CN108285706A - A kind of waterborne metal anti-corrosive paint - Google Patents
A kind of waterborne metal anti-corrosive paint Download PDFInfo
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- CN108285706A CN108285706A CN201810166835.2A CN201810166835A CN108285706A CN 108285706 A CN108285706 A CN 108285706A CN 201810166835 A CN201810166835 A CN 201810166835A CN 108285706 A CN108285706 A CN 108285706A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of waterborne metal anti-corrosive paints, are related to technical field of coatings, include the raw material of following parts by weight：70 80 parts of acrylic resin, 10 18 parts of amino resins, aqueous epoxy resin emulsion 7 15, 37 parts of modified graphene, 25 parts of attapulgite, 25 parts of bentonite, 13 parts of nano silicon dioxide, 24 parts of potassium titanate crystal whisker, 13 parts of barium sulfate, 0.5 2 parts of silane coupling agent, 13 parts of cumyl peroxide, 25 parts of polyvinyl alcohol, 0.5 2 parts of disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, 0.5 2 parts of ethyl acetate, 26 parts of Dipropylene glycol mono-n-butyl Ether, 0.5 2 parts of polyethylene wax, 0.5 2 parts of hydroxypropyl methyl cellulose, 0.2 1 parts of levelling agent, 0.2 1 parts of antifoaming agent, 13 parts of anti-flash rusting agent, 10 20 parts of deionized water.The present invention is using water-based acrylic resin as main film forming substance, amino resins is added and aqueous epoxy resin emulsion is modified, added with ingredients such as modified graphene, potassium titanate crystal whiskers, coating obtained has excellent water-fast, acid-alkali-corrosive-resisting performance, can extend the service life of metal.
Description
Technical field
The present invention relates to technical field of coatings more particularly to a kind of waterborne metal anti-corrosive paints.
Background technology
Corrosion of metal is metal by electrochemistry or the chemical action of surrounding medium and there is a phenomenon where destroy.Metal erosion
Throughout the every field of national economy, massive losses are brought to national economy.In the country of industry prosperity, metal erosion is made
At direct economic loss account for the 1%~4% of total value of production in national economy, every year since the steel of rust corrosion accounts for about total output
20%, there are about 30% equipment to be scrapped because of metal erosion.And in China, every year due to economic loss caused by metal erosion
Account for the 4% of gross national product.Just because of this, there is the excellent corrosive metal anti-corrosive paint of rust-preventing characteristic and resistant to chemical media
It is able to fast development, is widely used in all trades and professions.Due to the popularity that metal product uses, many metal products are long
Phase is subjected to friction test, is such as not coated by anticorrosive paint, and the use environment of metal erosion and friction makes metal product service life
Substantially reduce, coating anticorrosive paint can reduce corrosion generate, but the acid-alkali-corrosive-resisting effect of existing metal anti-corrosive paint compared with
Difference, it is water-fast impervious general, cause preservative efficiency relatively low.
Invention content
Technical problems based on background technology, the present invention propose a kind of waterborne metal anti-corrosive paint, with aqueous third
Olefin(e) acid resin is main film forming substance, and amino resins and aqueous epoxy resin emulsion is added, and is also added with modified graphene, metatitanic acid
The ingredients such as potassium whisker, coating obtained have excellent water-fast, acid-alkali-corrosive-resisting performance, can extend the service life of metal.
A kind of waterborne metal anti-corrosive paint proposed by the present invention, includes the raw material of following parts by weight：Acrylic resin 70-80
Part, 10-18 parts of amino resins, aqueous epoxy resin emulsion 7-15,3-7 parts of modified graphene, 2-5 parts of attapulgite, bentonite
2-5 parts, 1-3 parts of nano silicon dioxide, 2-4 parts of potassium titanate crystal whisker, 1-3 parts of barium sulfate, 0.5-2 parts of silane coupling agent, peroxidating
1-3 parts of diisopropylbenzene (DIPB), 2-5 parts of polyvinyl alcohol, 0.5-2 parts of disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, 0.5-2 parts of ethyl acetate, two
2-6 parts of propylene glycol monobutyl ether, 0.5-2 parts of polyethylene wax, 0.5-2 parts of hydroxypropyl methyl cellulose, 0.2-1 parts of levelling agent, defoaming
0.2-1 parts of agent, 1-3 parts of anti-flash rusting agent, 10-20 parts of deionized water.
Preferably, include the raw material of following parts by weight：72-78 parts of acrylic resin, 12-16 parts of amino resins, aqueous ring
8-12 parts of oxygen resin emulsion, 4-6 parts of modified graphene, 3-4 parts of attapulgite, 3-4 parts of bentonite, 1-2 parts of nano silicon dioxide,
2-3 parts of potassium titanate crystal whisker, 1-2 parts of barium sulfate, 1-1.5 parts of silane coupling agent, 1.5-2.5 parts of cumyl peroxide, polyethylene
3-4 parts of alcohol, 1-1.5 parts of ethyl acetate, 3-5 parts of Dipropylene glycol mono-n-butyl Ether, gathers 1-1.5 parts of disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate
0.5-1 parts of ethylene waxes, 0.8-1.3 parts of hydroxypropyl methyl cellulose, 0.5-1 parts of levelling agent, 0.5-1 parts of antifoaming agent, anti-flash rusting agent
1.5-2.5 13-20 parts of part, deionized water.
Preferably, the preparation process of the modified graphene is as follows：Into reaction vessel be added graphene oxide, DMF,
THF and hydroquinone are placed in ultrasonic disperse in 0 DEG C of ice bath, and glycidyl methacrylate, ethanol amine, carbon are added thereto
Sour potassium, is dispersed with stirring, then temperature reaction, cools down after reaction, and hexachlorocyclotriph,sphazene is added, and is placed in 0 DEG C of ice bath ultrasonic
Dispersion, then temperature reaction, centrifuge, washing, vacuum drying to get.
Preferably, the preparation process of the modified graphene is as follows：Into reaction vessel be added 1-3 parts of graphene oxides,
60-70 parts DMF, 60-70 parts THF and 0.01-0.05 parts of hydroquinones are placed in ultrasonic disperse 40-60min, Xiang Qi in 0 DEG C of ice bath
35-45 parts of glycidyl methacrylate of middle addition, 15-20 parts of ethanol amines, 3-4 parts of potassium carbonate, are dispersed with stirring 20-30min,
60-70 DEG C is then heated to, 3-5h is reacted, is down to room temperature after reaction, 12-19 parts of hexachlorocyclotriph,sphazenes are added, are placed in 0 DEG C
Ultrasonic disperse 20-30min in ice bath, then heats to 25-35 DEG C, reacts 20-26h, centrifuges, washing, vacuum drying to get.
Preferably, the vacuum drying temperature is 60-65 DEG C.
Preferably, the anti-flash rusting agent is nitrite or borate.
Advantageous effect：Using water-based acrylic resin as main film forming substance in the present invention, the carboxyl in molecule and addition
Amino resins in amino and epoxy resin in epoxy group crosslink reaction in film forming, formation cross-linked structure, material
Water resistance significantly improve, thermal stability makes moderate progress；The modified graphene of addition due to its stabilization benzene six-membered ring structure and
The specific surface area of super large makes it have very strong impervious and chemical stability, is added in coating as filler, can
It is etch-proof to play the role of physical barrier, potassium titanate crystal whisker has good wear-resisting humidification, modified graphene, potassium titanate brilliant
It must act synergistically under the action of silane coupling agent with attapulgite, bentonite, nano silicon dioxide, barium sulfate as filler,
Assign water-based acrylic resin coating excellent wear-corrosion resistance；The waterborne metallic paint of preparation have it is excellent it is water-fast,
Corrosion resistance has good promotional value.
In graphene method of modifying, in the presence of ethanol amine and potassium carbonate, one side ethanol amine passes through amino and oxidation stone
Epoxy group on black alkene carries out ring-opening reaction, and ethanol amine is grafted in graphene oxide layer, is formed on its surface a phenol hydroxyl
Base and an alcoholic extract hydroxyl group increase surface of graphene oxide hydroxy radical content；Ring in another aspect glycidyl methacrylate
Oxygroup open loop is bonded with the hydroxyl of surface of graphene oxide, and carbon-carbon double bond is introduced in the lamellar structure of graphene oxide；
Hexachlorocyclotriph,sphazene is then added into reaction system again, since its molecule contains the good hexatomic ring of stability, makes it have excellent
Different acidproof, alkaline-resisting and high temperature resistance is occurred by groups such as the hydroxyls of phosphorus chlorine key and surface of graphene oxide in molecule
Substitution reaction is grafted on graphene oxide, and the acid-alkali-corrosive-resisting performance and high temperature resistance super of graphene oxide are improved
Property；Modified graphene passes through double bond, carboxyl, hydroxyl, Lin Lvjian isoreactivities functional group and film forming matter acrylic resin, amino tree
Fat, aqueous epoxy resin emulsion crosslink, and form fine and close three-dimensional net structure, on the one hand can improve the polymerization of aqueous coating
On the other hand object structure is expected to block polarity water transport channel, to effectively hinder the infiltration and diffusion of water and corrosive medium, improve
The water resistance and impermeability of coating enhance its corrosion-resistant, rustless property.
Specific implementation mode
In the following, technical scheme of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of waterborne metal anti-corrosive paint proposed by the present invention, includes the raw material of following parts by weight：70 parts of acrylic resin,
10 parts of amino resins, 7 parts of aqueous epoxy resin emulsion, 3 parts of modified graphene, 2 parts of attapulgite, 2 parts of bentonite, nano-silica
1 part of SiClx, 2 parts of potassium titanate crystal whisker, 1 part of barium sulfate, 0.5 part of silane coupling agent, 1 part of cumyl peroxide, polyvinyl alcohol 2
Part, 0.5 part of disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, 0.5 part of ethyl acetate, 2 parts of Dipropylene glycol mono-n-butyl Ether, 0.5 part of polyethylene wax,
0.5 part of hydroxypropyl methyl cellulose, 0.2 part of levelling agent, 0.2 part of antifoaming agent, 1 part of anti-flash rusting agent, 10 parts of deionized water.
Embodiment 2
A kind of waterborne metal anti-corrosive paint proposed by the present invention, includes the raw material of following parts by weight：72 parts of acrylic resin,
12 parts of amino resins, 8 parts of aqueous epoxy resin emulsion, 4 parts of modified graphene, 3 parts of attapulgite, 3 parts of bentonite, nano-silica
1 part of SiClx, 2 parts of potassium titanate crystal whisker, 1 part of barium sulfate, 1 part of silane coupling agent, 1.5 parts of cumyl peroxide, polyvinyl alcohol 3
Part, 1 part of disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, 1 part of ethyl acetate, 3 parts of Dipropylene glycol mono-n-butyl Ether, 0.5 part of polyethylene wax, hydroxypropyl
0.8 part of ylmethyl cellulose, 0.5 part of levelling agent, 0.5 part of antifoaming agent, 1.5 parts of anti-flash rusting agent, 13 parts of deionized water.
Wherein, the preparation process of modified graphene is as follows：Into reaction vessel be added 1 part of graphene oxide, 60 parts of DMF,
60 parts of THF and 0.01 part of hydroquinones, are placed in ultrasonic disperse 40min in 0 DEG C of ice bath, and 35 parts of methacrylic acid contractings are added thereto
Water glyceride, 15 parts of ethanol amines, 3 parts of potassium carbonate, are dispersed with stirring 20min, then heat to 60 DEG C, react 3h, after reaction
It is down to room temperature, 12 parts of hexachlorocyclotriph,sphazenes are added, are placed in ultrasonic disperse 20min in 0 DEG C of ice bath, then heats to 25 DEG C, reaction
20h, centrifuge, washing, vacuum drying to get.
Embodiment 3
A kind of waterborne metal anti-corrosive paint proposed by the present invention, includes the raw material of following parts by weight：75 parts of acrylic resin,
15 parts of amino resins, 10 parts of aqueous epoxy resin emulsion, 5 parts of modified graphene, 4 parts of attapulgite, 3 part, nanometer two of bentonite
1.5 parts of silica, 2.5 parts of potassium titanate crystal whisker, 1 part of barium sulfate, 1.2 parts of silane coupling agent, 2 parts of cumyl peroxide, poly- second
4 parts of enol, 1 part of disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, 1.5 parts of ethyl acetate, 3.5 parts of Dipropylene glycol mono-n-butyl Ether, polyethylene wax
0.7 part, 1 part of hydroxypropyl methyl cellulose, 0.8 part of levelling agent, 0.7 part of antifoaming agent, 2 parts of anti-flash rusting agent, 18 parts of deionized water.
Wherein, the preparation process of modified graphene is as follows：Into reaction vessel be added 2 parts of graphene oxides, 65 parts of DMF,
65 parts of THF and 0.03 part of hydroquinones, are placed in ultrasonic disperse 45min in 0 DEG C of ice bath, and 40 parts of methacrylic acid contractings are added thereto
Water glyceride, 17 parts of ethanol amines, 3.2 parts of potassium carbonate, are dispersed with stirring 25min, then heat to 65 DEG C, react 4h, and reaction terminates
After be down to room temperature, 15 parts of hexachlorocyclotriph,sphazenes are added, is placed in ultrasonic disperse 25min in 0 DEG C of ice bath, then heats to 30 DEG C, instead
Answer 22h, centrifuge, washing, at 60 DEG C be dried in vacuo to get.
Wherein, anti-flash rusting agent is nitrite.
Embodiment 4
A kind of waterborne metal anti-corrosive paint proposed by the present invention, includes the raw material of following parts by weight：78 parts of acrylic resin,
16 parts of amino resins, aqueous epoxy resin emulsion 12,6 parts of modified graphene, 4 parts of attapulgite, 4 parts of bentonite, nano-silica
2 parts of SiClx, 3 parts of potassium titanate crystal whisker, 2 parts of barium sulfate, 1.5 parts of silane coupling agent, 2.5 parts of cumyl peroxide, polyvinyl alcohol 4
Part, 1.5 parts of disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, 1.5 parts of ethyl acetate, 5 parts of Dipropylene glycol mono-n-butyl Ether, 1 part of polyethylene wax, hydroxyl
1.3 parts of propyl methocel, 1 part of levelling agent, 1 part of antifoaming agent, 2.5 parts of anti-flash rusting agent, 20 parts of deionized water.
Wherein, the preparation process of modified graphene is as follows：Into reaction vessel be added 2.4 parts of graphene oxides, 68 parts
DMF, 62 parts of THF and 0.04 part of hydroquinones, are placed in ultrasonic disperse 50min in 0 DEG C of ice bath, and 42 parts of metering systems are added thereto
Acid glycidyl ester, 18 parts of ethanol amines, 3.6 parts of potassium carbonate, are dispersed with stirring 25min, then heat to 65 DEG C, react 4.5h, instead
It is down to room temperature after answering, 17 parts of hexachlorocyclotriph,sphazenes are added, is placed in ultrasonic disperse 30min in 0 DEG C of ice bath, then heats to 30
DEG C, reaction for 24 hours, centrifuge, washing, at 65 DEG C be dried in vacuo to get.
Wherein, anti-flash rusting agent is borate.
Embodiment 5
A kind of waterborne metal anti-corrosive paint proposed by the present invention, includes the raw material of following parts by weight：80 parts of acrylic resin,
18 parts of amino resins, aqueous epoxy resin emulsion 15,7 parts of modified graphene, 5 parts of attapulgite, 5 parts of bentonite, nano-silica
3 parts of SiClx, 4 parts of potassium titanate crystal whisker, 3 parts of barium sulfate, 2 parts of silane coupling agent, 3 parts of cumyl peroxide, 5 parts of polyvinyl alcohol,
2 parts of disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, 2 parts of ethyl acetate, 6 parts of Dipropylene glycol mono-n-butyl Ether, 2 parts of polyethylene wax, hydroxypropyl first
2 parts of base cellulose, 1 part of levelling agent, 1 part of antifoaming agent, 3 parts of anti-flash rusting agent, 20 parts of deionized water.
Wherein, the preparation process of modified graphene is as follows：Into reaction vessel be added 3 parts of graphene oxides, 70 parts of DMF,
70 parts of THF and 0.05 part of hydroquinones, are placed in ultrasonic disperse 60min in 0 DEG C of ice bath, and 45 parts of methacrylic acid contractings are added thereto
Water glyceride, 20 parts of ethanol amines, 4 parts of potassium carbonate, are dispersed with stirring 30min, then heat to 70 DEG C, react 5h, after reaction
It is down to room temperature, 19 parts of hexachlorocyclotriph,sphazenes are added, are placed in ultrasonic disperse 30min in 0 DEG C of ice bath, then heats to 35 DEG C, reaction
26h, centrifuge, washing, at 65 DEG C be dried in vacuo to get.
Wherein, anti-flash rusting agent is nitrite.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (6)
1. a kind of waterborne metal anti-corrosive paint, which is characterized in that include the raw material of following parts by weight：70-80 parts of acrylic resin,
10-18 parts of amino resins, aqueous epoxy resin emulsion 7-15,3-7 parts of modified graphene, 2-5 parts of attapulgite, bentonite 2-5
Part, 1-3 parts of nano silicon dioxide, 2-4 parts of potassium titanate crystal whisker, 1-3 parts of barium sulfate, 0.5-2 parts of silane coupling agent, peroxidating two are different
1-3 parts of propyl benzene, 2-5 parts of polyvinyl alcohol, 0.5-2 parts of disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, 0.5-2 parts of ethyl acetate, dipropyl two
2-6 parts of alcohol monobutyl ether, 0.5-2 parts of polyethylene wax, 0.5-2 parts of hydroxypropyl methyl cellulose, 0.2-1 parts of levelling agent, antifoaming agent
0.2-1 parts, 1-3 parts of anti-flash rusting agent, 10-20 parts of deionized water.
2. waterborne metal anti-corrosive paint according to claim 1, which is characterized in that include the raw material of following parts by weight：Third
72-78 parts of olefin(e) acid resin, 12-16 parts of amino resins, 8-12 parts of aqueous epoxy resin emulsion, 4-6 parts of modified graphene, concave convex rod
3-4 parts native, 3-4 parts of bentonite, 1-2 parts of nano silicon dioxide, 2-3 parts of potassium titanate crystal whisker, 1-2 parts of barium sulfate, silane coupling agent
1-1.5 parts, 1.5-2.5 parts of cumyl peroxide, 3-4 parts of polyvinyl alcohol, 1-1.5 parts of disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate,
1-1.5 parts of ethyl acetate, 3-5 parts of Dipropylene glycol mono-n-butyl Ether, 0.5-1 parts of polyethylene wax, hydroxypropyl methyl cellulose 0.8-1.3
Part, 0.5-1 parts of levelling agent, 0.5-1 parts of antifoaming agent, 1.5-2.5 parts of anti-flash rusting agent, 13-20 parts of deionized water.
3. waterborne metal anti-corrosive paint according to claim 1, which is characterized in that the preparation process of the modified graphene
It is as follows：Graphene oxide, DMF, THF and hydroquinone are added into reaction vessel, is placed in ultrasonic disperse in 0 DEG C of ice bath, Xiang Qi
Middle addition glycidyl methacrylate, ethanol amine, potassium carbonate, are dispersed with stirring, then temperature reaction, drop after reaction
Hexachlorocyclotriph,sphazene is added in temperature, is placed in ultrasonic disperse in 0 DEG C of ice bath, and then temperature reaction centrifuges, and washs, vacuum drying, i.e.,
.
4. waterborne metal anti-corrosive paint according to claim 3, which is characterized in that the preparation process of the modified graphene
It is as follows：It is added that 1-3 parts of graphene oxides, 60-70 parts DMF, 60-70 parts THF and 0.01-0.05 parts to benzene two into reaction vessel
Phenol is placed in ultrasonic disperse 40-60min in 0 DEG C of ice bath, and 35-45 parts of glycidyl methacrylate, 15-20 are added thereto
Part ethanol amine, 3-4 parts of potassium carbonate, are dispersed with stirring 20-30min, then heat to 60-70 DEG C, react 3-5h, drop after reaction
To room temperature, 12-19 parts of hexachlorocyclotriph,sphazenes are added, is placed in ultrasonic disperse 20-30min in 0 DEG C of ice bath, then heats to 25-35
DEG C, react 20-26h, centrifuge, washing, vacuum drying to get.
5. waterborne metal anti-corrosive paint according to claim 3, which is characterized in that the vacuum drying temperature is 60-65
℃。
6. waterborne metal anti-corrosive paint according to claim 1, which is characterized in that the anti-flash rusting agent be nitrite or
Borate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201810166835.2A CN108285706A (en) | 2018-02-28 | 2018-02-28 | A kind of waterborne metal anti-corrosive paint |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810166835.2A CN108285706A (en) | 2018-02-28 | 2018-02-28 | A kind of waterborne metal anti-corrosive paint |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108486421A (en) * | 2018-04-25 | 2018-09-04 | 合肥市旺友门窗有限公司 | A kind of anticorrosion aluminium door and window |
| CN109749544A (en) * | 2018-12-27 | 2019-05-14 | 安徽伊法拉电力科技有限公司 | A kind of anticorrosive paint and preparation method thereof prepared by high voltage electricity transmission conductive wire modified manometer silicon dioxide |
| CN110387180A (en) * | 2019-06-21 | 2019-10-29 | 王玉琢 | A kind of preparation method of shock resistance acid and alkali-resistance reflecting coating |
| CN116355449A (en) * | 2023-06-01 | 2023-06-30 | 广州鸿泰新材料科技有限公司 | Acid and alkali resistant spray valve sealing cup coating |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108486421A (en) * | 2018-04-25 | 2018-09-04 | 合肥市旺友门窗有限公司 | A kind of anticorrosion aluminium door and window |
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| CN110387180A (en) * | 2019-06-21 | 2019-10-29 | 王玉琢 | A kind of preparation method of shock resistance acid and alkali-resistance reflecting coating |
| CN116355449A (en) * | 2023-06-01 | 2023-06-30 | 广州鸿泰新材料科技有限公司 | Acid and alkali resistant spray valve sealing cup coating |
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Application publication date: 20180717 |