CN105374499B - A kind of solid isolation transformer - Google Patents
A kind of solid isolation transformer Download PDFInfo
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- CN105374499B CN105374499B CN201510500095.8A CN201510500095A CN105374499B CN 105374499 B CN105374499 B CN 105374499B CN 201510500095 A CN201510500095 A CN 201510500095A CN 105374499 B CN105374499 B CN 105374499B
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- 238000002955 isolation Methods 0.000 title claims abstract description 9
- 239000007787 solid Substances 0.000 title claims abstract description 9
- 238000000576 coating method Methods 0.000 claims abstract description 19
- 239000011248 coating agent Substances 0.000 claims abstract description 18
- 239000004033 plastic Substances 0.000 claims abstract description 8
- 229920003023 plastic Polymers 0.000 claims abstract description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 16
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 16
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 14
- 239000002202 Polyethylene glycol Substances 0.000 claims description 12
- 239000003054 catalyst Substances 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 239000007800 oxidant agent Substances 0.000 claims description 12
- 230000001590 oxidative effect Effects 0.000 claims description 12
- 229920001223 polyethylene glycol Polymers 0.000 claims description 12
- 239000003085 diluting agent Substances 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 8
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 8
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims description 8
- 229910021389 graphene Inorganic materials 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 8
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 8
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical group [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 8
- 239000004408 titanium dioxide Substances 0.000 claims description 8
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 7
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 7
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 7
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 7
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 7
- 229910052982 molybdenum disulfide Inorganic materials 0.000 claims description 6
- -1 poly dimethyl silicon Oxygen alkane Chemical class 0.000 claims description 5
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 4
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical group Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 229930192474 thiophene Natural products 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 238000002242 deionisation method Methods 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 239000005543 nano-size silicon particle Substances 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- QVTVDJWJGGEOGX-UHFFFAOYSA-N urea;cyanide Chemical compound N#[C-].NC(N)=O QVTVDJWJGGEOGX-UHFFFAOYSA-N 0.000 claims 1
- 238000005260 corrosion Methods 0.000 abstract description 5
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 2
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 238000001723 curing Methods 0.000 description 4
- 230000002045 lasting effect Effects 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 241000790917 Dioxys <bee> Species 0.000 description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920005573 silicon-containing polymer Polymers 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000005674 electromagnetic induction Effects 0.000 description 1
- JCHMFMSWRWHRFI-HMMYKYKNSA-N ethyl (2e)-2-[(2,5-dichlorophenyl)hydrazinylidene]-2-(2,6-dimethylmorpholin-4-yl)acetate Chemical group C1C(C)OC(C)CN1/C(C(=O)OCC)=N/NC1=CC(Cl)=CC=C1Cl JCHMFMSWRWHRFI-HMMYKYKNSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Abstract
The invention belongs to transformer technology field, discloses a kind of solid isolation transformer, and it includes magnetic core, coil and plastic casing, and coating is coated outside the plastic casing.Solid isolation transformer of the present invention possesses preferable insulating properties, corrosion-resistant, antistatic, mechanical strength is big and has electro-magnetic screen function.
Description
Technical field
The present invention relates to the technical field of transformer, and in particular to a kind of solid isolation transformer.
Background technology
Transformer（Transformer）It is the device for changing alternating voltage using the principle of electromagnetic induction, main member
It is primary coil, secondary coil and iron core（Magnetic core）.Major function has：Voltage transformation, current transformation, impedance are converted, isolated, be steady
Pressure（Magnetic saturation transformer）Deng.It can be divided into, according to use,：Distribution transformer, power transformer, full-sealed transformer, combined variable
Depressor, dry-type transformer, oil-filled transformer, single-phase transformer, furnace transformer, rectifier transformer etc..
Transformer shell is mainly used in the security protection at operating transformer scene.Avoid because the foreign matter such as toy, rainwater
Cause interruption of service into transformer, can effectively protect personal safety and play certain electromagnetic shielding action.By structural material not
It is same to be divided into：Aluminium alloy grinds card transformer shell, stainless steel transformer shell and spraying steel plate transformer shell three major types.By making
It is different with occasion：It is divided to two kinds of indoor transformer shell and outdoor depressor housing.Research of the prior art to transformer shell is less,
But because potential safety hazard caused by the damage of housing is more and more；In order to ensure the safety of people's production and life, we
Need to study that a kind of good insulation preformance, corrosion-resistant, antistatic, mechanical strength be big and transformer shell with electro-magnetic screen function
Body.
The content of the invention
Present invention aim to address many defects of transformer in the prior art, by lot of experiments and exploration, to becoming
Depressor housing is transformed, and it is possessed preferable insulating properties, corrosion-resistant, antistatic, mechanical strength big and have electromagnetism
Function of shielding.
To achieve these goals, technical scheme is realized in the following way：
A kind of solid isolation transformer, it includes magnetic core, coil and plastic casing；
Characterized in that, coat coating outside the housing；The coating is prepared by the raw material of following parts by weight：
It is modified poly-（3,4- ethene dioxythiophenes）- polystyrolsulfon acid 9-12 parts, aromatic urethane acrylate 16-22
Part, organic siliconresin 12-17 parts, dimethylaminoethyl acrylate 9-12 parts, diluent 50-65 parts, triallyl isocyanuric acid
Ester 1-2 parts, levelling agent 0.7-0.9 parts, graphene 15-20 parts, magnesium chloride 4-6 parts, nano-silver powder 4-6 parts, nanometer silicon carbide 2-3
Part, organobentonite 0.5-1 parts, nanometer titanium dioxide 0.5-1 parts, talcum powder 0.2-0.3 parts, sodium tripolyphosphate 0.1-0.2 parts, two
Molybdenum sulfide 0.1-0.2 parts.
The modification gathers（3,4- ethene dioxythiophenes）The preparation method of-polystyrolsulfon acid is as follows：
Under conditions of temperature is 35 DEG C, sulfonated graphene, 3,4-rthylene dioxythiophene and polyethylene glycol are dispersed in
In ionized water, the concentration that makes contained polyethylene glycol in the mixed system to be formed is 0.05wt%, and sulfonated graphene, 3,4- ethene
Dioxy thiophene, the mass ratio of polyethylene glycol is 2:3:0.1, then the pH value of the mixed system is adjusted to 4.5, and with 500 turns/
Min speed is stirred, while adds oxidant and catalyst, wherein the mass ratio of oxidant and 3,4-rthylene dioxythiophene
It is 1:2, the mass ratio 0.01 of catalyst and 3,4-rthylene dioxythiophene:1, then continue stirring reaction 10-72h, remove afterwards
Foreign ion in reaction product mixture, is produced；The oxidant is sodium peroxydisulfate, and the catalyst is ferric trichloride.
The diluent is：Water：Isopropanol：Ethanol（Volume ratio）=1:7:1；
The levelling agent is：Dimethyl silicone polymer；
Its preparation method comprises the following steps：
Will be modified poly-（3,4- ethene dioxythiophenes）- polystyrolsulfon acid, which is placed in high speed dispersor, to be dissipated, and 1000 turns of rotating speed/
Min, stir 60min, then successively add aromatic urethane acrylate, organic siliconresin, dimethylaminoethyl acrylate,
Diluent, Triallyl isocyanurate, levelling agent, graphene, magnesium chloride, nano-silver powder, nanometer silicon carbide, organic swelling
Soil, nanometer titanium dioxide, talcum powder, sodium tripolyphosphate and molybdenum disulfide, 1500 turns/min stirring 15-30min, are produced.
Beneficial effect of the present invention mainly includes the following aspects：
The present invention uses plastic casing, good insulation preformance；A certain amount of fireproof agent is added in coating, improves fire resistance
Energy；Using graphene anti-corrosion, and effect stability, action effective are grown；The present invention has stronger antibacterial effect using nano-silver powder,
And the duration is grown, and has good compatibility with curing system；The combination such as nanometer titanium dioxide and nanometer silicon carbide possess compared with
Good radiation-resistant corrosion and mechanical performance；Modification prepared by the present invention gathers（3,4- ethene dioxythiophenes）- polystyrene sulphur
Acid can not only meet the requirement of Antistatic radiation-proof, and have a good compatibility with photocuring system, dilution oligomer,
Regulation system viscosity.It is mutually coordinated between each component material of the present invention, pass through big change of variable condition, parameter, warp for the applicant
Single factor experiment is crossed, factorial experiment obtains, and the application operating parameter is that inventor operates acquisition through creative work, and it is prepared
The solidification of coating film forming after there is self assembly characteristic, can freely spread in substrate, and build high-effective conductive network, make painting
Material surface has high transmission rate, high conductivity and stability, while can also make have more preferable mechanical property after curing of coatings,
Particularly there is the characteristics of activeness and quietness effect and high-wearing feature, make it have more preferable Antistatic radiation-proof durability, simultaneously
With excellent decay resistance.
Embodiment
Embodiment 1
A kind of solid isolation transformer, it includes magnetic core, coil and plastic casing；
Coating is coated outside the housing；The coating is prepared by the raw material of following parts by weight：
It is modified poly-（3,4- ethene dioxythiophenes）9 parts of-polystyrolsulfon acid, 16 parts of aromatic urethane acrylate, have
12 parts of machine silicones, 9 parts of dimethylaminoethyl acrylate, 50 parts of diluent, 1 part of Triallyl isocyanurate, levelling agent 0.7
Part, 15 parts of graphene, 4 parts of magnesium chloride, 4 parts of nano-silver powder, 2 parts of nanometer silicon carbide, 0.5 part of organobentonite, nanometer titanium dioxide
0.5 part, 0.2 part of talcum powder, 0.1 part of sodium tripolyphosphate, 0.1 part of molybdenum disulfide.
The modification gathers（3,4- ethene dioxythiophenes）The preparation method of-polystyrolsulfon acid is as follows：
Under conditions of temperature is 35 DEG C, sulfonated graphene, 3,4-rthylene dioxythiophene and polyethylene glycol are dispersed in
In ionized water, the concentration that makes contained polyethylene glycol in the mixed system to be formed is 0.05wt%, and sulfonated graphene, 3,4- ethene
Dioxy thiophene, the mass ratio of polyethylene glycol is 2:3:0.1, then the pH value of the mixed system is adjusted to 4.5, and with 500 turns/
Min speed is stirred, while adds oxidant and catalyst, wherein the mass ratio of oxidant and 3,4-rthylene dioxythiophene
It is 1:2, the mass ratio 0.01 of catalyst and 3,4-rthylene dioxythiophene:1, then continue stirring reaction 20h, remove mixing afterwards
Foreign ion in reaction product, is produced；The oxidant is sodium peroxydisulfate, and the catalyst is ferric trichloride.
The diluent is：Water：Isopropanol：Ethanol（Volume ratio）=1:7:1；
The levelling agent is：Dimethyl silicone polymer；
Its preparation method comprises the following steps：
Will be modified poly-（3,4- ethene dioxythiophenes）- polystyrolsulfon acid, which is placed in high speed dispersor, to be dissipated, and 1000 turns of rotating speed/
Min, stir 60min, then successively add aromatic urethane acrylate, organic siliconresin, dimethylaminoethyl acrylate,
Diluent, Triallyl isocyanurate, levelling agent, graphene, magnesium chloride, nano-silver powder, nanometer silicon carbide, organic swelling
Soil, nanometer titanium dioxide, talcum powder, sodium tripolyphosphate and molybdenum disulfide, 1500 turns/min stirring 15min, are produced.
After brushing paint, transformer shell surface of the present invention is dried without skinning and lump phenomenon, energy rapid curing, environmentally friendly nothing
Poison, not tacky, do not return viscous, scratch resistance is wear-resisting；Antistatic property is excellent and lasting stability, coating surface resistance are 6.8 × 105
Ω/sq, coating surface resistance 7.4 × 10 after placing 1 year5Ω/sq, antistatic property are lasting.Coating hardness 5H, adhesive force 1
Level, impact strength 59kg.cm.
Decay resistance is tested：Paint film uniform hue, it is smooth；
Salt water resistance（3% sodium chloride, 24h）It is non-foaming, do not fall off, without turning white；
X-ray shield rate can reach more than 80%.
Embodiment 2
A kind of solid isolation transformer, it includes magnetic core, coil and plastic casing；
Characterized in that, coat coating outside the housing；The coating is prepared by the raw material of following parts by weight：
It is modified poly-（3,4- ethene dioxythiophenes）12 parts of-polystyrolsulfon acid, 22 parts of aromatic urethane acrylate, have
17 parts of machine silicones, 12 parts of dimethylaminoethyl acrylate, 65 parts of diluent, 2 parts of Triallyl isocyanurate, levelling agent
0.9 part, 20 parts of graphene, 6 parts of magnesium chloride, 6 parts of nano-silver powder, 3 parts of nanometer silicon carbide, 1 part of organobentonite, nanometer titanium dioxide
1 part, 0.3 part of talcum powder, 0.2 part of sodium tripolyphosphate, 0.2 part of molybdenum disulfide.
The modification gathers（3,4- ethene dioxythiophenes）The preparation method of-polystyrolsulfon acid is as follows：
Under conditions of temperature is 35 DEG C, sulfonated graphene, 3,4-rthylene dioxythiophene and polyethylene glycol are dispersed in
In ionized water, the concentration that makes contained polyethylene glycol in the mixed system to be formed is 0.05wt%, and sulfonated graphene, 3,4- ethene
Dioxy thiophene, the mass ratio of polyethylene glycol is 2:3:0.1, then the pH value of the mixed system is adjusted to 4.5, and with 500 turns/
Min speed is stirred, while adds oxidant and catalyst, wherein the mass ratio of oxidant and 3,4-rthylene dioxythiophene
It is 1:2, the mass ratio 0.01 of catalyst and 3,4-rthylene dioxythiophene:1, then continue stirring reaction 72h, remove mixing afterwards
Foreign ion in reaction product, is produced；The oxidant is sodium peroxydisulfate, and the catalyst is ferric trichloride.
The diluent is：Water：Isopropanol：Ethanol（Volume ratio）=1:7:1；
The levelling agent is：Dimethyl silicone polymer；
Its preparation method comprises the following steps：
Will be modified poly-（3,4- ethene dioxythiophenes）- polystyrolsulfon acid, which is placed in high speed dispersor, to be dissipated, and 1000 turns of rotating speed/
Min, stir 60min, then successively add aromatic urethane acrylate, organic siliconresin, dimethylaminoethyl acrylate,
Diluent, Triallyl isocyanurate, levelling agent, graphene, magnesium chloride, nano-silver powder, nanometer silicon carbide, organic swelling
Soil, nanometer titanium dioxide, talcum powder, sodium tripolyphosphate and molybdenum disulfide, 1500 turns/min stirring 30min, are produced.
After brushing paint, transformer shell surface of the present invention is dried without skinning and lump phenomenon, energy rapid curing, environmentally friendly nothing
Poison, not tacky, do not return viscous, scratch resistance is wear-resisting；Antistatic property is excellent and lasting stability, coating surface resistance are 6.9 × 105
Ω/sq, coating surface resistance 7.5 × 10 after placing 1 year5Ω/sq, antistatic property are lasting.Coating hardness 5H, adhesive force 1
Level, impact strength 60kg.cm.
Decay resistance is tested：Paint film uniform hue, it is smooth；
Salt water resistance（3% sodium chloride, 24h）It is non-foaming, do not fall off, without turning white；
X-ray shield rate can reach more than 80%.
The present invention is done it is noted that although description above has been carried out by the example of the present invention certainly
Go out will be apparent to those skilled in the science it is such and other improvement and change be deemed to fall such as set forth herein
Broad range of the present invention in.Therefore, although the present invention reference has been made to preferred embodiment and be described, it is anticipated
It is not that the product for making tool novelty is restricted therefrom, on the contrary, it is intended to include to meet part disclosed above, claim
Broad range within various improvement and equivalent modifications.
Claims (1)
1. a kind of solid isolation transformer, it includes magnetic core, coil and plastic casing, it is characterised in that the plastic casing
Outer coating coating,
The coating is prepared by the raw material of following parts by weight：Polymer-modified 9-12 parts, aromatic urethane acrylate
16-22 parts, organic siliconresin 12-17 parts, dimethylaminoethyl acrylate 9-12 parts, diluent 50-65 parts, triallyl isocyanide
Urea acid esters 1-2 parts, levelling agent 0.7-0.9 parts, graphene 15-20 parts, magnesium chloride 4-6 parts, nano-silver powder 4-6 parts, nano silicon carbide
Silicon 2-3 parts, organobentonite 0.5-1 parts, nanometer titanium dioxide 0.5-1 parts, talcum powder 0.2-0.3 parts, sodium tripolyphosphate 0.1-0.2
Part, molybdenum disulfide 0.1-0.2 parts；
The polymer-modified preparation method is as follows：
Under conditions of temperature is 35 DEG C, sulfonated graphene, 3,4-rthylene dioxythiophene and polyethylene glycol are dispersed in deionization
In water, the concentration that makes contained polyethylene glycol in the mixed system to be formed is 0.05wt%, and sulfonated graphene, 3,4- ethylene dioxies
Thiophene, the mass ratio of polyethylene glycol is 2:3:0.1, then the pH value of the mixed system is adjusted to 4.5, and with 500 turns/min's
Speed is stirred, while adds oxidant and catalyst, and the mass ratio of wherein oxidant and 3,4-rthylene dioxythiophene is 1:
2, the mass ratio 0.01 of catalyst and 3,4-rthylene dioxythiophene:1, then continue stirring reaction 10-72h, remove mixing afterwards
Foreign ion in reaction product, is produced；
The oxidant is sodium peroxydisulfate, and the catalyst is ferric trichloride；
The diluent is water：Isopropanol：Ethanol is according to 1:7:1 volume ratio, which mixes, to be produced；The levelling agent is poly dimethyl silicon
Oxygen alkane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510500095.8A CN105374499B (en) | 2015-08-16 | 2015-08-16 | A kind of solid isolation transformer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510500095.8A CN105374499B (en) | 2015-08-16 | 2015-08-16 | A kind of solid isolation transformer |
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| Publication Number | Publication Date |
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| CN105374499A CN105374499A (en) | 2016-03-02 |
| CN105374499B true CN105374499B (en) | 2018-02-23 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107917939B (en) * | 2017-11-27 | 2020-02-04 | 电子科技大学 | Electromagnetic chemical sensor based on conductive polymer and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JPH10273609A (en) * | 1997-03-31 | 1998-10-13 | I & P Kk | Electromagnetic shielding coating material paint |
| CN102558772B (en) * | 2011-12-15 | 2013-03-06 | 河海大学 | Poly(3,4-ethylenedioxythiophene)/sulfonated graphene composite hydrogel and preparation method thereof |
| CN202796317U (en) * | 2012-09-11 | 2013-03-13 | 河南省电力公司鹤壁供电公司 | Dry type electric power transformer |
| CN103788859B (en) * | 2014-01-08 | 2016-06-08 | 华东理工大学 | A kind of antistatic coating for ultra-violet curing and preparation method thereof |
| CN103937372B (en) * | 2014-04-16 | 2016-06-01 | 江苏华盛电气股份有限公司 | The oil-filled transformer of a kind of corrosion-and high-temp-resistant |
| CN104293102A (en) * | 2014-09-25 | 2015-01-21 | 安徽蓝翔电器成套设备有限公司 | High-temperature resistant insulating transformer and processing method thereof |
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