CN105463853A - Finishing method of flame-retardant and heat-resistant linen fabric - Google Patents
Finishing method of flame-retardant and heat-resistant linen fabric Download PDFInfo
- Publication number
- CN105463853A CN105463853A CN201510989511.5A CN201510989511A CN105463853A CN 105463853 A CN105463853 A CN 105463853A CN 201510989511 A CN201510989511 A CN 201510989511A CN 105463853 A CN105463853 A CN 105463853A
- Authority
- CN
- China
- Prior art keywords
- flame
- imvite
- montmorillonite
- adds
- resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/55—Epoxy resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/72—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with metaphosphoric acids or their salts; with polyphosphoric acids or their salts; with perphosphoric acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Abstract
The invention discloses a finishing method of a flame-retardant and heat-resistant linen fabric. The method comprises organic treatment of montmorillonite, modification of the montmorillonite by a surfactant, preparation of an epoxy resin/montmorillonite nanocomposite material, preparation of a flame-retardant treatment liquid and flame-retardant treatment of the linen fabric. An intumescent flame-retardant system is prepared from the epoxy resin/montmorillonite nanocomposite material as a carbon source and high-polymer ammonium phosphate as an acid source and air source; the treatment liquid is attached to the linen fabric through a padding method; and the linen fabric can obtain excellent flame retardant property and high temperature resistance.
Description
Technical field
The present invention relates to antiflaming finishing agent field, particularly relate to a kind of preparation method of flame-resistant high-temperature-resistant linen.
Background technology
The fire-retardant introducing method by production process and fire retardant of textiles is roughly divided into the flame treatment of fiber and flame-proof treatment two class of fabric.In recent years, the development trend of textiles efficient flame-retarding agent is low toxicity, low cigarette, low stain and low-corrosiveness.Hexachlorocyclotriph,sphazene (HCCP) as the representative of phosphazene flame retardant, phosphorus and nitrogen element content higher, there is excellent fire resistance, but its washability is poor, content of halogen is high, because which limit the application of HCCP in fabric fire-retardant finishing.
Bast-fibre has that moisture absorption is loose wet fast, pulling force strong, good luster, insulation well, acid and alkali-resistance, the feature such as anticorrosive, have good health care performance and ventilative, smooth, rough, bold and unconstrained, texture natural, soft, the well-pressed individual style such as generous of tone.At home and abroad, gunny products is widely used in clothes, decoration and other field.At present, the demand of developed country to gunny products increases day by day, and one of them main application makees the decoration in room, as tablecloth, sofa cloth, wall paper, curtain and bedding etc.From housing safety fire prevention angle, the flame-proof treatment of crudefiber crop goods is increasingly important, and extremely Textile Engineering technical staff pays close attention to.
Flax fibre belongs to cellulose fibre category, what the current flame-proof treatment for cellulose fibre was more is organic phosphorus flame retardant, this type of flame retardant molecule is baking in process and can be cross-linked with the light base in cellulose macromolecule, forms covalent bonds, has durable flame-proof.Cellulosic fabric is after organic phosphorus flame retardant arranges; reduce the initial cleavage temperature of fiber; phosphonium flame retardant is that decomposable asymmetric choice net generates phosphoric acid at a lower temperature; be coated on fabric table and, form the protective layer of fixedness, separation layer can be played; the catalyst action that burns oxygen changes into carbon monoxide can be played again; decrease the generation of carbon dioxide, thus restrained effectively the release of heat, hinder than cellulosic burning.Along with the rising of temperature, the thermal decomposition product of fire retardant becomes poly-metaphosphoric acid further, and poly-metaphosphoric acid is a kind of strong dehydrating agent, cellulose rapid dehydration can be facilitated to carbonize, inhibit the generation of flammable pyrolysis product, thus plays fire retardation.
Flame-proof treatment, mainly in the process of textiles post-production, processes fabric face.Its process because of the kind of fire retardant different and different from pending fiber.The method of fabric being carried out to flame-proof treatment is mainly divided into following several: 1. pad baking process; 2. drying method is flooded; 3. coating; 4. spray-on process; 5. organic solvent method.Current antiflaming finishing agent presses ignition-proof element kind, is often divided into halogenated flame retardant, phosphorus flame retardant, nitrogenated flame retardant, expansion type flame retardant, silicon-series five-retardant, inorganic combustion inhibitor etc.The material fire-retardant due to halogenated flame retardant can produce poisonous, mordant smog in a large number when burning, and has pollution, corrosiveness to environment, air.Based on the requirement of environmental protection and sustainable development, halogen-free flame-retardant system has boundless development prospect.
Summary of the invention
The object of the invention is: a kind of method for sorting making linen obtain the flame-resistant high-temperature-resistant performance of excellence, the flame-resistant high-temperature-resistant linen of environmental protection is provided.
The technical solution adopted for the present invention to solve the technical problems is: a kind of method for sorting of flame-resistant high-temperature-resistant linen, comprises the following steps:
(1) organic-treating of imvite:
Softex kw is placed in container, adds deionized water, ultrasonic 30min; Separately getting imvite adds in container, adds deionized water, is heated to 80 DEG C, and then Keep agitation 30min adds the softex kw aqueous solution, and ultrasonic 1h, naturally cools to room temperature; After supercentrifuge centrifugation, wash with deionized water, then with ethanolic solution washing repeatedly, sediment separate out vacuumize, grind, sieve, obtain organic-treating imvite;
(2) surfactant modified imvite:
In absolute ethyl alcohol, drip glacial acetic acid, add the new trimerization quaternary cationics containing Hexahydrotriazine, the ethanolic solution of preparation percentage by weight 2%, leave standstill hydrolysis, add above-mentioned organic-treating imvite, ultrasonic 15min, then with ethanol washing, dry;
(3) preparation of Epoxy/montmorillonite Nanocomposite:
The aqueous solution of octadecyl trimethyl ammonium chloride is added according to a certain percentage in the aqueous dispersions of above-mentioned modified montmorillonite, filter stir 20h at 70 DEG C after, wash to filtrate not chloride ion-containing, after oven dry, grinding, obtained organo montmorillonite; Epoxy resin is warming up to 70 DEG C, adds organo montmorillonite and silane coupler stirring 2h, epoxy resin is entered between organic cheating engaging layer, obtains Epoxy/montmorillonite Nanocomposite;
(4) preparation of fire retarding treating liquid:
Take a certain amount of Epoxy/montmorillonite Nanocomposite in flask, heating and melting, drips acetic acid and emulsifying agent, adds the process of deionized water ultrasonic wave, obtained aqueous dispersions, adds high ammonium polyphosphate in dispersion liquid and resin cross-linking agent prepares fire retarding treating liquid;
(5) flame-proof treatment of linen:
Be placed in above-mentioned fire retarding treating liquid by fabric and soak, through padding machine roll compacting, adopt two leachings two to roll, pick-up rate is after 100%, in an oven through secondary drying, obtains flame-resistant high-temperature-resistant linen.
Further, the organic-treating ultrasonic frequency of step (one) imvite selects 30kHz, imvite ultrasonic vibration one hour under softex kw reagent.
Owing to have employed above-mentioned technical scheme, the present invention compared with prior art, there is following advantage and good effect: (1) imvite is a kind of natural clay material, rich reserves, widely distributed, cheap, environmental protection, and because of the structure of its uniqueness, by the method for intercalation synthesis, polymer can be made to insert silicate plate interlayer, realizes the compound on polymer and phyllosilicate nano yardstick.(2) Nano composite material of montmorillonite has good heat endurance, and wherein the imvite of nano-dispersed has excellent gas barrier effect and flame retardant effect, and does not affect the transparency of material.(3) epoxide resin material is conveniently easy to get, and has the advantages such as the flexibility of excellent mechanical performance, electrical insulating property, adhesive property and technique; (4) ultrasonic technique intercalated montmorillonite, has the advantage of time-saving energy-saving, makes modified cheating engaging layer spacing obtain further increase, respond well, is the imvite modified method of the application be worthy to be popularized; (5) the linen washability after flame treatment is good, and the damage of fabric strength is less, and wrinkle resistance is significantly improved; (6) features such as the present invention has good combination property, environmental friendliness, cost is reasonable, product is stable, easy and simple to handle, GRR is excellent, can make linen obtain excellent flame-resistant high-temperature-resistant performance.
Detailed description of the invention
Below in conjunction with specific embodiment, set forth the present invention further.The present invention includes the preparation of Epoxy/montmorillonite Nanocomposite and arrange with the high ammonium polyphosphate flame-resistant high-temperature-resistant making antiflaming finishing agent and linen that acts synergistically.The present invention is using Epoxy/montmorillonite Nanocomposite as charcoal source, using high ammonium polyphosphate as acid source and source of the gas composition Intumscent Flame Retardant System, through padding method, dressing liquid is attached on linen, such linen high ammonium phosphate wherein when being heated decomposes and produces phosphoric acid and ammonia, wherein the epoxy reaction of phosphoric acid and epoxy resin generates layer of charcoal, the existence of nano imvite makes the formation of layer of charcoal more rapid, more fine and close in structure; Ammonia makes the layer of charcoal of formation expand, thus the porous layer of charcoal formed prevents the invasion of heat and oxygen, thus reaches the object of flame-resistant high-temperature-resistant.A method for sorting for flame-resistant high-temperature-resistant linen, specifically comprises the following steps:
(1) organic-treating is carried out to imvite:
The softex kw (CTAB) accurately taking 1.000g is placed in beaker, adds 30mL deionized water, ultrasonic 30min.Separately getting the imvite (MMT) that 2.500g crosses 200 mesh sieves adds in there-necked flask, adds 150mL deionized water, in thermostat water bath heating water bath to 80 DEG C, Keep agitation 30min, then add the CTAB aqueous solution, ultrasonic 1h, then leave standstill and naturally cool to room temperature; Leave standstill after 30min and be washed till supernatant clarification with deionized water after supercentrifuge centrifugation, then wash repeatedly with the ethanolic solution of 50%, until with the Ag-N0 of 0.1mol/L
3detect supernatant without Br
-.Finally, sediment separate out, in 80 DEG C of vacuumize 4h, grinding, excessively 200 mesh sieve, obtains organic-treating imvite.
(2) surfactant modified imvite:
In absolute ethyl alcohol, drip glacial acetic acid, regulate about pH=5, add the new trimerization quaternary cationics containing Hexahydrotriazine, the ethanolic solution of preparation 2% (percentage by weight), leave standstill hydrolysis 10min.Add organic-treating imvite, control certain liquid-solid ratio, ultrasonic 15min, then with ethanol washing, 70 DEG C of oven dry.
(3) preparation of Epoxy/montmorillonite Nanocomposite:
The aqueous solution of octadecyl trimethyl ammonium chloride (OTAC) is added in the aqueous dispersions of modified montmorillonite according to a certain percentage, filter stir 20h at 70 DEG C after, wash to filtrate not chloride ion-containing, dry, grind rear obtained organo montmorillonite (OMMT), epoxy resin is warming up to 70 DEG C, add organo montmorillonite (OMMT) and KH560 silane coupler stirring 2h, epoxy resin is entered between organic cheating engaging layer, obtains Epoxy/montmorillonite Nanocomposite.
(4) preparation of fire retarding treating liquid:
Take a certain amount of Epoxy/montmorillonite Nanocomposite in flask, heating and melting, drip acetic acid and emulsifying agent, add deionized water ultrasonic wave process 15min, obtained aqueous dispersions.High ammonium polyphosphate (APP, mass concentration 160g/L) is added and resin cross-linking agent (mass concentration 100g/L) prepares fire retarding treating liquid in dispersion liquid.
(5) flame-proof treatment of linen:
The flame-proof treatment of linen adopts padding method, is placed in dressing liquid soaks by fabric, and through padding machine roll compacting, (two leachings two are rolled, pick-up rate is 100%) after, in the baking oven of 80 DEG C, preliminary drying 5min, finally bakes 3min at 150 DEG C, obtains flame-resistant high-temperature-resistant linen.
Imvite is as a kind of clay material, and stable performance, especially thermal stability is very outstanding, and the imvite surface property organised reduces, and can gather material surface when burning thus reach fire-retardant object.The adding of nano imvite in dressing liquid, imvite becomes carbon when promoting material combustion and plays the feature that iris action has Lewis acid, plays catalysis incarbonization.Imvite is as one-tenth carbon promoter, the degradation rate that can suppress molten drop, reduce the HRR of linen, reduce linen, its excellent insulating properties, can be used as mass transfer barrier, the fuel gas not only making the stratiform imvite being positioned at burning surface can intercept linen decomposition generation spreads to combustion boundary, and the speed that extraneous oxygen enters linen inside further can be delayed, thus play the effect of retarded combustion.Nano grade imvite has more nano effect, and the layer of charcoal that burning is formed is more fine and close.
The charcoal source of Intumescent Retardant System adopts epoxy resin, epoxy radicals active in epoxy molecule structure and high ammonium phosphate decompose the phosphoric acid generated and are combined, deviate from carboxylic acid and form layer of charcoal closely, layer of charcoal becomes bulk multi-hole because high ammonium phosphate decomposes the ammonia generated again, this layer of charcoal can stop the diffusion of heat transfer between linen and thermal source and oxygen, reduce the decomposition temperature of linen, the diffusion of volatile combustible component can also be stoped.
The organic-treating of imvite comprises for clay/polymer composites, general polymerization thing is all hydrophobic, good compound action to be reached between the two make to carry out modification to clay material, improve its compatibility in the polymer and dispersiveness.For imvite, imvite platelet is hydrophilic and oleophobic due to the existence of interlayer cation, and epoxy resin is hydrophobic, lacks affinity between the two, is difficult to mix.Treated organo montmorillonite is only had to react with vinyl monomer further.The selection principle of organ-mmt modification: can ionize or react generation organic cations organic matter in water; Volume is comparatively large, can strut between cheating engaging layer, expands imvite interlamination region; There is modification to imvite surface, make it become lipophilic-hydrophobic property from hydrophily.
During the preparation of Epoxy Resin/Montmorillonite, the chemical reagent organised that the organic-treating of imvite uses is softex kw, belong to long chain alkyl ammonium salt, after water-soluble, be dissociated into the quaternary ammonium ion of positively charged, utilize ion exchange, exchangeable cations between cheating engaging layer by organic surface active agent cation exchange out, embed the organic modifiers between cheating engaging layer simultaneously, interlayer microenvironment can be made to become oleophyllie hydrophobic, interlamellar spacing can be made again to increase, be conducive to entering of follow-up polymer or monomer; Especially when addition is 7 parts, linen burn rate growth indices can be reduced significantly, the time of retarded combustion, thus the fire resistance improving linen on the whole.
Time prepared by Epoxy/montmorillonite Nanocomposite, under the organic-treating of imvite is in ul-trasonic irradiation.Ultrasonic frequency selects 30kHz, imvite ultrasonic vibration one hour under softex kw reagent.Ultrasonic wave can make material do violent forced movement and produce unidirectional force, accelerates the transmission of material, diffusion, alternative mechanical agitation, material can be made from sur-face peeling, thus interface is more disperseed.
Time prepared by Epoxy/montmorillonite Nanocomposite, the intercalator choice for use of imvite contains the new trimerization quaternary cationics of Hexahydrotriazine, it being inserted in has in the nano imvite of layer structure, then monomer is made to aggregate into macromolecule at its interlayer, thus obtained polymer is by pressing the cation exchange reaction of salt surfactant and imvite chip layer long-chain season, surface active agent ion is made to enter imvite chip layer, through T
16the imvite interlamination region of modification obviously increases, and increases to 3.324nm from 1.468nm; Improve interlayer microenvironment simultaneously, make to become lipophilic-hydrophobic property from hydrophilic oleophobic property further between cheating engaging layer, thus imvite compatibility in the polymer and dispersiveness improve further.
Claims (2)
1. a method for sorting for flame-resistant high-temperature-resistant linen, is characterized in that, comprises the following steps:
(1) organic-treating of imvite:
Softex kw is placed in container, adds deionized water, ultrasonic 30min; Separately getting imvite adds in container, adds deionized water, is heated to 80 DEG C, and then Keep agitation 30min adds the softex kw aqueous solution, and ultrasonic 1h, naturally cools to room temperature; After supercentrifuge centrifugation, wash with deionized water, then with ethanolic solution washing repeatedly, sediment separate out vacuumize, grind, sieve, obtain organic-treating imvite;
(2) surfactant modified imvite:
In absolute ethyl alcohol, drip glacial acetic acid, add the new trimerization quaternary cationics containing Hexahydrotriazine, the ethanolic solution of preparation percentage by weight 2%, leave standstill hydrolysis, add above-mentioned organic-treating imvite, ultrasonic 15min, then with ethanol washing, dry;
(3) preparation of Epoxy/montmorillonite Nanocomposite:
The aqueous solution of octadecyl trimethyl ammonium chloride is added according to a certain percentage in the aqueous dispersions of above-mentioned modified montmorillonite, filter stir 20h at 70 DEG C after, wash to filtrate not chloride ion-containing, after oven dry, grinding, obtained organo montmorillonite; Epoxy resin is warming up to 70 DEG C, adds organo montmorillonite and silane coupler stirring 2h, epoxy resin is entered between organic cheating engaging layer, obtains Epoxy/montmorillonite Nanocomposite;
(4) preparation of fire retarding treating liquid:
Take a certain amount of Epoxy/montmorillonite Nanocomposite in flask, heating and melting, drips acetic acid and emulsifying agent, adds the process of deionized water ultrasonic wave, obtained aqueous dispersions, adds high ammonium polyphosphate in dispersion liquid and resin cross-linking agent prepares fire retarding treating liquid;
(5) flame-proof treatment of linen:
Be placed in above-mentioned fire retarding treating liquid by fabric and soak, through padding machine roll compacting, adopt two leachings two to roll, pick-up rate is after 100%, in an oven through secondary drying, obtains flame-resistant high-temperature-resistant linen.
2. the method for sorting of flame-resistant high-temperature-resistant linen according to claim 1, it is characterized in that, under the organic-treating of step (one) imvite is in ul-trasonic irradiation, ultrasonic frequency selects 30kHz, imvite ultrasonic vibration one hour under softex kw reagent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510989511.5A CN105463853A (en) | 2015-12-28 | 2015-12-28 | Finishing method of flame-retardant and heat-resistant linen fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510989511.5A CN105463853A (en) | 2015-12-28 | 2015-12-28 | Finishing method of flame-retardant and heat-resistant linen fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105463853A true CN105463853A (en) | 2016-04-06 |
Family
ID=55601978
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510989511.5A Pending CN105463853A (en) | 2015-12-28 | 2015-12-28 | Finishing method of flame-retardant and heat-resistant linen fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105463853A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107173669A (en) * | 2017-07-01 | 2017-09-19 | 河北工业大学 | A kind of mineral substance mycotoxin takes off mould dose and preparation method thereof |
| WO2021192767A1 (en) * | 2020-03-27 | 2021-09-30 | 株式会社ユポ・コーポレーション | Aqueous flame-retardant coating composition and flame-retardant thermoplastic resin film |
| CN114555679A (en) * | 2019-10-10 | 2022-05-27 | 株式会社庆东元 | Organic-inorganic composite synthetic resin using high flame-retardant organic modified silicate and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2400107A (en) * | 2003-03-04 | 2004-10-06 | Kay Metzeler Ltd | Montmorillonite flame retardant polyurethane |
| CN102899885A (en) * | 2012-11-05 | 2013-01-30 | 陕西科技大学 | Method for preparing imvite-phosphorus synergistic flame retardant for cotton fabrics |
| CN102926200A (en) * | 2012-09-25 | 2013-02-13 | 台州学院 | Flame-retardant cotton fiber and preparation method thereof |
| CN103266468A (en) * | 2013-05-30 | 2013-08-28 | 东华大学 | Flame retardant conditioning method of intumescent flame retardant system on pure cotton fabrics |
| CN103923436A (en) * | 2013-01-11 | 2014-07-16 | 广达电脑股份有限公司 | Organic montmorillonite reinforced epoxy resin and preparation method thereof |
-
2015
- 2015-12-28 CN CN201510989511.5A patent/CN105463853A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2400107A (en) * | 2003-03-04 | 2004-10-06 | Kay Metzeler Ltd | Montmorillonite flame retardant polyurethane |
| CN102926200A (en) * | 2012-09-25 | 2013-02-13 | 台州学院 | Flame-retardant cotton fiber and preparation method thereof |
| CN102899885A (en) * | 2012-11-05 | 2013-01-30 | 陕西科技大学 | Method for preparing imvite-phosphorus synergistic flame retardant for cotton fabrics |
| CN103923436A (en) * | 2013-01-11 | 2014-07-16 | 广达电脑股份有限公司 | Organic montmorillonite reinforced epoxy resin and preparation method thereof |
| CN103266468A (en) * | 2013-05-30 | 2013-08-28 | 东华大学 | Flame retardant conditioning method of intumescent flame retardant system on pure cotton fabrics |
Non-Patent Citations (1)
| Title |
|---|
| 张志慧: ""聚磷酸铵阻燃环氧树脂/有机蒙脱土纳米复合材料的制备和性能研究"", 《道客巴巴》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107173669A (en) * | 2017-07-01 | 2017-09-19 | 河北工业大学 | A kind of mineral substance mycotoxin takes off mould dose and preparation method thereof |
| CN114555679A (en) * | 2019-10-10 | 2022-05-27 | 株式会社庆东元 | Organic-inorganic composite synthetic resin using high flame-retardant organic modified silicate and preparation method thereof |
| CN114555679B (en) * | 2019-10-10 | 2024-03-19 | 株式会社庆东元 | Organic-inorganic composite synthetic resin using high flame-retardant organic modified silicate and preparation method thereof |
| WO2021192767A1 (en) * | 2020-03-27 | 2021-09-30 | 株式会社ユポ・コーポレーション | Aqueous flame-retardant coating composition and flame-retardant thermoplastic resin film |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104153035B (en) | Fire-retardant nice and cool recycled polyester filament fiber and production method thereof | |
| Jia et al. | Synthesis and evaluation of an efficient, durable, and environmentally friendly flame retardant for cotton | |
| Liu et al. | Eco-friendly flame retardant and smoke suppression coating containing boron compounds and phytic acids for nylon/cotton blend fabrics | |
| CN104975497B (en) | Flame retardant, preparation method and applications thereof | |
| CN103878847B (en) | A kind of difficult firebrand material and its preparation method and application | |
| Xu et al. | Highly efficient flame-retardant kraft paper | |
| CN103938456B (en) | A kind of preparation method of the wool spinning fabric with anti-flaming function | |
| CN110273295A (en) | A kind of cellulose fiber Wesy flame-proof antibiotic phytic acid ammonium finishing agent and its method for sorting | |
| CN105463853A (en) | Finishing method of flame-retardant and heat-resistant linen fabric | |
| CN109942882A (en) | A kind of phosphorous inherent fire-retardant fiber element base heat-barrier material and preparation method thereof | |
| Liao et al. | A biological reactive flame retardant for flame retardant modification of cotton fabric | |
| Su et al. | A novel biomass vitamin B6-based flame retardant for lyocell fibers | |
| CN104072633A (en) | Phosphorus-containing fire retardant as well as preparation method and application thereof | |
| CN114990876A (en) | Novel flame-retardant fabric for protective clothing and preparation method thereof | |
| Liu et al. | Fully bio-based coating for nylon/cotton blend fabrics with improved flame retardancy and smoke suppression properties | |
| Li et al. | Improving the fire performance and washing durability of nylon-cotton blend fabrics by the incorporation taurine derivatives | |
| CN108457124B (en) | Flame retardant and preparation method and application thereof | |
| CN105316936A (en) | Flame-retardant finishing agent and use thereof | |
| Liu et al. | Preparation of flame retardant, smoke suppression and reinforced polyacrylonitrile composite fiber by using fully biomass intumescent flame retardant system and its sustainable recycle application | |
| CN105780502A (en) | Flame-retardant down fiber and preparation method thereof | |
| CN107190550B (en) | A kind of flame-retardant polyester-type air filter paper and preparation method thereof | |
| CN103343484B (en) | Filter paper of filter flame retardant treating agent and preparation method thereof and purposes | |
| CN104831543B (en) | Environment friendly non-halogen microcapsule flame retardant used for textiles and preparation method thereof | |
| CN106518923A (en) | Preparation method and application of nitrogen-phosphorus synergetic type phosphorus-containing flame retardant | |
| CN110592950A (en) | Method for preparing flame-retardant cotton fabric without solvent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160406 |
|
| WD01 | Invention patent application deemed withdrawn after publication |