CN104844851B - Make the sizing material and manufacturing method of soft mould of hard alloy blank soft mode - Google Patents
Make the sizing material and manufacturing method of soft mould of hard alloy blank soft mode Download PDFInfo
- Publication number
- CN104844851B CN104844851B CN201510244953.7A CN201510244953A CN104844851B CN 104844851 B CN104844851 B CN 104844851B CN 201510244953 A CN201510244953 A CN 201510244953A CN 104844851 B CN104844851 B CN 104844851B
- Authority
- CN
- China
- Prior art keywords
- parts
- rubber
- butadiene
- soft mode
- zinc oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000956 alloy Substances 0.000 title claims abstract description 36
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 35
- 239000000463 material Substances 0.000 title claims abstract description 27
- 238000004513 sizing Methods 0.000 title claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 title description 13
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 50
- 229920001971 elastomer Polymers 0.000 claims abstract description 43
- 239000005060 rubber Substances 0.000 claims abstract description 43
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 37
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 37
- 229920001194 natural rubber Polymers 0.000 claims abstract description 37
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 27
- 239000011787 zinc oxide Substances 0.000 claims abstract description 25
- 239000005062 Polybutadiene Substances 0.000 claims abstract description 24
- 229920002857 polybutadiene Polymers 0.000 claims abstract description 24
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims abstract description 22
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 19
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 19
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000008117 stearic acid Substances 0.000 claims abstract description 19
- 238000004073 vulcanization Methods 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims description 15
- 238000007493 shaping process Methods 0.000 claims description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 10
- 239000005864 Sulphur Substances 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 9
- 239000003963 antioxidant agent Substances 0.000 claims description 7
- 230000003078 antioxidant effect Effects 0.000 claims description 7
- 239000006229 carbon black Substances 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- OUBMGJOQLXMSNT-UHFFFAOYSA-N N-isopropyl-N'-phenyl-p-phenylenediamine Chemical compound C1=CC(NC(C)C)=CC=C1NC1=CC=CC=C1 OUBMGJOQLXMSNT-UHFFFAOYSA-N 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- 239000004200 microcrystalline wax Substances 0.000 claims description 5
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 claims description 4
- 230000000704 physical effect Effects 0.000 claims description 3
- 239000004014 plasticizer Substances 0.000 abstract description 8
- 239000012744 reinforcing agent Substances 0.000 abstract description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 229920002635 polyurethane Polymers 0.000 description 6
- 239000004814 polyurethane Substances 0.000 description 6
- 229920000915 polyvinyl chloride Polymers 0.000 description 6
- 239000004800 polyvinyl chloride Substances 0.000 description 6
- 239000010410 layer Substances 0.000 description 5
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000005018 casein Substances 0.000 description 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 2
- 235000021240 caseins Nutrition 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000013047 polymeric layer Substances 0.000 description 2
- 235000011118 potassium hydroxide Nutrition 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920001596 poly (chlorostyrenes) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920003225 polyurethane elastomer Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- 238000010074 rubber mixing Methods 0.000 description 1
- 238000010092 rubber production Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of sizing material for making hard alloy blank soft mode, for the dry bag formula isostatic pressed rubber soft mode sizing material based on natural rubber；Component and parts by weight proportioning are as follows：55 100 parts of natural rubber, 0 45 parts of butadiene-styrene rubber, 0 45 parts of butadiene rubber, 35 parts of zinc oxide, 13 parts of stearic acid, 53 130 parts of auxiliary addition agent；Described auxiliary addition agent includes age resistor, reinforcing agent, plasticizer, vulcanizing agent and accelerator；Zinc oxide, stearic acid and auxiliary addition agent are added after natural rubber and two kinds of sizing materials of butadiene-styrene rubber or butadiene rubber are uniformly kneaded, then hard alloy blank rubber soft mode is made in overall vulcanization.
Description
Technical field
The present invention relates to a kind of rubber soft mode sizing material and preparation method thereof, refers in particular to a kind of pressure of hard alloy blank
The preparation method of system and molded rubber soft mode sizing material and its rubber soft mode, it is mainly used in making hard alloy compacting rubber soft mode,
Belong to rubber soft mode field of material technology.
Background technology：
Hard alloy be by refractory metal hard compounds and binding metal by powder metallurgical technique made of it is a kind of
Alloy material, there are a series of premium properties such as hardness is high, wear-resisting, intensity and toughness are preferable, heat-resisting, corrosion-resistant, now extensively
As various high-abrasive materials.Its production process be generally the producing of powder, the mixing of powder, the compacting of blank and shaping, sintering,
Post processing, the compacting of wherein blank are one of key links of hard alloy manufacture.When making blank, typically now all adopt
Produced with dry bag formula isostatic pressed rubber soft mode.Because mould must possess certain tensile strength and tearing strength, while not
Physics chemical action can occur with medium, be not easy to adhere to pressed compact, so dry bag formula isostatic tooling is typically from polyurethane, polychlorostyrene
Matrix material of the vinyl material as mould.
Polyurethane rubber mould is using relatively broad, but because the processing characteristics of polyurethane, its shrinkage factor can be with productions
Slightly changing for technique and have larger fluctuation, and it is influenceed, tensile strength during long-term storage by moisture in air
It can be declined to a great extent Deng key performance, have a strong impact on the quality of product.Polyvinyl chloride mould is due to its matrix material polyvinyl chloride
The material property of itself, mould elasticity is general poor, and the product appearance after shaping is poor, and size is irregular, and processing capacity is big, serious shadow
Ring the benefit to enterprise.Simultaneously because cemented carbide powder cost is higher, the defects of rubber mold quality, can be caused not toward contact
Appreciable loss.It is necessary that this is improved.
By patent retrieval and do not find there be the patent literature constructed with the present invention, related to the present invention is main
Have following：
1st, Patent No. CN99114708, the patent of invention of entitled " preparation method of soft mould of natural rubber ", the patent
Disclose a kind of preparation method of soft mould of natural rubber, it be by natural rubber and altax, Vulcanization accelerator TMTD, zinc oxide,
After the complete mixing of antioxidant A W, sulphur, casein, ammoniacal liquor, potassium hydroxide and distilled water stirs, equably smear or be sprayed on
On duplicate, removed after dry.Soft mode, which is made, with the present invention had both had technique simple, low manufacture cost and elasticity good etc. excellent
Point, there is stretch-proof, tear-proof, abrasion performance, warping strength and endurance again, service life is grown, at normal temperatures can
Made, the soft mode especially suitable for the glass fiber reinforced plastics product of tack extra-heavy makes.
2nd, Patent No. CN200510132686, the patent of invention of entitled " method of manufacture soft mode ", the patent disclose
A kind of method for manufacturing soft mode, wherein the size regardless of the master mold for forming soft mode, process matching degree are all very high.
Method for manufacturing soft mode includes：Master mold is placed on fixture；Pre-polymer layer is formed in the fixture；Backplane substrate is attached
In the pre-polymer layer；Optionally solidify the pre-polymer layer to be formed selectively polymeric layer；From the fixture
The polymeric layer and the pre-polymer layer are peeled off with the master mold；And remove uncured pre-polymer layer.
3rd, Patent No. CN200710104859, the patent of invention of entitled " soft mold and its manufacture method ", the patent
Disclose a kind of soft mold and its manufacture method.The soft mold includes：Photocurable materials；And light trigger, wherein, it is described soft
Mould meets formula, wherein, γ dM are the scattered items of the surface energy of the soft mold, and γ pM are the surface energies of the soft mold
Polarity item, and γ L are the surface energies of deionized water.
Though these above-mentioned patents have been directed to the manufacture method of some soft molds, wherein having also related to some materials
Improvement, especially first patent（CN99114708）Propose a kind of method and glue that soft mode is prepared using natural rubber
Material, but this method proposed it is simply a kind of by natural rubber and altax, Vulcanization accelerator TMTD, zinc oxide, antioxidant A W,
After the complete mixing of sulphur, casein, ammoniacal liquor, potassium hydroxide and distilled water stirs, equably smear or be sprayed on duplicate,
Removed after dry straightforward procedure, this method is not adapt to make hard alloy soft jelly mould, the material proposed
Also it is not suitable with and makes hard alloy, therefore it is still necessary to is improved.
The content of the invention
The purpose of the present invention is exactly to suppress the problems of soft mode according to current hard alloy blank, proposes that one kind can fit
The rubber soft mode sizing material and its rubber manufacturing method of soft mould for answering hard alloy blank to suppress and be molded.
According to foregoing invention purpose, technical scheme proposed by the invention is：A kind of hard alloy blank soft mode of making
Sizing material, for the dry bag formula isostatic pressed rubber soft mode sizing material based on natural rubber；Component and parts by weight proportioning are as follows：
Natural rubber 55-100 parts
Butadiene-styrene rubber 0-45 parts
Butadiene rubber 0-45 parts
Zinc oxide 3-5 parts
Stearic acid 1-3 parts
Auxiliary addition agent 53-130 parts；
Natural rubber and butadiene-styrene rubber or butadiene rubber are uniformly kneaded with zinc oxide, stearic acid and auxiliary addition agent, then it is whole
Hard alloy blank rubber soft mode is made in body vulcanization.
Further, described zinc oxide includes 20-30% activated zinc oxide, using activated zinc oxide and zinc oxide
It is used in combination, further improves the physical property of sizing material.
Further, described auxiliary addition agent includes age resistor, reinforcing agent, plasticizer, vulcanizing agent and accelerator, each component
Weight deal proportioning it is as follows：
Age resistor 1-4 parts
Reinforcing agent 50-100 parts
Plasticizer 0-20 parts
Vulcanizing agent 1-3 parts
Accelerator 1-3 parts.
Described age resistor, reinforcing agent, plasticizer, vulcanizing agent and accelerator is the age resistor commonly used in rubber production, mended
Strong agent, plasticizer, vulcanizing agent and accelerator.
Further, rubber soft mode sizing material component and the parts by weight proportioning of the compacting of described hard alloy blank and shaping
It is as follows：
80 parts of natural rubber
20 parts of butadiene-styrene rubber
Sulphur is 2 parts of vulcanizing agent
1.2 parts of accelerator
5 parts of zinc oxide
1.5 parts of stearic acid
4 parts of age resistor
60 parts of carbon black.
Further, rubber soft mode sizing material component and the parts by weight proportioning of the compacting of described hard alloy blank and shaping
It is as follows：
80 parts of natural rubber
20 parts of butadiene rubber
5 parts of zinc oxide
1.5 parts of stearic acid
1 part of antioxidant D
1.5 parts of antioxidant 4010NA
1.5 parts of microwax
55 parts of high wear-resistant carbon black
15 parts of semi-reinforcing hydrocarbon black
2 parts of tackifier RH
1.2 parts of accelerant CZ
2 parts of sulphur.
A kind of preparation method for the rubber soft mode for realizing the compacting of above-mentioned hard alloy blank and shaping, using natural rubber with
Butadiene-styrene rubber or butadiene rubber are kneaded, and accordingly adjust formula system, and the compacting of hard alloy blank and shaping are made after vulcanization
Rubber soft mode.
Further, described use natural rubber and butadiene-styrene rubber or butadiene rubber and zinc oxide, stearic acid and auxiliary
Auxiliary agent is uniformly kneaded, then hard alloy blank rubber soft mode is made in overall vulcanization.
Further, the preparation method of described rubber soft mode is as follows：
1）Choose dispensing：
Natural rubber 55-100 parts
Butadiene-styrene rubber 0-45 parts
Butadiene rubber 0-45 parts
Zinc oxide 3-5 parts
Stearic acid 1-3 parts
Auxiliary addition agent 53-130 parts
Age resistor 1-4 parts
Reinforcing agent 50-100 parts
Plasticizer 0-20 parts
Vulcanizing agent 1-3 parts
Accelerator 1-3 parts
2）Natural rubber and butadiene-styrene rubber or butadiene rubber are added into zinc oxide, stearic acid and auxiliary addition agent in banbury
And it is kneaded uniform, addition accelerator and vulcanizing agent in mill.
3）The rubber soft mode of the compacting of hard alloy blank and shaping is made in vulcanization.
The advantage of the invention is that：The present invention is using natural rubber and with a small amount of butadiene-styrene rubber or butadiene rubber, and phase
Formula system should be adjusted, it is the standby isostatic pressed soft mode poor dimensional stability of main system, use that can solve with polyurethane, polyvinyl chloride
The deficiencies of short life.Dry bag formula isostatic pressed rubber soft mode dimensional stability of the present invention based on natural rubber is high, elasticity is good,
Tensile strength is high.The hard alloy dry bag formula isostatic pressed rubber soft mode prepared according to inventive formulation uses under hydraulic pressure environment
When, service life may be up to 2000 times, remote ultra-traditional polyurethane, polyvinyl chloride hard alloy dry bag formula isostatic pressed rubber soft mode
500-600 service life.
Embodiment
Below in conjunction with embodiment, the present invention will be further described.
Embodiment one to three
A kind of dry bag formula isostatic pressed rubber soft mode sizing compound formula based on natural rubber, the parts by weight of its formula material
Including：
| Natural rubber | 55-100 parts |
| Butadiene-styrene rubber | 0-45 parts |
| Butadiene rubber | 0-45 parts |
| Zinc oxide | 3-5 parts |
| Stearic acid | 1-3 parts |
| Age resistor | 1-4 parts |
| Reinforcing agent | 50-100 parts |
| Plasticizer | 0-20 parts |
| Vulcanizing agent | 1-3 parts |
| Accelerator | 1-3 parts |
The hard alloy dry bag formula isostatic pressed rubber soft mode based on natural rubber described in the above embodiment of the present invention
Sizing compound formula, its parts by weight of raw materials are most preferably：
| Natural rubber | 80 parts |
| Butadiene rubber | 20 parts |
| Zinc oxide | 5 parts |
| Stearic acid | 1.5 part |
| Antioxidant D | 1 part |
| Antioxidant 4010NA | 1.5 part |
| Microwax | 1.5 part |
| High wear-resistant carbon black | 55 parts |
| Semi-reinforcing hydrocarbon black | 15 parts |
| Tackifier RH | 2 parts |
| Accelerant CZ | 1.2 part |
| Sulphur | 2 parts |
The collocation of the type selecting of three kinds of sizing materials and various auxiliary agents is as follows：
| Raw material title | Embodiment one is formulated | Embodiment two is formulated | Embodiment three is formulated |
| Natural rubber | 80 parts | 65 parts | 80 parts |
| Butadiene rubber | 20 parts | 20 parts | 20 parts |
| Butadiene-styrene rubber | 0 part | 15 parts | 0 part |
| Zinc oxide | 5 parts | 5 parts | 5 parts |
| Stearic acid | 1.5 part | 1.5 part | 1.5 part |
| Antioxidant D | 1 part | 1 part | 1 part |
| Antioxidant 4010NA | 1.5 part | 1.5 part | 1.5 part |
| Microwax | 1.5 part | 1.5 part | 1.5 part |
| High wear-resistant carbon black | 55 parts | 55 parts | 55 parts |
| Semi-reinforcing hydrocarbon black | 15 parts | 15 parts | 15 parts |
| Tackifier RH | 2 parts | 2 parts | 2 parts |
| Accelerant CZ | 1.2 part | 1.2 part | 1.5 part |
| Sulphur | 2 parts | 2 parts | 3 parts |
It is as follows by the rubber soft mode physical property obtained by sulfidization molding according to above-mentioned formula：
| Project | Test recipe 1 | Test recipe 2 | Test recipe 3 |
| Hardness, shore A | 76 | 76 | 78 |
| 100% stretches surely, MPa | 4.29 | 4.17 | 6.13 |
| 200% stretches surely, MPa | 9.53 | 9.33 | 13.47 |
| 300% stretches surely, MPa | 14.75 | 14.54 | 0 |
| Elongation, % | 399.80 | 392.00 | 272.50 |
| Tensile strength, MPa | 19.07 | 18.52 | 17.67 |
| Tearing strength, KN/m | 105.40 | 45.05 | 45.25 |
| Have no progeny deformation, % | 14.00 | 12.00 | 12.00 |
| Compression set, % | 22.60 | 23.27 | 21.36 |
It can reach 2000 according to hard alloy dry bag formula isostatic pressed rubber soft mode, service life made from inventive formulation
More than secondary.
It can be seen from above-described embodiment that the present invention relates to the rubber soft mode of a kind of compacting of hard alloy blank and shaping
Preparation method, be kneaded using natural rubber and butadiene-styrene rubber or butadiene rubber, and accordingly adjust formula system, made after vulcanization
Go out the rubber soft mode of the compacting of hard alloy blank and shaping.
Further, described is to use natural rubber and fourth using natural rubber and butadiene-styrene rubber or butadiene rubber mixing
Benzene rubber or butadiene rubber are kneaded uniformly with zinc oxide, stearic acid, auxiliary addition agent in banbury, are added and are promoted in mill
Hard alloy blank rubber soft mode is made in agent, vulcanizing agent, then overall vulcanization.
Further, the preparation method of described rubber soft mode is as follows：
4）Choose dispensing：
Natural rubber 55-100 parts
Butadiene-styrene rubber 0-45 parts
Butadiene rubber 0-45 parts
Zinc oxide 3-5 parts
Stearic acid 1-3 parts
Auxiliary addition agent 53-130 parts
Age resistor 1-4 parts
Reinforcing agent 50-100 parts
Plasticizer 0-20 parts
Vulcanizing agent 1-3 parts
Accelerator 1-3 parts
5）Natural rubber and butadiene-styrene rubber or butadiene rubber and zinc oxide, stearic acid, auxiliary addition agent are mixed in banbury
Refining is uniform, and accelerator, vulcanizing agent are added in mill.
6）The rubber soft mode of the compacting of hard alloy blank and shaping is made in vulcanization.
The advantage of the invention is that：The present invention is using natural rubber and with a small amount of butadiene-styrene rubber or butadiene rubber, and phase
Vulcanizing system should be adjusted, it is the standby isostatic pressed soft mode poor dimensional stability of main system, use that can solve with polyurethane, polyvinyl chloride
The deficiencies of short life.Dry bag formula isostatic pressed rubber soft mode dimensional stability of the present invention based on natural rubber is high, elasticity is good,
Tensile strength is high.The hard alloy dry bag formula isostatic pressed rubber soft mode prepared according to inventive formulation uses under hydraulic pressure environment
When, service life may be up to 2000 times, remote ultra-traditional polyurethane, polyvinyl chloride hard alloy dry bag formula isostatic pressed rubber soft mode
500-600 service life.
Above example is simply to illustrate that the present invention, some cited more preferably embodiments, this area skill
The usual variations and alternatives that art personnel are carried out in the range of the technical program should include within the scope of the present invention.
Claims (2)
- A kind of 1. sizing material for making hard alloy blank soft mode, it is characterised in that：Sizing material is the dry bag based on natural rubber Formula isostatic pressed rubber soft mode sizing material；Component and parts by weight proportioning are as follows：65 parts of natural rubber20 parts of butadiene rubber15 parts of butadiene-styrene rubber5 parts of zinc oxide1.5 parts of stearic acid1 part of antioxidant D1.5 parts of antioxidant 4010NA1.5 parts of microwax55 parts of high wear-resistant carbon black15 parts of semi-reinforcing hydrocarbon black2 parts of tackifier RH1.2 parts of accelerant CZ2 parts of sulphur；Natural rubber, butadiene-styrene rubber and butadiene rubber and zinc oxide, stearic acid, auxiliary addition agent are kneaded uniformly in banbury, Accelerator, sulphur are added in mill, then hard alloy blank rubber soft mode is made in overall vulcanization；Wrapped in described zinc oxide 20-30% activated zinc oxide is included, is used in combination using activated zinc oxide and zinc oxide, further improves the physical property of sizing material.
- 2. a kind of method that the compacting of hard alloy blank and molded rubber soft mode are made using sizing material described in claim 1, is used Natural rubber is kneaded with butadiene rubber and butadiene-styrene rubber, and accordingly adjusts formula system, and hard alloy blank is made after vulcanization Compacting and the rubber soft mode of shaping；The preparation method of described rubber soft mode is as follows：1) dispensing is chosen：65 parts of natural rubber20 parts of butadiene rubber15 parts of butadiene-styrene rubber5 parts of zinc oxide1.5 parts of stearic acid1 part of antioxidant D1.5 parts of antioxidant 4010NA1.5 parts of microwax55 parts of high wear-resistant carbon black15 parts of semi-reinforcing hydrocarbon black2 parts of tackifier RH1.2 parts of accelerant CZ2 parts of sulphur；2) natural rubber and butadiene-styrene rubber and butadiene rubber, zinc oxide, stearic acid and auxiliary addition agent are kneaded uniform；In mill Middle addition accelerator, sulphur；3) the rubber soft mode of the compacting of hard alloy blank and shaping is made in vulcanization.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510244953.7A CN104844851B (en) | 2015-05-14 | 2015-05-14 | Make the sizing material and manufacturing method of soft mould of hard alloy blank soft mode |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510244953.7A CN104844851B (en) | 2015-05-14 | 2015-05-14 | Make the sizing material and manufacturing method of soft mould of hard alloy blank soft mode |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104844851A CN104844851A (en) | 2015-08-19 |
| CN104844851B true CN104844851B (en) | 2017-12-08 |
Family
ID=53844871
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510244953.7A Expired - Fee Related CN104844851B (en) | 2015-05-14 | 2015-05-14 | Make the sizing material and manufacturing method of soft mould of hard alloy blank soft mode |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104844851B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105414547B (en) * | 2015-12-18 | 2017-08-25 | 株洲美特优硬质合金有限公司 | Ultra-fine grain list double straight-hole hard alloy pole manufacture method |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102030928A (en) * | 2010-12-10 | 2011-04-27 | 上海众力汽车部件有限公司 | Rubber with low dynamic to static ratio for resisting compression and fatigue |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1266864A (en) * | 1999-03-12 | 2000-09-20 | 李培蕾 | Process for preparing soft mould of natural rubber |
| JP2009234108A (en) * | 2008-03-27 | 2009-10-15 | Mitsuboshi Belting Ltd | Rubber mold for shaping rubber belt |
-
2015
- 2015-05-14 CN CN201510244953.7A patent/CN104844851B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102030928A (en) * | 2010-12-10 | 2011-04-27 | 上海众力汽车部件有限公司 | Rubber with low dynamic to static ratio for resisting compression and fatigue |
Non-Patent Citations (1)
| Title |
|---|
| "活性氧化锌对天然橡胶 顺丁橡胶 丁苯橡胶胶料性能的影响";赵艳芳等;《橡胶科技市场》;20080101(第1期);第17-19页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104844851A (en) | 2015-08-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104194079A (en) | Composite seal ring and manufacturing process thereof | |
| CN102604174B (en) | White carbon black reinforced high-wear-resistance covering rubber and preparation method thereof | |
| CN105315521A (en) | High-damping material for high-temperature co-curing with composite material and preparation method of high-damping material | |
| CN101613496B (en) | Method for preparing blended vulcanizate of modified rubber power and rubber | |
| CN102617898B (en) | Tire tread material and tire rubber prepared by utilizing material | |
| WO2006028505A1 (en) | Flat free tire and method of preparing same | |
| CN105175976B (en) | Composite toughening modifier and its preparation method and application | |
| CN106882542A (en) | A kind of super abrasive Anti-adhesion conveyor belt and preparation method thereof | |
| CN105418998A (en) | Sidewall rubber and preparation method thereof | |
| CN102127252B (en) | High hardness butadiene-acrylonitrile rubber and preparation method thereof | |
| CN108276837B (en) | Anti-adhesion conveyer belt with ultra-high molecular polyethylene coating and preparation method thereof | |
| CN100548655C (en) | Processing technics of steel thin plate rolling plate type roller | |
| CN104844851B (en) | Make the sizing material and manufacturing method of soft mould of hard alloy blank soft mode | |
| CN102093608B (en) | Reclaimed rubber/coal ash composite material and preparation method thereof | |
| CN106977779A (en) | A kind of tire sidewall glue exempted from demoulding agent of mould | |
| CN102634082A (en) | Tire tread base rubber composition and preparation method | |
| CN1308097A (en) | Waste rubber regenerating process and waste rubber regenerant | |
| CN104031298B (en) | A kind of tire flame retardant rubber and its preparation method and application | |
| CN105086013A (en) | No-blooming wear-resistant rubber and preparing method thereof | |
| CN103554562A (en) | Frosted ruber sole rubber and preparation method thereof, and preparation method of product of frosted ruber sole rubber | |
| CN102775662A (en) | Tire flat rubber material | |
| CN112300453A (en) | Graphene modified rubber and preparation process thereof | |
| CN102241144A (en) | Production process of radial tire | |
| CN110204803B (en) | Light-weight rubber product and preparation method thereof | |
| US2690461A (en) | Nonskid vehicle tire and method for making same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20171208 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |