CN105419454A - Toughened glass deinking agent and preparation method therefor - Google Patents
Toughened glass deinking agent and preparation method therefor Download PDFInfo
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- CN105419454A CN105419454A CN201511017334.0A CN201511017334A CN105419454A CN 105419454 A CN105419454 A CN 105419454A CN 201511017334 A CN201511017334 A CN 201511017334A CN 105419454 A CN105419454 A CN 105419454A
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- toughened glass
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- deinking agent
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/04—Chemical paint or ink removers with surface-active agents
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- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
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Abstract
The invention discloses a toughened glass deinking agent and a preparation method therefor. The toughened glass deinking agent is prepared from the following raw materials, by weight, 5-8 parts of polyoxyethylene fatty alcohol sodium sulfate, 8-10 parts of fatty alcohol polyoxyethylene (9) ether, 10-12 parts of fatty acid alkanolamide, 2-3 parts of vinyl acetate, 35-45 parts of absolute ethyl alcohol, 0.5-1.5 parts of dibutyl phthalate, 1-3 parts of polyacrylamide, 1-2 parts of essence, 1-2 parts of activating agent, the balance being deionized water. The obtained toughened glass deinking agent has a strong removal capability, has no residues, is extremely easy to clean, is not easy to volatilize, is not easy to decompose, has strong endurance, and is safe has no corrosion to various metals, plastic cement, fibers and the like.
Description
Technical field
The invention belongs to technical field of ink, be specifically related to toughened glass deinking agent and preparation method thereof.
Background technology
Along with the development of the industries such as building, automobile, decorations, furniture, information industry technology and people are to the raising of living space environmental requirement, the functional converted products such as shatter proof glass, energy-conservation double glazing is used widely.The supply and demand general layout of sheet glass and consumption structure change.
Toughened glass is widespread use in life, and glass surface silk-screen can leave ink, and glass edge can apply Photoresist, tusche etc.Some ink is containing toxic stronger organic solvent, as benzene class, ketones solvent or containing heavy metal element in ink, in Printing ink producing process when solvent treatment not at that time, easily the health of people is damaged, the evaporation of the solvent that contained toxicity is stronger in ink during printing, also can produce certain injury to the health of people, due to a certain amount of solvent residual on printed matter, these solvents will produce peculiar smell and affect the healthy of printed matter user.
In existing ink, some ink is to the strong adhesion of glass baseplate, water tolerance is strong, all there will not be coating shedding after moist or muddy water contact, weathering resistance by force, not easy to change etc., also have, for various dissimilar ink, be difficult to disposablely thoroughly remove ink, and mirror-like silver logo and other minute surface rare metal logo is difficult to effectively thoroughly remove, therefore, develop toughened glass deinking agent and there are good market outlook.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of toughened glass deinking agent be provided, have removal power by force, residual and very easily clean, not volatile, not easily decompose, the advantages such as stamina is strong.The invention still further relates to the preparation method of this toughened glass deinking agent.
The preparation method of toughened glass deinking agent of the present invention, comprises the steps:
1) get the raw materials ready: the starting material preparing following weight percent: polyoxyethylenated alcohol sodium sulfate 5-8, aliphatic alcohol polyethenoxy (9) ether 8-10, lipid acid alkanol phthalein amine 10-12, vinyl-acetic ester 2-3, dehydrated alcohol 35-45, dibutyl phthalate 0.5-1.5, polyacrylamide 1-3, essence 1-2, activator 1-2, surplus are deionized water;
2) batch mixing: polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (9) ether, lipid acid alkanol phthalein amine, vinyl-acetic ester are joined in deionized water, heated and stirred, then dibutyl phthalate, polyacrylamide, essence, activator is added, heated and stirred, add dehydrated alcohol, stir, leave standstill, obtain finished product;
Step 1) described in activator, obtained by following steps:
1. high speed dispersion emulsification: smashed by squaw weed, adds the pure water of identical weight, puts into the process of high speed dispersion mulser, obtains high speed dispersion emulsification;
2. pressurised extraction: the emulsification after step 1. being processed, puts into pressure pan, adds the pure water of identical weight, is forced into 4kg/cm
2, make its pressure uniform, and keep 10-15min, then in 1-3s, recover normal pressure, filter, obtain extracting solution;
3. collect the extracting solution that 2. step obtains, filter, filtrate is concentrated into the medicinal extract that relative density is 1.10 (surveying when 70 DEG C), obtains activator.
Step 1 of the present invention) described in get the raw materials ready, the starting material of preferred following weight percent: polyoxyethylenated alcohol sodium sulfate 6, aliphatic alcohol polyethenoxy (9) ether 8, lipid acid alkanol phthalein amine 10, vinyl-acetic ester 3, dehydrated alcohol 40, dibutyl phthalate 1, polyacrylamide 2, essence 1.5, activator 1.5, surplus are deionized water.
Step 2) described in heated and stirred, be preferably heated to 35-45 DEG C, stir 5-10min, rotating speed 2000-3000r/min, described leave standstill, preferred 10-20min.
The invention still further relates to the toughened glass deinking agent adopting above-mentioned preparation method to obtain.
Compared to existing technology, the invention has the advantages that:
1, the toughened glass deinking agent that obtains of the present invention, removal power by force, residual and very easily clean, not volatile, not easily decompose, stamina is strong, to all safe non-corrosivenesss such as various metal, plastic cement, fibers.
2, the present invention adopts high speed dispersion emulsification to obtain activator, the rotor of high speed dispersion mulser is when high speed rotating, produce material ejection from the elongated cuts (slit) rotated that very large centrifugal force makes to be processed, and under the acting in conjunction of stator, make the material be processed be subject to the reactive force of two aspects: force it by the positive force of slit and the resistance that stops it to pass through.Meanwhile, when processed material sprays from slit, be also subject to the shearing action of slit, and the rotational shear produced by turning stator relative movement makes under the effect of multi-acting force material obtain homogeneous, emulsification.It is narrow that the plant material processed has particle distribution range, good evenness, and without dead angle, material 100% is by the feature of dispersion and emulsion.
3, the present invention obtains activator by pressure treatment, particularly " is forced into 4kg/cm
2make its pressure uniform, and keep 10-15min, then in 1-3s, recover normal pressure "; the pressure of employing is far smaller than existing pressure technique pressure used; and by instantaneously pressure being reduced to 0, the active substance in plant is isolated, and compared to existing technology; effective; the time is short, energy efficient, safety.
Embodiment
With embodiment, the invention will be further described below, but the present invention is not limited to these embodiments.
Embodiment 1:
The preparation method of toughened glass deinking agent, comprises the steps:
1) get the raw materials ready: the starting material preparing following weight percent: polyoxyethylenated alcohol sodium sulfate 5, aliphatic alcohol polyethenoxy (9) ether 10, lipid acid alkanol phthalein amine 10, vinyl-acetic ester 3, dehydrated alcohol 35, dibutyl phthalate 1.5, polyacrylamide 1, essence 2, activator 1, surplus are deionized water;
2) batch mixing: polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (9) ether, lipid acid alkanol phthalein amine, vinyl-acetic ester are joined in deionized water, be heated to 35 DEG C, stir 10min, rotating speed 3000r/min, then dibutyl phthalate, polyacrylamide, essence, activator is added, be heated to 35 DEG C, stir 10min, rotating speed 3000r/min, add dehydrated alcohol, stir, leave standstill 20min, obtain finished product;
Step 1) described in activator, obtained by following steps:
1. high speed dispersion emulsification: smashed by squaw weed, adds the pure water of identical weight, puts into the process of high speed dispersion mulser, obtains high speed dispersion emulsification;
2. pressurised extraction: the emulsification after step 1. being processed, puts into pressure pan, adds the pure water of identical weight, is forced into 4kg/cm
2, make its pressure uniform, and keep 10-15min, then in 1-3s, recover normal pressure, filter, obtain extracting solution;
3. collect the extracting solution that 2. step obtains, filter, filtrate is concentrated into the medicinal extract that relative density is 1.10 (surveying when 70 DEG C), obtains activator.
Embodiment 2:
The preparation method of toughened glass deinking agent, comprises the steps:
1) get the raw materials ready: the starting material preparing following weight percent: polyoxyethylenated alcohol sodium sulfate 8, aliphatic alcohol polyethenoxy (9) ether 8, lipid acid alkanol phthalein amine 12, vinyl-acetic ester 2, dehydrated alcohol 45, dibutyl phthalate 0.5, polyacrylamide 3, essence 1, activator 2, surplus are deionized water;
2) batch mixing: polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (9) ether, lipid acid alkanol phthalein amine, vinyl-acetic ester are joined in deionized water, be heated to 45 DEG C, stir 5min, rotating speed 2500r/min, then dibutyl phthalate, polyacrylamide, essence, activator is added, be heated to 45 DEG C, stir 5min, rotating speed 2500r/min, add dehydrated alcohol, stir, leave standstill 10min, obtain finished product;
Step 1) described in activator, obtained by following steps:
1. high speed dispersion emulsification: smashed by squaw weed, adds the pure water of identical weight, puts into the process of high speed dispersion mulser, obtains high speed dispersion emulsification;
2. pressurised extraction: the emulsification after step 1. being processed, puts into pressure pan, adds the pure water of identical weight, is forced into 4kg/cm
2, make its pressure uniform, and keep 10-15min, then in 1-3s, recover normal pressure, filter, obtain extracting solution;
3. collect the extracting solution that 2. step obtains, filter, filtrate is concentrated into the medicinal extract that relative density is 1.10 (surveying when 70 DEG C), obtains activator.
Embodiment 3:
1) get the raw materials ready: the starting material preparing following weight percent: polyoxyethylenated alcohol sodium sulfate 6, aliphatic alcohol polyethenoxy (9) ether 8, lipid acid alkanol phthalein amine 10, vinyl-acetic ester 3, dehydrated alcohol 40, dibutyl phthalate 1, polyacrylamide 2, essence 1.5, activator 1.5, surplus are deionized water;
2) batch mixing: polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (9) ether, lipid acid alkanol phthalein amine, vinyl-acetic ester are joined in deionized water, be heated to 40 DEG C, stir 8min, rotating speed 2000r/min, then dibutyl phthalate, polyacrylamide, essence, activator is added, be heated to 40 DEG C, stir 8min, rotating speed 2000r/min, add dehydrated alcohol, stir, leave standstill 15min, obtain finished product;
Step 1) described in activator, obtained by following steps:
1. high speed dispersion emulsification: smashed by squaw weed, adds the pure water of identical weight, puts into the process of high speed dispersion mulser, obtains high speed dispersion emulsification;
2. pressurised extraction: the emulsification after step 1. being processed, puts into pressure pan, adds the pure water of identical weight, is forced into 4kg/cm
2, make its pressure uniform, and keep 10-15min, then in 1-3s, recover normal pressure, filter, obtain extracting solution;
3. collect the extracting solution that 2. step obtains, filter, filtrate is concentrated into the medicinal extract that relative density is 1.10 (surveying when 70 DEG C), obtains activator.
Comparative example 1:
1) get the raw materials ready: the starting material preparing following weight percent: polyoxyethylenated alcohol sodium sulfate 6, aliphatic alcohol polyethenoxy (9) ether 8, lipid acid alkanol phthalein amine 10, vinyl-acetic ester 3, dehydrated alcohol 40, dibutyl phthalate 1, polyacrylamide 2, essence 1.5, activator 1.5, surplus are deionized water;
2) batch mixing: polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (9) ether, lipid acid alkanol phthalein amine, vinyl-acetic ester are joined in deionized water, be heated to 40 DEG C, stir 8min, rotating speed 2000r/min, then dibutyl phthalate, polyacrylamide, essence, activator is added, be heated to 40 DEG C, stir 8min, rotating speed 2000r/min, add dehydrated alcohol, stir, leave standstill 15min, obtain finished product;
Step 1) described in activator, obtained by following steps: smashed by squaw weed, add the pure water of identical weight, decoct twice, merge decoction liquor, the medicinal extract that to be concentrated into relative density be 1.10 (surveying when 70 DEG C), obtains activator.
Comparative example 2:
Polyoxyethylenated alcohol sodium sulfate 8%, aliphatic alcohol polyethenoxy (9) ether 10%, lipid acid alkanol phthalein amine 15%, dehydrated alcohol 40%, polypropylene phthalein amine (auxiliary agent) 1%, essence 3%, sodium laurylsulfonate (surfactant) 1%, surplus are softening water, and the Hardness Control of softening water is at 30ppm;
Polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (9) ether, lipid acid alkanol phthalein amine are joined in softening water, 6min is stirred within the scope of 40 DEG C, then auxiliary agent, essence and surfactant is added successively, 12min is stirred within the scope of 30 DEG C, finally add dehydrated alcohol, stir 7min, standing 40min after completing.
Comparative result:
Adopt toughened glass deinking agent prepared by method of the present invention, elimination effect is good, uses rear glass transmission rate high, does not almost have water wave.
Claims (4)
1. the preparation method of toughened glass deinking agent, is characterized in that, comprises the steps:
1) get the raw materials ready: the starting material preparing following weight percent: polyoxyethylenated alcohol sodium sulfate 5-8, aliphatic alcohol polyethenoxy (9) ether 8-10, lipid acid alkanol phthalein amine 10-12, vinyl-acetic ester 2-3, dehydrated alcohol 35-45, dibutyl phthalate 0.5-1.5, polyacrylamide 1-3, essence 1-2, activator 1-2, surplus are deionized water;
2) batch mixing: polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (9) ether, lipid acid alkanol phthalein amine, vinyl-acetic ester are joined in deionized water, heated and stirred, then dibutyl phthalate, polyacrylamide, essence, activator is added, heated and stirred, add dehydrated alcohol, stir, leave standstill, obtain finished product;
Step 1) described in activator, obtained by following steps:
1. high speed dispersion emulsification: smashed by squaw weed, adds the pure water of identical weight, puts into the process of high speed dispersion mulser, obtains high speed dispersion emulsification;
2. pressurised extraction: the emulsification after step 1. being processed, puts into pressure pan, adds the pure water of identical weight, is forced into 4kg/cm
2, make its pressure uniform, and keep 10-15min, then in 1-3s, recover normal pressure, filter, obtain extracting solution;
3. collect the extracting solution that 2. step obtains, filter, filtrate is concentrated into the medicinal extract that relative density is 1.10 (surveying when 70 DEG C), obtains activator.
2. the preparation method of toughened glass deinking agent according to claim 1, it is characterized in that: step 1) described in get the raw materials ready, the starting material for following weight percent: polyoxyethylenated alcohol sodium sulfate 6, aliphatic alcohol polyethenoxy (9) ether 8, lipid acid alkanol phthalein amine 10, vinyl-acetic ester 3, dehydrated alcohol 40, dibutyl phthalate 1, polyacrylamide 2, essence 1.5, activator 1.5, surplus are deionized water.
3. the preparation method of toughened glass deinking agent according to claim 1, is characterized in that: step 2) described in heated and stirred, refer to be heated to 35-45 DEG C, stir 5-lOmin, rotating speed 2000-3000r/min, described leave standstill, be 10-20min.
4. the toughened glass deinking agent that obtains of preparation method according to any one of claim 1-3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511017334.0A CN105419454A (en) | 2015-12-30 | 2015-12-30 | Toughened glass deinking agent and preparation method therefor |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511017334.0A CN105419454A (en) | 2015-12-30 | 2015-12-30 | Toughened glass deinking agent and preparation method therefor |
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| CN105419454A true CN105419454A (en) | 2016-03-23 |
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| CN201511017334.0A Pending CN105419454A (en) | 2015-12-30 | 2015-12-30 | Toughened glass deinking agent and preparation method therefor |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107500568A (en) * | 2016-06-14 | 2017-12-22 | 蓝思科技股份有限公司 | A kind of process of doing over again of the substandard products of toughened glass panel |
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| JPH08100140A (en) * | 1994-09-28 | 1996-04-16 | Shiyachihata Kogyo Kk | Ink erasor and wiping off using the same |
| JP2003096490A (en) * | 2001-09-19 | 2003-04-03 | Lion Corp | Liquid cleanser composition |
| CN102391713A (en) * | 2011-10-25 | 2012-03-28 | 华南理工大学 | Deinking agent containing modified product of lignin and preparation method thereof |
| CN104744994A (en) * | 2015-03-25 | 2015-07-01 | 安徽物宝光电材料有限公司 | Tempered glass deinking agent and production method thereof |
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2015
- 2015-12-30 CN CN201511017334.0A patent/CN105419454A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08100140A (en) * | 1994-09-28 | 1996-04-16 | Shiyachihata Kogyo Kk | Ink erasor and wiping off using the same |
| JP2003096490A (en) * | 2001-09-19 | 2003-04-03 | Lion Corp | Liquid cleanser composition |
| CN102391713A (en) * | 2011-10-25 | 2012-03-28 | 华南理工大学 | Deinking agent containing modified product of lignin and preparation method thereof |
| CN104744994A (en) * | 2015-03-25 | 2015-07-01 | 安徽物宝光电材料有限公司 | Tempered glass deinking agent and production method thereof |
Non-Patent Citations (5)
| Title |
|---|
| 戴好富等: "《黎族药志（第三册）》", 31 January 2014, 中国科学技术出版社 * |
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| 李捍东等: "《苯系化学品理化毒理信息手册》", 31 July 2015, 中国环境出版社 * |
| 林尚安 等: "《高分子化学》", 31 May 1982, 科学出版社 * |
| 柯铭清: "《中草药有效成分理化与药理特性》", 29 February 1980, 湖南科学技术出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107500568A (en) * | 2016-06-14 | 2017-12-22 | 蓝思科技股份有限公司 | A kind of process of doing over again of the substandard products of toughened glass panel |
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Application publication date: 20160323 |
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