CN105440330A - Halogen-free environmental-friendly elevator balance compensating chain, and preparation method therefor and application thereof - Google Patents

Halogen-free environmental-friendly elevator balance compensating chain, and preparation method therefor and application thereof Download PDF

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Publication number
CN105440330A
CN105440330A CN201510729044.2A CN201510729044A CN105440330A CN 105440330 A CN105440330 A CN 105440330A CN 201510729044 A CN201510729044 A CN 201510729044A CN 105440330 A CN105440330 A CN 105440330A
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parts
copolymer
maleic anhydride
ethylene
anhydride grafted
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魏维
毛亮
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JIANGSU XINGHUA RUBBER CO Ltd
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JIANGSU XINGHUA RUBBER CO Ltd
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Priority to CN201510729044.2A priority Critical patent/CN105440330A/en
Priority to PCT/CN2015/097892 priority patent/WO2017071022A1/en
Publication of CN105440330A publication Critical patent/CN105440330A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16GBELTS, CABLES, OR ROPES, PREDOMINANTLY USED FOR DRIVING PURPOSES; CHAINS; FITTINGS PREDOMINANTLY USED THEREFOR
    • F16G13/00Chains
    • F16G13/18Chains having special overall characteristics
    • F16G13/22Chains having special overall characteristics extensible
    • F16G13/24Chains having special overall characteristics extensible resilient

Abstract

The present invention provides a halogen-free environmental-friendly elevator balance compensating chain and a preparation method therefor and an application thereof. The compensating chain comprises one or more strands of steel wire rope inner cores and a rubber layer, wherein the rubber layer is prepared from the following raw materials in parts by weight: natural rubber, an ethylene-propylene-diene monomer and an ethylene-octene-pentene copolymer, a maleic anhydride grafted ethylene-acetic acid ethenyl ester copolymer, a maleic anhydride grafted ethylene-octene copolymer, a maleic anhydride grafted ethylene-butene copolymer, high-density filler, epoxy soybean oil, a lubricant and a flame retardant. By combining various copolymers, in particular, the ethylene-octene-pentene ternary copolymer as one of raw materials, the copolymerization effect is better when the rubber layer is prepared; the density of the rubber layer is smaller, so that the molecular surface of the rubber layer is arranged more closely, and the performance of wear resistance and tear resistance can be better.

Description

A kind of halogen-free environmental Elevator balance compensation chain and Manufacture Method and application
Technical field
The present invention relates to elevator technology field, particularly relate to a kind of halogen-free environmental elevator balanced compensated chain, also relate to a kind of manufacture method of halogen-free environmental elevator balanced compensated chain, and use the express elevator of this elevator balanced compensated chain.
Background technology
Elevator balanced compensated chain, for connecting car and the counterweight of elevator, is mainly used in the weight balancing hoist ropes and trailing cable, plays poising action to the operation of elevator, requires that it has bearing load large, runs noise little, flexibly the feature such as bending.At present, for the chain of elevator lifting balanced compensated chain, one is use metal light chain, and in the operational process of elevator, mutually directly clash between chain, noise is large, easily gets rusty; Two is metal light chain overcoat one deck plastic jackets, although the shock of chain interannular can be slowed down, but this compensated chain plastics jacket is easy to crack, come off, work-ing life is short, and three is add at metal light interchain to wear the rope made of hemp or wireline, this compensated chain is easy distortion in operational process, come off, work-ing life is short, and noise is large, poor safety performance, can only be applicable to slower elevators.
Recently; the Plastic coated steel chain balanced compensated for elevator lifting has occurred, this compensated chain, based on iron chains, adds the firm plastic protective layer of last layer on the surface of each ring of iron chains; layer is moulded in each chain link Surface coating one deck leaching of this compensated chain, and it is PVC material that layer is moulded in leaching.Each chain link contacts with each other a little or interviews the surface that layer is moulded in leaching, and it can reduce noise when elevator runs.But during this compensated chain traction car, bearing load is large, each chain link is through the slide-bar of vertex, and chain link changes direction of motion, is subjected to displacement and violent distortion between chain link, and layer wear resisting property is moulded in its leaching and resistance to performance of tearing is not good yet.
Such as Chinese patent 0331665.4 discloses a kind of Elevator balance compensation chain and Manufacture Method.It comprises iron chains (1), rubber cylinder (2), layer of fibers (3), above-mentioned iron chains (1) is placed in above-mentioned rubber cylinder (2), and above-mentioned rubber cylinder (2) is wrapped with layer of fibers (3).This manufacture method is: iron chains (1) eliminates rust; Sizing material is expressed in mould to be wrapped on iron chains (1) and makes rubber cylinder (2); Rubber cylinder (2) is inserted mould, then fiber material is expressed in mould be wrapped in rubber cylinder (2) outside surface form layer of fibers (3); After sulfuration, cooling and shaping, deburring arranges and namely makes.When the elevator balanced compensated chain of this technical scheme runs, noise is low, wear resistance good, tear strength and elongation at break high.But this elevator balanced compensated chain making work is complicated, and the auxiliary material of use is more, require higher to starting material, therefore cost of manufacture is higher, and performance does not reach desirable level.
For another example Chinese patent CN104140600A discloses a kind of halogen-free environmental high-speed elevator compensation chain material, it is characterized in that, with parts by weight, the composition of raw materials of described elevator compensation chain material is as follows: ethylene-propylene diene copolymer 40 ~ 60 parts, ethylene-octene copolymer 20 ~ 40 parts, maleated ethylene vinyl acetate copolyme and/or maleic anhydride grafted ethene-octene copolymer 10 ~ 30 parts, high-density stopping composition 250 ~ 450 parts, epoxy soybean oil 15 ~ 25 parts, 1 ~ 2 part, oxidation inhibitor, lubricant 2 ~ 5 parts, wherein: in ethylene-propylene diene copolymer, ethylene content is 60wt% ~ 70wt%, Third monomer content is 2wt% ~ 10wt%, mooney viscosity is 20 ~ 60, the Shore A hardness of described maleated ethylene vinyl acetate copolyme and/or maleic anhydride grafted ethene-octene copolymer is between 65 ~ 85.The hardness about 85 of the elevator balanced compensated chain that this technical scheme provides; Have good intensity and elongation, can ensure that cable is in operation can not rupture; Softness can meet the bending back and forth requirement that elevator runs; By the impact of temperature, greasy dirt erosion, not easy to wear, damage, noise is little, have longer work-ing life.But this elevator balanced compensated chain making work is complicated, and the auxiliary material of use is more, require higher to starting material, therefore cost of manufacture is higher, and performance does not reach desirable level.
Summary of the invention
For the auxiliary material overcoming the use existed in prior art is more, require higher to starting material, therefore the problem that cost of manufacture is higher, the express elevator that the invention provides a kind of halogen-free environmental Elevator balance compensation chain and Manufacture Method and use this halogen-free environmental elevator balanced compensated chain to produce.
The technical solution used in the present invention is: a kind of halogen-free environmental elevator balanced compensated chain, comprise one or more strands of wireline inner core and rubber layer, this wireline inner core is placed in rubber layer, its innovative point is: described rubber layer is made up of the raw material of following weight: natural rubber 20 ~ 40 parts, ethylene-propylene diene copolymer 20 ~ 30 parts, ethylene-octene-pentene copolymer 10 ~ 20 parts, maleated ethylene vinyl acetate copolyme 8 ~ 25 parts, maleic anhydride grafted ethene-octene copolymer 8 ~ 25 parts, maleic anhydride grafted ethene-butylene copolymer 8 ~ 25 parts, high-density stopping composition 100 ~ 250 parts, epoxy soybean oil 12 ~ 22 parts, lubricant 2 ~ 5 parts, fire retardant 1 ~ 2 part.
On this basis, described natural rubber 25 ~ 35 parts, ethylene-propylene diene copolymer 22 ~ 28 parts, ethylene-octene-pentene copolymer 12 ~ 18 parts, maleated ethylene vinyl acetate copolyme 12 ~ 20 parts, maleic anhydride grafted ethene-octene copolymer 12 ~ 20 parts, maleic anhydride grafted ethene-butylene copolymer 12 ~ 20 parts, high-density stopping composition 130 ~ 200 parts, epoxy soybean oil 15 ~ 20 parts, lubricant 2 ~ 5 parts, fire retardant 1 ~ 2 part.
On this basis, described natural rubber 30 parts, ethylene-propylene diene copolymer 25 parts, ethylene-octene-pentene copolymer 15 parts, maleated ethylene vinyl acetate copolyme 15 parts, maleic anhydride grafted ethene-octene copolymer 15 parts, maleic anhydride grafted ethene-butylene copolymer 15 parts, high-density stopping composition 180 parts, epoxy soybean oil 18 parts, lubricant 3 parts, fire retardant 2 parts.
On this basis, the Shore A hardness of described maleated ethylene vinyl acetate copolyme, maleic anhydride grafted ethene-octene copolymer and maleic anhydride grafted ethene-butylene copolymer is all between 60 ~ 70.
On this basis, described high-density stopping composition is the mixture of polymer-glass fibre composite or modified barium sulphate and aluminium hydroxide.
On this basis, in the mixture of described modified barium sulphate and aluminium hydroxide, blending ratio is 1.5 ~ 3:1 ~ 2.
On this basis, described lubricant comprises non-silicone base plinth stock oil and silicone oil, and the blending ratio of described non-silicone base plinth stock oil and silicone oil is 3 ~ 5:6 ~ 10.
The present invention also provides a kind of manufacture method of halogen-free environmental elevator balanced compensated chain, comprise rust cleaning, film-making shape glue, glue layer and vulcanisation step, its innovative point is: the concrete steps of film-making shape glue are: by raw material according to following order of addition(of ingredients): first the natural rubber of dosage ratio and ethylene-propylene diene copolymer are dropped into rubber mixing machine and first plasticate, at the banburying temperature of 140 ~ 160 DEG C, roll spacing is 2 ~ 5mm, plasticate 5min, after rubber mixing machine passes through 2 ~ 3 times, bag roller, add the ethylene-octene-pentene copolymer of dosage ratio subsequently successively, maleated ethylene vinyl acetate copolyme, maleic anhydride grafted ethene-octene copolymer, maleic anhydride grafted ethene-butylene copolymer, high-density stopping composition, epoxy soybean oil, lubricant and fire retardant, thin evenly crowded, make sheet glue.
On this basis, the concrete steps of described glue layer are: dropped into by obtained tablet-type gum in the mould of forcing machine, the feed zone temperature arranging forcing machine is 110-120 DEG C, the temperature of extruder discharging section is 120-150 DEG C, above-mentioned tablet-type gum is expressed in mould, and be wrapped in iron chains surface, looping rubber layer, controlling rubber layer radial thickness is 2 ~ 2.5mm.
Another object of the present invention is to provide a kind of environment-friendly type express elevator adopting halogen-free environmental elevator balanced compensated chain to make.
Compared with prior art, beneficial effect of the present invention is as follows:
(1) halogen-free environmental elevator balanced compensated chain of the present invention, main containing natural rubber in the raw material adopted, ethylene-octene-pentene copolymer, maleic anhydride grafted ethene-butylene copolymers etc., utilize multiple multipolymer to coordinate, especially use ethylene-octene-amylene terpolymer as one of raw material, copolymerization better effects if when making to make rubber layer, the density of rubber layer is less, and be conducive to the arrangement of rubber layer molecular surface tightr, wear-resisting resistance to performance of tearing is higher.
(2) halogen-free environmental elevator balanced compensated chain of the present invention, raw material mainly comprises natural rubber, ethylene-propylene diene copolymer, ethylene-octene-pentene copolymer, maleated ethylene vinyl acetate copolyme, maleic anhydride grafted ethene-octene copolymer, maleic anhydride grafted ethene-butylene copolymer, high-density stopping composition, epoxy soybean oil, lubricant and fire retardant, proportioning is suitable, amount ratio amount ratio of the prior art all minimizing to a certain extent, and without the need to using whipping agent, anti-aging agent and oxidation inhibitor, just can obtain effective antioxygen property, reduce raw-material use, stop the wasting of resources.
(3) halogen-free environmental elevator balanced compensated chain of the present invention, first by maleated ethylene vinyl acetate copolyme, maleic anhydride grafted ethene-octene copolymer and maleic anhydride grafted ethene-butylene copolymer three mixing, obtain beyond thought performance, when effectively can ensure that elevator runs, compensated chain has significant bending property, tensile property and rebound performance, as bending radius is greater than 1.5m.
(4) halogen-free environmental elevator balanced compensated chain of the present invention, utilizes distinctive raw material to form and proportioning combination between raw material, obtains that hardness is high, elongation good, long service life, can do shape that is circular or flat, elevator compensation chain smooth surface, when elevator runs, noise significantly reduces.
(5) halogen-free environmental elevator balanced compensated chain of the present invention, high-density stopping composition is chosen as the mixture of polymer-glass fibre composite or modified barium sulphate and aluminium hydroxide, compound or the stopping composition after combining, elevator compensation chain surface can be made firmer, in the mixture of especially modified barium sulphate and aluminium hydroxide, blending ratio is 1.5 ~ 3:1 ~ 2, after the mixing of this ratio, performance is best.
(6) halogen-free environmental elevator balanced compensated chain of the present invention, the lubricant comprising non-silicone base plinth stock oil and silicone oil two kinds mixing selected by lubricant, and the blending ratio setting non-silicone base plinth stock oil and silicone oil is 3 ~ 5:6 ~ 10, can ensure, in this lubricant use procedure, there is good lubricant effect, ensure in preparation process simultaneously, extruding in operation, compensated chain is functional, and makes compensated chain smooth surface without particle.
(7) manufacture method of halogen-free environmental elevator balanced compensated chain of the present invention, determine specific order of addition(of ingredients), banburying temperature, time and roll spacing, be conducive to making method of the present invention, preparation time shortens greatly, preparation efficiency improves greatly, improve 1.5 times than the production rate of prior art, simultaneously, the feed zone temperature that the present invention also arranges forcing machine is especially 110-120 DEG C, the temperature of extruder discharging section is 120-150 DEG C, the rubber layer being conducive to extruding has good toughness, controlling rubber layer radial thickness is 2 ~ 2.5mm, ensure the demand of thickness in actual production.
Embodiment
Following examples, are further elaborated to the present invention.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
Embodiment 1
The present embodiment provides a kind of halogen-free environmental elevator balanced compensated chain, comprise one or more strands of wireline inner core and rubber layer, this wireline inner core is placed in rubber layer, wherein, rubber layer is made up of the raw material of following weight: natural rubber 20 parts, ethylene-propylene diene copolymer 20 parts, ethylene-octene-pentene copolymer 10 parts, maleated ethylene vinyl acetate copolyme 8 parts, maleic anhydride grafted ethene-octene copolymer 8 parts, maleic anhydride grafted ethene-butylene copolymer 8 parts, high-density stopping composition 100 parts, epoxy soybean oil 12 parts, lubricant 2 parts, fire retardant 1 part.
As preferably, the Shore A hardness of maleated ethylene vinyl acetate copolyme, maleic anhydride grafted ethene-octene copolymer and maleic anhydride grafted ethene-butylene copolymer is all 60.
As preferably, high-density stopping composition is the mixture of polymer-glass fibre composite or modified barium sulphate and aluminium hydroxide, and aluminium hydroxide adopts the 104LEO of Albemarle Corporation.Preferred further, in the mixture of modified barium sulphate and aluminium hydroxide, blending ratio is 1.5:1.
As preferably, lubricant comprises non-silicone base plinth stock oil and silicone oil, and the blending ratio of non-silicone base plinth stock oil and silicone oil is 1:2.
Embodiment 2
The present embodiment provides a kind of halogen-free environmental elevator balanced compensated chain, comprise one or more strands of wireline inner core and rubber layer, this wireline inner core is placed in rubber layer, wherein, rubber layer is made up of the raw material of following weight: natural rubber 40 parts, ethylene-propylene diene copolymer 30 parts, ethylene-octene-pentene copolymer 20 parts, maleated ethylene vinyl acetate copolyme 25 parts, maleic anhydride grafted ethene-octene copolymer 25 parts, maleic anhydride grafted ethene-butylene copolymer 25 parts, high-density stopping composition 250 parts, epoxy soybean oil 22 parts, lubricant 5 parts, fire retardant 2 parts.
As preferably, the Shore A hardness of maleated ethylene vinyl acetate copolyme, maleic anhydride grafted ethene-octene copolymer and maleic anhydride grafted ethene-butylene copolymer is all 70.
As preferably, high-density stopping composition is the mixture of polymer-glass fibre composite or modified barium sulphate and aluminium hydroxide, and aluminium hydroxide adopts the 104LEO of Albemarle Corporation.Preferred further, in the mixture of modified barium sulphate and aluminium hydroxide, blending ratio is 3:1.
As preferably, lubricant comprises non-silicone base plinth stock oil and silicone oil, and the blending ratio of described non-silicone base plinth stock oil and silicone oil is 5:6.
Embodiment 3
The present embodiment provides a kind of halogen-free environmental elevator balanced compensated chain, comprise one or more strands of wireline inner core and rubber layer, this wireline inner core is placed in rubber layer, wherein, natural rubber 25 parts, ethylene-propylene diene copolymer 22 parts, ethylene-octene-pentene copolymer 12 parts, maleated ethylene vinyl acetate copolyme 12 parts, maleic anhydride grafted ethene-octene copolymer 12 parts, maleic anhydride grafted ethene-butylene copolymer 12 parts, high-density stopping composition 130 parts, epoxy soybean oil 15 parts, lubricant 2 parts, fire retardant 1 part.
As preferably, the Shore A hardness of maleated ethylene vinyl acetate copolyme, maleic anhydride grafted ethene-octene copolymer and maleic anhydride grafted ethene-butylene copolymer is all 63.
As preferably, high-density stopping composition is the mixture of polymer-glass fibre composite or modified barium sulphate and aluminium hydroxide.Preferred further, in the mixture of modified barium sulphate and aluminium hydroxide, blending ratio is 3:1, and aluminium hydroxide adopts the 104LEO of Albemarle Corporation.
As preferably, lubricant comprises non-silicone base plinth stock oil and silicone oil, and the blending ratio of described non-silicone base plinth stock oil and silicone oil is 3:6.
Embodiment 4
The present embodiment provides a kind of halogen-free environmental elevator balanced compensated chain, comprise one or more strands of wireline inner core and rubber layer, this wireline inner core is placed in rubber layer, wherein, natural rubber 35 parts, ethylene-propylene diene copolymer 28 parts, ethylene-octene-pentene copolymer 18 parts, maleated ethylene vinyl acetate copolyme 20 parts, maleic anhydride grafted ethene-octene copolymer 20 parts, maleic anhydride grafted ethene-butylene copolymer 20 parts, high-density stopping composition 200 parts, epoxy soybean oil 20 parts, lubricant 5 parts, fire retardant 2 parts.
As preferably, the Shore A hardness of maleated ethylene vinyl acetate copolyme, maleic anhydride grafted ethene-octene copolymer and maleic anhydride grafted ethene-butylene copolymer is all 65.
As preferably, high-density stopping composition is the mixture of polymer-glass fibre composite or modified barium sulphate and aluminium hydroxide.Preferred further, in the mixture of modified barium sulphate and aluminium hydroxide, blending ratio is 2.2:1.5, and aluminium hydroxide adopts the 104LEO of Albemarle Corporation.
As preferably, lubricant comprises non-silicone base plinth stock oil and silicone oil, and the blending ratio of non-silicone base plinth stock oil and silicone oil is 4:7.
Embodiment 5
The present embodiment provides a kind of halogen-free environmental elevator balanced compensated chain, comprise one or more strands of wireline inner core and rubber layer, this wireline inner core is placed in rubber layer, wherein, natural rubber 30 parts, ethylene-propylene diene copolymer 25 parts, ethylene-octene-pentene copolymer 15 parts, maleated ethylene vinyl acetate copolyme 15 parts, maleic anhydride grafted ethene-octene copolymer 15 parts, maleic anhydride grafted ethene-butylene copolymer 15 parts, high-density stopping composition 180 parts, epoxy soybean oil 18 parts, lubricant 3 parts, fire retardant 2 parts.
As preferably, the Shore A hardness of maleated ethylene vinyl acetate copolyme, maleic anhydride grafted ethene-octene copolymer and maleic anhydride grafted ethene-butylene copolymer is all 68.
As preferably, high-density stopping composition is the mixture of polymer-glass fibre composite or modified barium sulphate and aluminium hydroxide.Preferred further, in the mixture of modified barium sulphate and aluminium hydroxide, blending ratio is 3:2, and aluminium hydroxide adopts the 104LEO of Albemarle Corporation.
As preferably, lubricant comprises non-silicone base plinth stock oil and silicone oil, and the blending ratio of non-silicone base plinth stock oil and silicone oil is 5:8.
Embodiment 6
On the basis of embodiment 1 ~ 5, utilize the composition of raw materials of any one embodiment of embodiment 1 ~ 5 to carry out manufacture halogen-free environmental elevator balanced compensated chain, concrete steps are as follows:
Rust cleaning: one or more strands of wireline inner core is carried out deburring, conventional processing of rust removing.
Film-making shape glue: by the composition of raw materials of any one embodiment of embodiment 1 ~ 5 according to following order of addition(of ingredients): first the natural rubber of dosage ratio and ethylene-propylene diene copolymer are dropped into rubber mixing machine and first plasticate, at the banburying temperature of 140 ~ 160 DEG C, roll spacing is 2 ~ 5mm, plasticate 5min, after rubber mixing machine passes through 2 ~ 3 times, bag roller, add the ethylene-octene-pentene copolymer of dosage ratio subsequently successively, maleated ethylene vinyl acetate copolyme, maleic anhydride grafted ethene-octene copolymer, maleic anhydride grafted ethene-butylene copolymer, high-density stopping composition, epoxy soybean oil, lubricant and fire retardant, thin evenly crowded, make sheet glue.
Glue layer: obtained tablet-type gum is dropped in the mould of forcing machine, the feed zone temperature arranging forcing machine is 110-120 DEG C, the temperature of extruder discharging section is 120-150 DEG C, above-mentioned tablet-type gum is expressed in mould, and be wrapped in iron chains surface, looping rubber layer, controlling rubber layer radial thickness is 2 ~ 2.5mm.
Sulfuration: by mold heated to 100 ~ 120 DEG C, puts into the mould of vulcanizer by above-mentioned rubber layer, coating that releasing agent continues to be warming up to curing temperature is 160 ~ 180 DEG C, pressure is 9 ~ 15MPA, and the time is 1 ~ 3min, and after sulfuration, mold takes out, cooling and shaping, namely makes product.
Comparative example 1
This example provides a kind of halogen-free environmental elevator balanced compensated chain, and its formula is basic with embodiment 1, does not contain ethylene-octene-pentene copolymer unlike in this example.
Comparative example 2
This example provides a kind of halogen-free environmental elevator balanced compensated chain, and its formula is basic with embodiment 1, does not contain maleic anhydride grafted ethene-butylene copolymer unlike in this example.
Comparative example 3
This example provides a kind of halogen-free environmental elevator balanced compensated chain, and its formula is basic is 30 parts with embodiment 1 unlike ethylene-octene-pentene copolymer consumption, maleic anhydride grafted ethene-butylene copolymer 40 parts.
The mechanical property of the material of the above embodiments 1 ~ 5 and comparative example 1 ~ 3 gained is tested, the results are shown in table 1:
table 1
Above-mentioned explanation illustrate and describes the preferred embodiments of the present invention, as previously mentioned, be to be understood that the present invention is not limited to the form disclosed by this paper, should not regard the eliminating to other embodiments as, and can be used for other combinations various, amendment and environment, and can in invention contemplated scope described herein, changed by the technology of above-mentioned instruction or association area or knowledge.And the change that those skilled in the art carry out and change do not depart from the spirit and scope of the present invention, then all should protecting in scope in claims of the present invention.

Claims (10)

1. a halogen-free environmental elevator balanced compensated chain, comprise one or more strands of wireline inner core and rubber layer, this wireline inner core is placed in rubber layer, it is characterized in that: described rubber layer is made up of the raw material of following weight: natural rubber 20 ~ 40 parts, ethylene-propylene diene copolymer 20 ~ 30 parts, ethylene-octene-pentene copolymer 10 ~ 20 parts, maleated ethylene vinyl acetate copolyme 8 ~ 25 parts, maleic anhydride grafted ethene-octene copolymer 8 ~ 25 parts, maleic anhydride grafted ethene-butylene copolymer 8 ~ 25 parts, high-density stopping composition 100 ~ 250 parts, epoxy soybean oil 12 ~ 22 parts, lubricant 2 ~ 5 parts, fire retardant 1 ~ 2 part.
2. halogen-free environmental elevator balanced compensated chain according to claim 1, is characterized in that: described natural rubber 25 ~ 35 parts, ethylene-propylene diene copolymer 22 ~ 28 parts, ethylene-octene-pentene copolymer 12 ~ 18 parts, maleated ethylene vinyl acetate copolyme 12 ~ 20 parts, maleic anhydride grafted ethene-octene copolymer 12 ~ 20 parts, maleic anhydride grafted ethene-butylene copolymer 12 ~ 20 parts, high-density stopping composition 130 ~ 200 parts, epoxy soybean oil 15 ~ 20 parts, lubricant 2 ~ 5 parts, fire retardant 1 ~ 2 part.
3. halogen-free environmental elevator balanced compensated chain according to claim 1 and 2, is characterized in that: described natural rubber 30 parts, ethylene-propylene diene copolymer 25 parts, ethylene-octene-pentene copolymer 15 parts, maleated ethylene vinyl acetate copolyme 15 parts, maleic anhydride grafted ethene-octene copolymer 15 parts, maleic anhydride grafted ethene-butylene copolymer 15 parts, high-density stopping composition 180 parts, epoxy soybean oil 18 parts, lubricant 3 parts, fire retardant 2 parts.
4. halogen-free environmental elevator balanced compensated chain according to claim 1, is characterized in that: the Shore A hardness of described maleated ethylene vinyl acetate copolyme, maleic anhydride grafted ethene-octene copolymer and maleic anhydride grafted ethene-butylene copolymer is all between 60 ~ 70.
5. halogen-free environmental elevator balanced compensated chain according to claim 1, is characterized in that: described high-density stopping composition is the mixture of polymer-glass fibre composite or modified barium sulphate and aluminium hydroxide.
6. halogen-free environmental elevator balanced compensated chain according to claim 5, is characterized in that: in the mixture of described modified barium sulphate and aluminium hydroxide, blending ratio is 1.5 ~ 3:1 ~ 2.
7. halogen-free environmental elevator balanced compensated chain according to claim 1, is characterized in that: described lubricant comprises non-silicone base plinth stock oil and silicone oil, and the blending ratio of described non-silicone base plinth stock oil and silicone oil is 3 ~ 5:6 ~ 10.
8. the manufacture method of a halogen-free environmental elevator balanced compensated chain according to claim 1, comprise rust cleaning, film-making shape glue, glue layer and vulcanisation step, it is characterized in that: the concrete steps of film-making shape glue are: by raw material according to following order of addition(of ingredients): first the natural rubber of dosage ratio and ethylene-propylene diene copolymer are dropped into rubber mixing machine and first plasticate, at the banburying temperature of 140 ~ 160 DEG C, roll spacing is 2 ~ 5mm, plasticate 5min, after rubber mixing machine passes through 2 ~ 3 times, bag roller, add the ethylene-octene-pentene copolymer of dosage ratio subsequently successively, maleated ethylene vinyl acetate copolyme, maleic anhydride grafted ethene-octene copolymer, maleic anhydride grafted ethene-butylene copolymer, high-density stopping composition, epoxy soybean oil, lubricant and fire retardant, thin evenly crowded, make sheet glue.
9. the manufacture method of halogen-free environmental elevator balanced compensated chain according to claim 8, it is characterized in that: the concrete steps of described glue layer are: obtained tablet-type gum is dropped in the mould of forcing machine, the feed zone temperature arranging forcing machine is 110-120 DEG C, the temperature of extruder discharging section is 120-150 DEG C, above-mentioned tablet-type gum is expressed in mould, and be wrapped in iron chains surface, looping rubber layer, controlling rubber layer radial thickness is 2 ~ 2.5mm.
10. an application for the halogen-free environmental elevator balanced compensated chain according to any one of claim 1 ~ 9, is mainly used in express elevator field.
CN201510729044.2A 2015-10-30 2015-10-30 Halogen-free environmental-friendly elevator balance compensating chain, and preparation method therefor and application thereof Pending CN105440330A (en)

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PCT/CN2015/097892 WO2017071022A1 (en) 2015-10-30 2015-12-18 Halogen-free environmentally friendly elevator balance compensating chain, and manufacturing method and use therefor

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106192498A (en) * 2016-09-13 2016-12-07 宣城市华菱精工科技股份有限公司 Corrosion-resistant compensating cable of elevator and processing technology thereof
CN106182670A (en) * 2016-09-13 2016-12-07 宣城市华菱精工科技股份有限公司 Elevator compensated cable processing technique
CN107127943A (en) * 2017-06-30 2017-09-05 南通兴华达高实业有限公司 A kind of buckle-type elevator balanced compensated chain and its production technology

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62227938A (en) * 1986-03-29 1987-10-06 Japan Synthetic Rubber Co Ltd Oil and weather resistant polymer composition
CN1455131A (en) * 2003-06-05 2003-11-12 魏昌林 Elevator balance compensating chain and manufacturing method thereof
CN104140600A (en) * 2014-08-11 2014-11-12 江苏德威新材料股份有限公司 Halogen-free environment-friendly high-speed elevator compensation chain material and application thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4872477B2 (en) * 2006-06-16 2012-02-08 マツダ株式会社 Thermoplastic elastomer composition and molded member thereof
CN103881242B (en) * 2014-03-31 2016-06-08 江苏德威新材料股份有限公司 A kind of high speed flat lift cable wear-resisting halogen-free flameproof elastic material and its preparation method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62227938A (en) * 1986-03-29 1987-10-06 Japan Synthetic Rubber Co Ltd Oil and weather resistant polymer composition
CN1455131A (en) * 2003-06-05 2003-11-12 魏昌林 Elevator balance compensating chain and manufacturing method thereof
CN104140600A (en) * 2014-08-11 2014-11-12 江苏德威新材料股份有限公司 Halogen-free environment-friendly high-speed elevator compensation chain material and application thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
丁丽芹等: "《润滑油及其添加剂(第1版)》", 30 June 2015, 中国石化出版社 *
山西省化工研究所: "《塑料橡胶加工助剂(第二版)》", 31 October 2002, 化学工业出版社 *
陈永平: "《天然橡胶共混原理及应用》", 31 December 2010, 中国石化出版社 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106192498A (en) * 2016-09-13 2016-12-07 宣城市华菱精工科技股份有限公司 Corrosion-resistant compensating cable of elevator and processing technology thereof
CN106182670A (en) * 2016-09-13 2016-12-07 宣城市华菱精工科技股份有限公司 Elevator compensated cable processing technique
CN106192498B (en) * 2016-09-13 2019-07-19 宣城市华菱精工科技股份有限公司 Corrosion-resistant compensating cable of elevator and its manufacture craft
CN107127943A (en) * 2017-06-30 2017-09-05 南通兴华达高实业有限公司 A kind of buckle-type elevator balanced compensated chain and its production technology
CN107127943B (en) * 2017-06-30 2023-12-26 南通兴华达高实业有限公司 Buckle type elevator balance compensation chain and production process thereof

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