CN105440891A - Anticorrosive coating and preparation method thereof - Google Patents
Anticorrosive coating and preparation method thereof Download PDFInfo
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- CN105440891A CN105440891A CN201510988687.9A CN201510988687A CN105440891A CN 105440891 A CN105440891 A CN 105440891A CN 201510988687 A CN201510988687 A CN 201510988687A CN 105440891 A CN105440891 A CN 105440891A
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/06—Elements
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/103—Anti-corrosive paints containing metal dust containing Al
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/106—Anti-corrosive paints containing metal dust containing Zn
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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Abstract
The invention provides an anticorrosive coating and a preparation method. The anticorrosive coating comprises the following components in parts by weight: 35-55 parts of metal powder, 45-55 parts of resin, 1-5 parts of functional filler, 10-50 parts of an auxiliary material mixture and 20-40 parts of a curing agent, wherein the functional filler added in the anticorrosive coating is one or more of conductive carbon black, conductive carbon fiber or graphene, so that the anticorrosive coating obtained by the method provided by the invention still has very good anticorrosive performance under the condition that the content of the metal powder is relatively low, and the anticorrosive coating also has good adhesive force; moreover, the anticorrosive coating provided by the invention is stable in performance, has no special requirement for construction conditions, and can be applied widely.
Description
Technical field
The present invention relates to corrosion protection of metal surface technology, particularly relate to a kind of protective system and preparation method thereof.
Background technology
Because metallic corrosion brings massive losses to global economy, therefore metallic corrosion protection is paid much attention to by countries in the world.At present, metallic corrosion protection mainly adopts the mode of coating coating, and zinc-rich paint is widely used because performance is outstanding.
Disclosed zinc-rich paint is for improving Anticorrosive Character at present, and on the one hand, by increasing Zn content in coating, but when in coating, Zn content increases, the performance degradations such as the sticking power of coating, affect preservative effect on the contrary; On the other hand, by preparing solvent based coating, improve sticking power and reduce zinc amount, but preservative effect is also bad.Therefore, how to provide a kind of mechanical property good, and the good protective system of antiseptic property is the problem needing at present to solve.
Summary of the invention
In view of this, technical problem to be solved by this invention is to provide a kind of protective system, and not only sticking power is good but also antiseptic property is good for protective system provided by the invention.
The invention provides a kind of protective system, with weight parts, comprising:
Described functional stuffing is one or more in graphitized carbon black, conductive carbon fibres peacekeeping Graphene.
Preferably, described metal powder is one or both in zinc powder and aluminum zinc powder.
Preferably, described resin is one or more in epoxy resin, acrylic resin and fluorocarbon resin.
Preferably, described solidifying agent is polyamide curing agent or aliphatics amine curing agent.
Preferably, described auxiliary material is one or more in binding agent, dispersion agent, coupling agent and anti-wear agent.
Preferably, described binding agent is silicon sol.
Preferably, described dispersion agent is one or both in propylene glycol and propyl carbinol.
Preferably, described coupling agent is silane coupling agent.
Preferably, described anti-wear agent is one or both in ceramics powder and titanium dioxide.
Present invention also offers a kind of preparation method of coating of the present invention, comprising:
The auxiliary material of the resin of the metal powder of 35 ~ 55 weight parts, 45 ~ 55 weight parts, the functional stuffing of 1 ~ 5 weight part and 10 ~ 50 weight parts is mixed, obtains mixture;
By mixing of mixture and 20 ~ 40 weight part solidifying agent, obtain protective system;
Wherein, described functional stuffing is one or more in graphitized carbon black, conductive carbon fibres peacekeeping Graphene.
Compared with prior art, the invention provides a kind of protective system, the functional stuffing of the metal powder of 35 ~ 55 weight parts, the resin of 45 ~ 55 weight parts, 1 ~ 5 weight part, the auxiliary material mixing of 10 ~ 50 weight parts and 20 ~ 40 weight part solidifying agent; Wherein, be one or more in graphitized carbon black, conductive carbon fibres peacekeeping Graphene by adding described functional stuffing in protective system; The protective system that the present invention is obtained, when metal powder content is lower, still has good antiseptic property, and the sticking power of protective system that the present invention obtains is also fine; In addition, protective system stable performance provided by the invention, does not have particular requirement to execution conditions, is widely used; Experimental result shows, the adhesion strength of protective system provided by the invention can reach 1 grade, and salt spray resistance ability reaches more than 1500h, and in the seawater, and lower 24 hours of 85 DEG C of conditions, coating is intact.
Embodiment
The invention provides a kind of protective system, with weight parts, comprising:
Described functional stuffing is one or more in graphitized carbon black, conductive carbon fibres peacekeeping Graphene.
According to the present invention, described metal powder is one or both in zinc powder and aluminum zinc powder, the present invention does not have particular requirement to the shape of metal powder and the size of particle, wherein, when described metal powder is aluminum zinc powder, the mass ratio of described zinc and aluminium is preferably (6 ~ 9): (1 ~ 4), is more preferably 8:2.The shape of described aluminum zinc powder is preferably sheet, and it is 5 ~ 10 microns that the size of described sheet aluminum zinc powder is preferably surface-area, and thickness is the sheet aluminum zinc powder of 0.1 ~ 0.3 micron thickness.In described impregnating material, the content of described metal powder is preferably 38 ~ 50 weight parts, is more preferably 40 ~ 45 weight parts.
According to the present invention, described resin is one or more in epoxy resin, acrylic resin and fluorocarbon resin, is more preferably epoxy resin, and most preferably being model is one or more in E51 epoxy resin, E44 epoxy resin and E54 epoxy resin; In described impregnating material, the content of described resin is preferably 30 ~ 50 weight parts, is more preferably 35 ~ 45 weight parts.
According to the present invention, described functional stuffing is preferably graphitized carbon black and conductive carbon fibre; Wherein, when functional stuffing be graphitized carbon black and conductive carbon fibre time, the mass ratio of described graphitized carbon black and conductive carbon fibre is (0.1 ~ 0.5): (1 ~ 3), is more preferably (0.2 ~ 0.3): (2 ~ 2.5).In described impregnating material, the content of described functional stuffing is preferably 1.2 ~ 3.5 weight parts, is more preferably 2 ~ 3 weight parts.
According to the present invention, described auxiliary material is one or more in binding agent, dispersion agent, coupling agent and anti-wear agent; Wherein, described binding agent is preferably silicon sol; Described dispersion agent be preferably in propylene glycol and propyl carbinol one or both; Described coupling agent is preferably silane coupling agent, one or more more preferably in vinyltrimethoxy silane, vinyltriethoxysilane, vinyl three ('beta '-methoxy oxyethyl group) silane and carbonic acid four butyl ester; Described anti-wear agent be preferably in ceramics powder and titanium dioxide one or both.In described impregnating material, the content of described auxiliary material is preferably 40 ~ 50 weight parts, is more preferably 45 ~ 48 weight parts.Wherein, when auxiliary material is binding agent, dispersion agent, coupling agent and anti-wear agent, the mass ratio of binding agent, dispersion agent, coupling agent and anti-wear agent is preferably (25 ~ 30): (4 ~ 8): (1 ~ 3): (6 ~ 10), are more preferably (28 ~ 29): (5 ~ 6): (2 ~ 2.5): (7 ~ 9).
According to the present invention, described solidifying agent is preferably polyamide curing agent or aliphatics amine curing agent, and in described impregnating material, the content of described solidifying agent is preferably 25 ~ 35 weight parts, is more preferably 28 ~ 30 weight parts.
Present invention also offers a kind of preparation method of described coating, comprising:
The auxiliary material of the resin of the metal powder of 35 ~ 55 weight parts, 45 ~ 55 weight parts, the functional stuffing of 1 ~ 5 weight part and 10 ~ 50 weight parts is mixed, obtains mixture;
By mixing of mixture and 20 ~ 40 weight part solidifying agent, obtain protective system;
Wherein, described functional stuffing is one or more in graphitized carbon black, conductive carbon fibres peacekeeping Graphene.
According to the present invention, the auxiliary material of the resin of the metal powder of 35 ~ 55 weight parts, 45 ~ 55 weight parts, the functional stuffing of 1 ~ 5 weight part and 10 ~ 50 weight parts mixes by the present invention, obtains mixture; Described metal powder is one or both in zinc powder and aluminum zinc powder, the present invention does not have particular requirement to the shape of metal powder and the size of particle, wherein, when described metal powder is aluminum zinc powder, the mass ratio of described zinc and aluminium is preferably (6 ~ 9): (1 ~ 4), is more preferably 8:2.The shape of described aluminum zinc powder is preferably sheet, and it is 5 ~ 10 microns that the size of described sheet aluminum zinc powder is preferably surface-area, and thickness is the sheet aluminum zinc powder of 0.1 ~ 0.3 micron thickness.The consumption of described metal powder is preferably 38 ~ 50 weight parts, is more preferably 40 ~ 45 weight parts.Described resin is one or more in epoxy resin, acrylic resin and fluorocarbon resin, is more preferably epoxy resin, and most preferably being model is one or more in E51 epoxy resin, E44 epoxy resin and E54 epoxy resin; The consumption of described resin is preferably 30 ~ 50 weight parts, is more preferably 35 ~ 45 weight parts.Described functional stuffing is preferably graphitized carbon black and conductive carbon fibre; Wherein, when functional stuffing be graphitized carbon black and conductive carbon fibre time, the mass ratio of described graphitized carbon black and conductive carbon fibre is (0.1 ~ 0.5): (1 ~ 3), is more preferably (0.2 ~ 0.3): (2 ~ 2.5).The consumption of described functional stuffing is preferably 1.2 ~ 3.5 weight parts, is more preferably 2 ~ 3 weight parts.Described auxiliary material is one or more in binding agent, dispersion agent, coupling agent and anti-wear agent; Wherein, described binding agent is preferably silicon sol; Described dispersion agent be preferably in propylene glycol and propyl carbinol one or both; Described coupling agent is preferably silane coupling agent, one or more more preferably in vinyltrimethoxy silane, vinyltriethoxysilane, vinyl three ('beta '-methoxy oxyethyl group) silane and carbonic acid four butyl ester; Described anti-wear agent be preferably in ceramics powder and titanium dioxide one or both.The consumption of described auxiliary material is preferably 40 ~ 50 weight parts, is more preferably 45 ~ 48 weight parts.Wherein, when auxiliary material is binding agent, dispersion agent, coupling agent and anti-wear agent, the mass ratio of binding agent, dispersion agent, coupling agent and anti-wear agent is preferably (25 ~ 30): (4 ~ 8): (1 ~ 3): (6 ~ 10), are more preferably (28 ~ 29): (5 ~ 6): (2 ~ 2.5): (7 ~ 9).
In the present invention, the mode of the present invention to mixing does not have particular requirement, well known to a person skilled in the art the method for protective system mixing.
According to the present invention, the mixture obtained mixes with solidifying agent by the present invention, obtains impregnating material, and wherein said solidifying agent is preferably polyamide curing agent or aliphatics amine curing agent, the mass ratio of described solidifying agent and described mixture is 1:(3 ~ 5), be more preferably 1:4.The mode of the present invention to mixing does not have particular requirement, blending means well known in the art.
The invention provides a kind of protective system, the functional stuffing of the metal powder of 35 ~ 55 weight parts, the resin of 45 ~ 55 weight parts, 1 ~ 5 weight part, the auxiliary material mixing of 10 ~ 50 weight parts and 20 ~ 40 weight part solidifying agent; Wherein, be one or more in graphitized carbon black, conductive carbon fibres peacekeeping Graphene by adding described functional stuffing in protective system; The protective system that the present invention is obtained, when metal powder content is lower, still has good antiseptic property, and the sticking power of protective system that the present invention obtains is also fine; In addition, protective system stable performance provided by the invention, does not have particular requirement to execution conditions, is widely used; Meanwhile, impregnating material of the present invention, by adding assistant agent, makes material have good heat-proof quality and abrasion resistance.
Technical scheme below in conjunction with the embodiment of the present invention is clearly and completely described, and obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1
By silicon sol 28 weight part, epoxy resin 30 weight part, propylene glycol 3 weight part, propyl carbinol 2 weight part, silane coupling agent (kh550) 2 weight part mixes, then by conductive carbon black 0.2 weight part, conductive carbon fibre 1 weight part, nano-ceramic powder 3 weight part, titanium dioxide 4 weight part, sheet aluminum zinc powder (mass ratio of zinc and aluminium is 8:2) 38 weight parts progressively add, and 1000 ~ 1200 revs/min stir, namely obtain mixture.By mixture with polyamide curing agent in mass ratio for 4:1 mixes, obtain protective system;
By the protective system film obtained, this film normal temperature 6min surface drying, after 24h, coating is done solid work.
Detect according to GB1720-79 standard the coating obtained, result shows, the adhesion strength of this coating 1 grade.
Detected antiseptic property by GB/T1771-91 standard, result shows, its salt spray resistance ability is more than 1500h, and soak 24h at 85 degree of sea water resistances, coating is intact.
Embodiment 2
By silicon sol 29 weight part, epoxy resin 30 weight part, propylene glycol 4 weight part, propyl carbinol 2 weight part, silane coupling agent (kh550) 2 weight part mixes, then by conductive carbon black 0.1 weight part, conductive carbon fibre 3 weight part, nano-ceramic powder 4 weight part, titanium dioxide 4 weight part, sheet aluminum zinc powder (mass ratio of zinc and aluminium is 8:2) 45 weight parts progressively add, and 1000 ~ 1200 revs/min stir, namely obtain mixture.By mixture with polyamide curing agent in mass ratio for 4:1 mixes, obtain protective system;
By the protective system film obtained, this film normal temperature 7min surface drying, after 24h, coating is done solid work.
Detect according to GB1720-79 standard the coating obtained, result shows, the adhesion strength of this coating 1 grade.
Detected antiseptic property by GB/T1771-91 standard, result shows, its salt spray resistance ability is more than 1500h, and soak 24h at 85 degree of sea water resistances, coating is intact.
Carry out wearability test to the film obtained according to GB1768-79 standard, its wear-resisting (500g, 1000 turns) are≤40mg.
Embodiment 3
By silicon sol 30 weight part, epoxy resin 29 weight part, propylene glycol 3 weight part, propyl carbinol 3 weight part, silane coupling agent (kh550) 2 weight part mixes, then by conductive carbon black 0.2 weight part, conductive carbon fibre 2 weight part, nano-ceramic powder 5 weight part, titanium dioxide 4 weight part, sheet aluminum zinc powder (mass ratio of zinc and aluminium is 8:2) 50 weight parts progressively add, and 1000 ~ 1200 revs/min stir, namely obtain mixture.By mixture with polyamide curing agent in mass ratio for 4:1 mixes, obtain protective system;
By the protective system film obtained, this film normal temperature 6min surface drying, after 24h, coating is done solid work.
Detect according to GB1720-79 standard the coating obtained, result shows, the adhesion strength of this coating 1 grade.
Detected antiseptic property by GB/T1771-91 standard, result shows, its salt spray resistance ability is more than 1500h, and soak 24h at 85 degree of sea water resistances, coating is intact.
The explanation of above embodiment just understands method of the present invention and core concept thereof for helping.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also carry out some improvement and modification to the present invention, these improve and modify and also fall in the protection domain of the claims in the present invention.
Claims (10)
1. a protective system, with weight parts, comprising:
Described functional stuffing is one or more in graphitized carbon black, conductive carbon fibres peacekeeping Graphene.
2. coating according to claim 1, is characterized in that, described metal powder is one or both in zinc powder and aluminum zinc powder.
3. coating according to claim 1, is characterized in that, described resin is one or more in epoxy resin, acrylic resin and fluorocarbon resin.
4. coating according to claim 1, is characterized in that, described solidifying agent is polyamide curing agent, aliphatics amine curing agent, isocyanate curing agent or amino resin curing agents.
5. coating according to claim 1, is characterized in that, described auxiliary material is one or more in binding agent, dispersion agent, coupling agent and anti-wear agent.
6. coating according to claim 5, is characterized in that, described binding agent is silicon sol.
7. coating according to claim 5, is characterized in that, described dispersion agent is one or both in propylene glycol and propyl carbinol.
8. coating according to claim 5, is characterized in that, described coupling agent is silane coupling agent.
9. coating according to claim 5, is characterized in that, described anti-wear agent is one or both in ceramics powder and titanium dioxide.
10. a preparation method for the coating described in claim 1 ~ 9 any one, comprising:
The auxiliary material of the resin of the metal powder of 35 ~ 55 weight parts, 45 ~ 55 weight parts, the functional stuffing of 1 ~ 5 weight part and 10 ~ 50 weight parts is mixed, obtains mixture;
By mixing of mixture and 20 ~ 40 weight part solidifying agent, obtain protective system;
Wherein, described functional stuffing is one or more in graphitized carbon black, conductive carbon fibres peacekeeping Graphene.
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| CN201510988687.9A CN105440891B (en) | 2015-12-25 | 2015-12-25 | A kind of anticorrosive paint and preparation method thereof |
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| CN201510988687.9A CN105440891B (en) | 2015-12-25 | 2015-12-25 | A kind of anticorrosive paint and preparation method thereof |
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| CN105925140A (en) * | 2016-06-21 | 2016-09-07 | 江苏士林电气设备有限公司 | Anti-corrosion coating for low-voltage bus duct and coating process thereof |
| CN105949829A (en) * | 2016-06-12 | 2016-09-21 | 安徽威龙电力器材有限公司 | Coating for electric power fittings and preparation method thereof |
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| CN109207019A (en) * | 2018-08-27 | 2019-01-15 | 国网河南省电力公司检修公司 | A kind of conductive anti-corrosion coating and preparation method thereof |
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| CN109651919A (en) * | 2018-11-05 | 2019-04-19 | 浙江山力得新材料科技有限公司 | A kind of ceramic filler epoxy zinc-rich anticorrosion coating material and preparation method thereof |
| CN109735201A (en) * | 2018-12-14 | 2019-05-10 | 中国石油天然气集团有限公司 | A kind of solvent-free conductive coating of graphene and preparation method thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5989460A (en) * | 1994-11-21 | 1999-11-23 | Garland Floor Co. | Electrically conductive coating |
| CN102746766A (en) * | 2012-07-23 | 2012-10-24 | 江苏华夏制漆科技有限公司 | Water -borne anticorrosion paint and method for preparing same |
| CN105086758A (en) * | 2013-03-06 | 2015-11-25 | 常州第六元素材料科技股份有限公司 | Preparation method of graphene anticorrosive paint |
-
2015
- 2015-12-25 CN CN201510988687.9A patent/CN105440891B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5989460A (en) * | 1994-11-21 | 1999-11-23 | Garland Floor Co. | Electrically conductive coating |
| CN102746766A (en) * | 2012-07-23 | 2012-10-24 | 江苏华夏制漆科技有限公司 | Water -borne anticorrosion paint and method for preparing same |
| CN105086758A (en) * | 2013-03-06 | 2015-11-25 | 常州第六元素材料科技股份有限公司 | Preparation method of graphene anticorrosive paint |
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