CN105383123A - SGP laminated glass and preparation method thereof - Google Patents
SGP laminated glass and preparation method thereof Download PDFInfo
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- CN105383123A CN105383123A CN201510946584.6A CN201510946584A CN105383123A CN 105383123 A CN105383123 A CN 105383123A CN 201510946584 A CN201510946584 A CN 201510946584A CN 105383123 A CN105383123 A CN 105383123A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/061—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of metal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
- B32B3/18—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by an internal layer formed of separate pieces of material which are juxtaposed side-by-side
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/02—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
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Abstract
Description
技术领域technical field
本发明属于夹层玻璃技术领域,具体涉及一种SGP夹胶玻璃及其制备方法。The invention belongs to the technical field of laminated glass, and in particular relates to a SGP laminated glass and a preparation method thereof.
背景技术Background technique
夹层玻璃是由两片或多片玻璃,之间夹了一层或多层有机聚合物中间膜,经过特殊的高温预压及高温高压工艺处理后,使玻璃和中间膜永久粘合为一体的复合玻璃产品。常用的夹层玻璃中间膜有PVB、SGP、EVA、PU等。夹层玻璃中的玻璃即使碎裂,碎片也会被粘在薄膜上,破碎的玻璃表面仍保持整洁光滑。这不仅为了避免伤害事故,还因为夹层玻璃有极好的抗震入侵能力,中间膜能抵御锤子、劈柴刀等凶器的连续攻击,还能在相当长时间内抵御子弹穿透,其安全防范程度可谓极高。Laminated glass is composed of two or more pieces of glass with one or more layers of organic polymer intermediate film sandwiched between them. After special high-temperature pre-pressing and high-temperature and high-pressure processing, the glass and the intermediate film are permanently bonded together. Composite glass products. Commonly used laminated glass interlayers include PVB, SGP, EVA, PU, etc. Even if the glass in the laminated glass is broken, the fragments will be stuck to the film, and the broken glass surface remains clean and smooth. This is not only to avoid injury accidents, but also because laminated glass has excellent anti-seismic intrusion capabilities. The interlayer film can resist continuous attacks from weapons such as hammers and hatchets, and can also resist bullet penetration for a long time. The degree of safety protection can be described as extremely high.
其中,SGP胶片是夹层玻璃离子聚合物中间膜,其性能优异,撕裂强度是一般PVB膜的5倍,硬度是PVB膜的30-l00倍。低变形率时,SGP夹层玻璃表现为弹塑料特性而PVB为超弹塑性,而高变形率时,PVB变硬并成为弹塑料特性,SGP在整个范围内刚性较高。SGP夹层玻璃和同样厚度的单片玻璃多少乎有相等的弯曲强度。同其他中间膜夹层玻璃相比,SGP夹层玻璃有更高的强度性能和刚性,能有效地减少玻璃厚度,特别是有益于点式支撑玻璃。SGP夹层玻璃在玻璃采光顶和玻璃外窗、幕墙应用前景广阔、良好。SGP夹胶玻璃作为非常可靠的安全玻璃,在建筑领域特别是在一些重要的防爆场所被广泛使用,SGP夹胶玻璃是由2片以上玻璃和SGP胶片通过一定的生产工艺生产出来,由于SGP胶片的材质较硬,胶片只能生产出一定规格的板材,无法满足各种各样的夹胶玻璃的需求,这就需要根据玻璃尺寸大小来拼接,并保证在对接处没有对接痕迹和没有气泡等缺陷。在现有的SGP夹胶玻璃生产工艺中,在胶片尺寸无法满足订单需要时,将所需胶片按照玻璃板面尺寸进行裁剪,并使用电烙铁将SGP胶片拼接起来,再按照夹胶玻璃生产方式进行生产加工,该生产工艺为不连续生产,生产效率很低。SGP胶片需要大量的时间进行拼接,并在拼接处可见拼接的印迹和容易在拼接处产生许多小气泡,产品的煮沸实验也无法达到国际的要求。导致上述缺点的原因是由于玻璃板面较大,将2片或多片SGP胶片所有的拼接处全部用电烙铁熔接在一起所耗时间较长;在后续生产加工完成后,可以清楚的看见拼接的痕迹;如果拼接工作处理不好,很容易在拼接处产生小气泡从而造成废品。Among them, SGP film is a laminated glass ionomer interlayer film with excellent performance, the tear strength is 5 times that of ordinary PVB film, and the hardness is 30-100 times that of PVB film. At low deformation rate, SGP laminated glass exhibits elastic-plastic properties while PVB is super-elastic-plastic, while at high deformation rate, PVB hardens and becomes elastic-plastic properties, and SGP has higher rigidity in the entire range. SGP laminated glass has almost the same bending strength as monolithic glass of the same thickness. Compared with other interlayer laminated glass, SGP laminated glass has higher strength and rigidity, which can effectively reduce the thickness of the glass, especially beneficial to point-supported glass. SGP laminated glass has broad and good application prospects in glass lighting roofs, glass exterior windows, and curtain walls. As a very reliable safety glass, SGP laminated glass is widely used in the construction field, especially in some important explosion-proof places. SGP laminated glass is produced by more than two pieces of glass and SGP film through a certain production process. Due to the SGP film The material is relatively hard, and the film can only produce plates of a certain specification, which cannot meet the needs of various laminated glass. This requires splicing according to the size of the glass, and ensuring that there are no butt marks and no bubbles at the butt joints, etc. defect. In the existing SGP laminated glass production process, when the size of the film cannot meet the needs of the order, the required film is cut according to the size of the glass plate, and the SGP film is spliced together with an electric soldering iron, and then according to the laminated glass production method For production and processing, the production process is discontinuous production, and the production efficiency is very low. SGP film needs a lot of time for splicing, and splicing marks can be seen at the splicing place and many small bubbles are easily generated at the splicing place, and the boiling test of the product cannot meet the international requirements. The reason for the above shortcomings is that due to the large glass plate, it takes a long time to weld all the joints of 2 or more SGP films together with an electric soldering iron; after the subsequent production and processing are completed, the splicing can be clearly seen traces; if the splicing work is not handled well, it is easy to produce small air bubbles at the splicing place, resulting in waste.
发明内容Contents of the invention
为了解决上述问题,本发明的目的在于提供一种拼接处没有对接痕迹和气泡等缺陷的SGP夹胶玻璃。In order to solve the above problems, the object of the present invention is to provide a SGP laminated glass without defects such as butt marks and bubbles at the splicing.
本发明的目的之二是提供了所述SGP夹胶玻璃的制备方法,该方法不仅提高了生产效率和产品质量,同时使得SGP夹胶玻璃的生产工艺过程实现了连续生产。The second object of the present invention is to provide the preparation method of the SGP laminated glass, which not only improves the production efficiency and product quality, but also enables the continuous production of the production process of the SGP laminated glass.
本发明是通过以下技术方案来实现的:The present invention is achieved through the following technical solutions:
一种SGP夹胶玻璃,包括至少两块玻璃和夹设在两块玻璃之间的SGP胶层,所述SGP胶层由至少两块SGP基片拼接而成,所述两块SGP基片拼接处还夹设有一条与所述SGP基片材质相同的SGP胶条。SGP基片不能熔融在一起,缝隙的地方本身就是缺胶的,只有贴一条SGP补充才能把拼接的地方填空。A kind of SGP laminated glass, comprising at least two pieces of glass and an SGP glue layer sandwiched between the two pieces of glass, the SGP glue layer is formed by splicing at least two SGP substrates, and the two SGP substrates are spliced There is also an SGP adhesive strip made of the same material as the SGP substrate. The SGP substrates cannot be fused together, and the gap itself is lack of glue, and only a piece of SGP can be pasted to fill the splicing place.
较佳地,所述SGP胶条的长度与所述SGP基片的宽度相同。Preferably, the length of the SGP adhesive strip is the same as the width of the SGP substrate.
较佳地,所述SGP胶条的厚度为0.89mm。Preferably, the thickness of the SGP strip is 0.89mm.
较佳地,所述SGP胶条的宽度为6~10mm。Preferably, the width of the SGP strip is 6-10mm.
较佳地,所述两块SGP基片的厚度为1.52~3.04mm。SGP胶条的大小较为关键,不用太多也不用太少,太多最后还是会有明显接缝痕迹,影响美观;太少填不满缝隙,会产生气泡,最好恰好能填满接缝的容量就够了。Preferably, the thickness of the two SGP substrates is 1.52-3.04mm. The size of the SGP adhesive strip is critical, neither too much nor too little, too much will still have obvious seam marks in the end, which will affect the appearance; too little will not fill the gaps, and air bubbles will be generated, it is best to just fill the capacity of the seam enough.
所述的SGP夹胶玻璃的制备方法,具体为:The preparation method of described SGP laminated glass is specifically:
A.根据玻璃长度和规格选择一定规格的SGP基片;A. Select a certain specification of SGP substrate according to the length and specification of the glass;
B.根据SGP基片裁剪好相应尺寸的SGP胶条,在第一片玻璃上铺设SGP基片;B. According to the SGP substrate, cut the SGP adhesive tape of the corresponding size, and lay the SGP substrate on the first piece of glass;
C.在各个SGP基片接缝处的上部搭接一条所述的SGP胶条;SGP胶搭接在两块SGP基片接缝处的上部。C. Lap one of the SGP glue strips on the upper part of the seams of each SGP substrate; the SGP glue is lapped on the upper part of the seams of two SGP substrates.
D.所有的接缝处都搭接完成SGP胶条后,再将第二片玻璃与第一片进行合片;D. After all the joints are overlapped with SGP adhesive strips, the second piece of glass is combined with the first piece;
如果是多层夹胶玻璃,这可重复上述步骤。If it is laminated glass, this can repeat the above steps.
E.将合片后的玻璃放入到真空袋中进行抽真空处理;E. Put the laminated glass into a vacuum bag for vacuum treatment;
F.最后进行压合处理,制得所述SGP夹胶玻璃。F. Finally, carry out pressing treatment to obtain the SGP laminated glass.
较佳地,所述步骤E中,真空度为-0.6MP~-1.0MP以上。抽真空,能接缝处空气排出来,避免形成汽泡。Preferably, in the step E, the degree of vacuum is above -0.6MP to -1.0MP. Vacuuming allows air to escape from the seams and prevents the formation of air bubbles.
较佳地,所述步骤F中,压合压力12~14MP,温度135~145℃。Preferably, in the step F, the pressing pressure is 12-14MP, and the temperature is 135-145°C.
本发明包括上下两块玻璃和夹设在两块玻璃之间的SGP胶层,所述SGP胶层由至少两块SGP基片拼接而成,所述两块SGP基片拼接处还夹设有一条与所述SGP基片材质相同的SGP胶条;并通过抽真空和高温压合制得。其主要是利用胶片在高压釜中胶片在高压和高温的状态下,胶片具有流动性的特点,搭接的一条胶片在高温和高压下熔融并将胶片的接缝处的空隙填满,从而达到产品要求。使最终制得的SGP夹胶玻璃拼接处没有胶片对接痕迹和气泡等缺陷。该方法不仅提高了生产效率和产品质量,同时使得SGP夹胶玻璃的生产工艺过程实现了连续生产;及后续生产工艺的相互配合,使产品质量达到国标要求。The present invention comprises two pieces of glass above and below and an SGP glue layer sandwiched between the two pieces of glass. The SGP glue layer is formed by splicing at least two SGP substrates, and the joint of the two SGP substrates is also sandwiched with a A SGP adhesive strip made of the same material as the SGP substrate; and made by vacuumizing and high-temperature pressing. It mainly uses the film in the autoclave under the state of high pressure and high temperature, the film has the characteristics of fluidity, and a lapped film melts under high temperature and high pressure and fills the gap at the joint of the film, so as to achieve product requirement. Make the final SGP laminated glass splicing without defects such as film butt marks and bubbles. This method not only improves the production efficiency and product quality, but also makes the production process of SGP laminated glass realize continuous production; and the mutual cooperation of subsequent production processes makes the product quality meet the national standard requirements.
附图说明Description of drawings
图1本发明中实施例1压合前的结构示意图,Fig. 1 is a schematic structural view of embodiment 1 before lamination in the present invention,
图2本发明中实施例1的结构示意图,The structural representation of embodiment 1 among the Fig. 2 present invention,
图3本发明中实施例2的结构示意图,The structural representation of embodiment 2 in Fig. 3 the present invention,
图4本发明中实施例3的结构示意图。Fig. 4 is a schematic structural diagram of Embodiment 3 of the present invention.
具体的实施方式specific implementation
下面结合具体实施方式对本发明作进一步的详细说明,以助于本领域技术人员理解本发明。The present invention will be further described in detail below in combination with specific embodiments, so as to help those skilled in the art understand the present invention.
实施例1Example 1
见图1、图2,一种SGP夹胶玻璃,包括上下两块玻璃(12、11)和夹设在两块玻璃之间的SGP胶层,SGP胶层由两块SGP基片(21、22)拼接而成,两块SGP基片(21、22)拼接处还夹设有一条与所述SGP基片材质相同的SGP胶条31。SGP胶条31的长度与所述SGP基片的宽度相同,SGP胶条的厚度为0.89mm,SGP胶条的宽度为6mm。所述两块SGP基片的厚度为1.52mm。See Fig. 1, Fig. 2, a kind of SGP laminated glass, comprise upper and lower two pieces of glass (12,11) and the SGP adhesive layer that is arranged between two pieces of glass, SGP adhesive layer is made of two SGP substrates (21, 22) spliced together, where two SGP substrates (21, 22) are spliced, and an SGP adhesive strip 31 with the same material as the SGP substrate is sandwiched. The length of the SGP adhesive strip 31 is the same as the width of the SGP substrate, the thickness of the SGP adhesive strip is 0.89mm, and the width of the SGP adhesive strip is 6mm. The thickness of the two SGP substrates is 1.52 mm.
所述SGP夹胶玻璃的制备方法,具体为:The preparation method of the SGP laminated glass is specifically:
A.根据玻璃长度和规格选择一定规格的SGP基片;A. Select a certain specification of SGP substrate according to the length and specification of the glass;
B.根据SGP基片裁剪好相应尺寸的SGP胶条,在第一片玻璃11上铺设SGP基片(21、22);B. according to SGP substrate cutting the SGP glue strip of corresponding size, lay SGP substrate (21,22) on the first piece of glass 11;
C.在SGP基片(21、22)接缝处的上部搭接一条所述的SGP胶条31;为了表示两块SGP基片(21、22)之间的缝隙,故而图中显示两块SGP基片(21、22)之间有一定距离,实际上两块SGP基片(21、22)是紧挨着的。C. Lap a described SGP glue strip 31 on the top of the SGP substrate (21, 22) seam; in order to represent the gap between two SGP substrates (21, 22), so two pieces are shown in the figure There is a certain distance between the SGP substrates (21, 22), and actually the two SGP substrates (21, 22) are next to each other.
D.将第二片玻璃12与第一片玻璃11进行合片;将合片后的玻璃放入到真空袋中进行抽真空处理;真空度为-0.6MP~-1.0MP以上。D. Combine the second piece of glass 12 with the first piece of glass 11; put the combined glass into a vacuum bag for vacuum treatment; the degree of vacuum is above -0.6MP~-1.0MP.
E.最后进行压合处理(压力12~14MP,温度135~145℃),制得所述SGP夹胶玻璃。E. Finally, perform pressing treatment (pressure 12-14MP, temperature 135-145° C.) to obtain the SGP laminated glass.
实施例2Example 2
见图3,一种SGP夹胶玻璃,包括上下两块玻璃(11、12)和夹设在两块玻璃之间的SGP胶层,SGP胶层由多块SGP基片(21、22、23)拼接而成,两块SGP基片拼接处还夹设有一条与所述SGP基片材质相同的SGP胶条(31、31、32、33)。SGP胶条的长度与所述SGP基片的宽度相同,SGP胶条的厚度为0.89mm,SGP胶条的宽度为10mm。所述两块SGP基片的厚度为3.04mm。所述的SGP夹胶玻璃的制备方法,同具体实施1。See Fig. 3, a kind of SGP laminated glass, comprise upper and lower two pieces of glass (11,12) and the SGP glue layer that is sandwiched between two pieces of glass, SGP glue layer is made of a plurality of SGP substrates (21,22,23 ) are spliced together, and an SGP adhesive strip (31, 31, 32, 33) of the same material as the SGP substrate is sandwiched between the two SGP substrates. The length of the SGP adhesive strip is the same as the width of the SGP substrate, the thickness of the SGP adhesive strip is 0.89mm, and the width of the SGP adhesive strip is 10mm. The thickness of the two SGP substrates is 3.04mm. The preparation method of the described SGP laminated glass is the same as the specific implementation 1.
实施例3Example 3
见图4,一种SGP夹胶玻璃,包括上下三块玻璃(11、12、13)和夹设在三块玻璃之间的第一SGP胶层和第二SGP胶层,第一SGP胶层由两块SGP基片(21、22)拼接而成,当然此处也可以根据玻璃的大小由多块SGP基片拼接。两块SGP基片(21、22)拼接处还夹设有一条与所述SGP基片材质相同的SGP胶条31。第二SGP胶层由两块SGP基片(23、24)拼接而成,当然此处也可以根据玻璃的大小由多块SGP基片拼接。两块SGP基片(23、24)拼接处还夹设有一条与所述SGP基片材质相同的SGP胶条32。SGP胶条的长度、宽度和厚度根据SGP基片的厚度而定。See Fig. 4, a kind of SGP laminated glass, comprise upper and lower three pieces of glass (11,12,13) and the first SGP adhesive layer and the second SGP adhesive layer sandwiched between the three glasses, the first SGP adhesive layer It is formed by splicing two SGP substrates (21, 22), of course, it can also be spliced by multiple SGP substrates according to the size of the glass. An SGP adhesive strip 31 made of the same material as the SGP substrates is sandwiched between the joints of the two SGP substrates (21, 22). The second SGP adhesive layer is formed by splicing two SGP substrates (23, 24), and of course it can also be spliced by multiple SGP substrates according to the size of the glass. An SGP adhesive strip 32 made of the same material as the SGP substrates is sandwiched between the joints of the two SGP substrates (23, 24). The length, width and thickness of the SGP strips depend on the thickness of the SGP substrate.
所述的SGP夹胶玻璃的制备方法,具体为:The preparation method of described SGP laminated glass is specifically:
A.根据玻璃长度和规格选择一定规格的SGP基片;A. Select a certain specification of SGP substrate according to the length and specification of the glass;
B.根据SGP基片裁剪好相应尺寸的SGP胶条,在第一片玻璃11上铺设第一层的两块SGP基片(21、22);B. according to the SGP base sheet cutting the SGP glue strip of corresponding size, lay two SGP base sheets (21,22) of the first layer on the first glass 11;
C.在第一层的两块SGP基片(21、22)接缝处的上部搭接一条SGP胶条31;SGP胶搭接在两块SGP基片接缝处的上部。C. Lap an SGP glue strip 31 on the upper part of the seam of the two SGP substrates (21, 22) of the first layer; SGP glue is lapped on the upper part of the seam of the two SGP substrates.
D.所有的接缝处都搭接完成SGP胶条后,再将第二片玻璃12压盖在第一层的SGP胶片上;D. After all the seams are overlapped with SGP adhesive strips, the second piece of glass 12 is pressed on the first layer of SGP film;
E.在第二片玻璃12上铺设第二层的两块SGP基片(23、24);E. lay two SGP substrates (23,24) of the second layer on the second sheet of glass 12;
F.在第二层的两块SGP基片(23、24)接缝处的上部搭接一条SGP胶条32;SGP胶搭接在两块SGP基片接缝处的上部。F. Lap an SGP glue strip 32 on the upper part of the joint of the two SGP substrates (23, 24) on the second layer; SGP glue is lapped on the upper part of the joint of the two SGP substrates.
G.所有的接缝处都搭接完成SGP胶条后,再将第三片玻璃13压盖在第二层的SGP胶片上;如果是多层夹胶玻璃,这可重复上述步骤。G. After all the seams are overlapped with the SGP adhesive tape, press the third piece of glass 13 on the second layer of SGP film; if it is multi-layer laminated glass, repeat the above steps.
H.将合片后的玻璃放入到真空袋中进行抽真空处理;真空度为-0.6MP~-1.0MP以上。H. Put the laminated glass into a vacuum bag for vacuum treatment; the vacuum degree is above -0.6MP~-1.0MP.
I.最后进行压合处理(压力12~14MP,温度135~145℃),制得所述SGP夹胶玻璃。I. Finally, carry out pressing treatment (pressure 12~14MP, temperature 135~145 ℃), make described SGP laminated glass.
上述实施例,只是本发明的较佳实施例,并非用来限制本发明实施范围,故凡以本发明权利要求所述的特征及原理所做的等效变化或修饰,均应包括在本发明权利要求范围之内。The above-described embodiments are only preferred embodiments of the present invention, and are not intended to limit the scope of the present invention. Therefore, all equivalent changes or modifications made with the features and principles described in the claims of the present invention should be included in the present invention. within the scope of the claims.
Claims (8)
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CN109435414A (en) * | 2018-11-07 | 2019-03-08 | 南京工道光电技术有限公司 | A kind of still kettle vacuumizes the method for preparing doubling glass |
CN112757748A (en) * | 2020-12-31 | 2021-05-07 | 天津南玻节能玻璃有限公司 | Laminated glass splicing method and laminated glass |
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