CN105385122B - Application of bridged DOPO-based compound, product thereof and preparation method of product - Google Patents
Application of bridged DOPO-based compound, product thereof and preparation method of product Download PDFInfo
- Publication number
- CN105385122B CN105385122B CN201510669828.0A CN201510669828A CN105385122B CN 105385122 B CN105385122 B CN 105385122B CN 201510669828 A CN201510669828 A CN 201510669828A CN 105385122 B CN105385122 B CN 105385122B
- Authority
- CN
- China
- Prior art keywords
- product
- application
- preparation
- based compound
- polylactic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 150000001875 compounds Chemical class 0.000 title claims abstract description 35
- DWSWCPPGLRSPIT-UHFFFAOYSA-N benzo[c][2,1]benzoxaphosphinin-6-ium 6-oxide Chemical compound C1=CC=C2[P+](=O)OC3=CC=CC=C3C2=C1 DWSWCPPGLRSPIT-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 42
- 239000004626 polylactic acid Substances 0.000 claims abstract description 41
- 239000003063 flame retardant Substances 0.000 abstract description 34
- 229920000747 poly(lactic acid) Polymers 0.000 abstract description 27
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 18
- 230000000694 effects Effects 0.000 abstract description 6
- 230000003287 optical effect Effects 0.000 abstract description 3
- 238000002347 injection Methods 0.000 abstract description 2
- 239000007924 injection Substances 0.000 abstract description 2
- 239000002667 nucleating agent Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 13
- 238000007792 addition Methods 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 238000002485 combustion reaction Methods 0.000 description 7
- 239000002585 base Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 239000010439 graphite Substances 0.000 description 5
- 229910002804 graphite Inorganic materials 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 239000010410 layer Substances 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 229910052901 montmorillonite Inorganic materials 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920001342 Bakelite® Polymers 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- 239000004637 bakelite Substances 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- -1 boron phenol Urea formaldehyde Chemical compound 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000004079 fireproofing Methods 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241001269238 Data Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- VYGRRCKMMADGBB-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] phosphono hydrogen phosphate Chemical compound OCC(CO)(CO)COP(O)(=O)OP(O)(O)=O VYGRRCKMMADGBB-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 229920002988 biodegradable polymer Polymers 0.000 description 1
- 239000004621 biodegradable polymer Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- TVHALOSDPLTTSR-UHFFFAOYSA-H hexasodium;[oxido-[oxido(phosphonatooxy)phosphoryl]oxyphosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O TVHALOSDPLTTSR-UHFFFAOYSA-H 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000003930 superacid Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
Landscapes
- Biological Depolymerization Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510669828.0A CN105385122B (en) | 2015-10-18 | 2015-10-18 | Application of bridged DOPO-based compound, product thereof and preparation method of product |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510669828.0A CN105385122B (en) | 2015-10-18 | 2015-10-18 | Application of bridged DOPO-based compound, product thereof and preparation method of product |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105385122A CN105385122A (en) | 2016-03-09 |
CN105385122B true CN105385122B (en) | 2017-04-19 |
Family
ID=55417925
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510669828.0A Active CN105385122B (en) | 2015-10-18 | 2015-10-18 | Application of bridged DOPO-based compound, product thereof and preparation method of product |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105385122B (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106280341B (en) * | 2016-08-31 | 2018-12-14 | 江林(贵州)高科发展股份有限公司 | Halogen-free flameproof long glass fiber reinforced lactic acid composite material and preparation method thereof |
JP7114895B2 (en) * | 2017-12-19 | 2022-08-09 | 三菱ケミカル株式会社 | polyethylene terephthalate film |
CN108059824B (en) * | 2017-12-20 | 2020-09-04 | 贵州省材料产业技术研究院 | Transparent flame-retardant high-temperature nylon and preparation method thereof |
CN108485208A (en) * | 2018-03-29 | 2018-09-04 | 贵州省材料产业技术研究院 | A kind of DOPO derivatives Flame-retardant PET transparent composite and preparation method |
CN108822508A (en) * | 2018-05-17 | 2018-11-16 | 贵州省材料产业技术研究院 | A kind of flame-proof polylactic acid composite material and preparation method and application |
CN111763412A (en) * | 2020-05-29 | 2020-10-13 | 贵州省材料产业技术研究院 | Flame-retardant toughened polylactic acid-based composite material and preparation and application thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102174250A (en) * | 2011-03-15 | 2011-09-07 | 上海大学 | Organic nucleating agent for rapidly crystallizing polylactic acid and rapidly-crystallized polylactic acid resin of organic nucleating agent |
CN104250434A (en) * | 2014-10-24 | 2014-12-31 | 北京工商大学 | Phosphorus-nitrogen halogen-free flame-retardant polylactic acid material |
CN104262398A (en) * | 2014-09-23 | 2015-01-07 | 厦门大学 | Phosphorus-nitrogen type flame retardant containing active double bond as well as preparation method and application thereof |
CN104877172A (en) * | 2015-05-13 | 2015-09-02 | 常州龙骏天纯环保科技有限公司 | Method for modifying fast-crystallization high-crystallinity polylactic acid |
CN105001122A (en) * | 2015-07-02 | 2015-10-28 | 浙江工业大学 | Polylactic acid organic nucleating agent as well as preparation method therefor and application thereof |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3308335B2 (en) * | 1993-04-13 | 2002-07-29 | 三井化学株式会社 | Lactic acid-based polymer composition, pellets thereof, molded body thereof and molding method thereof |
-
2015
- 2015-10-18 CN CN201510669828.0A patent/CN105385122B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102174250A (en) * | 2011-03-15 | 2011-09-07 | 上海大学 | Organic nucleating agent for rapidly crystallizing polylactic acid and rapidly-crystallized polylactic acid resin of organic nucleating agent |
CN104262398A (en) * | 2014-09-23 | 2015-01-07 | 厦门大学 | Phosphorus-nitrogen type flame retardant containing active double bond as well as preparation method and application thereof |
CN104250434A (en) * | 2014-10-24 | 2014-12-31 | 北京工商大学 | Phosphorus-nitrogen halogen-free flame-retardant polylactic acid material |
CN104877172A (en) * | 2015-05-13 | 2015-09-02 | 常州龙骏天纯环保科技有限公司 | Method for modifying fast-crystallization high-crystallinity polylactic acid |
CN105001122A (en) * | 2015-07-02 | 2015-10-28 | 浙江工业大学 | Polylactic acid organic nucleating agent as well as preparation method therefor and application thereof |
Also Published As
Publication number | Publication date |
---|---|
CN105385122A (en) | 2016-03-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105385122B (en) | Application of bridged DOPO-based compound, product thereof and preparation method of product | |
CN101260228B (en) | Method for preparing natural fiber/polylactic acid composite material with anti-flaming function | |
Shumao et al. | Influence of ammonium polyphosphate on the flame retardancy and mechanical properties of ramie fiber‐reinforced poly (lactic acid) biocomposites | |
CN107286563B (en) | Intumescent flame retardant for ABS electrical switch outer cover and preparation and application thereof | |
CN102002222B (en) | Halogen-free flame retardant polylactic acid composite material | |
CN101591468A (en) | A kind of low-smoke halogen-free flame retardant PC/ABS Alloy And Preparation Method | |
CN101765629A (en) | Halogen-free flame-proofing agent | |
CN102964667B (en) | Halogen-free flame-retardant polyethylene composite material and preparation method thereof | |
CN102942728A (en) | Antistatic halogen-free fire retardation ultra-high molecule weight polyethylene material and preparation method thereof | |
CN111333960A (en) | Antimony-free flame-retardant polypropylene composition and preparation method thereof | |
CN103756136B (en) | A kind of halogen-free flame-retardant polypropylene composition and preparation method thereof | |
CN103013081B (en) | High temperature resistant scratch resistant halogen-free flame retardant polycarbonate film | |
CN103333469A (en) | Halogen-free flame-retardant PET (polyethylene terephthalate) composite material and preparation method thereof | |
CN106009585A (en) | Halogen-free flame retardation polycarbonate material and preparation method thereof | |
Wang et al. | Synergistic effect of aluminum hydroxide and expandable graphite on the flame retardancy of polyisocyanurate–polyurethane foams | |
Xu et al. | Melamine polyphosphate/silicon‐modified phenolic resin flame retardant glass fiber reinforced polyamide‐6 | |
CN105219038A (en) | A kind of beta-cyclodextrin is the expandable flame retardant thermoplastic polyether ester elastomer in charcoal source and preparation method thereof | |
CN115260754A (en) | High-toughness halogen-free flame-retardant PA66 material and preparation method thereof | |
Yemisci et al. | Improvement of the flame retardancy of plasticized poly (lactic acid) by means of phosphorus‐based flame retardant fillers | |
Zeng et al. | Co‐flame retarding effect of ethanolamine modified titanium‐containing polyhedral oligomeric silsesquioxanes in epoxy resin | |
CN104327441A (en) | Montmorillonite synergistic flame-retardant ABS composite material and preparation method thereof | |
CN102816405B (en) | Low-smoke halogen-free flame-retardant thermoplastic elastomer and preparation method thereof | |
CN103709666A (en) | Halogen-free and flame retardation modified PET engineering plastic and preparation method thereof | |
JP2016060911A (en) | Organic material as fire and flame retardant synergist | |
CN104327474A (en) | Montmorillonite synergic flame-retardation PC/ABS alloy material and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20200720 Address after: 561116 No.1, Longteng Road, xiayun Industrial Park, Pingba District, Anshun City, Guizhou Province Patentee after: KANGMINGYUAN (GUIZHOU) TECHNOLOGY DEVELOPMENT Co.,Ltd. Address before: 550014, A2-6, new material industrial park, Baiyun North Road, Baiyun District, Guizhou, Guiyang Patentee before: GUIZHOU MATERIAL INDUSTRIAL TECHNOLOGY INSTITUTE |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Application of bridge chain DOPO based compounds and preparation of their products Effective date of registration: 20210413 Granted publication date: 20170419 Pledgee: Gui'an New District Green Financing Guarantee Co.,Ltd. Pledgor: KANGMINGYUAN (GUIZHOU) TECHNOLOGY DEVELOPMENT Co.,Ltd. Registration number: Y2021980002618 |
|
PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20220420 Granted publication date: 20170419 Pledgee: Gui'an New District Green Financing Guarantee Co.,Ltd. Pledgor: KANGMINGYUAN (GUIZHOU) TECHNOLOGY DEVELOPMENT Co.,Ltd. Registration number: Y2021980002618 |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Application of bridged DOPO based compounds and their products and their preparation methods Effective date of registration: 20220525 Granted publication date: 20170419 Pledgee: Gui'an New District Green Financing Guarantee Co.,Ltd. Pledgor: KANGMINGYUAN (GUIZHOU) TECHNOLOGY DEVELOPMENT Co.,Ltd. Registration number: Y2022980006330 |
|
PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20230606 Granted publication date: 20170419 Pledgee: Gui'an New District Green Financing Guarantee Co.,Ltd. Pledgor: KANGMINGYUAN (GUIZHOU) TECHNOLOGY DEVELOPMENT Co.,Ltd. Registration number: Y2022980006330 |