CN105462363A - Ceramic color penetration marking ink and preparing method and application thereof - Google Patents
Ceramic color penetration marking ink and preparing method and application thereof Download PDFInfo
- Publication number
- CN105462363A CN105462363A CN201510939740.6A CN201510939740A CN105462363A CN 105462363 A CN105462363 A CN 105462363A CN 201510939740 A CN201510939740 A CN 201510939740A CN 105462363 A CN105462363 A CN 105462363A
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- China
- Prior art keywords
- ink
- ceramic
- pullulan
- pottery
- marking ink
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/463—Organic solvents
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5007—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with salts or salty compositions, e.g. for salt glazing
- C04B41/5011—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with salts or salty compositions, e.g. for salt glazing containing halogen in the anion
- C04B41/5012—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with salts or salty compositions, e.g. for salt glazing containing halogen in the anion chlorides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention belongs to the technical field of ceramic ink and discloses ceramic color penetration marking ink and the preparing method and application thereof. The ink is prepared from, by mass, 0.5-2.5% of pullulan microorganism macromolecule additive, 51.2-60% of nonferrous metal compound, 0.5-5% of ethanediol and the balance water. The nonferrous metal compound is cobalt chloride, or manganese chloride or nickel nitrate. The ink can also contain 0.1-0.5% of polyvinylpyrrolidone and 0.2-0.8% of carrageenan. The components are made into the ceramic color penetration marking ink with the dispersion method. The ink can be used for preparing architectural ceramic color-penetrated tiles. The pullulan microorganism macromolecule additive is adopted, the structural characteristics of pullulan are utilized, the rotatability of the polysaccharide macromolecular structure enables a main chain to be stable within a wide pH range, and through the action between hydroxyl groups of polysaccharide macromolecules and metal ions, metal ions are stable in a pullulan solution and sedimentation is avoided.
Description
Technical field
The invention belongs to ceramic marking ink technical field, particularly a kind of pottery utilizing pullulan microorganism pluronic polymer to make oozes colored marking ink and its preparation method and application.
Background technology
The principle of ceramic decoration employing spray ink Printing is: tinting material is made multi-color ink, it is directly printed on ceramic surface, can stablize color development after burning till product by the mode of spray ink Printing.Inkjet technology is compared with existing ceramic decoration means, and tool has the following advantages: the first, product exquisiteness true to nature, can obtain the texture variations abundanter than conventional ceramic tile; The second, can realize personalized designs and manufacture, ink jet printing only needs In-put design pattern on computers just can run, and is conducive to the Ceramic Production of multiple patterns short run; 3rd, spray ink Printing, without the need to contacting base substrate, can reduce ceramic tile breakage rate; 4th, on ceramic tile three-dimensional contouring face, especially various concavo-convex surface is earned with on face, oblique angle, can print out imitative oil painting more true to nature, imitative bark, imitative wood grain, the products such as imitative high-grade rock ceramic tile.
The key application of inkjet technology on pottery is the preparation of ceramic ink.So-called ceramic ink is exactly the ink containing certain ceramic batch, ceramic pigment or ceramic colorant.The composition of ceramic ink is relevant with ink purposes with the principle of work of printer with performance.Ceramic ink is made up of ceramic powder (colorant, tinting material), solvent, dispersion agent, bonding agent, tensio-active agent and other auxiliary material usually.
At the beginning of 21 century, Ferro Corporation develops the oil-based ink being adapted at pottery carrying out spray ink Printing, and crossing the corresponding patent No. at me is 00818261.2, from then on starts the widespread use of inkjet technology at ceramic building production field.Application number be 201010117934.5,201110375883.0 and the Chinese invention patent of 201210489664.X individually disclose ceramic ink jet printing ink and preparation method thereof; Application number be 201210138634.1 Chinese invention patent disclose a kind of aqueous ceramic solid pattern marking ink and preparation method thereof.But ceramic ink jet ink disclosed in these, all needs to be further improved in stability, hair color effect and ink-jet printer are compatible etc.
At present, ceramic ink in actual applications Problems existing due to: (1) relates to multiple high-technology field due to ceramic ink technology of preparing, and research and development difficulty is large, thus can commercial ceramic ink kind also little; (2) to different types of product, need to research and develop corresponding special spray ink Printing machine, this makes the application of ceramic ink be subject to a definite limitation; (3) production cost is higher.Therefore, in the urgent need to developing a kind of stable performance, hair color effect is good, moderate, the ink compatible good with ink-jet printer.
Summary of the invention
In order to solve above-mentioned the deficiencies in the prior art part, primary and foremost purpose of the present invention is to provide a kind of pottery to ooze colored marking ink.
Another object of the present invention is to provide above-mentioned pottery to ooze the preparation method of colored ink.
Another object of the present invention is to provide above-mentioned pottery to ooze the application of colored ink.
Object of the present invention is realized by following technical proposals:
A kind of pottery oozes colored marking ink, and this ink comprises following component by mass percentage:
Microorganism pluronic polymer 0.5 ~ 2.5%
Non-ferrous metal compound 51.2 ~ 60%
Ethylene glycol 0.5 ~ 5%
Surplus is water;
Described microorganism pluronic polymer is pullulan;
Described non-ferrous metal compound is cobalt chloride, Manganous chloride tetrahydrate or nickelous nitrate.
Described ink also comprises following component by mass percentage: polyvinylpyrrolidone 0.1 ~ 0.5%, carrageenin 0.2 ~ 0.8%.
Said components is prepared according to dispersion method by the preparation method that above-mentioned pottery oozes colored marking ink.
Above-mentioned pottery oozes colored marking ink and can be applied to and prepare architectural pottery pattern permeating tile.
Principle of the present invention:
Pottery of the present invention oozes in colored ink set and adopts pullulan microorganism pluronic polymer, utilize the feature of pullulan structure, the rotatory of polysaccharide polymer structure makes main chain at wider pH range stabilises, add the oh group of polysaccharide polymer and the effect of metal ion, serve metal ion stable not sedimentation in pullulan solution, in ink production process, serve well stable and dissemination.
Hinge structure of the present invention, there is following advantage and beneficial effect: the present invention adopts microorganism pluronic polymer pullulan first, the effect of stablizer and dispersion agent can be played, synergistic effect is played with other dispersion agents, tensio-active agent and solvent in formula, improve colorant, tinting material and the auxiliary material stability in ink set, the mechanical stability in print system and compatibility.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, but embodiments of the present invention are not limited thereto.
Embodiment 1:
The present embodiment pottery oozes colored marking ink and is made up of following component by mass percentage:
Said components is prepared into blue ceramic according to dispersion method and oozes colored marking ink.
The Detection of Stability of gained ink is as shown in table 1, thus good stability, also very good with the compatibility of ink-jet printer.
Table 1 embodiment 1 gained stability of ink is checked
Embodiment 2:
The present embodiment pottery oozes colored marking ink and is made up of following component by mass percentage:
Said components is prepared into red ceramic according to dispersion method and oozes colored marking ink.
The Detection of Stability of gained ink is as shown in table 2, thus good stability, also very good with the compatibility of ink-jet printer.
Table 2 embodiment 2 gained stability of ink is checked
Embodiment 3:
The present embodiment pottery oozes colored marking ink and is made up of following component by mass percentage:
Said components is prepared into tawny pottery according to dispersion method and oozes colored marking ink.
The Detection of Stability of gained ink is as shown in table 3, thus good stability, also very good with the compatibility of ink-jet printer.
Table 3 embodiment 3 gained stability of ink is checked
Embodiment 4:
The present embodiment pottery oozes colored marking ink and is made up of following component by mass percentage:
Said components is prepared into tawny pottery according to dispersion method and oozes colored marking ink.
The Detection of Stability of gained ink is as shown in table 4, thus good stability, also very good with the compatibility of ink-jet printer.
Table 4 embodiment 4 gained stability of ink is checked
Above-described embodiment is the present invention's preferably embodiment; but embodiments of the present invention are not restricted to the described embodiments; change, the modification done under other any does not deviate from spirit of the present invention and principle, substitute, combine, simplify; all should be the substitute mode of equivalence, be included within protection scope of the present invention.
Claims (4)
1. pottery oozes a colored marking ink, it is characterized in that: this ink comprises following component by mass percentage:
Microorganism pluronic polymer 0.5 ~ 2.5%
Non-ferrous metal compound 51.2 ~ 60%
Ethylene glycol 0.5 ~ 5%
Surplus is water;
Described microorganism pluronic polymer is pullulan;
Described non-ferrous metal compound is cobalt chloride, Manganous chloride tetrahydrate or nickelous nitrate.
2. a kind of pottery according to claim 1 oozes colored marking ink, it is characterized in that: described ink also comprises following component by mass percentage: polyvinylpyrrolidone 0.1 ~ 0.5%, carrageenin 0.2 ~ 0.8%.
3. a kind of pottery according to claim 1 and 2 oozes the preparation method of colored marking ink, it is characterized in that: this preparation method is prepared according to dispersion method.
4. pottery according to claim 1 and 2 oozes colored marking ink and is preparing the application in architectural pottery pattern permeating tile.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510939740.6A CN105462363A (en) | 2015-12-15 | 2015-12-15 | Ceramic color penetration marking ink and preparing method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510939740.6A CN105462363A (en) | 2015-12-15 | 2015-12-15 | Ceramic color penetration marking ink and preparing method and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105462363A true CN105462363A (en) | 2016-04-06 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510939740.6A Pending CN105462363A (en) | 2015-12-15 | 2015-12-15 | Ceramic color penetration marking ink and preparing method and application thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004051882A (en) * | 2002-07-23 | 2004-02-19 | Konica Minolta Holdings Inc | Water-based ink for ink-jet recording, method for producing the same, ink-jet recording apparatus and ink-jet recording method |
| CN102249741A (en) * | 2011-07-05 | 2011-11-23 | 佛山欧神诺陶瓷股份有限公司 | Ceramic penetration glaze suitable for spray ink printing and method for using same to produce ceramic tiles |
| CN102382518A (en) * | 2011-11-23 | 2012-03-21 | 佛山市明朝科技开发有限公司 | Ceramic ink-jet ink with low viscosity and preparation method thereof |
| CN104910691A (en) * | 2014-03-15 | 2015-09-16 | 兄弟工业株式会社 | Water-Based Ink for Ink-Jet Recording, Ink Box, Water-Based Ink Set for Ink-Jet Recording, Treatment Agent And Box |
| CN105131715A (en) * | 2015-10-15 | 2015-12-09 | 王护来 | Water ink for ceramic ink-jet printing and preparation method thereof |
-
2015
- 2015-12-15 CN CN201510939740.6A patent/CN105462363A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004051882A (en) * | 2002-07-23 | 2004-02-19 | Konica Minolta Holdings Inc | Water-based ink for ink-jet recording, method for producing the same, ink-jet recording apparatus and ink-jet recording method |
| CN102249741A (en) * | 2011-07-05 | 2011-11-23 | 佛山欧神诺陶瓷股份有限公司 | Ceramic penetration glaze suitable for spray ink printing and method for using same to produce ceramic tiles |
| CN102382518A (en) * | 2011-11-23 | 2012-03-21 | 佛山市明朝科技开发有限公司 | Ceramic ink-jet ink with low viscosity and preparation method thereof |
| CN104910691A (en) * | 2014-03-15 | 2015-09-16 | 兄弟工业株式会社 | Water-Based Ink for Ink-Jet Recording, Ink Box, Water-Based Ink Set for Ink-Jet Recording, Treatment Agent And Box |
| CN105131715A (en) * | 2015-10-15 | 2015-12-09 | 王护来 | Water ink for ceramic ink-jet printing and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 尹光琳等: "《发酵工业全书》", 31 July 1996, 中国医药科技出版社 * |
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Application publication date: 20160406 |
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