CN105415477B - A kind of environment protection type sheet material and its manufacture method for production of having furniture made to order - Google Patents
A kind of environment protection type sheet material and its manufacture method for production of having furniture made to order Download PDFInfo
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/08—Moulding or pressing
- B27N3/10—Moulding of mats
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/08—Moulding or pressing
- B27N3/18—Auxiliary operations, e.g. preheating, humidifying, cutting-off
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Abstract
本发明是一种用于定制家具生产的环保型板材及其制造方法,该环保型板材包括至少三层木质纤维或木质刨花,以及设置于每层木质刨花或木质纤维上下表面之间的经等离子改性处理的热塑性薄膜材料构成的粘结层。以等离子改性处理的热塑性薄膜材料作为胶黏剂,采用分层铺装的方法,利用热压–冷压串联的平压工艺,与改性木质刨花或木质纤维进行复合。优点:环保型板材无甲醛释放、耐水性能优异,改善了热塑性薄膜与木质纤维或木质刨花的相容性,利于熔融后的热塑性薄膜材料在木质纤维或木质刨花表面润湿和渗透,并形成机械性能可靠的胶接结构,提高了板材的力学性能。制造过程没有施胶过程,工艺简单,可广泛用于定制家具生产。
The present invention relates to an environment-friendly board for customized furniture production and a manufacturing method thereof. Adhesive layer made of modified thermoplastic film material. The plasma-modified thermoplastic film material is used as an adhesive, and the method of layered paving is used to compound with modified wood shavings or wood fibers using a flat pressing process in series of hot pressing-cold pressing. Advantages: The environmentally friendly board has no formaldehyde release, excellent water resistance, improves the compatibility of thermoplastic film and wood fiber or wood shavings, and facilitates the wetting and penetration of the melted thermoplastic film material on the surface of wood fiber or wood shavings, and forms a mechanical The reliable bonding structure improves the mechanical properties of the board. There is no gluing process in the manufacturing process, the process is simple, and it can be widely used in the production of customized furniture.
Description
技术领域technical field
本发明涉及的是一种用于定制家具生产的环保型板材及其制造方法。The invention relates to an environment-friendly plate used for custom-made furniture production and a manufacturing method thereof.
背景技术Background technique
定制家具能够打破空间的局限性,具有和空间主体高度的匹配度,能充分提高空间利用率,节省住房面积,并能充分满足不同消费者对家具风格的个性化追求,已经成为了当今社会非常流行的置办家具的方式。Customized furniture can break the limitations of space, has a high degree of matching with the main body of space, can fully improve space utilization, save housing area, and can fully meet the individual pursuit of different consumers for furniture styles. It has become a very important feature in today's society. A popular way to organize your furniture.
目前定制家具生产所用的基材通常采用实木颗粒板(刨花板)和中密度纤维板,这些材料具有重量轻、强度比高、弹性好、耐冲击、纹理色调丰富美观和加工容易等优势,但是实木颗粒板和中密度纤维板生产过程中大部分以液态含醛的合成树脂,如脲醛树脂、三聚氰胺树脂等作为胶黏剂,其产品在制造和使用过程中都会释放出的甲醛,会对人体和环境产生极大的危害。同时,实木颗粒板和中密度纤维板在应用中还存在防水性能和尺寸稳定性不理想等问题,严重限制了定制家具的发展。At present, the substrates used in custom furniture production usually use solid wood particle board (particle board) and medium density fiberboard. These materials have the advantages of light weight, high strength ratio, good elasticity, impact resistance, rich and beautiful texture and tone, and easy processing. Most of the board and medium density fiberboard production process uses liquid aldehyde-containing synthetic resins, such as urea-formaldehyde resins, melamine resins, etc., as adhesives. Great harm. At the same time, there are still problems such as unsatisfactory waterproof performance and dimensional stability in the application of solid wood particle board and medium density fiberboard, which seriously limit the development of customized furniture.
虽然贴面和涂饰可以有效地缓解上述问题,但是在定制家具加工过程中,钻孔加工是必须的工序,这会导致封闭效果减弱,不可避免的释放游离甲醛。另外,在家具使用过程中,封边的脱落也是一个常见的缺陷,它不仅影响美观,而且大大地增加游离甲醛的释放和水分子进入的机会。因此,使用高性能、绿色环保型的胶黏剂是根本性的措施。Although veneering and finishing can effectively alleviate the above problems, drilling is a necessary process in the process of custom furniture processing, which will lead to weakened sealing effect and the inevitable release of free formaldehyde. In addition, during the use of furniture, the peeling off of the edge banding is also a common defect, which not only affects the appearance, but also greatly increases the release of free formaldehyde and the chance of water molecules entering. Therefore, the use of high-performance, green and environmentally friendly adhesives is a fundamental measure.
以薄膜状的热塑性树脂替代常规的木材胶黏剂制备人造板,生产工艺简单,设备投资少、生产效率高,能从根源上解决游离甲醛释放的问题。如公开号为CN 102181239 A的中国发明专利,提出了一种利用无甲醛薄膜胶黏剂制作胶合板和同向积层材的方法,获得了兼具高防水性、断裂伸长率和缺口冲击强度等优点的胶合板和同向积层材。同时,公开号为CN 104308915 A《一种无甲醛胶合板生产工艺》、CN 103144152 A《一种无甲醛胶合板及其制备方法》、CN 104139445 A《无醛胶合室内胶合板或地板基材的制造方法》和CN103934877A《一种零甲醛刨花板及其制造方法》等中国发明专利都在热塑性人造板方面作了探索,但上述方法在木质原料的选择上都有一定的局限性,如薄膜状的热塑性树脂一般只用于与单板类木质原料复合。而与木质刨花或木质纤维胶合时,通常选用粒子或粉末形式的热塑性树脂,不仅增加了混料工序,而且容易出现原料混合不均、胶黏不充分的现象。Using film-like thermoplastic resin instead of conventional wood adhesives to prepare wood-based panels has a simple production process, low equipment investment, and high production efficiency, which can solve the problem of free formaldehyde release from the root. For example, the Chinese invention patent with the publication number CN 102181239 A proposes a method for making plywood and syntropic laminates with formaldehyde-free film adhesives, and obtains high water resistance, elongation at break and notched impact strength. Plywood and laminated wood with other advantages. At the same time, the publication numbers are CN 104308915 A "A Production Process of Formaldehyde-free Plywood", CN 103144152 A "A Formaldehyde-free Plywood and Its Preparation Method", CN 104139445 A "Manufacturing Method of Formaldehyde-Free Glued Indoor Plywood or Floor Substrate" Chinese invention patents such as CN103934877A "a kind of zero-formaldehyde particleboard and its manufacturing method" have been explored in thermoplastic wood-based panels, but the above-mentioned methods have certain limitations in the selection of wood raw materials, such as film-like thermoplastic resins. It is only used for compounding with veneer wood raw materials. When gluing wood shavings or wood fibers, thermoplastic resins in the form of particles or powders are usually used, which not only increases the mixing process, but also tends to cause uneven mixing of raw materials and insufficient adhesion.
与此同时,非极性的热塑性薄膜与极性的木质原料在热力学上是不相容的,这极大地约束了其在更多领域的应用。虽然利用各种方法对木质原料进行预处理,能够提高板材的性能,但由于存在工艺复杂、成本高、能耗高、化学药剂污染等问题难以实现大规模生产。At the same time, non-polar thermoplastic films are thermodynamically incompatible with polar wood materials, which greatly restricts their application in more fields. Although pretreatment of wood raw materials by various methods can improve the performance of the board, it is difficult to achieve large-scale production due to problems such as complex process, high cost, high energy consumption, and chemical pollution.
发明内容Contents of the invention
本发明提出的是一种用于定制家具生产的环保型板材及其制造方法,其目的在于克服现有技术所存在的上述缺陷,具有无甲醛释放,制造工艺简单且易控制,产品耐水性能好、强度高等特点。The present invention proposes an environment-friendly board for customized furniture production and its manufacturing method. Its purpose is to overcome the above-mentioned defects in the prior art. It has no formaldehyde release, simple and easy-to-control manufacturing process, and good water resistance. , high strength and other characteristics.
本发明的技术解决方案:一种用于定制家具生产的环保型板材,其结构是包括至少三层木质纤维或木质刨花,设置于每层木质刨花或木质纤维上下表面之间的经等离子改性处理的热塑性薄膜材料构成的粘结层,所述的刨花板或纤维板中的一种或两种。The technical solution of the present invention: an environment-friendly board for customized furniture production, its structure is to include at least three layers of wood fibers or wood shavings, and the plasma-modified panels are arranged between the upper and lower surfaces of each layer of wood shavings or wood fibers. An adhesive layer of treated thermoplastic film material, one or both of said particleboard or fiberboard.
其制备方法,包括如下步骤:Its preparation method comprises the following steps:
1)将木质纤维或木质刨花干燥至含水率0~15%,再根据目标板材的厚度确定每层木质刨花或木质纤维的用量以及热塑性薄膜的层数;1) Dry the wood fiber or wood shavings to a moisture content of 0-15%, and then determine the amount of each layer of wood shavings or wood fiber and the number of layers of thermoplastic film according to the thickness of the target board;
2)将热塑性薄膜裁切成与目标板材幅面相同的尺寸,并进行等离子处理;2) Cut the thermoplastic film to the same size as the target sheet and perform plasma treatment;
3)分次将步骤1)中干燥后的木质纤维或木质刨花均匀地铺撒在所述的等离子处理的热塑性薄膜材料上面,其中最后一层木质刨花或木质纤维上表面铺设一层等离子处理的热塑性薄膜;3) Evenly spread the dried wood fibers or wood shavings in step 1) on the plasma-treated thermoplastic film material, wherein the last layer of wood shavings or wood fibers is covered with a layer of plasma-treated thermoplastic film. film;
4)将步骤3)中铺装好的物料送入热压机中,在热压工艺条件下进行热压,使每层木质纤维或木质刨花之间等离子处理的热塑性薄膜充分熔融、铺展并渗入木质纤维或木质刨花的多孔性结构中;4) Put the material paved in step 3) into the hot press machine, and perform hot pressing under the hot pressing process conditions, so that the plasma-treated thermoplastic film between each layer of wood fiber or wood shavings is fully melted, spread and infiltrated In the porous structure of wood fibers or wood shavings;
5)将步骤4)中热压后的板材转入冷压机中进行后期定型处理。5) Transfer the hot-pressed plate in step 4) to a cold press for post-setting treatment.
本发明的优点在于:The advantages of the present invention are:
(1)可生产出不含甲醛的环保型实木颗粒板和纤维板,这是最显著的特点;(2)制备的板材具有较高的胶合强度、抗弯性能以及良好的耐水性能,同时由于采用了等离子对热塑性薄膜进行了预处理,增加热塑性薄膜的表面活性,改善了热塑性薄膜与木质纤维或木质刨花之间的界面结合力,大大提高了板材的力学性能。(1) Formaldehyde-free environmentally friendly solid wood particle board and fiberboard can be produced, which is the most notable feature; (2) The prepared board has high bonding strength, bending resistance and good water resistance, and due to the use of The thermoplastic film is pretreated by plasma, the surface activity of the thermoplastic film is increased, the interface bonding force between the thermoplastic film and wood fiber or wood shavings is improved, and the mechanical properties of the board are greatly improved.
附图说明Description of drawings
附图1是用于定制家具生产的环保型板材的结构示意图。Accompanying drawing 1 is the structural representation of the environment-friendly board material that is used for custom-made furniture production.
具体实施方式detailed description
一种用于定制家具生产的环保型板材,其结构包括至少三层木质纤维或木质刨花,以及设置于每层木质刨花或木质纤维上下表面之间的经等离子改性处理的热塑性薄膜材料构成的粘结层,所述的环保型板材为刨花板或纤维板中的一种或两种。An environment-friendly board for custom furniture production, its structure includes at least three layers of wood fiber or wood shavings, and a plasma-modified thermoplastic film material disposed between the upper and lower surfaces of each layer of wood shavings or wood fibers As for the bonding layer, the environment-friendly board is one or both of particleboard and fiberboard.
所述的经等离子改性处理的热塑性薄膜材料的粘结层,采用分层铺装的方法,即利用热压–冷压串联的平压工艺,与改性木质刨花或木质纤维进行复合。The bonding layer of the plasma-modified thermoplastic film material is laminated with modified wood shavings or wood fibers by means of layered paving, that is, using a hot pressing-cold pressing series flat pressing process.
所述木质刨花或木质纤维的含水率控制在0~15%。The moisture content of the wood shavings or wood fibers is controlled at 0-15%.
所述的热塑性薄膜材料为成卷供应的聚乙烯薄膜PE、聚丙烯薄膜PP、聚氯乙烯薄膜PVC中的一种,厚度控制在0.01~0.08 mm。The thermoplastic film material is one of polyethylene film PE, polypropylene film PP and polyvinyl chloride film PVC supplied in rolls, and the thickness is controlled at 0.01-0.08 mm.
所述的热塑性薄膜材料与木质纤维或木质刨花复合前,预先用等离子进行表面预处理。Before the thermoplastic film material is compounded with wood fiber or wood shavings, the surface is pretreated with plasma.
下面结合附图1及实施例,对本发明作进一步详细说明。Below in conjunction with accompanying drawing 1 and embodiment, the present invention will be described in further detail.
实施例1:Example 1:
1)将木质刨花干燥至含水率2%,再将干燥后的木质刨花均分为19份;1) Dry the wood shavings to a moisture content of 2%, and then divide the dried wood shavings into 19 parts;
2)选取厚度为0.02 mm的PE薄膜作为胶黏剂,并将PE薄膜裁切成与目标板材幅面相同的尺寸,同时利用等离子体对PE薄膜表面进行改性处理;2) Select a PE film with a thickness of 0.02 mm as the adhesive, and cut the PE film into the same size as the target board, and use plasma to modify the surface of the PE film;
3)将经等离子改性处理后的PE薄膜与干燥后的木质刨花按照附图1的方式进行组坯,使得每层木质刨花a均匀地铺撒在PE薄膜b上面,同时在最后一层木质刨花a上表面铺设一层等离子处理的PE薄膜;3) The plasma-modified PE film and the dried wood shavings are assembled according to the method shown in Figure 1, so that each layer of wood shavings a is evenly spread on the PE film b, and at the same time, the last layer of wood shavings a layer of plasma-treated PE film is laid on the upper surface;
4)将铺装好的物料送入热压机中,使PE薄膜充分熔融、铺展并渗入木质刨花的多孔性结构中。其中热压温度为150℃,热压压力为1.0 MPa,热压时间为1.0 min·mm-1;4) Send the paved material into the hot press, so that the PE film is fully melted, spread and infiltrated into the porous structure of the wood shavings. The hot-pressing temperature is 150°C, the hot-pressing pressure is 1.0 MPa, and the hot-pressing time is 1.0 min·mm -1 ;
5)将热压后的板材迅速转入冷压机中进行后期定型处理,使已熔融的PE薄膜通过机械锁合作用与木质刨花紧密结合在一起。其中,冷压压力:1 MPa,冷压时间:10 min;5) The hot-pressed board is quickly transferred to the cold press for post-setting treatment, so that the melted PE film is tightly combined with the wood shavings through mechanical locking. Among them, cold pressing pressure: 1 MPa, cold pressing time: 10 min;
6)将刨花板型材依次进行剪切、砂光,制得刨花板成品,并置于自然条件下放置48h,最终得到密度为0.8 g·cm-3的环保型板材。6) The particleboard profiles were cut and sanded in sequence to obtain finished particleboards, which were placed under natural conditions for 48 hours, and finally an environmentally friendly board with a density of 0.8 g·cm -3 was obtained.
实施例2:Example 2:
本实施例与实施例1的区别在于:PE薄膜的厚度为0.04 mm,其余相同。The difference between this embodiment and Embodiment 1 is that the thickness of the PE film is 0.04 mm, and the rest are the same.
实施例3:Example 3:
本实施例与实施例1的区别在于:最终得到板材的密度为1.0 g·cm-3,其余相同。The difference between this embodiment and Embodiment 1 is that the density of the finally obtained board is 1.0 g·cm -3 , and the rest are the same.
实施例4:Example 4:
本实施例与实施例1的区别在于:热塑性薄膜选用PP薄膜,热压温度为190℃,其余相同。The difference between this embodiment and embodiment 1 is that: the thermoplastic film is made of PP film, the hot pressing temperature is 190° C., and the rest are the same.
按照GB/T 17657-2013《人造板及饰面人造板理化性能试验方法》的规定和要求,对上述4个实施例制得的标准试件进行测试,测试结果如表1。总之,采用本发明方法制备的环保型板材无甲醛释放、耐水性好,性能优于普通人造板,是目前普通刨花板及中密度纤维板的良好替代品,可广泛用于定制家具的制造。According to the provisions and requirements of GB/T 17657-2013 "Test Methods for Physical and Chemical Properties of Wood-based Panels and Decorative Wood-based Panels", the standard test pieces prepared in the above four examples were tested, and the test results are shown in Table 1. In a word, the environment-friendly board prepared by the method of the present invention has no formaldehyde release, good water resistance, and better performance than ordinary wood-based boards. It is a good substitute for ordinary particle boards and medium-density fiberboards, and can be widely used in the manufacture of customized furniture.
表1 不同条件下环保型板材的性能Table 1 Performance of environment-friendly panels under different conditions
以上所述是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,凡依本发明申请专利范围所做的均等变化与修饰,皆应属本发明的涵盖范围。The above is a preferred embodiment of the present invention. It should be pointed out that for those of ordinary skill in the art, all equivalent changes and modifications made according to the patent scope of the present invention should fall within the scope of the present invention.
Claims (2)
- A kind of 1. environment protection type sheet material for production of having furniture made to order, it is characterized in that being one kind in particieboard or fiberboard or two Kind, particieboard or fiberboard comprise at least three layers of wood fibre or wood particle, and are arranged at every layer of wood particle or wooden The tack coat that the thermoplastic film material handled through plasma modification between fiber upper and lower surface is formed;The tack coat of the described thermoplastic film material handled through plasma modification, the method mated formation using layering, that is, is utilized The concora crush technique of hot pressing-cold pressing series connection, carried out with modified wood particle or wood fibre compound;The moisture control of the wood particle or wood fibre is 0 ~ 15%;Described thermoplastic film material is polyethylene film PE, polypropylene film PP, the polyvinyl chloride film PVC supplied in rolls In one kind, thickness control is in 0.01 ~ 0.08 mm;Before described thermoplastic film material and wood fibre or wood particle are compound, carry out surface with plasma in advance and locate in advance Reason.
- A kind of 2. preparation method of environment protection type sheet material for production of having furniture made to order as claimed in claim 1, it is characterized in that including such as Lower step:1)By wood fibre or wood particle drying to moisture content 0 ~ 15%, further according to target plate thickness determine every layer it is wooden The number of plies of the dosage and thermoplastic film of wood shavings or wood fibre;2)By thermoplastic film cut into target plate breadth identical size, and carry out plasma treatment;3)By several times by step 1)In dried wood fibre or wood particle equably thermoplasticity of the spreading in plasma treatment Above thin-film material, the thermoplasticity of one layer of plasma treatment of wherein last layer of wood particle or the laying of wood fibre upper surface is thin Film;4)By step 3)In the material that paves be sent into hot press, hot pressing is carried out under hot pressing technique, make every layer it is wooden The thermoplastic film of plasma treatment is fully melted, sprawled and penetrates into wood fibre or wood particle between fiber or wood particle Cellular structure in;5)By step 4)Sheet material after middle hot pressing is transferred to progress later stage heat treatment in cold press;Described hot pressing technique is:Hot pressing temperature is 120 ~ 200 DEG C, and hot pressing pressure is 0.5 ~ 5 MPa, and hot pressing time is 0.5~2 min·mm-1;Described hot pressing pressure is identical with cold pressing pressure, and the cold pressing time is 5 ~ 20 min.
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| CN201510842965.XA CN105415477B (en) | 2015-11-27 | 2015-11-27 | A kind of environment protection type sheet material and its manufacture method for production of having furniture made to order |
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| CN201510842965.XA CN105415477B (en) | 2015-11-27 | 2015-11-27 | A kind of environment protection type sheet material and its manufacture method for production of having furniture made to order |
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| CN105415477B true CN105415477B (en) | 2017-12-08 |
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| CN107030802B (en) * | 2016-12-26 | 2019-07-26 | 中国林业科学研究院木材工业研究所 | Method for improving the bonding performance of decorative veneer and veneer interface by plasma modification |
| CN108312284A (en) * | 2018-01-23 | 2018-07-24 | 柏之意重庆智能家居有限公司 | A kind of environmental protection furniture material production technology |
| CN108501469A (en) * | 2018-06-29 | 2018-09-07 | 南京林业大学 | A kind of mosquito repellent ornament materials and preparation method thereof |
| CN111907144A (en) * | 2020-08-28 | 2020-11-10 | 江苏鹏森环保材料有限公司 | Environment-friendly composite wood furniture board and production method thereof |
| CN113843863A (en) * | 2021-07-28 | 2021-12-28 | 湖州高裕家居科技有限公司 | Artificial wood board for furniture and bedstead using same |
| CN115891351A (en) * | 2022-12-14 | 2023-04-04 | 江山花木匠家居有限公司 | A kind of PVC film facing wooden electromagnetic shielding composite material and preparation method thereof |
| CN119116087B (en) * | 2024-08-01 | 2025-12-26 | 南京林业大学 | Plywood containing modal fibers and its production process |
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| CN105415477A (en) | 2016-03-23 |
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Application publication date: 20160323 Assignee: NANJING DIOU FURNITURE CO.,LTD. Assignor: Nanjing Forestry University Contract record no.: 2019320000144 Denomination of invention: Environment-friendly plate for custom furniture production and manufacturing method of environment-friendly plate Granted publication date: 20171208 License type: Common License Record date: 20190517 Application publication date: 20160323 Assignee: Nanjing Dongfang Weiye Furniture Co.,Ltd. Assignor: Nanjing Forestry University Contract record no.: 2019320000145 Denomination of invention: Environment-friendly plate for custom furniture production and manufacturing method of environment-friendly plate Granted publication date: 20171208 License type: Common License Record date: 20190517 |
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Effective date of registration: 20211228 Address after: 226600 No. 309, Tan Gang Road, Hai'an high tech Industrial Development Zone, Nantong City, Jiangsu Province Patentee after: Jiangsu Zhenlei New Materials Co.,Ltd. Address before: No. 159, jianglongpan Road, Nanjing, Jiangsu 210037 Patentee before: NANJING FORESTRY University |
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Granted publication date: 20171208 |