CN105400297A - Color paste and preparation method thereof - Google Patents
Color paste and preparation method thereof Download PDFInfo
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- CN105400297A CN105400297A CN201510996077.3A CN201510996077A CN105400297A CN 105400297 A CN105400297 A CN 105400297A CN 201510996077 A CN201510996077 A CN 201510996077A CN 105400297 A CN105400297 A CN 105400297A
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- mixture
- dispersion agent
- mill base
- carbon black
- water
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
- C09D17/005—Carbon black
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/001—Pigment pastes, e.g. for mixing in paints in aqueous medium
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a color paste. The color paste is prepared from water, a carbon black pigment, a dispersant and a functional assistant; the carbon black pigment comprises high color black, medium color black and rubber carbon black; the dispersant comprises a block phosphate ester dispersant, a polyester dispersant and an acrylate dispersant; and the functional assistant comprises propylene glycol, glycerol, polyethylene glycol, ammonia water, triethanolamine, pearl essence and aluminum trichloride. The color blacks, the dispersant and the functional assistant are specifically selected in the invention, so the color paste has a good stereo effect when applied. The invention also provides a preparation method of the color paste. The stereo effect of the color paste is further improved in the invention.
Description
Technical field
The present invention relates to technical field of fine, particularly relate to a kind of mill base and preparation method thereof.
Background technology
Mill base is the work piece be dispersed in by pigment or pigment and stopping composition in paint vehicle.According to the difference of the solvent that mill base adopts, mill base is divided into aqueous color paste, oil pastes and resin mill base; With the mill base that pure oil is tackiness agent, be called oil pastes; With the mill base that resin paint vehicle is tackiness agent, be called resin mill base; Take water as the pigment slurry that medium adds surfactant-dispersed, be called aqueous color paste.
Along with the develop rapidly of building industry, industry trends towards efficiently by look, low carbon development.And as the important branch of coating industry, aqueous color paste, under the drive of industry, house property, furniture, household electrical appliances and building materials household, shoots up as consumption main flow, play more and more important role in modern house finishing, home decoration life.
Mill base of the prior art is generally that water, dispersion agent and pigment are reached the mill base after certain fineness by dispersion grinding, and this kind of mill base is applied in the related productss such as coating, and the color effect of performance is plane effect.The novel product solid paint of coating industry adopts coating thickening, the mode of repeatedly constructing to reach its stereoeffect, but effect is not all clearly.
Summary of the invention
The technical problem that the present invention solves is to provide a kind of mill base with stereoeffect and preparation method thereof.
In view of this, this application provides a kind of mill base, prepared by the raw material comprising following component: water, charcoal blacks, dispersion agent and functional aid;
Described charcoal blacks is made up of high-carbon black pigment, middle colour carbon black and rubber black;
Described dispersion agent comprises blocked phosphoric acid ester dispersion agent, polyester dispersion agent and esters of acrylic acid dispersion agent;
Described functional aid comprises propylene glycol, glycerol, polyoxyethylene glycol, ammoniacal liquor, trolamine, pearlescence and aluminum chloride.
Preferably, described dispersion agent is the 28wt% ~ 60wt% of described charcoal blacks, and described functional aid is the 100wt% ~ 130wt% of described charcoal blacks.
Preferably, the mass ratio of described high pigment mill base, middle pigment mill base and described rubber black is (15 ~ 25): (1 ~ 10): 1.
Preferably, the specific surface area of described charcoal blacks is 50 ~ 500m
2/ g, oil-absorption(number)≤140cm
3/ 100g.
Preferably, the weight-average molecular weight of described dispersion agent is 2000 ~ 10000.
Present invention also provides a kind of preparation method of mill base, comprise the following steps:
Water, blocked phosphoric acid ester dispersion agent, trolamine, propylene glycol, polyoxyethylene glycol and high-carbon black pigment are mixed, obtains the first mixture;
Water, blocked phosphoric acid ester dispersion agent, polyester dispersion agent, trolamine, propylene glycol, glycerol and middle colour carbon black are mixed, obtains the second mixture;
Water, esters of acrylic acid dispersion agent, glycerol, polyoxyethylene glycol and rubber black are mixed, obtains the 3rd mixture;
Mix after described first mixture grinding with described second mixture, after grinding, obtain 4 mixture;
Mix after described 3rd mixture grinding with pearlescence, aluminum chloride and ammoniacal liquor, then mix with 4 mixture, obtain mill base.
Preferably, the fineness of described first mixture is 3 ~ 5 μm, and the fineness of described second mixture is 3 ~ 5 μm, and the fineness of described 3rd mixture is 3 ~ 5 μm.
Preferably, the median size of described 4 mixture is less than 0.85 μm.
Preferably, the particle diameter of described pearlescence is 2 ~ 100 μm.
This application provides a kind of mill base, it is prepared by the raw material comprising following component: water, charcoal blacks, dispersion agent and functional aid; Described charcoal blacks is made up of high-carbon black pigment, middle colour carbon black and rubber black; Described dispersion agent comprises blocked phosphoric acid ester dispersion agent, polyester dispersion agent and esters of acrylic acid dispersion agent; Described functional aid comprises propylene glycol, glycerol, polyoxyethylene glycol, ammoniacal liquor, trolamine, pearlescence and aluminum chloride.The application by adopting the pigment of carbon black as mill base of different pigment, and passes through to add pearlescence in mill base, and makes mill base have good stereoeffect.
Further, the application, in the process preparing mill base, by being mixed according to a definite sequence by raw material, enabling pearlescence give full play to its stereoeffect, finally making the stereoeffect of mill base better.
Embodiment
In order to understand the present invention further, below in conjunction with embodiment, the preferred embodiment of the invention is described, but should be appreciated that these describe just for further illustrating the features and advantages of the present invention, instead of limiting to the claimed invention.
The embodiment of the invention discloses a kind of mill base, prepared by the raw material comprising following component: water, charcoal blacks, dispersion agent and functional aid;
Described charcoal blacks is made up of high-carbon black pigment, middle colour carbon black and rubber black;
Described dispersion agent comprises blocked phosphoric acid ester dispersion agent, polyester dispersion agent and esters of acrylic acid dispersion agent;
Described functional aid comprises propylene glycol, glycerol, polyoxyethylene glycol, ammoniacal liquor, trolamine, pearlescence and aluminum chloride.
The application, by selecting specific pigment, dispersion agent and functional aid in mill base, enables mill base have stereoeffect.
According to the present invention, the charcoal blacks in described mill base is made up of high-carbon black pigment, middle colour carbon black and rubber black; Wherein the particle size range of high-carbon black pigment is 9 ~ 17nm, and middle colour carbon black and rubber black are carbon black well known to those skilled in the art, and the application does not limit especially.The mass ratio of high-carbon black pigment, middle colour carbon black and rubber black described in the application is preferably (15 ~ 25): (1 ~ 10): 1, is preferably 16:4:1 in an embodiment.The application, by adding the carbon black of different pigment in mill base, makes mill base can have good stereoeffect.The specific surface area of described charcoal blacks is preferably 50 ~ 500m
2/ g, oil-absorption(number) preferably≤140cm
3/ 100g, the carbon black preferably with above-mentioned parameter makes mill base have different blackness, tinting strength and opacifying power.
Dispersion agent in the application's mill base comprises blocked phosphoric acid ester dispersion agent, polyester dispersion agent and esters of acrylic acid dispersion agent.Concrete, phosphoric acid ester dispersion agent and esters of acrylic acid dispersion agent have good dispersion effect to carbon black and have film-formation result, phosphoric acid ester dispersion agent can improve brightness greatly simultaneously, and esters of acrylic acid dispersion agent improves blackness, and polyester dispersion agent plays the effect of stable three-dimensional system; Blocked phosphoric acid ester dispersion agent very little time, there is no larger difference between high-carbon black pigment and middle colour carbon black, can visual effect be had influence on, the versatility of mill base consistency can be reduced simultaneously; There will be storing state instability too much; Esters of acrylic acid dispersion agent also not very little, otherwise can make the black surface of rubber unglazed, has influence on the stereoeffect of pearlescence; The effect of middle colour carbon black can be had influence on too much.The weight-average molecular weight of described dispersion agent is preferably 2000 ~ 10000.Described functional aid comprises: propylene glycol, glycerol, polyoxyethylene glycol, ammoniacal liquor, trolamine, pearlescence and aluminum chloride.Wherein, propylene glycol, as frostproofer, solvent, can regulate evaporation rate simultaneously; Described glycerol mainly regulates the evaporation rate of mill base; Described polyoxyethylene glycol, as solvent, wetting Agent for Printing Inks, can improve dispersiveness and consistency; Described ammoniacal liquor and trolamine have the effect regulating mill base pH; Described pearlescence can improve the stereoeffect of mill base, and particle diameter is preferably 2 ~ 100 μm; Described aluminum chloride can improve the effect of pearlescence.Described in the application, mill base also comprises wetting agent, and described wetting agent is well known to those skilled in the art, has preferably alcohol ether series lubricant agent; The amount of wetting agent can not be too many, otherwise can have influence on water tolerance, makes it to be deteriorated, and increases the foam of system, or occur that the hydrophilic and oleophilic of system is uneven; Tinting strength and color development performance can be had influence on very little.
The content of content in described mill base of lubricant described in the application is less than 2wt%, is preferably 0.5wt% ~ 1.1wt%; The content of content in described mill base of described propylene glycol is less than 10wt%, is preferably 4wt% ~ 8.9wt%; The content of content in described mill base of described glycerol is less than 10wt%, is preferably 4wt% ~ 9wt%; The content of content in described mill base of described polyoxyethylene glycol is less than 20wt%, is preferably 5wt% ~ 15wt%; The content of content in described mill base of described ammoniacal liquor is 1wt% ~ 4wt%; The content of content in described mill base of described aluminum chloride is 1wt% ~ 4wt%; The content of content in described mill base of described colourless pearlescence is less than 5wt%, is preferably 1wt% ~ 3.5wt%.
Dispersion agent described in the application is preferably the 28wt% ~ 60wt% of described charcoal blacks, and described functional aid is preferably the 100wt% ~ 130wt% of described charcoal blacks.
Present invention also provides the preparation method of described mill base, comprise the following steps:
Water, blocked phosphoric acid ester dispersion agent, trolamine, propylene glycol, polyoxyethylene glycol and high-carbon black pigment are mixed, obtains the first mixture;
Water, blocked phosphoric acid ester dispersion agent, polyester dispersion agent, trolamine, propylene glycol, glycerol and middle colour carbon black are mixed, obtains the second mixture;
Water, esters of acrylic acid dispersion agent, glycerol, polyoxyethylene glycol and rubber black are mixed, obtains the 3rd mixture;
Mix after described first mixture grinding with described second mixture, after grinding, obtain 4 mixture;
Mix after described 3rd mixture grinding with pearlescence, aluminum chloride and ammoniacal liquor, then mix with 4 mixture, obtain mill base.
In the process preparing mill base, first water, blocked phosphoric acid ester dispersion agent, trolamine, propylene glycol, polyoxyethylene glycol and high-carbon black pigment mix by the application, obtain the first mixture; Concrete: water, blocked phosphoric acid ester dispersion agent, wetting agent, trolamine, propylene glycol and polyoxyethylene glycol are mixed, under rotating speed is 500 ~ 700r/min, disperses 5 ~ 10min; Add high pigment mill base again, under rotating speed is 1000 ~ 1400r/min, disperses 100 ~ 150min, obtains the first mixture that fineness is 3 ~ 5 μm.Meanwhile, prepare the second mixture, be specially: by water, blocked phosphoric acid ester dispersion agent, polyester dispersion agent, wetting agent, trolamine, propylene glycol, glycerol mixing, under rotating speed is 500 ~ 700r/min, disperse 5 ~ 10min; Add middle colour carbon black again, under rotating speed is 1000 ~ 1400r/min, disperses 100 ~ 150min, obtains the second mixture that fineness is 3 ~ 5 μm.Meanwhile, preparation the 3rd mixture, is specially: by water, esters of acrylic acid dispersion agent, glycerol, polyoxyethylene glycol mixing, under rotating speed is 500 ~ 700r/min, disperse 5 ~ 10min; Add rubber black again, under rotating speed is 1000 ~ 1400r/min, disperses 100 ~ 150min, obtains the 3rd mixture that fineness is 3 ~ 5 μm.
After prepared by described first mixture, the second mixture and the 3rd mixture, the application has then carried out the process mixed, and mixes, obtain 4 mixture after grinding by after the first mixture grinding with the second mixture.Concrete: the first mixture is disperseed 30 ~ 50min under 2000 ~ 2500r/min, obtains the 4 mixture that median size is 0.65 μm.
The application finally mixes after described 3rd mixture grinding with pearlescence, aluminum chloride and ammoniacal liquor, then mixes with 4 mixture, obtains mill base.
Look described in the application will adopt aforesaid method to prepare, and be conducive to the stereoeffect improving mill base further.
Mill base described in the application is through dispersion, grinding and aftertreatment, reach blackness difference, gloss difference, reflect different effects, pearlescence can give the pattern of decorative pattern simultaneously, to reach well arranged and figuratum mill base, this mill base in the industries such as coating, should can not destroy its structure because of the dispersion of coating.
In order to understand the present invention further, be described in detail to mill base provided by the invention and preparation method thereof below in conjunction with embodiment, protection scope of the present invention is not limited by the following examples.
Embodiment 1
Table 1 is the formula table that embodiment 1 prepares each component of mill base, prepares mill base according to the content of each component of table 1.
1) weigh by the quantity of formula 1, deionized water, dispersion agent 1, wetting agent, trolamine, propylene glycol, polyoxyethylene glycol are joined in dispersion cylinder, 10min is disperseed under 600r/min, property adds high-carbon black pigment again, under 1200r/min, disperse 120min, obtain fineness at the mixture of 3 ~ 5 μm;
2) weigh by the quantity of formula 2, deionized water, dispersion agent 1, dispersion agent 2, wetting agent, trolamine, propylene glycol, glycerol are joined in dispersion cylinder, under 600r/min, dispersion 10min, property adds middle colour carbon black again, under 1200r/min, disperse 120min, obtain fineness at the mixture of 3 ~ 5 μm;
3) weigh by the quantity of formula 3, deionized water, dispersion agent 3, wetting agent, glycerol, polyoxyethylene glycol are joined in dispersion cylinder, under 600r/min, disperses 10min, disposablely add rubber black, under 1200r/min, disperse 120min, obtain fineness at the mixture of 3 ~ 5 μm;
4) by step 1) mixture join in shredder, under 2300r/min, grind 45min, obtain the mixture that median size is less than 0.65 μm, then adding step 2) material, under 1900r/min, grind 30min, obtain the mixture that median size is less than 0.85 μm;
5) by step 3) material join in shredder, under 2300r/min, grind 40min, obtain the mixture that median size is less than 0.65 μm;
6) by step 5) mixture mix the pearlescence and the aluminum chloride that wrap up formula 4 afterwards with ammoniacal liquor;
7) step 6) pearly-lustre mill base join in the mixture of step 4, be uniformly dispersed, obtain mill base.
The data sheet (weight part) of the component of mill base prepared by table 1 embodiment 1
| Raw material | Formula 1 | Formula 2 | Formula 3 | Formula 4 |
| Deionized water | 250.0 | 140.0 | 40.0 | |
| Blocked phosphoric acid ester dispersion agent | 80.0 | 20.0 | ||
| Polyester dispersion agent | 8.0 | |||
| Esters of acrylic acid dispersion agent | 6.0 | |||
| Wetting agent | 4.0 | 2.0 | ||
| Trolamine | 25.0 | 5.0 | ||
| Propylene glycol | 10.0 | 40.0 | ||
| Glycerol | 15.0 | 5.0 | ||
| Polyoxyethylene glycol | 60.0 | 20.0 | ||
| Ammoniacal liquor | 20.0 | |||
| High-carbon black pigment | 160.0 | |||
| Middle colour carbon black | 40.0 | |||
| Rubber black | 10.0 | |||
| Aluminum chloride (50%) | 20.0 | |||
| Colourless pearlescence | 20.0 |
Above experimental products have in water-borne acrylic resin, waterborne polyurethane resin, benzene emulsion and pure-acrylic emulsion good color developing and consistency (without flocculating, without loss of gloss, colourless silk, without mist shadow), conventional mill base there will be compatibility problem at above resin or emulsion, and phenomenon shows as: loss of gloss, have mist shadow, not black or color silk.
Simultaneously when the mass ratio of resin or emulsion and mill base is 15:1, there is good stereoscopic sensation;
Above-mentioned formula is the formula after optimizing, and stereoeffect is comparatively obvious, and when increasing the amount of rubber black, colourless pearlescence can not adsorb rubber black completely, causes rubber black to enter in other two carbon blacks, affects gloss and blackness; Otherwise colourless pearlescence can adsorb other carbon blacks, cause the blackness of pearly-lustre pearl close with other, stereoeffect is not strong;
During as primary colors, resin or emulsion: the mass ratio of mill base is 15:1, adopt the mode of spraying (load wants large) or roller coating, can obtain three-dimensional and visual effect preferably; During as light color, the effect of this mill base is consistent with the effect of common mill base.
Embodiment 2
Preparation method is identical with embodiment 1, and difference is: the content of component is had any different, as shown in table 2.
Embodiment 3
Preparation method is identical with embodiment 1, and difference is: the content of component is had any different, as shown in table 3.
The data sheet (weight part) of the component of mill base prepared by table 2 embodiment 2
| Raw material | Formula 1 | Formula 2 | Formula 3 | Formula 4 |
| Deionized water | 250.0 | 140.0 | 40.0 | |
| Blocked phosphoric acid ester dispersion agent | 80.0 | 20.0 | ||
| Polyester dispersion agent | 8.0 | |||
| Esters of acrylic acid dispersion agent | 6.0 | |||
| Wetting agent | 4.0 | 2.0 | ||
| Trolamine | 25.0 | 5.0 | ||
| Propylene glycol | 10.0 | 40.0 | ||
| Glycerol | 15.0 | 5.0 | ||
| Polyoxyethylene glycol | 60.0 | 20.0 | ||
| Ammoniacal liquor | 20.0 | |||
| High-carbon black pigment | 170.0 | |||
| Middle colour carbon black | 30.0 | |||
| Rubber black | 10.0 | |||
| Aluminum chloride (50%) | 20.0 | |||
| Colourless pearlescence | 20.0 |
The effect of embodiment 2 is similar to Example 1, but pearlescence can arrange out some decorative patterns.
The data sheet (weight part) of the component of mill base prepared by table 3 embodiment 3
| Raw material | Formula 1 | Formula 2 |
| Deionized water | 250.0 | 140.0 |
| Blocked phosphoric acid ester dispersion agent | 80.0 | 20.0 |
| Polyester dispersion agent | 8.0 | |
| Esters of acrylic acid dispersion agent | ||
| Wetting agent | 4.0 | 2.0 |
| Trolamine | 25.0 | 5.0 |
| Propylene glycol | 10.0 | 40.0 |
| Glycerol | 15.0 | |
| Polyoxyethylene glycol | 60.0 | |
| Ammoniacal liquor | ||
| High-carbon black pigment | 160.0 | |
| Middle colour carbon black | 40.0 | |
| Rubber black | ||
| Aluminum chloride (50%) | ||
| Colourless pearlescence |
Fill a prescription in table 3 and 34 do not add system with formula, make mill base there is no stronger stereoeffect, but having good luminance brightness, blackness with when resin or latex composite compounding.
The explanation of above embodiment just understands method of the present invention and core concept thereof for helping.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also carry out some improvement and modification to the present invention, these improve and modify and also fall in the protection domain of the claims in the present invention.
To the above-mentioned explanation of the disclosed embodiments, professional and technical personnel in the field are realized or uses the present invention.To be apparent for those skilled in the art to the multiple amendment of these embodiments, General Principle as defined herein can without departing from the spirit or scope of the present invention, realize in other embodiments.Therefore, the present invention can not be restricted to these embodiments shown in this article, but will meet the widest scope consistent with principle disclosed herein and features of novelty.
Claims (9)
1. a mill base, is prepared by the raw material comprising following component: water, charcoal blacks, dispersion agent and functional aid;
Described charcoal blacks is made up of high-carbon black pigment, middle colour carbon black and rubber black;
Described dispersion agent comprises blocked phosphoric acid ester dispersion agent, polyester dispersion agent and esters of acrylic acid dispersion agent;
Described functional aid comprises propylene glycol, glycerol, polyoxyethylene glycol, ammoniacal liquor, trolamine, pearlescence and aluminum chloride.
2. mill base according to claim 1, is characterized in that, described dispersion agent is the 28wt% ~ 60wt% of described charcoal blacks, and described functional aid is the 100wt% ~ 130wt% of described charcoal blacks.
3. mill base according to claim 1, is characterized in that, the mass ratio of described high pigment mill base, middle pigment mill base and described rubber black is (15 ~ 25): (1 ~ 10): 1.
4. mill base according to claim 1, is characterized in that, the specific surface area of described charcoal blacks is 50 ~ 500m
2/ g, oil-absorption(number)≤140cm
3/ 100g.
5. mill base according to claim 1, is characterized in that, the weight-average molecular weight of described dispersion agent is 2000 ~ 10000.
6. a preparation method for mill base, comprises the following steps:
Water, blocked phosphoric acid ester dispersion agent, trolamine, propylene glycol, polyoxyethylene glycol and high-carbon black pigment are mixed, obtains the first mixture;
Water, blocked phosphoric acid ester dispersion agent, polyester dispersion agent, trolamine, propylene glycol, glycerol and middle colour carbon black are mixed, obtains the second mixture;
Water, esters of acrylic acid dispersion agent, glycerol, polyoxyethylene glycol and rubber black are mixed, obtains the 3rd mixture;
Mix after described first mixture grinding with described second mixture, after grinding, obtain 4 mixture;
Mix after described 3rd mixture grinding with pearlescence, aluminum chloride and ammoniacal liquor, then mix with 4 mixture, obtain mill base.
7. preparation method according to claim 6, is characterized in that, the fineness of described first mixture is 3 ~ 5 μm, and the fineness of described second mixture is 3 ~ 5 μm, and the fineness of described 3rd mixture is 3 ~ 5 μm.
8. preparation method according to claim 6, is characterized in that, the median size of described 4 mixture is less than 0.85 μm.
9. preparation method according to claim 6, is characterized in that, the particle diameter of described pearlescence is 2 ~ 100 μm.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107760108A (en) * | 2017-09-25 | 2018-03-06 | 浙江纳美新材料股份有限公司 | A kind of seed coat agent wear-resisting mixing mill base and preparation method thereof |
| CN107955209A (en) * | 2017-11-17 | 2018-04-24 | 青岛黑猫炭黑科技有限责任公司 | A kind of method that carbon black wet-treating prepares slurries |
| CN108102467A (en) * | 2017-11-29 | 2018-06-01 | 广德粤华塑业制品有限公司 | A kind of aqueous carbon black environmental protection mill base |
| CN108219594A (en) * | 2017-11-29 | 2018-06-29 | 广德粤华塑业制品有限公司 | A kind of environmental protection pearly-lustre mill base |
| CN113004719A (en) * | 2021-01-28 | 2021-06-22 | 江西三越新材料有限公司 | Dispersant composition for low-oxidation-degree rubber carbon black and preparation method thereof |
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| CN1865365A (en) * | 2006-06-22 | 2006-11-22 | 华东理工大学 | Superthin aqueous carbon black color slurry and its preparation method |
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| EP0612821A1 (en) * | 1993-02-24 | 1994-08-31 | Merichem Company | Carbon black dispersant |
| CN1532241A (en) * | 2003-03-25 | 2004-09-29 | 深圳市海川实业股份有限公司 | Hydrophobic carbon black water color paste |
| CN1865365A (en) * | 2006-06-22 | 2006-11-22 | 华东理工大学 | Superthin aqueous carbon black color slurry and its preparation method |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107760108A (en) * | 2017-09-25 | 2018-03-06 | 浙江纳美新材料股份有限公司 | A kind of seed coat agent wear-resisting mixing mill base and preparation method thereof |
| CN107955209A (en) * | 2017-11-17 | 2018-04-24 | 青岛黑猫炭黑科技有限责任公司 | A kind of method that carbon black wet-treating prepares slurries |
| CN108102467A (en) * | 2017-11-29 | 2018-06-01 | 广德粤华塑业制品有限公司 | A kind of aqueous carbon black environmental protection mill base |
| CN108219594A (en) * | 2017-11-29 | 2018-06-29 | 广德粤华塑业制品有限公司 | A kind of environmental protection pearly-lustre mill base |
| CN113004719A (en) * | 2021-01-28 | 2021-06-22 | 江西三越新材料有限公司 | Dispersant composition for low-oxidation-degree rubber carbon black and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105400297B (en) | 2018-06-26 |
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