CN105442299A - Flame-retardant environment-friendly textile and preparation method thereof - Google Patents
Flame-retardant environment-friendly textile and preparation method thereof Download PDFInfo
- Publication number
- CN105442299A CN105442299A CN201610013553.XA CN201610013553A CN105442299A CN 105442299 A CN105442299 A CN 105442299A CN 201610013553 A CN201610013553 A CN 201610013553A CN 105442299 A CN105442299 A CN 105442299A
- Authority
- CN
- China
- Prior art keywords
- textiles
- flame
- textile
- friendly
- retardant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004753 textile Substances 0.000 title claims abstract description 99
- 239000003063 flame retardant Substances 0.000 title claims abstract description 37
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 23
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 22
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical group C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 17
- 239000000835 fiber Substances 0.000 claims abstract description 15
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 19
- 239000000347 magnesium hydroxide Substances 0.000 claims description 19
- 239000005011 phenolic resin Substances 0.000 claims description 15
- 229920001568 phenolic resin Polymers 0.000 claims description 15
- 230000008569 process Effects 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 14
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 13
- 229920000742 Cotton Polymers 0.000 claims description 12
- 239000000853 adhesive Substances 0.000 claims description 6
- 230000001070 adhesive effect Effects 0.000 claims description 6
- 230000010355 oscillation Effects 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 239000012790 adhesive layer Substances 0.000 claims description 4
- 241000208202 Linaceae Species 0.000 claims description 3
- 235000004431 Linum usitatissimum Nutrition 0.000 claims description 3
- 239000003292 glue Substances 0.000 claims description 3
- 239000010410 layer Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 238000007598 dipping method Methods 0.000 claims description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract description 18
- 229910052736 halogen Inorganic materials 0.000 abstract description 5
- 150000002367 halogens Chemical class 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 4
- 238000004140 cleaning Methods 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 239000008213 purified water Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 239000004744 fabric Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000003344 environmental pollutant Substances 0.000 description 3
- 239000004745 nonwoven fabric Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 231100000719 pollutant Toxicity 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000009938 salting Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 231100000075 skin burn Toxicity 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/41—Phenol-aldehyde or phenol-ketone resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention relates to a flame-retardant environment-friendly textile and a preparation method thereof. The flame-retardant environment-friendly textile comprises a textile body and a flame-retardant finishing material which is cured in gaps of fibers of the textile and on the surfaces of the fibers, wherein the flame-retardant finishing material comprises a magnesium hydrate flame retardant and a crosslinking agent; 5 to 8wt% of magnesium hydrate flame retardant is cured in the textile, the crosslinking agent is dicumyl peroxide, and 0.8 to 2wt% of dicumyl peroxide is cured in the textile. The preparation method comprises the following steps: adding the magnesium hydrate flame retardant and the dicumyl peroxide crosslinking agent to purified water according to a certain proportion to prepare a finishing solution, putting the textile in the finishing solution and carrying out padding treatment, and carrying out drying, baking, cleaning and other working procedures according to a specific method. The flame-retardant environment-friendly textile disclosed by the invention has flame retardant capability, durable flame retardant capability and resistance to washing, and no halogen, organophosphorus or formaldehyde is added in the production process.
Description
Technical field
The present invention relates to a kind of fire proofing and preparation method thereof, particularly relate to a kind of anti-flaming environment-friendly textiles and preparation method thereof.
Background technology
In recent years along with decorative textile product consumption figure increases rapidly, the fire caused by textiles constantly increases, wherein on fire for one of the main reasons with bedding, home decoration cloth.After the textiles of burning and human contact, gently then cause skin burn, heavy then threat to life.In textile combustion, the health of a large amount of pernicious gases discharged also entail dangers to people, comprises and dying as the multiple gases such as carbon monoxide, hydrogen cyanide and aldehydes all can cause people to be choked to death.Therefore, while fire preventing occurs, how to improve Fire-proof Finishing Agents for Textile performance, alleviate the loss that fire causes, day by day become the important topic of finishing functions of textile fabrics working research.
Traditional fire retardant mostly is organophosphor or halogen containing flame-retardant, but the halogen content in content of formaldehyde free in the textiles after arranging or fire retardant is high, human body is worked the mischief, not environmentally, the process discharge of pollutant is also more difficult, simultaneously, traditional method for sorting, be all utilize finishing agent to dip textiles, the textiles washability after the method arranges is poor, and the water proof fire retardant performance duration of textiles is shorter.
In the Patents applied at home, patent " a kind of easily decomposition flame-resistant temperature-adjustmenon-woven environment-friendlynon-woven non-woven fabric and preparation method thereof " (application number: 201510387416.8, publication date: 2015.11.11) provide a kind of easily decomposition flame-resistant temperature-adjustmenon-woven environment-friendlynon-woven non-woven fabric and preparation method thereof, its material quality number is: polypropylene 2000 parts, coupling agent 5 ~ 10 parts, silicone oil 5 ~ 10 parts, nano-meter flame retardants 1 ~ 5 part, vector resin 3 ~ 8 parts, phase-changing and temperature-regulating element 50 ~ 100 parts, high purity water is appropriate, this method can produce to be had manufacturing of fire retardancy and easily decomposes flame-resistant temperature-adjustmenon-woven environment-friendlynon-woven non-woven fabric, but its complex process, raw material is adopted to comprise nano-meter flame retardants etc., cost is higher, manufactured goods direct spraying is on cloth simultaneously, adhesion is low, coating quality cannot ensure, patent " flame-retardant finishing method of cotton textiles or cotton blended fabric " (application number: 201510009393.7, publication date: 2015.05.13) provide the flame-retardant finishing method of a kind of cotton textiles or cotton blended fabric, its composition at least comprises phosphorus compound, aminated compounds, softener, the flame-proof treatment thing of cotton textiles or cotton blended fabric can be produced, but containing phosphide, formaldehyde in its additive, be unfavorable for environmental protection, be also unfavorable for the discharge of pollutant.Patent like this, the principal component of employing mostly is organic matter or phosphorus-containing compound, and the usual cost of raw material is high, not environmentally, do not meet the development trend that textile industry is current, adopts without phosphorus halogen-free flame retardants to be trend of the times.
Magnesium hydroxide is as the novel filled-type fire retardant of one, Bound moisture is discharged during decomposes, absorb a large amount of latent heat, reduce the surface temperature of synthetic material in flame that it fills, there is the effect suppressing polymer unwinds and cool produced fuel gas, it is comparatively ripe for flame retardant area, but because generally acknowledge that it is not easily solidificated in textiles, is ostracised inventor beyond the invisible all the time.Patent " a kind of preparation method of Novel waterproof flame-retarding textiles " (application number: 201510057835.5, publication date: 2015.04.29) provide a kind of preparation method of flame retardant textiles, overcome technology prejudice to a certain extent, have employed magnesium hydroxide as fire retardant, the steps include: to process in the ultrasonic preliminary treatment → low pressure plasma equipment of textiles → by fire retardant (be preferably magnesium hydroxide), polyacrylate, crosslinking agent, dispersant and deionized water mixing, ultrasonic process obtains water proof fire retardant finishing agent → bis-leaching two bundles, clean water, dry, bake, this method can produce the new textile with fire retardancy, but the polyacrylate cold resistance wherein increased is poor, not water-fast, steam, soda acid, salting liquid and organic polar solvent, poor flexibility under room temperature, wear no resistance, be unfavorable for the serviceability of textiles, the crosslinking agent simultaneously added is N ~ n-methylolacrylamide, belong to micro-poison containing formaldehyde crosslinking agent, certain stimulation and injury is had to human body.
Summary of the invention
For the problems referred to above, the object of this invention is to provide a kind of there is fire retardancy, textiles that fire retardancy durable, washable and production process halogen, organophosphor and formaldehyde add and preparation method thereof.
For achieving the above object, the present invention takes following technical scheme: a kind of anti-flaming environment-friendly textiles, comprise textiles itself and be solidificated in the flame-proof treatment thing with fiber surface in described textile fiber gap, described flame-proof treatment thing comprises flame retardant of magnesium hydroxide, crosslinking agent, it is characterized in that: be solidified with 5 ~ 8wt% flame retardant of magnesium hydroxide in described textiles; Described crosslinking agent is cumyl peroxide, is solidified with 0.8 ~ 2wt% cumyl peroxide crosslinking agent in described textiles.
Described textiles is cotton or linen textile.
Also include one deck phenolic resin adhesive layer between described textiles and flame-proof treatment thing, the thickness of phenolic resin adhesive is 1 ~ 15 millimeter.
The preparation method of above-mentioned anti-flaming environment-friendly textiles, comprises the following steps:
(1) a certain amount of pure water is prepared, volume integral another name according to described pure water gets described flame retardant of magnesium hydroxide 250 ~ 400g/L, cumyl peroxide 40 ~ 100g/L, above-mentioned substance is added in described pure water, again made mixed liquor is added in sonic oscillation generator, vibrate 20 ~ 100 minutes, for subsequent use as dressing liquid;
(2) textiles is immersed in the dressing liquid of previous step generation, carry out padding process, pick-up 60% ~ 80%;
(3) textiles carrying out padding process is dried under the temperature conditions of 80 ~ 100 DEG C, then bake under the high temperature of 150 ~ 160 DEG C;
(4), after baked pure water used for textiles being cleaned 2 ~ 5 times, dry at 80 ~ 100 DEG C, bake 15 ~ 20min at 150 ~ 160 DEG C, obtain anti-flaming environment-friendly textiles.
Before described step (1), also comprise impregnation operation, being immersed in viscosity at described textiles is 10 ~ 15CP
.s, solid content is that in the impregnating phenolic resin adhesive of 5 ~ 8%, dip time is 3 ~ 5min, after dipping, forms on flax fibre surface the phenolic resin glue rete that a layer thickness is 1 ~ 15 micron.
The present invention is owing to taking above technical scheme, it has the following advantages: the flame retardant of magnesium hydroxide added in the dressing liquid of textiles can improve the toughness of material, heat resistance and stability widely, textiles is made to have the high flame retardant usefulness pressing down cigarette, nontoxic, environmental protection, the cumyl peroxide crosslinking agent added in dressing liquid, significantly can improve the adhesion of effective fire-retardant composition and textiles in dressing liquid, make this textiles more washable, flame-retarded efficiency is longer than general flame-retardant textile; Owing to adding without any halogen, organophosphor or formaldehyde in whole production process, be conducive to the process discharge of environmental protection and pollutant, one deck phenolic resin adhesive layer is provided with between textiles and arrangement thing, enable the permanent surface being fixed on textiles of arrangement thing, in addition, phenolic resins has good fire resistance.
Below in conjunction with specific embodiment, the invention will be further described, not limitation of the present invention, and the equivalent replacement of every any this area of carrying out according to the disclosure of invention, all belongs to protection scope of the present invention.
Detailed description of the invention
Embodiment 1:
Anti-flaming environment-friendly cotton textiles, comprise cotton textiles itself and be solidificated in the flame-proof treatment thing with fiber surface in described textile fiber gap, described flame-proof treatment thing comprises magnesium hydroxide, cumyl peroxide, it is characterized in that: be solidified with 7wt% magnesium hydroxide in described textiles; Be solidified with 1.5wt% cumyl peroxide in described textiles, also include one deck phenolic resin adhesive layer between described textiles and flame-proof treatment thing, the thickness of phenolic resin adhesive is 10 millimeters.
Preparation method:
(1) cotton textiles are immersed in impregnating phenolic resin adhesive, dip time be 3min, the viscosity of described phenolic resins is 40CP.s, and solid content is 14%, and forming a layer thickness on flax fibre surface is the phenolic resin glue rete of 10 microns.
(2) a certain amount of pure water is prepared, volume integral another name according to described pure water gets magnesium hydroxide 350g/L, cumyl peroxide 75g/L, is added in described pure water by above-mentioned substance, then adds in sonic oscillation generator by made mixed liquor, vibrate 80 minutes, for subsequent use as dressing liquid;
(3) textiles is immersed in the dressing liquid of previous step generation, carry out padding process, pick-up 70%;
(4) textiles carrying out padding process is dried under the temperature conditions of 100 DEG C, then bake under the high temperature of 150 DEG C;
(5), after baked pure water used for textiles being cleaned 3 times, dry at 100 DEG C, bake 20min at 150 DEG C, obtain anti-flaming environment-friendly cotton textiles.
Embodiment 2:
Anti-flaming environment-friendly linen textile, comprise linen textile itself and be solidificated in described linen textile fibre gap and the flame-proof treatment thing of fiber surface, described flame-proof treatment thing comprises magnesium hydroxide, crosslinking agent, it is characterized in that: be solidified with 8wt% magnesium hydroxide in described textiles; Described crosslinking agent is cumyl peroxide, is solidified with 2wt% cumyl peroxide in described textiles.
Preparation method:
(1) a certain amount of pure water is prepared, volume integral another name according to described pure water gets described magnesium hydroxide 400g/L, cumyl peroxide 100g/L, above-mentioned substance is added in described pure water, again made mixed liquor is added in sonic oscillation generator, vibrate 100 minutes, for subsequent use as dressing liquid;
(2) textiles is immersed in the dressing liquid of previous step generation, carry out padding process, pick-up 80%;
(3) textiles carrying out padding process is dried under the temperature conditions of 100 DEG C, then bake under the high temperature of 150 DEG C;
(4), after baked pure water used for textiles being cleaned 5 times, dry at 100 DEG C, bake 15min at 150 DEG C, obtain anti-flaming environment-friendly textiles.
Embodiment 3:
Anti-flaming environment-friendly textiles, comprise textiles itself and be solidificated in the flame-proof treatment thing with fiber surface in described textile fiber gap, described flame-proof treatment thing comprises magnesium hydroxide, cumyl peroxide, it is characterized in that: be solidified with 5wt% flame retardant of magnesium hydroxide in described textiles; Described crosslinking agent is cumyl peroxide, is solidified with 2wt% cumyl peroxide in described textiles.
Preparation method:
(1) a certain amount of pure water is prepared, volume integral another name according to described pure water gets flame retardant of magnesium hydroxide 250g/L, cumyl peroxide 40g/L, above-mentioned substance is added in described pure water, again made mixed liquor is added in sonic oscillation generator, vibrate 20 minutes, for subsequent use as dressing liquid;
(2) textiles is immersed in the dressing liquid of previous step generation, carry out padding process, pick-up 60%;
(3) textiles carrying out padding process is dried under the temperature conditions of 80 DEG C, then bake under the high temperature of 160 DEG C;
(4), after baked pure water used for textiles being cleaned 2 times, dry at 80 DEG C, bake 20min at 160 DEG C, obtain anti-flaming environment-friendly textiles.
To the above-mentioned explanation of the disclosed embodiments, only in order to enable professional and technical personnel in the field realize or use the present invention.To be apparent for those skilled in the art to the multiple amendment of these embodiments, General Principle as defined herein can without departing from the spirit or scope of the present invention, realize in other embodiments.Therefore, the present invention can not be restricted to these embodiments shown in this article, but will meet the widest scope consistent with principle disclosed herein and features of novelty.
Claims (5)
1. an anti-flaming environment-friendly textiles, comprise textiles itself and be solidificated in the flame-proof treatment thing with fiber surface in described textile fiber gap, described flame-proof treatment thing comprises flame retardant of magnesium hydroxide, crosslinking agent, it is characterized in that: be solidified with 5 ~ 8wt% flame retardant of magnesium hydroxide in described textiles; Described crosslinking agent is cumyl peroxide, is solidified with 0.8 ~ 2wt% cumyl peroxide crosslinking agent in described textiles.
2. anti-flaming environment-friendly textiles according to claim 1, is characterized in that: described textiles is cotton or linen textile.
3. anti-flaming environment-friendly textiles according to claim 1, it is characterized in that: also include one deck phenolic resin adhesive layer between described textiles and flame-proof treatment thing, the thickness of phenolic resin adhesive is 1 ~ 15 millimeter.
4. a preparation method for anti-flaming environment-friendly textiles, is characterized in that, comprises the following steps:
(1) a certain amount of pure water is prepared, volume integral another name according to described pure water gets magnesium hydroxide 250 ~ 400g/L, described cumyl peroxide crosslinking agent 40 ~ 100g/L, above-mentioned substance is added in described pure water, again made mixed liquor is added in sonic oscillation generator, vibrate 20 ~ 100 minutes, for subsequent use as dressing liquid;
(2) textiles is immersed in the dressing liquid of previous step generation, carry out padding process, pick-up 60% ~ 80%;
(3) textiles carrying out padding process is dried under the temperature conditions of 80 ~ 100 DEG C, then bake under the high temperature of 150 ~ 160 DEG C.
(4), after baked pure water used for textiles being cleaned 2 ~ 5 times, dry at 80 ~ 100 DEG C, bake 15 ~ 20min at 150 ~ 160 DEG C, obtain anti-flaming environment-friendly textiles.
5. the preparation method of anti-flaming environment-friendly textiles according to claim 4, it is characterized in that: being immersed in viscosity at described textiles is 10 ~ 15CP.s, solid content is in the impregnating phenolic resin adhesive of 5 ~ 8%, dip time is 3 ~ 5min, after dipping, form on flax fibre surface the phenolic resin glue rete that a layer thickness is 1 ~ 15 micron.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610013553.XA CN105442299A (en) | 2016-01-08 | 2016-01-08 | Flame-retardant environment-friendly textile and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610013553.XA CN105442299A (en) | 2016-01-08 | 2016-01-08 | Flame-retardant environment-friendly textile and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105442299A true CN105442299A (en) | 2016-03-30 |
Family
ID=55552899
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610013553.XA Pending CN105442299A (en) | 2016-01-08 | 2016-01-08 | Flame-retardant environment-friendly textile and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105442299A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112656177A (en) * | 2020-11-11 | 2021-04-16 | 湖南艾佳家纺有限责任公司 | Flame-retardant cotton quilt and processing technology |
| CN112726213A (en) * | 2020-12-23 | 2021-04-30 | 广东金发科技有限公司 | Degradable flame-retardant non-woven fabric shower curtain and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102899913A (en) * | 2011-07-29 | 2013-01-30 | 上海大巨龙蓬盖新材料有限公司 | Manufacturing method for terylene strengthened filament weaving pattern rubber bottom coiled material |
| CN103114447A (en) * | 2013-03-08 | 2013-05-22 | 东莞市悠派户外用品制造有限公司 | Environment-friendly PVC (Polyvinyl Chloride) coating reflective fabric |
| CN103343454A (en) * | 2013-07-16 | 2013-10-09 | 徐州亿盈纺织科技有限公司 | Flame-retardant textile fabric and manufacturing method thereof |
| CN104562683A (en) * | 2015-02-04 | 2015-04-29 | 湖州厉华妤婕联合纺织有限公司 | Preparation method of novel waterproof fire-resistant textile |
| CN104746338A (en) * | 2013-12-31 | 2015-07-01 | 广东德美精细化工股份有限公司 | Inflaming retarding working solution and inflaming retarding finishing method of pure cotton fabric and/or cotton-polyester blended fabric |
| CN105220269A (en) * | 2015-10-26 | 2016-01-06 | 杭州先进富春化工有限公司 | A kind of production technology of PET/PBT composite fibre |
-
2016
- 2016-01-08 CN CN201610013553.XA patent/CN105442299A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102899913A (en) * | 2011-07-29 | 2013-01-30 | 上海大巨龙蓬盖新材料有限公司 | Manufacturing method for terylene strengthened filament weaving pattern rubber bottom coiled material |
| CN103114447A (en) * | 2013-03-08 | 2013-05-22 | 东莞市悠派户外用品制造有限公司 | Environment-friendly PVC (Polyvinyl Chloride) coating reflective fabric |
| CN103343454A (en) * | 2013-07-16 | 2013-10-09 | 徐州亿盈纺织科技有限公司 | Flame-retardant textile fabric and manufacturing method thereof |
| CN104746338A (en) * | 2013-12-31 | 2015-07-01 | 广东德美精细化工股份有限公司 | Inflaming retarding working solution and inflaming retarding finishing method of pure cotton fabric and/or cotton-polyester blended fabric |
| CN104562683A (en) * | 2015-02-04 | 2015-04-29 | 湖州厉华妤婕联合纺织有限公司 | Preparation method of novel waterproof fire-resistant textile |
| CN105220269A (en) * | 2015-10-26 | 2016-01-06 | 杭州先进富春化工有限公司 | A kind of production technology of PET/PBT composite fibre |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112656177A (en) * | 2020-11-11 | 2021-04-16 | 湖南艾佳家纺有限责任公司 | Flame-retardant cotton quilt and processing technology |
| CN112726213A (en) * | 2020-12-23 | 2021-04-30 | 广东金发科技有限公司 | Degradable flame-retardant non-woven fabric shower curtain and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2507209C (en) | Methods, systems and compositions for fire retarding substrates | |
| Gaan et al. | Flame retardant functional textiles | |
| CN103789858B (en) | A kind of environment-friendly type thermostable durable flame-retardant fiber and preparation method thereof | |
| CN104975497B (en) | Flame retardant, preparation method and applications thereof | |
| CN101210353A (en) | Anti-flame fusion-resisting cellulose viscose and producing method thereof | |
| US6066198A (en) | Process and product for rendering a substance flame resistant | |
| CN104818607B (en) | Method of producing flame retardant textile by electronic radiation technology | |
| CN101974849A (en) | Production technology for flame-retardant and antistatic woolen sweater | |
| Jin et al. | Developing flame-retardant, antibacterial cotton fabric by incorporating a linear polysiloxane-based coating | |
| CN102851953A (en) | Fiber fabric flame retardant agent | |
| CN105442299A (en) | Flame-retardant environment-friendly textile and preparation method thereof | |
| CN103361968A (en) | Preparation method of flame-retardant purified cotton fabric | |
| US9945068B2 (en) | Flame retardant fabrics and methods for manufacturing the same | |
| CN105780453A (en) | Flame-proof finishing agent based on imvite/DNA hydrosol as well as preparation method and application thereof | |
| CN108842440B (en) | Production process of flame-retardant blended fabric | |
| CN113802212B (en) | Flame-retardant fiber, preparation method thereof and flame-retardant fabric | |
| CN105463853A (en) | Finishing method of flame-retardant and heat-resistant linen fabric | |
| CN104264461A (en) | Preparation method of flame-retardant photochromic silk fabric | |
| KR101621368B1 (en) | The method of preparing material of fire retard using natural cotton | |
| CN108978183A (en) | A kind of water-fastness textile | |
| CA1077203A (en) | Flame resistant substrates | |
| CN108691197A (en) | A kind of High temperature textiles | |
| CN105218863A (en) | A kind of silica-based fire retardant | |
| CN106042560B (en) | Flax waterproof anti-corrosion fabric | |
| CN108859363A (en) | A kind of waterproof radiation protection flame-proof antibiotic shell fabric formula |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160330 |
|
| WD01 | Invention patent application deemed withdrawn after publication |