CN105369471A - Technology for producing glass fiber composite - Google Patents

Technology for producing glass fiber composite Download PDF

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Publication number
CN105369471A
CN105369471A CN201510929028.8A CN201510929028A CN105369471A CN 105369471 A CN105369471 A CN 105369471A CN 201510929028 A CN201510929028 A CN 201510929028A CN 105369471 A CN105369471 A CN 105369471A
Authority
CN
China
Prior art keywords
parts
mass
glass fiber
glass fibre
compound material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510929028.8A
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Chinese (zh)
Inventor
张志刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHANGSHU JIANGNAN GLASS FIBER Co Ltd
Original Assignee
CHANGSHU JIANGNAN GLASS FIBER Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHANGSHU JIANGNAN GLASS FIBER Co Ltd filed Critical CHANGSHU JIANGNAN GLASS FIBER Co Ltd
Priority to CN201510929028.8A priority Critical patent/CN105369471A/en
Publication of CN105369471A publication Critical patent/CN105369471A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04CBRAIDING OR MANUFACTURE OF LACE, INCLUDING BOBBIN-NET OR CARBONISED LACE; BRAIDING MACHINES; BRAID; LACE
    • D04C1/00Braid or lace, e.g. pillow-lace; Processes for the manufacture thereof
    • D04C1/02Braid or lace, e.g. pillow-lace; Processes for the manufacture thereof made from particular materials
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/02Inorganic fibres based on oxides or oxide ceramics, e.g. silicates
    • D10B2101/06Glass
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/12Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of cyclic compounds with one carbon-to-carbon double bond in the side chain
    • D10B2321/121Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of cyclic compounds with one carbon-to-carbon double bond in the side chain polystyrene
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides

Abstract

The invention discloses a technology for producing a glass fiber composite. The technology includes the following steps that 1, by mass, 1-2 parts of tetramethyl ammonium bromide, 1.8 parts of glycidyl methacrylate, 1.2 parts of aluminum oxide, 10 parts of glass fiber mineral powder, 0.4 part of pentaerythrite tetra-[beta-(3,5-di-tert-butyl-4-hydroxyphenyl)-propionate], 6.7 parts of AES resin, 2.3 parts of sodium pyrophosphate and 2.1 parts of alkene-octylene copolymers are mixed to be even, fused and drawn into yarns, and glass fibers are prepared; 2, by mass, 8 parts of PS resin and 3 parts of PA resin are mixed to be even and spun into polymer fibers; 3, the glass fibers and the polymer fibers are woven together, and the glass fiber composite is obtained. According to the technology for producing the glass fiber composite, the prepared glass fiber composite is good in acid-base resistance and rigidity and resistant to oxidation and aging.

Description

For the production of the technique of glass fiber compound material
Technical field
The present invention relates to the technique for the production of glass fiber compound material.
Background technology
The resistance to acids and bases of existing glass fiber compound material, rigidity, anti-oxidant, ageing resistace all have much room for improvement.
Summary of the invention
The object of the present invention is to provide a kind of technique for the production of glass fiber compound material, its glass fiber compound material resistance to acids and bases prepared, good rigidly, anti-oxidant, anti-aging.
For achieving the above object, technical scheme of the present invention is a kind of technique for the production of glass fiber compound material of design, comprises the steps:
1) by 1 ~ 2 parts by mass 4 bromide, 1.8 parts by mass glycidyl methacrylate, 1.2 parts by mass aluminium oxide, 10 parts by mass glass fibre mineral powders, 0.4 parts by mass four (β-(3,5 di-tert-butyl-hydroxy phenyls) propionic acid) pentaerythritol ester, 6.7 parts by mass AES resins, 2.3 parts by mass sodium pyrophosphates, 2.1 parts by mass alkene octene copolymers mix, melt drawing, obtained glass fibre;
2) by 8 parts by mass PS resins, 3 parts by mass PA mixed with resin evenly, spinning forms polymer fiber;
3), together with being woven into polymer fiber by glass fibre, glass fiber compound material is obtained.
Preferably, for the production of the technique of glass fiber compound material, comprise the steps:
1) by 1 parts by mass 4 bromide, 1.8 parts by mass glycidyl methacrylate, 1.2 parts by mass aluminium oxide, 10 parts by mass glass fibre mineral powders, 0.4 parts by mass four (β-(3,5 di-tert-butyl-hydroxy phenyls) propionic acid) pentaerythritol ester, 6.7 parts by mass AES resins, 2.3 parts by mass sodium pyrophosphates, 2.1 parts by mass alkene octene copolymers mix, melt drawing, obtained glass fibre;
2) by 8 parts by mass PS resins, 3 parts by mass PA mixed with resin evenly, spinning forms polymer fiber;
3), together with being woven into polymer fiber by glass fibre, glass fiber compound material is obtained.
Preferably, for the production of the technique of glass fiber compound material, comprise the steps:
1) by 2 parts by mass 4 bromides, 1.8 parts by mass glycidyl methacrylate, 1.2 parts by mass aluminium oxide, 10 parts by mass glass fibre mineral powders, 0.4 parts by mass four (β-(3,5 di-tert-butyl-hydroxy phenyls) propionic acid) pentaerythritol ester, 6.7 parts by mass AES resins, 2.3 parts by mass sodium pyrophosphates, 2.1 parts by mass alkene octene copolymers mix, melt drawing, obtained glass fibre;
2) by 8 parts by mass PS resins, 3 parts by mass PA mixed with resin evenly, spinning forms polymer fiber;
3), together with being woven into polymer fiber by glass fibre, glass fiber compound material is obtained.
Advantage of the present invention and beneficial effect are: provide a kind of technique for the production of glass fiber compound material, its glass fiber compound material resistance to acids and bases prepared, good rigidly, anti-oxidant, anti-aging.
Detailed description of the invention
Below in conjunction with embodiment, the specific embodiment of the present invention is further described.Following examples only for technical scheme of the present invention is clearly described, and can not limit the scope of the invention with this.
The technical scheme that the present invention specifically implements is:
Embodiment 1
For the production of a technique for glass fiber compound material, comprise the steps:
1) by 1 ~ 2 parts by mass 4 bromide, 1.8 parts by mass glycidyl methacrylate, 1.2 parts by mass aluminium oxide, 10 parts by mass glass fibre mineral powders, 0.4 parts by mass four (β-(3,5 di-tert-butyl-hydroxy phenyls) propionic acid) pentaerythritol ester, 6.7 parts by mass AES resins, 2.3 parts by mass sodium pyrophosphates, 2.1 parts by mass alkene octene copolymers mix, melt drawing, obtained glass fibre;
2) by 8 parts by mass PS resins, 3 parts by mass PA mixed with resin evenly, spinning forms polymer fiber;
3), together with being woven into polymer fiber by glass fibre, glass fiber compound material is obtained.
Embodiment 2
For the production of the technique of glass fiber compound material, comprise the steps:
1) by 1 parts by mass 4 bromide, 1.8 parts by mass glycidyl methacrylate, 1.2 parts by mass aluminium oxide, 10 parts by mass glass fibre mineral powders, 0.4 parts by mass four (β-(3,5 di-tert-butyl-hydroxy phenyls) propionic acid) pentaerythritol ester, 6.7 parts by mass AES resins, 2.3 parts by mass sodium pyrophosphates, 2.1 parts by mass alkene octene copolymers mix, melt drawing, obtained glass fibre;
2) by 8 parts by mass PS resins, 3 parts by mass PA mixed with resin evenly, spinning forms polymer fiber;
3), together with being woven into polymer fiber by glass fibre, glass fiber compound material is obtained.
Embodiment 3
For the production of the technique of glass fiber compound material, comprise the steps:
1) by 2 parts by mass 4 bromides, 1.8 parts by mass glycidyl methacrylate, 1.2 parts by mass aluminium oxide, 10 parts by mass glass fibre mineral powders, 0.4 parts by mass four (β-(3,5 di-tert-butyl-hydroxy phenyls) propionic acid) pentaerythritol ester, 6.7 parts by mass AES resins, 2.3 parts by mass sodium pyrophosphates, 2.1 parts by mass alkene octene copolymers mix, melt drawing, obtained glass fibre;
2) by 8 parts by mass PS resins, 3 parts by mass PA mixed with resin evenly, spinning forms polymer fiber;
3), together with being woven into polymer fiber by glass fibre, glass fiber compound material is obtained.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the prerequisite not departing from the technology of the present invention principle; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.

Claims (3)

1. for the production of the technique of glass fiber compound material, it is characterized in that, comprise the steps:
1) by 1 ~ 2 parts by mass 4 bromide, 1.8 parts by mass glycidyl methacrylate, 1.2 parts by mass aluminium oxide, 10 parts by mass glass fibre mineral powders, 0.4 parts by mass four (β-(3,5 di-tert-butyl-hydroxy phenyls) propionic acid) pentaerythritol ester, 6.7 parts by mass AES resins, 2.3 parts by mass sodium pyrophosphates, 2.1 parts by mass alkene octene copolymers mix, melt drawing, obtained glass fibre;
2) by 8 parts by mass PS resins, 3 parts by mass PA mixed with resin evenly, spinning forms polymer fiber;
3), together with being woven into polymer fiber by glass fibre, glass fiber compound material is obtained.
2. the technique for the production of glass fiber compound material according to claim 1, is characterized in that, comprise the steps:
1) by 1 parts by mass 4 bromide, 1.8 parts by mass glycidyl methacrylate, 1.2 parts by mass aluminium oxide, 10 parts by mass glass fibre mineral powders, 0.4 parts by mass four (β-(3,5 di-tert-butyl-hydroxy phenyls) propionic acid) pentaerythritol ester, 6.7 parts by mass AES resins, 2.3 parts by mass sodium pyrophosphates, 2.1 parts by mass alkene octene copolymers mix, melt drawing, obtained glass fibre;
2) by 8 parts by mass PS resins, 3 parts by mass PA mixed with resin evenly, spinning forms polymer fiber;
3), together with being woven into polymer fiber by glass fibre, glass fiber compound material is obtained.
3. the technique for the production of glass fiber compound material according to claim 1, is characterized in that, comprise the steps:
1) by 2 parts by mass 4 bromides, 1.8 parts by mass glycidyl methacrylate, 1.2 parts by mass aluminium oxide, 10 parts by mass glass fibre mineral powders, 0.4 parts by mass four (β-(3,5 di-tert-butyl-hydroxy phenyls) propionic acid) pentaerythritol ester, 6.7 parts by mass AES resins, 2.3 parts by mass sodium pyrophosphates, 2.1 parts by mass alkene octene copolymers mix, melt drawing, obtained glass fibre;
2) by 8 parts by mass PS resins, 3 parts by mass PA mixed with resin evenly, spinning forms polymer fiber;
3), together with being woven into polymer fiber by glass fibre, glass fiber compound material is obtained.
CN201510929028.8A 2015-12-15 2015-12-15 Technology for producing glass fiber composite Pending CN105369471A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510929028.8A CN105369471A (en) 2015-12-15 2015-12-15 Technology for producing glass fiber composite

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510929028.8A CN105369471A (en) 2015-12-15 2015-12-15 Technology for producing glass fiber composite

Publications (1)

Publication Number Publication Date
CN105369471A true CN105369471A (en) 2016-03-02

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510929028.8A Pending CN105369471A (en) 2015-12-15 2015-12-15 Technology for producing glass fiber composite

Country Status (1)

Country Link
CN (1) CN105369471A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102212205A (en) * 2011-04-01 2011-10-12 江苏金发科技新材料有限公司 Fiberglass composite reinforced material and preparation method thereof
US8057860B2 (en) * 2005-05-02 2011-11-15 Johns Manville Method for producing fiberglass materials and compositions resulting from the same
CN102898759A (en) * 2012-09-27 2013-01-30 上海锦湖日丽塑料有限公司 Acrylonitrile-ethylene-styrene (AES) resin composition and preparation method thereof
CN103740027A (en) * 2013-12-27 2014-04-23 安徽科聚新材料有限公司 Glass fiber reinforced AES composite material and preparation method thereof
CN104045957A (en) * 2014-06-17 2014-09-17 合肥杰事杰新材料股份有限公司 Glass fiber reinforced AES (Acrylonitrile-Ethylene-Propylene-Diene Monomer-Styrene) resin material and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8057860B2 (en) * 2005-05-02 2011-11-15 Johns Manville Method for producing fiberglass materials and compositions resulting from the same
CN102212205A (en) * 2011-04-01 2011-10-12 江苏金发科技新材料有限公司 Fiberglass composite reinforced material and preparation method thereof
CN102898759A (en) * 2012-09-27 2013-01-30 上海锦湖日丽塑料有限公司 Acrylonitrile-ethylene-styrene (AES) resin composition and preparation method thereof
CN103740027A (en) * 2013-12-27 2014-04-23 安徽科聚新材料有限公司 Glass fiber reinforced AES composite material and preparation method thereof
CN104045957A (en) * 2014-06-17 2014-09-17 合肥杰事杰新材料股份有限公司 Glass fiber reinforced AES (Acrylonitrile-Ethylene-Propylene-Diene Monomer-Styrene) resin material and preparation method thereof

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Application publication date: 20160302

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