CN105419393A - Corrosion-resistant blue ceramic pigment and preparation method thereof - Google Patents
Corrosion-resistant blue ceramic pigment and preparation method thereof Download PDFInfo
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- CN105419393A CN105419393A CN201510826699.1A CN201510826699A CN105419393A CN 105419393 A CN105419393 A CN 105419393A CN 201510826699 A CN201510826699 A CN 201510826699A CN 105419393 A CN105419393 A CN 105419393A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0009—Pigments for ceramics
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Abstract
The invention relates to a corrosion-resistant blue ceramic pigment and a preparation method thereof and belongs to the technical field of ceramic pigment production. The pigment is prepared from, by weight, 10-60 parts of potassium carbonate, 20-55 parts of diammonium phosphate, 20-65 parts of zirconium oxide, 10-30 parts of zinc oxide, 30-50 parts of aluminum oxide and 15-45 parts of cobaltous oxide. The preparation method comprises the steps of mixing the components to be uniform, conducting high temperature calcination at the temperature of 500-1000 DEG C, conducting cooling and pulverization, sieving the components with a 500-800-mesh sieve, conducting washing, after washing is ended, conducting further pulverization with a ball mill, sieving the components with a 100-300-mesh sieve, and obtaining the corrosion-resistant blue ceramic pigment. The ceramic pigment is bright in color development, and in addition, the pigment is simple in preparation process, resistant to corrosion and applicable to underglaze color, pigmented glaze and overglaze color.
Description
Technical field
The present invention relates to a kind of ceramic pigment, be specifically related to a kind of corrosion-resistant blue ceramic colorant and preparation method thereof, belong to ceramic pigment technical field.
Background technology
Ceramic pigment refers to the material for ceramic pigmented finiss.Ceramic decoration plays a part to set off, beautify to the quality of ceramic and moulding, the artistic effect of its energy reinforced article, the performance improving goods and class, to construction sanitary ceramic or domestic ceramics all most important, more play a part very important for the outlet and price that improve construction sanitary ceramic and domestic ceramic product, ceramic coloring decoration technique relates to multiple fields such as material, technique, tooling and industrial art, even relates to multi-door subject and the industries such as chemical industry metallurgical, automatically control, electronics ".The material that ceramic pigment comprises on glaze, in glaze, under glaze and makes glaze, cosmetic soil and base substrate painted, can think to introduce chromonic material the most basic in all ceramic coloring materials, it is the stable compound formed through high-temperature calcination by pure nonmetal oxide and some metal oxide, finished product is powdery, during use, added in the parent glaze (aqueous) prepared in advance and be adjusted to required color, spray to porcelain base surface, again through high-temperature calcination (glazing), ceramic is made to be stable color.
The blue beramic color of purple taste is a kind of beramic color of preciousness, has more obtained pottery, glass etc. abroad and generally use, and is greatly favored by consumers.Because the beramic color colour generation of rare earth ion color development is pure, homogeneous, therefore the making of the blue beramic color of purple taste is generally adopt the raw material containing rare earth, and this pigment cost is too high, is difficult to meet actual operation requirements.Also few to the development of high temperature decorating colour abroad, main research system concentrates on lanthanide oxide and sosoloid etc. thereof.
Corrosion-resistant colorant is that the ability of opposing surrounding medium corrosion failure effect is called erosion resistance.Determined by the composition, chemical property, tissue morphology etc. of material, therefore, the colorant in colour-stable under corrosive environment is relatively less, and color category lacks naturally, and the colorant that can develop the color under strong acid and strong base condition is just less, so study corrosion-resistant colorant, tool is had very great significance.
Patent CN01133266.2 discloses a kind of manufacture method of tin base ceramic pigment, the method mainly substitutes traditional use " tindioxide production tin base ceramic pigment " with metallic tin, its technological process comprises metallic tin melting slag making, mixes operations such as moistening mill, calcining synthesis, burned material fragmentation, rinsing and drying, product is chrome tin pink series ceramic colorant, the method has short flow, with low cost, the features such as non-environmental-pollution.But this ceramic pigment uses under not being adapted at the strong environment of corrodibility.Therefore develop a kind of corrosion resistant colorant, make its ceramic pigment color development bright-coloured, colorant withstand corrosion, is applicable under glazed, and color glaze and over-glaze decoration are very significant.
Summary of the invention
The object of this invention is to provide a kind of corrosion-resistant blue ceramic colorant and preparation method thereof, this ceramic pigment color development is bright-coloured, and this colorant preparation technology is simple in addition, and colorant withstand corrosion, is applicable under glazed, color glaze and over-glaze decoration.
In order to solve the problem, the technical solution adopted in the present invention is:
A kind of corrosion-resistant blue ceramic colorant, be made up of the component of following weight part:
Salt of wormwood 10-60 part, DAP 20-55 part, zirconium white 20-65 part, zinc oxide 10-30 part, aluminum oxide 30-50 part, cobalt oxide 15-45 part.
A kind of corrosion-resistant blue ceramic colorant, be made up of the component of following weight part:
Salt of wormwood 10-50 part, DAP 20-50 part, zirconium white 20-60 part, zinc oxide 10-25 part, aluminum oxide 30-45 part, cobalt oxide 15-40 part.
A kind of corrosion-resistant blue ceramic colorant, be made up of the component of following weight part:
Salt of wormwood 10-45 part, DAP 20-45 part, zirconium white 20-50 part, zinc oxide 10-20 part, aluminum oxide 30-40 part, cobalt oxide 15-30 part.
A kind of corrosion-resistant blue ceramic colorant, be made up of the component of following weight part:
Salt of wormwood 10-35 part, DAP 20-35 part, zirconium white 20-40 part, zinc oxide 10-20 part, aluminum oxide 30-35 part, cobalt oxide 15-25 part.
A kind of corrosion-resistant blue ceramic colorant, be made up of the component of following weight part:
Salt of wormwood 10-25 part, DAP 20-30 part, zirconium white 20-30 part, zinc oxide 10-15 part, aluminum oxide 30-40 part, cobalt oxide 15-20 part.
A preparation method for corrosion-resistant blue ceramic colorant, comprises the steps:
By salt of wormwood, DAP, zirconium white, cobalt oxide mixes, and through 500-1000 DEG C of high-temperature calcination, pulverizes after cooling, crosses 500-800 mesh sieve, wash, pulverize further after washing with ball mill, cross 300-100 mesh sieve, to obtain final product.
The present invention relative to the beneficial effect of prior art is:
Corrosion-resistant blue ceramic colorant of one disclosed by the invention and preparation method thereof, this ceramic pigment color development is bright-coloured, and this colorant preparation technology is simple in addition, colorant withstand corrosion, is applicable under glazed, color glaze and over-glaze decoration, reduce the difficulty of making processes, reduce scrap rate, save cost.
Embodiment
Be described in further details the present invention below by embodiment, these embodiments are only used for the present invention is described, do not limit the scope of the invention.
Embodiment 1
A kind of corrosion-resistant blue ceramic colorant, be made up of the component of following weight part:
15 parts, salt of wormwood, DAP 30 parts, zirconium white 35 parts, 10 parts, zinc oxide, 30 parts, aluminum oxide, cobalt oxide 20 parts;
Its preparation method comprises the steps:
By salt of wormwood, DAP, zirconium white, zinc oxide, aluminum oxide, cobalt oxide mixes, and through 500 DEG C of high-temperature calcinations, pulverizes after cooling, crosses 500 mesh sieves, wash, pulverize further after washing with ball mill, cross 300 mesh sieves, to obtain final product.
Embodiment 2
A kind of corrosion-resistant blue ceramic colorant, be made up of the component of following weight part:
20 parts, salt of wormwood, DAP 30 parts, zirconium white 25 parts, 15 parts, zinc oxide, 35 parts, aluminum oxide, cobalt oxide 25 parts;
Its preparation method comprises the steps:
By salt of wormwood, DAP, zirconium white, zinc oxide, aluminum oxide, cobalt oxide mixes, and through 600 DEG C of high-temperature calcinations, pulverizes after cooling, crosses 600 mesh sieves, wash, pulverize further after washing with ball mill, cross 250 mesh sieves, to obtain final product.
Embodiment 3
A kind of corrosion-resistant blue ceramic colorant, be made up of the component of following weight part:
40 parts, salt of wormwood, DAP 40 parts, zirconium white 50 parts, 20 parts, zinc oxide, 40 parts, aluminum oxide, cobalt oxide 35 parts;
Its preparation method comprises the steps:
By salt of wormwood, DAP, zirconium white, zinc oxide, aluminum oxide, cobalt oxide mixes, and through 700 DEG C of high-temperature calcinations, pulverizes after cooling, crosses 700 mesh sieves, wash, pulverize further after washing with ball mill, cross 200 mesh sieves, to obtain final product.
Embodiment 4
A kind of corrosion-resistant blue ceramic colorant, be made up of the component of following weight part:
50 parts, salt of wormwood, DAP 45 parts, zirconium white 55 parts, 25 parts, zinc oxide, 45 parts, aluminum oxide, cobalt oxide 35 parts;
Its preparation method comprises the steps:
By salt of wormwood, DAP, zirconium white, zinc oxide, aluminum oxide, cobalt oxide mixes, and through 800 DEG C of high-temperature calcinations, pulverizes after cooling, crosses 800 mesh sieves, wash, pulverize further after washing with ball mill, cross 100 mesh sieves, to obtain final product.
Embodiment 5
A kind of corrosion-resistant blue ceramic colorant, be made up of the component of following weight part:
60 parts, salt of wormwood, DAP 55 parts, zirconium white 65 parts, 30 parts, zinc oxide, 50 parts, aluminum oxide, cobalt oxide 45 parts;
Its preparation method comprises the steps:
By salt of wormwood, DAP, zirconium white, zinc oxide, aluminum oxide, cobalt oxide mixes, and through 1000 DEG C of high-temperature calcinations, pulverizes after cooling, crosses 800 mesh sieves, wash, pulverize further after washing with ball mill, cross 100 mesh sieves, to obtain final product.
Claims (6)
1. a corrosion-resistant blue ceramic colorant, is characterized in that: be made up of the component of following weight part:
Salt of wormwood 10-60 part, DAP 20-55 part, zirconium white 20-65 part, zinc oxide 10-30 part, aluminum oxide 30-50 part, cobalt oxide 15-45 part.
2. the corrosion-resistant blue ceramic colorant of one according to claim 1, is characterized in that: be made up of the component of following weight part:
Salt of wormwood 10-50 part, DAP 20-50 part, zirconium white 20-60 part, zinc oxide 10-25 part, aluminum oxide 30-45 part, cobalt oxide 15-40 part.
3. the corrosion-resistant blue ceramic colorant of one according to claim 1, is characterized in that: be made up of the component of following weight part:
Salt of wormwood 10-45 part, DAP 20-45 part, zirconium white 20-50 part, zinc oxide 10-20 part, aluminum oxide 30-40 part, cobalt oxide 15-30 part.
4. the corrosion-resistant blue ceramic colorant of one according to claim 1, is characterized in that: be made up of the component of following weight part:
Salt of wormwood 10-35 part, DAP 20-35 part, zirconium white 20-40 part, zinc oxide 10-20 part, aluminum oxide 30-35 part, cobalt oxide 15-25 part.
5. the corrosion-resistant blue ceramic colorant of one according to claim 1, is characterized in that: be made up of the component of following weight part:
Salt of wormwood 10-25 part, DAP 20-30 part, zirconium white 20-30 part, zinc oxide 10-15 part, aluminum oxide 30-40 part, cobalt oxide 15-20 part.
6. a preparation method for corrosion-resistant blue ceramic colorant, is characterized in that: preparation method is:
By salt of wormwood, DAP, zirconium white, zinc oxide, aluminum oxide, cobalt oxide mixes, and through 500-1000 DEG C of high-temperature calcination, pulverizes after cooling, crosses 500-800 mesh sieve, wash, pulverize further after washing with ball mill, cross 300-100 mesh sieve, to obtain final product.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510826699.1A CN105419393A (en) | 2015-11-25 | 2015-11-25 | Corrosion-resistant blue ceramic pigment and preparation method thereof |
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| CN201510826699.1A CN105419393A (en) | 2015-11-25 | 2015-11-25 | Corrosion-resistant blue ceramic pigment and preparation method thereof |
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| CN105419393A true CN105419393A (en) | 2016-03-23 |
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| CN201510826699.1A Pending CN105419393A (en) | 2015-11-25 | 2015-11-25 | Corrosion-resistant blue ceramic pigment and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110790508A (en) * | 2019-11-15 | 2020-02-14 | 黄山市晶特美新材料有限公司 | Cobalt blue agent for glass slurry and preparation method thereof |
| CN111849204A (en) * | 2020-07-28 | 2020-10-30 | 淄博科睿特新材料科技有限公司 | Chromophoric group cobalt-free blue glass pigment and method |
-
2015
- 2015-11-25 CN CN201510826699.1A patent/CN105419393A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110790508A (en) * | 2019-11-15 | 2020-02-14 | 黄山市晶特美新材料有限公司 | Cobalt blue agent for glass slurry and preparation method thereof |
| CN110790508B (en) * | 2019-11-15 | 2022-03-22 | 黄山市晶特美新材料有限公司 | Cobalt blue agent for glass slurry and preparation method thereof |
| CN111849204A (en) * | 2020-07-28 | 2020-10-30 | 淄博科睿特新材料科技有限公司 | Chromophoric group cobalt-free blue glass pigment and method |
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Application publication date: 20160323 |