CN105387470B - Liquid waste incineration reclaims precious metal device - Google Patents

Liquid waste incineration reclaims precious metal device Download PDF

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Publication number
CN105387470B
CN105387470B CN201510851296.2A CN201510851296A CN105387470B CN 105387470 B CN105387470 B CN 105387470B CN 201510851296 A CN201510851296 A CN 201510851296A CN 105387470 B CN105387470 B CN 105387470B
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China
Prior art keywords
tower
storage tank
burning
precious metal
zone
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CN201510851296.2A
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Chinese (zh)
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CN105387470A (en
Inventor
宋俊峰
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JIANGSU LIYU ENVIRONMENTAL TECHNOLOGY Co Ltd
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JIANGSU LIYU ENVIRONMENTAL TECHNOLOGY Co Ltd
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/04Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste liquors, e.g. sulfite liquors
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00Obtaining noble metals
    • C22B11/04Obtaining noble metals by wet processes
    • C22B11/042Recovery of noble metals from waste materials
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2209/00Specific waste
    • F23G2209/10Liquid waste
    • F23G2209/101Waste liquor
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)
  • Treating Waste Gases (AREA)

Abstract

Liquid waste incineration reclaims precious metal device, storage tank including horizontal drain and the 15 degree of settings that are inclined upwardly, burning tower and aeration tower straight up is set side by side with storage tank tip side wall, burn tower and aeration tower bottom is connected with storage tank, the burning tower includes tower, tower end sealing, tower is divided into the burning zone on top and the quench zone of bottom, waste liquid admission line is provided with the wall of burning zone stage casing side, quench zone side wall is provided with atomizing spray pipe, fully burnt with gaseous state, by the complicated of the inside, the not high nitrogen of content, phosphorus, it is more preferable that chlorine is handled, high heating value is made full use of to obtain solvent, save the consumption of fuel, ensure the low loss late of noble metal.

Description

Liquid waste incineration reclaims precious metal device
Technical field
Precious metal device is reclaimed the present invention relates to noble metal recycling field, more particularly to liquid waste incineration.
Background technology
Environmental protection treatment waste, burning is an important process.Contain the noble metal of recovery in need in waste liquid, be also that your gold contained A kind of normality of the dead catalyst of category.Both combine, and are exactly while noble metal is reclaimed, to dispose the process of organic liquid waste.
Waste liquid containing noble metal is generally organic solvent mostly hydrocarbon, and molecular structure is CXHYOZ,Part medical waste Containing a small amount of medicine intermediate, nitrogenous, chloride, part chemical waste fluid is phosphorous, containing iodine;But Main Ingredients and Appearance is all Nytron key.Shared feature, is exactly that calorific value is very high, has micro very miscellaneous composition, it is seldom that neat liquid form is present, and solid-liquid is mixed Close, depend on carbon carrier.This waste material, typically all takes burning disposal.At present, for the solidliquid mixture of this carbon carrier, adopt It is many with distillation pretreatment, distillation test residue and a small amount of distillate burning disposal in solid form.
For burning process, the burning that designer is both known about under gaseous state is most abundant, is exactly the waste of solid-state, It is, using in the state of secondary burning gaseous state, fully to burn.The burning disposal of prior art is not thorough, burns not abundant enough, has It is to be modified.
The content of the invention
In view of the deficiencies of the prior art, the present invention provides one kind is fully burnt with gaseous state, the composition of the inside is answered Miscellaneous, it is more preferable that the not high nitrogen of content, phosphorus, chlorine are handled, and makes full use of high heating value to obtain solvent, saves the consumption of fuel, it is ensured that your gold The liquid waste incineration for belonging to low loss late reclaims precious metal device.
To realize the object of the invention, there is provided following technical scheme:Liquid waste incineration reclaims precious metal device, it is characterised in that Burning tower straight up is set side by side with storage tank including horizontal drain and the 15 degree of settings that are inclined upwardly, storage tank tip side wall And aeration tower, burn tower and aeration tower bottom is connected with storage tank, the burning tower includes tower, tower end sealing, tower It is divided on the burning zone on top and the quench zone of bottom, burning zone stage casing side wall and is provided with waste liquid admission line, quench zone side Wall is provided with atomizing spray pipe, and aeration tower includes tower, and the nearly tip side wall of tower is provided with circulating water intake, and storage tank is inclined upwardly End bottom is provided with dosing mouth, and dosing mouth connection medicine system, medicine system includes the drug feeding pipeline being connected with dosing mouth and added Filter and circulating pump are provided with the dispensing canister of pencil road connection, the drug feeding pipeline, storage tank other end bottom, which is set, takes out true Vacant duct, vacuum lead connection vacuum filter and vacuum pumping pump, circulating water intake set pipeline to connect circulating pump.
Preferably, the waste liquid admission line includes body, body one end, which is provided with end plate, end plate, is provided with benefit wind Mouth, atomization waste liquid port and combustion-supporting gas port, body central are provided with conical jet pipe, and playpipe is stretched from body other end end plate Go out, stretch into burning zone.
Preferably, interleaved is provided with dividing plate from the top down in aeration tower tower.
Beneficial effect of the present invention:Embodiment in terms of 1 security, organic solvent volatility is very strong, inflammable;It is useless containing noble metal Expect solid-liquid mixing, when burning, it is not easy to control temperature, when heating low-temperature zone, control is bad, and gas ratio is controlled not It is good, easily fire.Liquid is separated, directly burnt up, safety.
2 energy-conserving and environment-protective, under pressurizing atomizing state, after direct and combustion adjuvant air is sufficiently mixed, directly light, burn Fully, clean tail gas.The heat of waste liquid itself is made full use of, fuel is saved.After chilling spray, all salt and noble metal, all In water.After vacuum filter, after being burned again as solid, lower end process is handed over to refine, water circulation use, without discharge of wastewater. Device can be used in series with solid stove, serve as dual firing chamber and the vent gas treatment of solid combustion stove, save device fabrication cost.
Brief description of the drawings
Fig. 1 is structural representation of the invention.
Fig. 2 is waste liquid admission line structural representation.
Embodiment
Embodiment 1:Liquid waste incineration reclaims precious metal device, including horizontal drain and the storage tank 1 for the 15 degree of settings that are inclined upwardly, Be set side by side with burning tower 2 and aeration tower 3 straight up on the tip side wall of storage tank 1, burn tower 2 and the bottom of aeration tower 3 with Storage tank 1 is connected, and the burning tower 2 includes tower, tower end sealing, and tower is divided into burning zone 2.1 and the bottom on top Waste liquid admission line 2.3 is provided with quench zone 2.2, the stage casing side wall of burning zone 2.1, the side wall of quench zone 2.2 is provided with atomization spray Shower pipe 2.4, aeration tower 3 includes tower, and the nearly tip side wall of tower is provided with circulating water intake 3.1, and storage tank 1, which is inclined upwardly, holds bottom Dosing mouth 1.1 is provided with, the connection medicine system 4 of dosing mouth 1.1, medicine system 4 includes the drug feeding pipeline being connected with dosing mouth 1.1 4.1st, filter 6 and circulating pump 7, storage tank 1 are provided with the dispensing canister 5 being connected with drug feeding pipeline 4.1, the drug feeding pipeline 4.1 Other end bottom sets vacuum lead 8, the connection vacuum filter 9 of vacuum lead 8 and vacuum pumping pump 10.The waste liquid air inlet Pipeline 2.3 includes body 2.3.1, and body 2.3.1 one end is provided with end plate 2.3.2, end plate 2.3.2 and is provided with wind-supplying mouth 2.3.3, atomization waste liquid port 2.3.4 and combustion-supporting gas port 2.3.5, body 2.3.1 are provided centrally with conical jet pipe 2.3.6, spray Penetrate pipe 2.3.6 to stretch out from body 2.3.1 other end end plates 2.3.2, stretch into burning zone 2.1.In the tower of aeration tower 3 from the top down Interleaved is provided with dividing plate 3.2.Circulating water intake 3.1 sets pipeline to connect circulating pump 7.

Claims (3)

1. liquid waste incineration reclaims precious metal device, it is characterised in that the storage tank including horizontal drain and the 15 degree of settings that are inclined upwardly, Burning tower and aeration tower straight up is set side by side with storage tank tip side wall, tower and aeration tower bottom is burned and connects with storage tank Logical, the burning tower includes tower, and tower end sealing, tower is divided into the burning zone on top and the quench zone of bottom, burns Waste liquid admission line is provided with the wall of section stage casing side, quench zone side wall is provided with atomizing spray pipe, and aeration tower includes tower, tower Nearly tip side wall is provided with circulating water intake, and storage tank, which is inclined upwardly, holds bottom to be provided with dosing mouth, and dosing mouth connects medicine system, Medicine system includes setting in the drug feeding pipeline being connected with dosing mouth, the dispensing canister being connected with drug feeding pipeline, the drug feeding pipeline There are filter and circulating pump, storage tank other end bottom sets vacuum lead, and vacuum lead connects vacuum filter and takes out true Empty pump, circulating water intake sets pipeline to connect circulating pump.
2. liquid waste incineration according to claim 1 reclaims precious metal device, it is characterised in that the waste liquid admission line bag Body is included, body one end, which is provided with end plate, end plate, is provided with wind-supplying mouth, atomization waste liquid port and combustion-supporting gas port, body central Conical jet pipe is provided with, playpipe stretches out from body other end end plate, stretched into burning zone.
3. liquid waste incineration according to claim 1 reclaims precious metal device, it is characterised in that in aeration tower tower on to Lower interleaved is provided with dividing plate.
CN201510851296.2A 2015-11-30 2015-11-30 Liquid waste incineration reclaims precious metal device Active CN105387470B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510851296.2A CN105387470B (en) 2015-11-30 2015-11-30 Liquid waste incineration reclaims precious metal device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510851296.2A CN105387470B (en) 2015-11-30 2015-11-30 Liquid waste incineration reclaims precious metal device

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CN105387470A CN105387470A (en) 2016-03-09
CN105387470B true CN105387470B (en) 2017-10-24

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3743535B1 (en) * 2018-01-24 2021-12-08 Heraeus Deutschland GmbH & Co. KG Process for the recovery of precious metal from petrochemical process residues

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112303641A (en) * 2019-08-02 2021-02-02 中国石油化工股份有限公司 Water-cooled wall type incineration device for recovering metal elements in solid waste, recovery method and application

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202382255U (en) * 2011-12-21 2012-08-15 江苏一环集团有限公司 Incineration device for liquid waste containing salt
CN103868077A (en) * 2012-12-10 2014-06-18 北京航天动力研究所 Method and system for incinerating iodine-containing organic waste liquor, purifying and treating tail gas
CN104197340A (en) * 2014-09-01 2014-12-10 北京航天动力研究所 Incineration disposal device and method for disposing BDO and IPA waste liquid and waste gas
CN105066146A (en) * 2015-07-24 2015-11-18 南京赛佳环保实业有限公司 System and method for treating high-concentration organic waste liquid
CN205261587U (en) * 2015-11-30 2016-05-25 江苏立宇环境科技有限公司 Noble metal device is retrieved to liquid waste incineration

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2753043A1 (en) * 2011-03-18 2012-09-18 Pyrogenesis Canada Inc. Steam plasma arc hydrolysis of ozone depleting substances

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202382255U (en) * 2011-12-21 2012-08-15 江苏一环集团有限公司 Incineration device for liquid waste containing salt
CN103868077A (en) * 2012-12-10 2014-06-18 北京航天动力研究所 Method and system for incinerating iodine-containing organic waste liquor, purifying and treating tail gas
CN104197340A (en) * 2014-09-01 2014-12-10 北京航天动力研究所 Incineration disposal device and method for disposing BDO and IPA waste liquid and waste gas
CN105066146A (en) * 2015-07-24 2015-11-18 南京赛佳环保实业有限公司 System and method for treating high-concentration organic waste liquid
CN205261587U (en) * 2015-11-30 2016-05-25 江苏立宇环境科技有限公司 Noble metal device is retrieved to liquid waste incineration

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3743535B1 (en) * 2018-01-24 2021-12-08 Heraeus Deutschland GmbH & Co. KG Process for the recovery of precious metal from petrochemical process residues

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