CN105414547B - Ultra-fine grain list double straight-hole hard alloy pole manufacture method - Google Patents
Ultra-fine grain list double straight-hole hard alloy pole manufacture method Download PDFInfo
- Publication number
- CN105414547B CN105414547B CN201510948865.5A CN201510948865A CN105414547B CN 105414547 B CN105414547 B CN 105414547B CN 201510948865 A CN201510948865 A CN 201510948865A CN 105414547 B CN105414547 B CN 105414547B
- Authority
- CN
- China
- Prior art keywords
- hard alloy
- alloy pole
- double straight
- hole hard
- single double
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/12—Both compacting and sintering
- B22F3/1208—Containers or coating used therefor
- B22F3/1216—Container composition
- B22F3/1233—Organic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/12—Both compacting and sintering
- B22F3/1208—Containers or coating used therefor
- B22F3/1258—Container manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/12—Both compacting and sintering
- B22F3/14—Both compacting and sintering simultaneously
- B22F3/15—Hot isostatic pressing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
- B22F5/10—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of articles with cavities or holes, not otherwise provided for in the preceding subgroups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0881—Titanium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0887—Tungsten
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Powder Metallurgy (AREA)
Abstract
A kind of single double straight-hole hard alloy pole preparation method, uses the dry bag formula isostatic pressed rubber soft mode sizing material based on natural rubber to make single double straight-hole hard alloy pole micro molding mould；Natural or synthetic rubber, zinc oxide, stearic acid and auxiliary addition agent are uniformly kneaded, and single double straight-hole hard alloy pole micropore blank molded rubber soft mode is made in the addition heat conduction hardening agent in mixing, then overall vulcanization；In the single double straight-hole hard alloy pole blank of compacting, pass through the forming temperature of the single double straight-hole hard alloy pole micropore of heat conduction hardening agent increase in molded rubber soft mode, and the hardening infiltration in heat conduction hardening agent is arrived in single double straight-hole hard alloy pole micropore interior surface layers, improve list double straight-hole hard alloy pole micropore inner surface hardness.
Description
Technical field
The present invention relates to a kind of method for preparing powder metallurgy, particularly single double straight-hole hard alloy pole manufacture method.Extensively
It is general to be used to make various production and processing fields：Such as:Make the micro- brills of various whole hard alloy PCB, drill bit, slotting cutter, reamer etc.
Instrument, for processing the products such as aluminium alloy, stainless steel, heat-resisting alloy steel, spheroidal graphite cast-iron, Ni-based and titanium alloy, non-ferrous metal；With
And make variously-shaped plug-in unit, silicon steel sheet and cold-reduced sheet, stainless steel drift, thimble, red needle etc..Belong to powder metallurgically manufacturing technology
Field.
Background technology：
In modern industry and the high speed development of technology, the application of hard alloy is more and more wider, but is closed using hard
Golden department is such as machined, performance of the electronics and information industry also to hard alloy proposes newest high request.Such as electricity
Sub-information industry it is highly integrated, electronic component miniaturization , Chu Now need the hard high-strength of processing PCB plate, and diameter is small to be reached
0.2mm micro- brill；And the novel aluminum alloy and composite of aerospace industry, it is desirable to high rigidity Precision hole dill has, and is permitted
Many special materials require high abrasion cutting tip, with up to its machining accuracy.Exactly under these new situations, soap-free emulsion polymeization has been promoted
The development of phase, low Binder Phase nano hard alloy.Especially, in terms of machining Xin Jin Chu Now single double straight-hole pole hard
Alloy makes various sintered-carbide tools, using single double straight-hole hard alloy pole tools there is center to carry micropore, just
Cooling or lubrication in being processed, can so greatly improve the service life of instrument, improve operating efficiency.But will be
It is very very difficult that micropore, especially diplopore are processed in hard alloy, and existing single double straight-hole pole hard alloy pole is general
Store-through is inconsistent in inside and outside quality, the deficiency of consistent influence overall performance.Such as add the sandpipe of sand water knife, to hard alloy
Propose rigors, plus sand water knife is to add tiny seed of pomegranate sand grains in water（Microhardness 1438HV.Proportion 3.98.Grain
Spend 60,80,100,120 mesh）, water under high pressure and sand are made the sand grains of high-speed jet by sandpipe, machined material carried out powerful
Abrasion.When sand water thread diameter is from 0.5 to 1.27mm, water pressure is about 300MPa~500MPa, and water sand mixed flow speed about 800~
1000 meter per seconds.Plus sand water knife is unique a kind of cold conditions high energy beam machining technology on our times.Stone material can be cut
Material, in the case where region heating need not be carried out to the thick metal for reaching 200mm（Such as inconel, titanium, tool steel）, Hua Gang
The various building stones such as rock, monocrystalline silicon, modern age height hard and tough composite, glass, ceramics or elastic caoutchouc etc. carry out cutting and added
Work.Such as auto industry, aircraft industry, building stones and tile industry, instrument and Making mold industry are all applied.But it is existing
Generally existing sandpipe inner surface hardness does not reach preferable state when some sandpipes are made using single double straight-hole hard alloy pole,
Under the impact of tiny seed of pomegranate sand grains, it is easy to wear and tear, so that the performance of influence sandpipe, necessary to this
Improved.
Do not have discovery to have the patent literature constructed with the present invention by patent retrieval, related to the present invention is main
Have following：
1st, Patent No. CN201410600566.8, entitled " a kind of hard alloy circular bar vacuum-sintering is anti-bending
Method " patent of invention, which disclose a kind of anti-bending method of hard alloy circular bar vacuum-sintering, its technique
Step includes：A, extruder are compressing；B, karbate impervious graphite boat load blank are to be spontaneously dried；C, blank are cut；d、
Blank is put into progress degumming pre-burning in degumming stove with degumming pre-burning graphite boat；E, blank machining；F, in graphite cover plate
Cover plate V-shaped groove surface, graphite bottom plate bottom plate V-shaped groove surface coating release coating；G, release coating are spontaneously dried；H, sintering
Graphite boat load blank is loaded, blank is fastened between bottom plate V-shaped groove and cover plate V-shaped groove；I, by blank with sintering load stone
Black boat is put into vacuum sintering furnace, is vacuumized after closing fire door；J, blank vacuum-sintering；K, cool to room temperature with the furnace, circle
Prepared by shape bar completes.
2nd, Patent No. CN201520357841, the hair of entitled " a kind of optimization mould for making hard alloy pole "
Bright patent, which disclose a kind of optimization mould for making hard alloy pole, it includes：Left mould tool, intermediate mold, right mould
Tool；The arc groove that described left mould tool, intermediate mold, right mould tool are provided with arc groove, three pieces of moulds constitute one it is complete
Circular hole, the pole circularity produced by the mould is high, than original pole made, and reduces by one of polishing operation,
Open reduction processing cost, improve the effect for the rate that comes into force.
3rd, Patent No. CN200410045029, the patent of invention of entitled " ultrafine crystal grain hard alloy material ", this is special
Profit discloses a kind of Hardmetal materials, particularly a kind of ultrafine crystal grain hard alloy material.Ultrafine crystal grain hard alloy material
It is made up of WC, metallic cobalt Co, carbide vanadium vc and chromium carbide Cr3C2 that ultra-fine grain tungsten carbide is 0.5 μm, between its each component
Percentage by weight is：WC: Co: VC: Cr3C2 is equal to 90~92.5: 7~9: 0.1~0.5: 0.3~0.7.The material had both had very
High hardness and anti-wear performance, while having very high intensity and toughness again.
Though these above-mentioned patents have been directed to hard alloy pole, single double straight-hole hard alloy circle is all not directed to
Rod, though Patent No. CN200410045029, the patent of invention of entitled " ultrafine crystal grain hard alloy material " is related to one
Kind of ultrafine crystal grain hard alloy material, but it is consistent to solve single double straight-hole hard alloy pole micropore surfaces externally and internally hardness
Problem, therefore it is still necessary to improved.
The content of the invention
The purpose of the present invention is exactly, according to the problems of single double straight-hole hard alloy pole at present, to propose that one kind can change
Kind list double straight-hole hard alloy pole bore area quality so that outside single double straight-hole hard alloy pole micropore inner surface and pole
The consistent single double straight-hole hard alloy pole preparation method of surface property and product.
According to foregoing invention purpose, technical scheme proposed by the invention is：A kind of single double straight-hole hard alloy pole system
Make method, use the dry bag formula isostatic pressed rubber soft mode sizing material based on natural rubber to make single double straight-hole hard alloy pole
Micro molding mould；Natural or synthetic rubber, zinc oxide, stearic acid and auxiliary addition agent are uniformly kneaded, and added in mixing
Single double straight-hole hard alloy pole micropore blank molded rubber soft mode is made in heat conduction hardening agent, then overall vulcanization；In compacting Dan Shuan
During straight hole hard alloy pole blank, single double straight-hole hard alloy pole is increased by the heat conduction hardening agent in molded rubber soft mode
The forming temperature of micropore, and cause hardening infiltration in heat conduction hardening agent to table in list double straight-hole hard alloy pole micropore
In surface layer, single double straight-hole hard alloy pole micropore inner surface hardness is improved.
Further, described heat conduction hardening agent be the metal fine powder with heat conduction hardening performance, including tungsten micro mist,
Metal zirconium micro mist or Titanium micro mist.
Further, described metal fine powder is micro mist of the granularity at 0.2-0.4 μm, and micro mist purity is in 97-99%.
Further, described metal fine powder is in the 2- that percentage by weight shared by molded rubber soft mode is overall material weight
5%, metal fine powder is added when material is mixed, and is stirred.
Further, the weight deal proportioning of described molded rubber soft mode each component is as follows：
Natural or synthetic rubber 45-80 parts
4-5 parts of zinc oxide
1-3 parts of stearic acid
23-35 parts of auxiliary addition agent
2-5 parts of heat conduction hardening agent；
Further, described auxiliary addition agent includes age resistor, reinforcing agent, plasticizer, vulcanizing agent and accelerator, according to property
It can need freely to assemble.
Further, described hard alloy pole blank technology flow is：
By purposes requirement formula → powder processed → making molded rubber soft mode → compacting → shaping → low pressure sintering → shaping hair
Product is made in base → peripheral milling is refined →.
The advantage of the invention is that：The present invention uses molded rubber soft mode when making single double straight-hole hard alloy pole,
And heat conduction hardening agent is with the addition of in dispensing, the increased single double straight-hole hard of heat conduction hardening agent can be passed through when compressing
The forming temperature of alloy pole micropore inner surface, and in forming process, superhard material is attached to list by way of infiltration
Double straight-hole hard alloy pole micropore inner surface, further enhances the hardness of bore area, can be improved after forming by a firing makes
3-4 times, remote ultra-traditional list double straight-hole hard alloy pole service life are may be up to the life-span.
Embodiment
Below in conjunction with embodiment, the present invention will be further described.
Embodiment one
A kind of single double straight-hole hard alloy pole preparation method, described hard alloy pole blank technology flow is：
By purposes requirement formula → powder processed → making molded rubber soft mode → compacting → shaping → low pressure sintering → shaping hair
Product is made in base → peripheral milling is refined →.Wherein, make molded rubber soft mode when based on natural rubber, add oxidation
Rubber soft mode is made by mixing in zinc, stearic acid, auxiliary addition agent, and adds heat conduction hardening agent in mixing；The weight of its formula material
Part includes：
| Natural rubber | 45 parts |
| Zinc oxide | 4 parts |
| Stearic acid | 1 part |
| Auxiliary addition agent | 23 parts |
| Heat conduction hardening agent | 2 parts |
Described auxiliary addition agent includes age resistor, reinforcing agent, plasticizer, vulcanizing agent and accelerator, according to conventional any group
Match somebody with somebody.Described heat conduction hardening agent is tungsten micro mist.Micro mist of the tungsten micro powder granule degree at 0.2-0.4 μm, micro mist purity exists
97-99%。
Embodiment two
A kind of single double straight-hole hard alloy pole preparation method, described hard alloy pole blank technology flow is：
By purposes requirement formula → powder processed → making molded rubber soft mode → compacting → shaping → low pressure sintering → shaping hair
Product is made in base → peripheral milling is refined →.Wherein, make molded rubber soft mode when based on butadiene-styrene rubber, add oxidation
Rubber soft mode is made by mixing in zinc, stearic acid, auxiliary addition agent, and adds heat conduction hardening agent in mixing；The weight of its formula material
Part includes：
| Butadiene-styrene rubber | 80 parts |
| Zinc oxide | 5 parts |
| Stearic acid | 3 parts |
| Auxiliary addition agent | 35 parts |
| Heat conduction hardening agent | 5 parts |
Described auxiliary addition agent includes age resistor, reinforcing agent, plasticizer, vulcanizing agent and accelerator, according to conventional any group
Match somebody with somebody.Described heat conduction hardening agent is metal zirconium micro mist.Micro mist of the metal zirconium micro powder granule degree at 0.2-0.4 μm, micro mist purity exists
97-99%。
Embodiment three
A kind of single double straight-hole hard alloy pole preparation method, described hard alloy pole blank technology flow is：
By purposes requirement formula → powder processed → making molded rubber soft mode → compacting → shaping → low pressure sintering → shaping hair
Product is made in base → peripheral milling is refined →.Wherein, make molded rubber soft mode when based on butadiene rubber, add oxidation
Rubber soft mode is made by mixing in zinc, stearic acid, auxiliary addition agent, and adds heat conduction hardening agent in mixing；The weight of its formula material
Part includes：
| Butadiene rubber | 65 parts |
| Zinc oxide | 4 parts |
| Stearic acid | 2 parts |
| Auxiliary addition agent | 33 parts |
| Heat conduction hardening agent | 3 parts |
Described auxiliary addition agent includes age resistor, reinforcing agent, plasticizer, vulcanizing agent and accelerator, according to conventional any group
Match somebody with somebody.Described heat conduction hardening agent is Titanium micro mist, and micro mist of the Titanium micro powder granule degree at 0.2-0.4 μm, micro mist purity exists
97-99%。。
It is as follows by the rubber soft mode physical property obtained by sulfidization molding according to above-mentioned formula：
| Project | Test recipe 1 | Test recipe 2 | Test recipe 3 |
| Hardness, shore A | 79 | 78 | 78 |
| 100% stretches surely, MPa | 6 | 6 | 6 |
| 200% stretches surely, MPa | 12 | 12 | 13 |
| 300% stretches surely, MPa | 14 | 14 | 14 |
| Elongation, % | 318 | 322 | 292 |
| Tensile strength, MPa | 19 | 18 | 17 |
| Tearing strength, KN/m | 55 | 45 | 45 |
| Have no progeny deformation, % | 13 | 12 | 12 |
| Compression set, % | 22 | 23 | 21 |
It can be seen from above-described embodiment that the present invention relates to a kind of preparation method of single double straight-hole hard alloy pole,
Described hard alloy pole blank technology flow is：By purposes requirement formula → powder processed → making molded rubber soft mode → pressure
Product is made in system → shaping → low pressure sintering → molded blank → peripheral milling is refined →.Wherein, make molded rubber soft mode when with
Butadiene rubber for main body, add zinc oxide, stearic acid, auxiliary addition agent rubber soft mode be made by mixing, and add and lead in mixing
Hot hardening agent；The surface quality of single double straight-hole hard alloy pole endoporus can so be greatly improved.
Above example is simply to illustrate that the present invention, some cited more preferably embodiments, this area skill
The usual variations and alternatives that art personnel are carried out in the range of the technical program should be comprising within the scope of the present invention.
The advantage of the invention is that：The present invention uses molded rubber soft mode when making single double straight-hole hard alloy pole,
And heat conduction hardening agent is with the addition of in dispensing, the increased single double straight-hole hard of heat conduction hardening agent can be passed through when compressing
The forming temperature of alloy pole micropore inner surface, and in forming process, superhard material is attached to list by way of infiltration
Double straight-hole hard alloy pole micropore inner surface, further enhances the hardness of bore area, can be improved after forming by a firing makes
3-4 times, remote ultra-traditional list double straight-hole hard alloy pole service life are may be up to the life-span.
Claims (6)
1. a kind of single double straight-hole hard alloy pole preparation method, uses the dry bag formula isostatic pressed rubber based on natural rubber
Soft mode sizing material makes single double straight-hole hard alloy pole micro molding mould；By natural or synthetic rubber, zinc oxide, stearic acid and
Auxiliary addition agent is uniformly kneaded, and single double straight-hole hard alloy pole is made in the addition heat conduction hardening agent in mixing, then overall vulcanization
Micropore blank molded rubber soft mode；In the single double straight-hole hard alloy pole blank of compacting, pass through leading in molded rubber soft mode
The forming temperature of the hot single double straight-hole hard alloy pole micropore of hardening agent increase, and the hardening material in heat conduction hardening agent is oozed
Arrive thoroughly in single double straight-hole hard alloy pole micropore interior surface layers, improve single double straight-hole hard alloy pole micropore inner surface hard
Degree；Described heat conduction hardening agent is the metal fine powder with heat conduction hardening performance, including tungsten micro mist, metal zirconium micro mist or gold
Belong to titanium micro mist.
2. list double straight-hole hard alloy pole preparation method as claimed in claim 1, it is characterised in that：Described metal fine powder
Micro mist for granularity at 0.2-0.4 μm, micro mist purity is in 97-99%.
3. list double straight-hole hard alloy pole preparation method as claimed in claim 2, it is characterised in that：Described metal fine powder
In the 2-5% that percentage by weight shared by molded rubber soft mode is overall material weight, metal fine powder is added when material is mixed, stirred
Mix uniform.
4. list double straight-hole hard alloy pole preparation method as claimed in claim 3, it is characterised in that：Described molded rubber
The weight deal proportioning of soft mode each component is as follows：
Natural or synthetic rubber 45-80 parts
4-5 parts of zinc oxide
1-3 parts of stearic acid
23-35 parts of auxiliary addition agent
2-5 parts of heat conduction hardening agent.
5. list double straight-hole hard alloy pole preparation method as claimed in claim 4, it is characterised in that：Described auxiliary addition agent
Including age resistor, reinforcing agent, plasticizer, vulcanizing agent and accelerator, need freely to assemble according to performance.
6. list double straight-hole hard alloy pole preparation method as claimed in claim 5, it is characterised in that：Described hard alloy
Pole blank technology flow is：
By purposes requirement formula → powder processed → making molded rubber soft mode → compacting → shaping → low pressure sintering → molded blank
→ peripheral milling refines → product is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510948865.5A CN105414547B (en) | 2015-12-18 | 2015-12-18 | Ultra-fine grain list double straight-hole hard alloy pole manufacture method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510948865.5A CN105414547B (en) | 2015-12-18 | 2015-12-18 | Ultra-fine grain list double straight-hole hard alloy pole manufacture method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105414547A CN105414547A (en) | 2016-03-23 |
| CN105414547B true CN105414547B (en) | 2017-08-25 |
Family
ID=55493328
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510948865.5A Active CN105414547B (en) | 2015-12-18 | 2015-12-18 | Ultra-fine grain list double straight-hole hard alloy pole manufacture method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105414547B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107052348A (en) * | 2017-04-11 | 2017-08-18 | 济南市冶金科学研究所有限责任公司 | A kind of manufacture method of inner-cooled hard alloy knife bar of the two ends with counterbore |
| CN107433329A (en) * | 2017-07-25 | 2017-12-05 | 厦门曦华新材料科技有限公司 | Carbide twist drill bit straight forming method |
| CN110449589A (en) * | 2019-09-05 | 2019-11-15 | 蓬莱市超硬复合材料有限公司 | Cold threaded hole bar forming method in one kind |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09296241A (en) * | 1996-04-08 | 1997-11-18 | Daido Steel Co Ltd | Sleeve for magnesium die casting cylinder, its production and magnesium die casting cylinder |
| CN102398031B (en) * | 2011-10-22 | 2013-10-30 | 四川科力特硬质合金股份有限公司 | Hard alloy product pressing die with major spiral on inner circle and shaping method |
| CN102392222B (en) * | 2011-11-01 | 2013-04-17 | 洛阳高新四丰电子材料有限公司 | Method for producing large high-purity molybdenum planar target material for flat panel displays |
| CN102717507B (en) * | 2012-06-21 | 2015-02-25 | 浙江华业塑料机械有限公司 | Metal cylinder and manufacturing method thereof |
| CN104844851B (en) * | 2015-05-14 | 2017-12-08 | 中国化工株洲橡胶研究设计院有限公司 | Make the sizing material and manufacturing method of soft mould of hard alloy blank soft mode |
-
2015
- 2015-12-18 CN CN201510948865.5A patent/CN105414547B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN105414547A (en) | 2016-03-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5427380B2 (en) | Carbide composite material and manufacturing method thereof | |
| CN103789596B (en) | A kind of polycrystalline CBN cutting tool material and preparation method thereof | |
| US11247268B2 (en) | Methods of making metal matrix composite and alloy articles | |
| JP5594441B2 (en) | Composite roll and rolling method | |
| CN105414547B (en) | Ultra-fine grain list double straight-hole hard alloy pole manufacture method | |
| CN105088044B (en) | A kind of preparation method of the mutually superhard level hard metal article of nanometer of soap-free emulsion polymeization | |
| JP6281959B2 (en) | Low carbon steel and cemented carbide wear parts | |
| CN104711441A (en) | Particulate strengthened alloy articles and methods of forming | |
| CN103233224A (en) | Method for preparing high-chromium wear-resistant alloy through laser cladding | |
| CN100419106C (en) | Carbide alloy, carbide bit and manufacturing method thereof | |
| CA3080463A1 (en) | Composite claddings and applications thereof | |
| CN103586457B (en) | A kind of Powder metallurgy tool | |
| Raj et al. | Influence of drill geometry on surface roughness in drilling of Al/SiC/Gr hybrid metal matrix composite | |
| Shankar et al. | Influence of WC and cobalt additions on the microstructural and mechanical properties of TiCN-Cr3C2-nano-TiB2 cermets fabricated by spark plasma sintering | |
| Gao et al. | Effects of WC grain size and Co content on microscale wear behavior of micro end mills in aluminum alloy 7075 machining | |
| CN106625198B (en) | Compound superhard honing stone containing zirconium oxide and preparation method thereof | |
| CN106378239B (en) | A kind of preparation method of the ball grinding machine lining board with the wear-resisting grid of diamond shape | |
| CN105861905B (en) | A kind of titanium carbide base hard alloy of modified by nano particles and preparation method thereof | |
| CN103602887B (en) | A kind of Powder metallurgy bit matrix and preparation method thereof | |
| CN104126021A (en) | Silicon eutectic alloy composition and method of making by rotational casting | |
| JP2005213599A (en) | TiCN-BASED CERMET AND ITS MANUFACTURING METHOD | |
| CN103589930B (en) | Powder metallurgy tool of a kind of stainless steel bonding and preparation method thereof | |
| CN112877578A (en) | Ultra-fine grain hard alloy and preparation method thereof | |
| CN105604490A (en) | High-temperature diamond-impregnated drill bit matrix and manufacturing method of drill bit | |
| Das et al. | An experimental investigation on the machinability of powder formed silicon carbide particle reinforced aluminium metal matrix composites |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20170717 Address after: 412000 No. 471 Jin Shan Road, Jinshan Science and Technology Industrial Park, lotus pond area, Hunan, Zhuzhou Applicant after: ZHUZHOU MEETYOU CEMENTED CARBIDE Co.,Ltd. Address before: 412000 No. 471 Jin Shan Road, Jinshan Industrial Park, lotus pond area, Hunan, Zhuzhou Applicant before: Yang Kangning |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Manufacturing method of ultrafine grain single-double straight hole hard alloy round rod Effective date of registration: 20180801 Granted publication date: 20170825 Pledgee: Bank of China Limited by Share Ltd. Zhuzhou East Branch Pledgor: ZHUZHOU MEETYOU CEMENTED CARBIDE Co.,Ltd. Registration number: 2018980000093 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20220725 Granted publication date: 20170825 Pledgee: Bank of China Limited by Share Ltd. Zhuzhou East Branch Pledgor: ZHUZHOU MEETYOU CEMENTED CARBIDE Co.,Ltd. Registration number: 2018980000093 |