treatment; improve the structure property of cooling fluid; greatly reduce the spot corrosion of engine coolant to engine-cooling system, improve the suppression protective value to cavitation corrosion, and the antifreeze effect of cooling fluid of the present invention is good; cooling fluid non-corrosiveness, can not pollute cooling line.
Embodiment
. a kind of anti-spot corrosion engine coolant, be made up of following composition by weight, propylene glycol and ethylene glycol blend 145 parts, citric acid 6 parts, dimethyl silicone oil 12 parts, ternary poly carboxylic acid 15 parts, nano aluminium oxide 8 parts, guar gum 14 parts, tetramethylolmethane 8 parts, glycerine 12 parts.
Further, described propylene glycol and ethylene glycol blend are after propylene glycol mixes in 1:3 ratio with ethylene glycol at 35-40 DEG C, and uniform stirring 30 minutes, stirring velocity is 300r/min.
Further, the granularity of described nano aluminium oxide is 10-12nm.
Further, ternary poly carboxylic acid is through pre-treatment: mixed at 25-30 DEG C with trolamine by ternary poly carboxylic acid, continues after 30 minutes, adds nano aluminium oxide and guar gum, uniform stirring 10 minutes.
Further, described dimethyl silicone oil is through pre-treatment: be that the oligoethylene glycol methyl glycidyl ether of 1 part mixes with dimethyl silicone oil with the mixture of octamethylcyclotetrasiloxane by total weight parts, at temperature is 60 DEG C, and reaction 1-2 hour; Described polyoxyethylene glycol methyl glycidyl ether mixes in 1:1 ratio with octamethylcyclotetrasiloxane.
The performance index of cooling fluid of the present invention are:
Index, unit Cooling fluid of the present invention General cooling fluid
Freezing point, DEG C -30~-42 -12~-30
Boiling point, DEG C 128~135 102~115
PH 7.5~9.0 7.5~10
Quality guaranteed period 4~6 1~2
Defoaming, mL/ (10min) ≤2 ≤4
Table 1
As can be seen from Table 1, cooling fluid performance of the present invention is more superior, applied widely.

Claims (5)

1. an anti-spot corrosion engine coolant, it is characterized in that, be made up of following composition by weight, propylene glycol and ethylene glycol blend 145 parts, citric acid 6 parts, dimethyl silicone oil 12 parts, ternary poly carboxylic acid 15 parts, nano aluminium oxide 8 parts, guar gum 14 parts, tetramethylolmethane 8 parts, glycerine 12 parts.
2. the anti-spot corrosion engine coolant of one according to claim 1, is characterized in that, described propylene glycol and ethylene glycol blend are after propylene glycol mixes in 1:3 ratio with ethylene glycol at 35-40 DEG C, and uniform stirring 30 minutes, stirring velocity is 300r/min.
3. the anti-spot corrosion engine coolant of one according to claim 1, is characterized in that, the granularity of described nano aluminium oxide is 10-12nm.
4. the anti-spot corrosion engine coolant of the one according to claim 1 or 3, it is characterized in that, ternary poly carboxylic acid is through pre-treatment: mixed at 25-30 DEG C with trolamine by ternary poly carboxylic acid, continues after 30 minutes, add nano aluminium oxide and guar gum, uniform stirring 10 minutes.
5. the anti-spot corrosion engine coolant of one according to claim 1, it is characterized in that, described dimethyl silicone oil is through pre-treatment: be that the oligoethylene glycol methyl glycidyl ether of 1 part mixes with dimethyl silicone oil with the mixture of octamethylcyclotetrasiloxane by total weight parts, at temperature is 60 DEG C, reaction 1-2 hour; Described polyoxyethylene glycol methyl glycidyl ether mixes in 1:1 ratio with octamethylcyclotetrasiloxane.
CN201510840872.3A 2015-11-27 2015-11-27 Pitting-prevention engine liquid coolant Pending CN105482782A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510840872.3A CN105482782A (en) 2015-11-27 2015-11-27 Pitting-prevention engine liquid coolant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510840872.3A CN105482782A (en) 2015-11-27 2015-11-27 Pitting-prevention engine liquid coolant

Publications (1)

Publication Number Publication Date
CN105482782A true CN105482782A (en) 2016-04-13

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Family Applications (1)

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CN201510840872.3A Pending CN105482782A (en) 2015-11-27 2015-11-27 Pitting-prevention engine liquid coolant

Country Status (1)

Country Link
CN (1) CN105482782A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105862176A (en) * 2016-04-14 2016-08-17 巢湖市荷花渔网有限公司 Efficient cooling liquid for fishing net line drawing
CN105862175A (en) * 2016-04-14 2016-08-17 巢湖市荷花渔网有限公司 Fishing net thread drafting cooling liquid
CN106479453A (en) * 2016-08-30 2017-03-08 宝捷润滑油镇江有限公司 A kind of automobile engine cooling liquid and preparation method thereof
CN106833544A (en) * 2017-03-27 2017-06-13 卓聪(上海)环保科技发展有限公司 IT communication equipment immersion cooling agents and preparation method thereof
CN107033856A (en) * 2017-05-22 2017-08-11 汪建军 A kind of environment-friendly type antifreeze coolant and preparation method thereof
CN107987802A (en) * 2016-10-26 2018-05-04 中国石油化工股份有限公司 A kind of heat safe engine coolant
CN111100609A (en) * 2019-12-17 2020-05-05 重庆国翰能源发展有限公司 High-power charging pile cooling liquid for heat dissipation
CN117447973A (en) * 2023-12-22 2024-01-26 纯牌科技股份有限公司 Cooling liquid for electric automobile and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102002347A (en) * 2010-12-23 2011-04-06 合肥工业大学 Non-aqueous coolant for engine
CN102559152A (en) * 2012-01-10 2012-07-11 广州市标榜汽车用品实业有限公司 All-organic waterless engine coolant
CN103571440A (en) * 2013-08-26 2014-02-12 安徽邦克节能科技有限公司 High-thermal-conductivity anhydrous engine cooling oil
CN103666681A (en) * 2013-11-22 2014-03-26 广西大学 Nanometer cooling liquid capable of enhancing heat transfer
CN104745151A (en) * 2013-12-26 2015-07-01 汤彬 Cooling liquid for engines

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102002347A (en) * 2010-12-23 2011-04-06 合肥工业大学 Non-aqueous coolant for engine
CN102559152A (en) * 2012-01-10 2012-07-11 广州市标榜汽车用品实业有限公司 All-organic waterless engine coolant
CN103571440A (en) * 2013-08-26 2014-02-12 安徽邦克节能科技有限公司 High-thermal-conductivity anhydrous engine cooling oil
CN103666681A (en) * 2013-11-22 2014-03-26 广西大学 Nanometer cooling liquid capable of enhancing heat transfer
CN104745151A (en) * 2013-12-26 2015-07-01 汤彬 Cooling liquid for engines

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105862176A (en) * 2016-04-14 2016-08-17 巢湖市荷花渔网有限公司 Efficient cooling liquid for fishing net line drawing
CN105862175A (en) * 2016-04-14 2016-08-17 巢湖市荷花渔网有限公司 Fishing net thread drafting cooling liquid
CN106479453A (en) * 2016-08-30 2017-03-08 宝捷润滑油镇江有限公司 A kind of automobile engine cooling liquid and preparation method thereof
CN107987802A (en) * 2016-10-26 2018-05-04 中国石油化工股份有限公司 A kind of heat safe engine coolant
CN106833544A (en) * 2017-03-27 2017-06-13 卓聪(上海)环保科技发展有限公司 IT communication equipment immersion cooling agents and preparation method thereof
CN107033856A (en) * 2017-05-22 2017-08-11 汪建军 A kind of environment-friendly type antifreeze coolant and preparation method thereof
CN111100609A (en) * 2019-12-17 2020-05-05 重庆国翰能源发展有限公司 High-power charging pile cooling liquid for heat dissipation
CN117447973A (en) * 2023-12-22 2024-01-26 纯牌科技股份有限公司 Cooling liquid for electric automobile and preparation method thereof

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Application publication date: 20160413