CN105462713A - Combined type degumming agent and preparation method and application thereof - Google Patents
Combined type degumming agent and preparation method and application thereof Download PDFInfo
- Publication number
- CN105462713A CN105462713A CN201510837905.9A CN201510837905A CN105462713A CN 105462713 A CN105462713 A CN 105462713A CN 201510837905 A CN201510837905 A CN 201510837905A CN 105462713 A CN105462713 A CN 105462713A
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- component
- degumming agent
- alcohol
- aldehyde
- hydroxide
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/264—Aldehydes; Ketones; Acetals or ketals
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/06—Hydroxides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/261—Alcohols; Phenols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3209—Amines or imines with one to four nitrogen atoms; Quaternized amines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5018—Halogenated solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5022—Organic solvents containing oxygen
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a combined type degumming agent prepared from 85 wt%-95 wt% of a component A, 1 wt%-10 wt% of a component B, and the balance a component C, wherein the component A is alcohol, ketone and/or aldehyde, the component B is an alkali and the component C is a solvent; the combined type degumming agent can be used for degumming of nickel buckle cathode plates; compared with a conventional degumming agent, the combined type degumming agent has the advantages of low cost, low toxicity, small volatility and the like, and has no corrosion to the nickel buckle cathode plates.
Description
Technical field
The present invention relates to a kind of combined degumming agent and its preparation method and application.
Background technology
Nickel button is the industrial anode material of a kind of important plating, electroformed nickel, can be widely used in the plating industry that becomes more meticulous.For the nickel process for processing base Jinchuan Non-ferrous Metals Company that the whole nation is maximum, nickel button is one of its important Industrial products.The equipment that refinery of Jinchuan Non-ferrous Metals Company production nickel button uses is conductive plate, is stayed on surface round-meshed non-setting adhesive (insulating material) to be attached on conductive plate (negative plate) during production.The conductive plate circular hole of these exposures defines electrolysis cathode, can be produced the nickel button of regular appearance by electrolytic process.In process of production, non-setting adhesive soaks for a long time in the electrolytic solution, there will be the problem such as crimping, hole area increase, affects the normal production of nickel button, so need often to change non-setting adhesive.But the non-setting adhesive after soaking often solidifies (effect of electric current, temperature and electrolytic solution), is difficult to it thoroughly to peel off from negative plate by conventional means; And the part remained on negative plate can affect the electrical properties of negative electrode, cause electrolysis gained nickel buckle-shaped shape irregularity even to occur sudden and violent button, have a strong impact on industrial production.For this problem, the existing solution of Jinchuan Non-ferrous Metals Company is rinsed with water more two days later by the negative plate high temperature alkali cooking after peeling off non-setting adhesive.Obviously process takies production unit and reduces industrial production efficiency for a long time, and hot conditions can accelerate the corrosion of alkali anticathode plate simultaneously.
Document " epoxy glue degumming agent " (engineering plastics are applied, 01 phase in 1985 the 46th page) discloses a kind of epoxy glue degumming agent, and its formula is methylene dichloride 80 milliliters, 15 milliliters, formic acid, phenol 5 grams, cresol 15 milliliters.Document " organic gel degumming agent " (New Technologies, phase nineteen eighty-two 01 the 7th page) disclose a kind of degumming agent for removing the organic gel such as epoxy resin, resol, its formula is methylene dichloride 30 milliliters, cresylol 15 milliliters, 5 milliliters, formic acid, liquid paraffin 1 milliliter, supervinyi chloride resin 1 gram.Document " organic gel degumming agent " is (bonding, 02 phase in 1987 the 41st page) disclose a kind of degumming agent for removing the organic gel such as epoxy, phenolic aldehyde, its formula is methylene dichloride 80 milliliters, 10 milliliters, formic acid, phenol 5 grams, cresylol 20 milliliters, liquid paraffin 1 milliliter.Though these degumming agents have certain removal effect to organic gel, their strong toxicity, pollute large, cost is high, and the corrosion of anticathode plate is strong.Therefore, development a kind of with low cost, toxicity is little, volatility is little, to base material corrosion is little and the significant degumming agent of degumming effect is imperative.
Summary of the invention
The technical problem to be solved in the present invention overcomes existing defect, provides a kind of combined degumming agent and its preparation method and application.
In order to solve the problems of the technologies described above, the invention provides following technical scheme:
A kind of combined degumming agent, by weight, by the B component of the component A of 85%-95%, 1-10%, surplus is that component C makes, and wherein, component A is alcohol, ketone and/or aldehyde, and B component is alkali, and component C is solvent.
Further, described alcohol is methyl alcohol, ethanol, propyl alcohol, Virahol, propyl carbinol, isopropylcarbinol, Pentyl alcohol and/or primary isoamyl alcohol; Described ketone is acetone, butanone, 2 pentanone, propione and/or pimelinketone; Described aldehyde is propionic aldehyde, butyraldehyde, valeral and/or phenyl aldehyde.
Further, described alkali is potassium hydroxide, sodium hydroxide, lithium hydroxide, cesium hydroxide, copper hydroxide, aluminium hydroxide, diethylamine, triethylamine, propylamine, butylamine, hexahydroaniline and/or quadrol.
Further, described solvent is water, dimethyl sulfoxide (DMSO), normal butane, trichloromethane, tetracol phenixin, ethyl acetate, sherwood oil or toluene.
The preparation method of aforesaid combination type degumming agent, B component is first dissolved with component C, then mixes with component A.
Described combined degumming agent is used for nickel button negative plate and comes unstuck.
Compared with existing degumming agent, it is low that combined degumming agent of the present invention has cost, the features such as toxicity is low, and volatility is little, and corrosion-free to nickel button negative plate.
Embodiment
Below the preferred embodiments of the present invention are described, should be appreciated that preferred embodiment described herein is only for instruction and explanation of the present invention, is not intended to limit the present invention.
The present invention's nickel button negative plate (electrolysis production nickel buckles adopted negative plate) used is provided by refinery of Jinchuan Non-ferrous Metals Company, and remained on surface has and removes unclean non-setting adhesive insulating material and sizing agent.
With plasticine, nickel is buckled negative plate and be divided into several dice, in each dice, use different organic solvents except glue respectively, experimental result is in table 1:
Table 1 organic solvent comes unstuck experimental result
Problems existing when the present invention is directed to existing nickel button negative plate degumming cleaning, provides a kind of combined degumming agent, by weight, by the component A of 85%-95%, the B component of 1-10%, surplus is that component C makes, wherein, component A is alcohol, ketone and/or aldehyde, and B component is alkali, and component C is solvent.Described alcohol is methyl alcohol, ethanol, propyl alcohol, Virahol, propyl carbinol, isopropylcarbinol, Pentyl alcohol and/or primary isoamyl alcohol; Described ketone is acetone, butanone, 2 pentanone, propione and/or pimelinketone; Described aldehyde is propionic aldehyde, butyraldehyde, valeral and/or phenyl aldehyde.Described alkali is potassium hydroxide, sodium hydroxide, lithium hydroxide, cesium hydroxide, copper hydroxide, aluminium hydroxide, diethylamine, triethylamine, propylamine, butylamine, hexahydroaniline and/or quadrol.Described solvent is water, dimethyl sulfoxide (DMSO), normal butane, trichloromethane, tetracol phenixin, ethyl acetate, sherwood oil or toluene.
B component is first dissolved with component C, then mixes with component A, namely obtains described combined degumming agent.
The test-results that the present invention soaks nickel button negative plate with different degumming agents is as shown in table 2:
No. 5 degumming agents are poured into 90 × 90 × 1.5cm
3plastic channel, just tearing in the nickel button negative plate insertion groove of non-setting adhesive of refinery of Jinchuan Non-ferrous Metals Company being provided is soaked one hour, finds that cathode plate surface sizing agent remove totally after rinsing with water.Negative plate after coming unstuck fastens lattice for the nickel of electrolysis production after sandblasting, pad pasting, does not occur sudden and violent button.
Last it is noted that the foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, although with reference to previous embodiment to invention has been detailed description, for a person skilled in the art, it still can be modified to the technical scheme described in foregoing embodiments, or carries out equivalent replacement to wherein portion of techniques feature.Within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (6)
1. a combined degumming agent, by weight, by the B component of the component A of 85%-95%, 1-10%, surplus is that component C makes, and wherein, component A is alcohol, ketone and/or aldehyde, and B component is alkali, and component C is solvent.
2. combined degumming agent according to claim 1, is characterized in that, described alcohol is methyl alcohol, ethanol, propyl alcohol, Virahol, propyl carbinol, isopropylcarbinol, Pentyl alcohol and/or primary isoamyl alcohol; Described ketone is acetone, butanone, 2 pentanone, propione and/or pimelinketone; Described aldehyde is propionic aldehyde, butyraldehyde, valeral and/or phenyl aldehyde.
3. combined degumming agent according to claim 1, it is characterized in that, described alkali is potassium hydroxide, sodium hydroxide, lithium hydroxide, cesium hydroxide, copper hydroxide, aluminium hydroxide, diethylamine, triethylamine, propylamine, butylamine, hexahydroaniline and/or quadrol.
4. combined degumming agent according to claim 1, is characterized in that, described solvent is water, dimethyl sulfoxide (DMSO), normal butane, trichloromethane, tetracol phenixin, ethyl acetate, sherwood oil or toluene.
5. the preparation method of the arbitrary described combined degumming agent of claim 1-4, B component is first dissolved with component C, then mixes with component A, and component A is alcohol, ketone and/or aldehyde, and B component is alkali, and component C is solvent.
6. claim 1-4 office is stated combined degumming agent and is come unstuck for nickel button negative plate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510837905.9A CN105462713B (en) | 2015-11-26 | 2015-11-26 | A kind of combined degumming agent and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510837905.9A CN105462713B (en) | 2015-11-26 | 2015-11-26 | A kind of combined degumming agent and its preparation method and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105462713A true CN105462713A (en) | 2016-04-06 |
| CN105462713B CN105462713B (en) | 2018-04-03 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510837905.9A Active CN105462713B (en) | 2015-11-26 | 2015-11-26 | A kind of combined degumming agent and its preparation method and application |
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| Country | Link |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106244350A (en) * | 2016-07-23 | 2016-12-21 | 扬中市创想驿站工业设计有限公司 | Organic washing agent |
| CN106381764A (en) * | 2016-09-23 | 2017-02-08 | 广东工业大学 | Degumming agent of pressure-sensitive adhesive and method for removing pressure-sensitive adhesive |
| CN109486567A (en) * | 2018-12-08 | 2019-03-19 | 深圳市金朝珠宝首饰有限公司 | A kind of liquid medicine for jewelry degumming |
| CN110204949A (en) * | 2019-06-21 | 2019-09-06 | 佛山市高明德健五金有限公司 | A kind of metal surface pressure sensitive membrane remover and preparation method thereof |
Citations (6)
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| CN101173156A (en) * | 2007-09-27 | 2008-05-07 | 夏晓军 | Conductive adhesive degumming agent and use method of the degumming agent |
| CN101251723A (en) * | 2008-03-19 | 2008-08-27 | 曹学增 | Negative colorful photoresist degumming agent and method for preparing the same |
| CN103343068A (en) * | 2013-06-18 | 2013-10-09 | 厦门市豪尔新材料有限公司 | Glue stripping agent |
| CN103804980A (en) * | 2012-11-07 | 2014-05-21 | 东友精细化工有限公司 | Cleaning solution composition for offset-printing gravure and cleaning method using the same |
| CN104024394A (en) * | 2012-11-21 | 2014-09-03 | 戴纳洛伊有限责任公司 | Process And Composition For Removing Substances From Substrates |
| CN104181782A (en) * | 2014-09-04 | 2014-12-03 | 苏州市晶协高新电子材料有限公司 | UV (ultraviolet) curing adhesive stripper, preparation method thereof and adhesive stripping method thereof |
-
2015
- 2015-11-26 CN CN201510837905.9A patent/CN105462713B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101173156A (en) * | 2007-09-27 | 2008-05-07 | 夏晓军 | Conductive adhesive degumming agent and use method of the degumming agent |
| CN101251723A (en) * | 2008-03-19 | 2008-08-27 | 曹学增 | Negative colorful photoresist degumming agent and method for preparing the same |
| CN103804980A (en) * | 2012-11-07 | 2014-05-21 | 东友精细化工有限公司 | Cleaning solution composition for offset-printing gravure and cleaning method using the same |
| CN104024394A (en) * | 2012-11-21 | 2014-09-03 | 戴纳洛伊有限责任公司 | Process And Composition For Removing Substances From Substrates |
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| CN104181782A (en) * | 2014-09-04 | 2014-12-03 | 苏州市晶协高新电子材料有限公司 | UV (ultraviolet) curing adhesive stripper, preparation method thereof and adhesive stripping method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106244350A (en) * | 2016-07-23 | 2016-12-21 | 扬中市创想驿站工业设计有限公司 | Organic washing agent |
| CN106381764A (en) * | 2016-09-23 | 2017-02-08 | 广东工业大学 | Degumming agent of pressure-sensitive adhesive and method for removing pressure-sensitive adhesive |
| CN109486567A (en) * | 2018-12-08 | 2019-03-19 | 深圳市金朝珠宝首饰有限公司 | A kind of liquid medicine for jewelry degumming |
| CN109486567B (en) * | 2018-12-08 | 2021-04-16 | 深圳市金朝珠宝首饰有限公司 | Liquid medicine for jewelry degumming |
| CN110204949A (en) * | 2019-06-21 | 2019-09-06 | 佛山市高明德健五金有限公司 | A kind of metal surface pressure sensitive membrane remover and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN105462713B (en) | 2018-04-03 |
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