CN105472996A - Method for preparing hydrogen negative ion containing material and hydrogen negative ion containing material prepared using same - Google Patents
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Abstract
The present invention relates to a method for preparing a hydrogen negative ion containing material and a hydrogen negative ion containing material prepared using the same. The hydrogen negative ion containing material can promote cell metabolism and remove active oxygen in the body. In addition, the hydrogen negative ion containing material prepared by the method can exhibit the above functions through addition to various beverages or various food materials since the hydrogen negative ion is not sensitive to a surrounding environment, for example, temperature change, and is not deformed despite exposure to air, and thus is easily preserved. In addition, the hydrogen negative ion containing material may be added to food materials, such as fruits, vegetables, fishes, and meats, to prevent oxidation of the food materials, thereby maintaining high freshness of the food materials for a long period of time. In addition, the hydrogen negative ion containing material allows oxidized skin and traumatized skin to recover through reduction.
Description
Technical field
The present invention relates to the preparation method of hydride ion inclusion and use it to the hydride ion inclusion of preparation, more specifically, relate to a kind of metabolism that can promote cell, and can the hydride ion inclusion prepared of the preparation method and using it to of hydride ion inclusion of active oxygen in removing body.
Background technology
Recently, along with the antioxidation of anion, selling the product of variform.Such as, researching and developing the ion generator that can purify the air of a room, the lime taste that running water can be removed, and the multiple anion product of Mineralization can realized.
Further, as mentioned above, only rest on and the anion of the improvement level of living environment is just being developed at present as consumable products, market is being sold the anion product that can take.But the anion product just commercially sold cannot seek antioxidation smoothly in vivo because of the poor solubility to water.Further, there is the defect that cannot take care of for a long time in the anion product just commercially sold, and cause many side effects because of the flour etc. used to prepare anion product.Therefore, up to the present, the anion product to absorbing also is needed constantly to study.
Summary of the invention
The technical problem solved
The object of the invention is to, the metabolism that can promote cell is provided, and can the preparation method of hydride ion inclusion of active oxygen in removing body.
Another object of the present invention is to, the hydride ion prepared by above-mentioned preparation method inclusion is provided.
Technical scheme
To achieve these goals, the preparation method of hydride ion inclusion comprises:
First calcining step, calcines the alkaline earth metal compound comprising organic calcium carbonate, prepares the first calcined body;
Second calcining step, calcines the alkaline earth oxide comprising above-mentioned first calcined body, prepares the second calcined body;
With to and the step that coordinates of above-mentioned second calcined body and organic acid.
Above-mentioned first calcining step carries out the step of the 2 little calcinings up to 10 hours at 300 DEG C to 1000 DEG C temperature to alkaline earth metal compound.
Above-mentioned alkaline earth metal compound also comprises beryllium compound, magnesium compound, barium compound or their mixture.
The interpolation of beryllium oxide, magnesium oxide, ba oxide or their mixture is comprised at above-mentioned second calcining step.And, relative to the calcium oxide of 100 moles, above-mentioned alkaline earth oxide comprise 1 mole to 60 moles beryllium oxide, magnesium oxide, ba oxide or their mixture.
Above-mentioned second calcining step comprises under a hydrogen atmosphere, alkaline earth oxide is carried out to the step of the 2 little calcinings up to 10 hours at the temperature of 300 DEG C to 1000 DEG C.
Calcium ion relative to 100 moles that the second calcined body comprises, above-mentioned second calcined body matches with the organic acid of 0.5 mole to 10 moles.
The hydride ion inclusion of another embodiment of the present invention is prepared from by above-mentioned preparation method.
The pH of the aqueous solution that above-mentioned hydride ion inclusion is formed after being dissolved in water is 6 to 12; Or the aqueous solution formed after being dissolved in water has the oxidation-reduction potential of-0.1mV to-900mV; Or there is the inclusion of the 1 little reducing power duration up to 150 hours.
Invention effect
Hydride ion inclusion disclosed by the invention can promote the metabolism of cell, and can active oxygen in removing body.And, because the hydride ion inclusion prepared by preparation method disclosed by the invention is insensitive to surrounding enviroment, such as, due to insensitive to the change of temperature, even if be exposed to air, also can not there is modification, thus be convenient to keeping, various beverage or various food materials can be added thus to, play above-mentioned functions.Further, above-mentioned hydride ion inclusion can add the food materials such as fruit, vegetables, fish and meat to, prevents their oxidation, thus can keep high freshness for a long time.Further, above-mentioned hydride ion inclusion can make oxidized skin by reduction and be subject to the skin recovery of wound.
Accompanying drawing explanation
Fig. 1 is the photo hydride ion inclusion prepared in embodiment 1 being implemented to the aqueous solution dissolved.
Best detailed description of the invention
Below, the present invention is described in more details.
The preparation method of disclosed hydride ion inclusion of the present invention comprises:
First calcining step, calcines the alkaline earth metal compound comprising organic calcium carbonate, prepares the first calcined body;
Second calcining step, calcines the alkaline earth oxide comprising above-mentioned first calcined body, prepares the second calcined body;
With to and the step that coordinates of above-mentioned second calcined body and organic acid.
Above-mentioned organic carbonate calcium, as bag organic matter calciferous, is different from the calcium carbonate gathered from the inorganic matter of mineral and so on.Organic carbonate calcium comprises very micro-heavy metal compared to the calcium carbonate gathered from the inorganic matter of mineral and so on, or does not comprise heavy metal completely.Further, organic carbonate calcium comprises the mineral matter abundanter than the calcium carbonate gathered from the inorganic matter of mineral and so on.Therefore, organic carbonate calcium is applicable to the edible hydride ion inclusion of preparation very much.
Can use such as, be selected from one or more in the group be made up of eggshell calcium, Calcium, shell calcium and sea algae calcium as above-mentioned organic carbonate calcium.
Above-mentioned eggshell calcium can be obtained from eggshell etc., shell calcium can be obtained from bone of oyster, clam, abalone or fish etc., pearl powder can be obtained from pearl, and above-mentioned sea algae calcium can be obtained from starfish or coral etc.In the middle of them, entering in water easiness, eggshell calcium, shell calcium and their mixture can be used as organic carbonate calcium.
The preparation method of above-mentioned hydride ion inclusion roughly can be performed by two kinds of modes.First embodiment is the form utilizing alkaline earth metal compound to coordinate with the compound of physical mode to the alkaline-earth metal comprised except organic calcium carbonate and calcium, and the second embodiment is use this form as alkaline earth metal compound of organic carbonate.
In above-mentioned first embodiment, above-mentioned alkaline earth metal compound also comprises beryllium compound, magnesium compound, barium compound or their mixture except organic carbonate calcium.The reducing power of multiple compounds to prepared hydride ion inclusion comprising other alkaline-earth metal except above-mentioned calcium has an impact, and therefore adopts suitable compound to regulate the reducing power of hydride ion inclusion.
In a kind of example, alkaline earth metal compound, except organic carbonate calcium, can also comprise magnesium compound.Above-mentioned magnesium compound can control the reducing power of hydride ion inclusion effectively.And, by the interaction between calcium, the external discharge of sodium can be helped, and the generation of accelerating oxidation nitrogen, thus the increase of blood flow can be contributed to, and reduce acetaldehyde etc. and remove and to be still drank after a night and tired.
As long as can generate magnesium oxide through the first calcining step, the kind of above-mentioned magnesium compound is not just by special restriction.As this magnesium compound, magnesium (Mg), magnesium chloride (MgCl can be exemplified
2), dolomol (Mg (C
18h
35o
2)
2), magnesium carbonate (MgCO
3), magnesium sulfate (MgSO
4), magnesium hydroxide (Mg (OH)
2), triphosphoric acid magnesium (Mg
3(PO
4)
2), biphosphate magnesium (MgHPO
4), magnesium silicate (MgSiO
3), magnesium gluconate (C
12h
22mgO
14), Pfansteihl magnesium (Mg (C
3h
5o
3)
22H
2o), magnesia (MgO) or their mixture etc.
The compound comprised except the alkaline-earth metal of above-mentioned calcium can consider the reducing power of required hydride ion inclusion, the concentration of reducing power duration and/or hydride ion uses with suitable content.In one example, relative to the calcium carbonate of 100 moles contained by organic carbonate calcium, the above-claimed cpd of 1 mole to 60 moles or 1.6 moles to 57 moles or 1.6 moles to 50 moles or 1.6 moles to 40 moles or 1.6 moles to 30 moles or 5 moles to 20 moles or 5 moles to 15 moles can be comprised.If the content of above-claimed cpd is less than above-mentioned scope, then the reducing power of hydride ion inclusion became weak or the reducing power duration becomes too short, and when the content of above-claimed cpd is greater than above-mentioned scope, can obtain and be not suitable for the hydride ion inclusion with large reducing power very taken, and this hydride ion inclusion may hinder the metabolism in body.
In one example, when the compound using magnesium compound as the alkaline-earth metal comprised outside deliming, relative to 80 weight portion to 99.5 weight portions organic carbonate calcium contained by calcium carbonate, the magnesium compound of 0.5 weight portion to 20 weight portion can be used.As a result, the hydride ion inclusion that can present above-mentioned effect can be provided.
Above-mentioned first calcining step can be included in the step of calcining alkaline earth metal compound in about 300 DEG C to 1000 DEG C or about 400 DEG C to 900 DEG C or about 500 DEG C to 800 DEG C or about 600 DEG C to 800 DEG C or about 650 DEG C to 800 DEG C or about 600 DEG C to 750 DEG C or about 650 DEG C to the temperature of 750 DEG C.Further, the calcining of above-mentioned alkaline earth metal compound can carry out more than about 2 hours or more than about 3 hours or more than about 4 hours.The upper limit of calcination time, not by special restriction, such as, can be adjusted to less than 10 hours.If above-mentioned calcining performs the time being less than above-mentioned scope in the temperature being less than above-mentioned scope, alkaline earth metal compound then likely cannot be made to be oxidized to required level, if above-mentioned calcining performs the time of more than above-mentioned scope in the temperature being greater than above-mentioned scope, then likely waste huge energy.
Above-mentioned first calcining step by special restriction, such as, can not carry out in atmospheric conditions.
After the preparation method of above-mentioned hydride ion inclusion can also be included in and carry out the first calcining step, make the step of the first calcined body cooling.Make the step of the first calcined body cooling not by special restriction, such as, nature cooling can be implemented.The first calcined body be contained in by the container heated can be shelved, until its temperature reaches normal temperature or required temperature, perform above-mentioned cooling naturally.In this manual, normal temperature means the naturally own temperature heating or do not lower the temperature.
If according to the first embodiment through the first calcining step, then the first calcined body can comprise the calcium oxide (CaO) obtained from organic carbonate calcium and the beryllium oxide (BeO), magnesium oxide (MgO), ba oxide (BaO) or their mixture that obtain from the compound of the alkaline-earth metal comprised outside deliming.
In one example, when the compound using magnesium compound as the alkaline-earth metal comprised outside deliming, the first calcined body can comprise calcium oxide and magnesium oxide.
On the contrary, if according to the second embodiment through the first calcining step, then the first calcined body comprises the calcium oxide (CaO) obtained from organic carbonate calcium.Therefore, in this case, the alkaline-earth metal comprised outside deliming can be added in the second calcining step, there is identical structure with the first calcined body prepared according to the first embodiment.The oxide comprising the alkaline-earth metal except above-mentioned calcium can be beryllium oxide (BeO), magnesium oxide (MgO), ba oxide (BaO) or their mixture.
In one example, the oxide comprising the alkaline-earth metal outside deliming can be magnesium oxide.That is, in the second embodiment, the first calcined body and magnesium oxide can be used as alkaline earth oxide.Therefore, no matter be the first embodiment or the second embodiment, alkaline earth oxide can have identical structure.
Relative to the calcium oxide of 100 moles, above-mentioned alkaline earth oxide can comprise the oxide comprising the alkaline-earth metal outside deliming of 1 mole to 60 moles or 1.6 moles to 57 moles or 1.6 moles to 50 moles or 1.6 moles to 40 moles or 1.6 moles to 30 moles or 5 moles to 20 moles or 5 moles to 15 moles.As a result, the hydride ion inclusion with suitable reducing power can be prepared.
Further, the first calcined body of the first embodiment and the second embodiment in addition to the above-mentioned components, comprises the various mineral matters coming from organic carbonate calcium.As a result, the hydride ion inclusion as end product also can comprise the various mineral matters coming from organic carbonate calcium.
Above-mentioned second calcining step can be included in the step of calcining alkaline earth oxide in about 300 DEG C to 1000 DEG C or about 300 DEG C to 900 DEG C or about 400 DEG C to 900 DEG C or about 400 DEG C to 800 DEG C or about 500 DEG C to 800 DEG C or about 500 DEG C to 700 DEG C or about 600 DEG C to the temperature of 700 DEG C.Further, the calcining of above-mentioned alkaline earth oxide can carry out more than about 2 hours or more than about 3 hours or more than about 4 hours.The upper limit of calcination time, not by special restriction, such as, can be adjusted to less than 10 hours.If above-mentioned calcining performs the time being less than above-mentioned scope in the temperature being less than above-mentioned scope, alkaline earth oxide then likely cannot be made to be reduced to required level, if above-mentioned calcining performs the time of more than above-mentioned scope in the temperature being greater than above-mentioned scope, then likely waste huge energy.
Above-mentioned second calcining step can be carried out under a hydrogen atmosphere.Therefore, can during the calcining carrying out alkaline earth oxide in supply hydrogen.Above-mentioned hydrogen can inject separately, or together can inject with other carrier gas.As long as the gas of anergy in above-mentioned calcination temperature range, above-mentioned carrier can use all gas usually used without restriction.As above-mentioned carrier gas, nitrogen, helium or argon etc. can be illustrated.
The preparation method of above-mentioned hydride ion inclusion makes the step of the second calcined body cooling after can also being included in and carrying out the second calcining step.Make the method for the second calcined body cooling not by special restriction, cooling can be implemented to make the identical method of the method for the first calcined body cooling.
The step that the preparation method of above-mentioned hydride ion inclusion makes the second calcined body and organic acid match after being included in and carrying out the second calcining step.
Above-mentioned second calcined body comprises deliming hydride (CaH
2) and calcium outside alkaline earth metal hydride (MH
2, M is Be, Mg or Ba).In this manual, in order to distinguish " the second calcined body " and " the second calcined body matched with organic acid ", the former be referred to as the second calcined body, the latter be referred to as hydride ion inclusion.
The step that this second calcined body is matched with organic acid performs in the mode of adding organic acid to the container that the second calcined body is housed and carrying out mixing in physical mode.
As above-mentioned organic acid, can use and be selected from by such as, more than one in the group that formic acid (formicacid), acetic acid (aceticacid), citric acid (citricacid), lactic acid (lacticacid), tartaric acid (tartaricacid), butanedioic acid (succinicacid) form.In one example, be used in for the material of solid is as organic acid under normal temperature condition, thus the hydride ion inclusion of powder morphology can be prepared.Therefore, citric acid, lactic acid, tartaric acid, butanedioic acid or their mixture can be used as organic acid.
In the step making above-mentioned second calcined body and organic acid match, the calcium ion that the second calcined body relative to 100 moles comprises, above-mentioned second calcined body can match with the organic acid of the organic acid of 0.5 mole to 10 moles or the organic acid of 0.88 mole to 10 moles or the organic acid of 1 mole to 9 moles or the organic acid of 2 moles to 8 moles or the organic acid of 3 moles to 8 moles or the organic acid of 3 moles to 7 moles or 3 moles to 6 moles.In this scope, hydride ion inclusion has and causes the suitable reducing power of suitable antioxidation and suitable reducing power duration in vivo.In foregoing, the reducing power duration means the time in during the aqueous solution of dissolved hydrogen anion inclusion presents the oxidation-reduction potential (Oxidation-ReductionPotential, ORP) of negative value.
Further, hydride ion inclusion can comprise organic acid by the content of above-mentioned scope, thus has the pH in applicable body.In one example, if the pH measured put into second calcined body of 400mg in the water of 300mL after is roughly about 10 to 12, then in this second calcined body, pH is made to be down to about about 6 to 11 with above-mentioned range fit organic acid.Therefore, the hydride ion inclusion that can not play effect required for the present invention on bringing impact in body can be provided.
Another embodiment of the present invention provides the hydride ion prepared by above-mentioned preparation method inclusion.
The pH after water that is dissolved in of the hydride ion inclusion prepared according to above-mentioned preparation method can be 6 to 12 or 7 to 12 or 8 to 12 or 8 to 11 or 9 to 11.And, above-mentioned hydride ion inclusion, after being dissolved in water, can have the suitable reducing power of the oxidation-reduction potential presenting-0.1mV to-900mV or-0.1mV to-800mV or-0.1mV to-700mV or-0.1mV to-600mV or-0.1mV to-500mV or-10mV to-450mV or-100mV to-400mV or-150mV to-300mV or-180mV to-250mV or-190mV to-230mV.And the above-mentioned reducing power duration can be 1 little of 150 hours or 5 little of 120 hours or 10 little of 100 hours or 30 little of 100 hours or 50 little of 100 hours or 70 little of 100 hours.Above-mentioned multiple physical property is that the hydride ion inclusion of adding 400mL in the water of 300mL measures.In one example, the pH after water that is dissolved in of the hydride ion inclusion prepared according to above-mentioned preparation method can be 9 to 11.Further, the oxidation-reduction potential of above-mentioned hydride ion inclusion after being dissolved in water can be-190mV to-230mV.And the reducing power duration can be 50 little of 100 hours.The hydride ion inclusion with this physical property can be absorbed bringing in body when impact, and can promote the metabolism of cell, can remove active oxygen swimmingly in vivo.The alkaline earth metal compound of proper content or oxide can be used to generate the hydride ion inclusion with above-mentioned physical property.
Because the hydride ion inclusion prepared by above-mentioned preparation method is not too responsive to the change of surrounding enviroment, the multiple fields needing antioxidation thus can be used in.Above-mentioned hydride ion inclusion may be used for preventing the oxidation of such as fruit, vegetables, fish and meat.Further, hydride ion inclusion can make oxidized skin by reduction and be subject to the skin recovery of wound.In addition, hydride ion inclusion can be widely used in beauty treatment material, healthy food and solution and to be still drank after a night the fields such as beverage.
Detailed description of the invention
Below, embodiments of the invention are described in detail, make general technical staff of the technical field of the invention easily can implement the present invention.But the present invention can embody with multiple different form, is not limited to embodiment described herein.
[preparation example: the preparation of hydride ion inclusion]
Embodiment 1
Under air atmosphere, with the temperature of 700 DEG C, the oyster shell after the cleaning of 100g is carried out to the calcining of 4 hours, obtain the first calcined body.Above-mentioned first calcined body comprises the calcium oxide of 56.08g.
Then, in the reaction vessel that above-mentioned first calcined body is housed, add the magnesium oxide (CaO:MgO=92.6 percentage by weight: 7.4 percentage by weights=100mol:11mol) of 4.45g.Afterwards, with the temperature of 650 DEG C, the alkaline earth oxide comprising the first calcined body and magnesium oxide is carried out to the calcining of more than 4 hours under a hydrogen atmosphere, thus obtain the second calcined body.
Then, in above-mentioned second calcined body, relative to whole hydride ion inclusion, with the ratio lemonade mixt of 17.5 percentage by weights, thus the hydride ion inclusion of powder morphology is prepared.
Embodiment 2
As shown in the following Table 1, except the content changing magnesium oxide in above-described embodiment 1 is except 0.66g, hydride ion inclusion has been prepared in the same manner as example 1.
Embodiment 3
As shown in the following Table 1, except the content changing magnesium oxide in above-described embodiment 1 is except 9.53g, hydride ion inclusion has been prepared in the same manner as example 1.
Embodiment 4
As shown in the following Table 1, except the content changing magnesium oxide in above-described embodiment 1 is except 22.95g, hydride ion inclusion has been prepared in the same manner as example 1.
Embodiment 5
As shown in the following Table 1, except in above-described embodiment 1 relative to whole hydride ion inclusion, outside the content changing the citric acid matched with the second calcined body with the ratio of 12.5 percentage by weights, prepare hydride ion inclusion in the same manner as example 1.
Embodiment 6
As shown in the following Table 1, except relative to whole hydride ion inclusion, the content of the citric acid matched with the second calcined body in above-described embodiment 1 is changed to outside the ratio of 25.0 percentage by weights, has prepared hydride ion inclusion in the same manner as example 1.
Table 1
[experimental example: the physical property measuring hydride ion inclusion]
Measure oxidation-reduction potential (ORP) change of the hydride ion inclusion prepared in the above-described embodiments, pH change and reducing power duration, and observe the turbidity of the aqueous solution being dissolved with above-mentioned hydride ion inclusion.And, compared with the physical property of the physical property of the hydride ion inclusion of embodiment and running water (comparative example 1) and the first calcined body (comparative example 2: the first calcined body using embodiment 1), and by the display of its result in table 2.
Table 2
(1) change of ORP (unit: mV) and pH: the running water dropping into 300mL to 8 beakers respectively, wherein, any material (comparative example 1) is not added in a beaker, in another beaker, dissolve first calcined body (comparative example 2) of the 400mg prepared in embodiment 1, in remaining 6 beakers, dissolve the hydride ion inclusion (embodiment 1 to embodiment 6) of embodiment 1 to the embodiment 6 of 400mg respectively.For the running water not adding any material and each aqueous solution prepared in foregoing, determine the moment (initial value) of dissolving first calcined body or hydride ion inclusion respectively, from ORP and pH of this moment through the time point of 4 hours, 20 hours, 40 hours, 60 hours, 80 hours, 100 hours.
(2) the reducing power duration: be the reducing power duration by the time rule during multiple aqueous solution of preparing in foregoing are during the oxidation-reduction potential maintaining negative value, and determine and become time 0 value from moment to the oxidation-reduction potential implementing to dissolve to the inclusion of the first calcined body or hydride ion.
(3) turbidity of the aqueous solution: to the first calcined body or make the aqueous solution that hydride ion inclusion is dissolved visually observe, if observed discovery is dusky, is then labeled as " muddiness ", finds very transparent, be then labeled as " clear " if observe.Typically, Fig. 1 discloses the photo of the aqueous solution of embodiment 1.
Above; the preferred embodiments of the present invention have been described in detail; but protection scope of the present invention is not limited thereto, the various deformation that general technical staff of the technical field of the invention utilizes in claims of the present invention the basic conception of the present invention defined to carry out and improvement form belong to protection scope of the present invention equally.
Utilizability in industry
The present invention can promote the metabolism of cell, and can active oxygen in removing body.And, due to surrounding enviroment, such as, due to insensitive to the change of temperature, even if be exposed to air, also can not there is modification, thus be convenient to keeping, various beverage or various food materials can be added thus to, play above-mentioned functions.Further, above-mentioned hydride ion inclusion can add the food materials such as fruit, vegetables, fish and meat to, prevents their oxidation, thus can keep high freshness for a long time.Further, above-mentioned hydride ion inclusion can make oxidized skin by reduction and be subject to the skin recovery of wound.
Claims (9)
1. the preparation method of hydride ion inclusion, is characterized in that, comprising:
First calcining step, calcines alkaline earth metal compound, prepares the first calcined body, and above-mentioned alkaline earth metal compound comprises organic calcium carbonate, and this organic carbonate calcium is selected from one or more in eggshell calcium, Calcium, shell calcium and sea algae calcium;
Second calcining step, calcines the alkaline earth oxide comprising above-mentioned first calcined body in a hydrogen atmosphere, prepares the second calcined body; And
To the step that above-mentioned second calcined body and organic acid coordinate.
2. the preparation method of hydride ion inclusion according to claim 1, is characterized in that, in above-mentioned first calcining step, in the temperature of 300 DEG C to 1000 DEG C, implements the 2 little calcinings up to 10 hours to alkaline earth metal compound.
3. the preparation method of hydride ion inclusion according to claim 1, is characterized in that, above-mentioned alkaline earth metal compound also comprises one or more in beryllium compound, magnesium compound, barium compound.
4. the preparation method of hydride ion inclusion according to claim 1, is characterized in that, in above-mentioned second calcining step, adds one or more in beryllium oxide, magnesium oxide, ba oxide.
5. the preparation method of hydride ion inclusion according to claim 1, it is characterized in that, relative to the calcium oxide of 100 moles, above-mentioned alkaline earth oxide comprise 1 mole to 60 moles beryllium oxide, magnesium oxide, ba oxide or their mixture.
6. the preparation method of hydride ion inclusion according to claim 1, is characterized in that, in above-mentioned second calcining step, in a hydrogen atmosphere, at the temperature of 300 DEG C to 1000 DEG C, implements the 2 little calcinings up to 10 hours to alkaline earth oxide.
7. the preparation method of hydride ion inclusion according to claim 1, is characterized in that, the calcium ion relative to 100 moles that the second calcined body comprises, and above-mentioned second calcined body matches with the organic acid of 0.5 mole to 10 moles.
8. hydride ion inclusion, is characterized in that, preparation method's preparation of hydride ion inclusion according to claim 1.
9. hydride ion inclusion according to claim 8, is characterized in that, the pH of the aqueous solution formed after being dissolved in water is 6 to 12; Or the aqueous solution formed after being dissolved in water has the oxidation-reduction potential of-0.1mV to-900mV; Or there is the 1 little reducing power duration up to 150 hours.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2013-0152162 | 2013-12-09 | ||
| KR1020130152162A KR101405431B1 (en) | 2013-12-09 | 2013-12-09 | Method of preparing hydride inclusions and hydride inclusions prepared by using the same |
| PCT/KR2014/005067 WO2015088114A1 (en) | 2013-12-09 | 2014-06-10 | Method for preparing hydrogen negative ion containing material and hydrogen negative ion containing material prepared using same |
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| JP (1) | JP6439994B2 (en) |
| KR (1) | KR101405431B1 (en) |
| CN (1) | CN105472996A (en) |
| WO (1) | WO2015088114A1 (en) |
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| KR101910334B1 (en) | 2016-10-07 | 2018-12-28 | 보비씨엔이(주) | Manufacturing method of antibiotic textile |
| KR101881316B1 (en) * | 2016-10-07 | 2018-07-26 | 보비씨엔이(주) | Composition having antibiotic and antioxidative property |
| WO2018139682A1 (en) * | 2017-01-24 | 2018-08-02 | (주)비피텍스 | Method for manufacturing antibacterial fabric by using calcium antibacterial agent |
| JP6244051B1 (en) * | 2017-05-09 | 2017-12-06 | 株式会社アッチェ | Method for producing hydrogen-supported powder |
| KR102039347B1 (en) | 2017-08-10 | 2019-11-01 | 보비씨엔이(주) | Anti-inflammatory composition having hydride ion |
| JP6337192B1 (en) * | 2017-10-23 | 2018-06-06 | 株式会社アッチェ | Hydrogen-carrying powder, and food and fertilizer containing the hydrogen-carrying powder |
| CN108542794B (en) * | 2018-05-24 | 2021-02-02 | 河北云悦生物科技有限公司 | Hydrogen-rich raw material and skin-care hydrogen-rich product |
| KR20200032460A (en) * | 2018-09-18 | 2020-03-26 | 보비씨엔이(주) | Composition containing h2-occluded calcium and having alcoholysis and acetaldehydelysis for hangover-relieving |
| WO2020080573A1 (en) * | 2018-10-18 | 2020-04-23 | 보비씨엔이(주) | Anti-inflammatory composition comprising hydrogen anions |
| KR102230498B1 (en) * | 2019-07-31 | 2021-03-22 | 보비씨엔이(주) | Composition containing h2-occluded calcium for the treatment of osteoporosis |
| KR102403488B1 (en) * | 2020-03-30 | 2022-05-30 | 보비씨엔이(주) | Skin moisturing composition having hydride ion |
| WO2024135810A1 (en) * | 2022-12-23 | 2024-06-27 | サントリーホールディングス株式会社 | Packaged beverage |
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| JPH1143365A (en) * | 1997-07-23 | 1999-02-16 | Tohoku Bankin Toso Kogyo Kk | Granular ceramic for producing reduced water and its production |
| JP4072787B2 (en) * | 2003-08-05 | 2008-04-09 | 有限会社光ベルコム | Acid-reduced water-generating tablets |
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| JPS61151057A (en) * | 1984-12-25 | 1986-07-09 | 清水建設株式会社 | Concrete material for surface enameling treatment |
| JP2006246706A (en) * | 2005-03-08 | 2006-09-21 | Masataka Sato | Egg-shell ion powder and method for producing the same |
| JP2007217351A (en) * | 2006-02-17 | 2007-08-30 | Amimoto Giken Kk | Anti-oxidizing composition and food/medicine/cosmetic containing the same |
| JP2007236851A (en) * | 2006-03-13 | 2007-09-20 | Gotoo Corporation:Kk | Deodorant composed of reduction firing hydrogenation metals, its manufacturing method, accessory with odor removing/deodorizing action, and simple method for producing alkali ion water |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1143365A (en) * | 1997-07-23 | 1999-02-16 | Tohoku Bankin Toso Kogyo Kk | Granular ceramic for producing reduced water and its production |
| JP4072787B2 (en) * | 2003-08-05 | 2008-04-09 | 有限会社光ベルコム | Acid-reduced water-generating tablets |
| JP4404657B2 (en) * | 2004-03-03 | 2010-01-27 | 株式会社創造的生物工学研究所 | Eating minus hydrogen ion production method |
| JP4472022B1 (en) * | 2009-12-11 | 2010-06-02 | 株式会社Ｅｎａｇｅｇａｔｅ | Hydrogen gas-containing calcium carbonate and method for producing the same |
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| JP6439994B2 (en) | 2018-12-19 |
| WO2015088114A1 (en) | 2015-06-18 |
| JP2017508714A (en) | 2017-03-30 |
| KR101405431B1 (en) | 2014-06-11 |
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