CN104045957A - Glass fiber reinforced AES (Acrylonitrile-Ethylene-Propylene-Diene Monomer-Styrene) resin material and preparation method thereof - Google Patents
Glass fiber reinforced AES (Acrylonitrile-Ethylene-Propylene-Diene Monomer-Styrene) resin material and preparation method thereof Download PDFInfo
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- CN104045957A CN104045957A CN201410269723.1A CN201410269723A CN104045957A CN 104045957 A CN104045957 A CN 104045957A CN 201410269723 A CN201410269723 A CN 201410269723A CN 104045957 A CN104045957 A CN 104045957A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/12—Making granules characterised by structure or composition
- B29B9/14—Making granules characterised by structure or composition fibre-reinforced
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/58—Component parts, details or accessories; Auxiliary operations
- B29B7/72—Measuring, controlling or regulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/12—Making granules characterised by structure or composition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/505—Screws
- B29C48/625—Screws characterised by the ratio of the threaded length of the screw to its outside diameter [L/D ratio]
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/46—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
Abstract
The invention provides a glass fiber reinforced AES (Acrylonitrile-Ethylene-Propylene-Diene Monomer-Styrene) resin material and a preparation method thereof. The material is prepared by mixing and extruding 50-90 parts of acrylonitrile-ethylene-propylene-diene monomer-styrene, 10-40 parts of glass fibers, 3-10 parts of a compatilizer, 0.5-2 parts of coupling reagent and 0.5-0.6 part of ethylene bis stearamide. The glass fiber reinforced AES resin material provided by the invention has excellent stretching and bending performances and balanced flowing property and impact performance. The cost of the AES material is lowered, so that the using range of the AES material is wider.
Description
Technical field
The present invention relates to modified plastics field, be specifically related to a kind of glass and strengthen AES resin material and preparation method thereof.
Background technology
AES resin claims again EPSAN resin, is the graft copolymer of terpolymer EP rubber and vinylbenzene, vinyl cyanide.Same ASA, ACS are the same is all a kind of polystyrene toughened resin poor for ABS weathering resistance and exploitation.AES does toughner with EPDM rubber, and EPDM is ethylene-propylene-diene terpolymers, and in its molecule, double bond content is few, thus AES weathering resistance than ABS will good 4-8 doubly.In addition, the thermostability of AES, water-intake rate and shock strength are all better than ABS resin, and other performance and ABS are suitable.So AES resin is owing to having good over-all properties and excellent weathering resistance, existing being applied to gradually in auto parts machinery, fishery and agricultural Turnover Box also has certain application in addition in the outdoor appliances such as door and window, billboard.
But for the intensity of the AES resin of enhancing modification exploitation is low, restricting it in the application of more field.Along with the expansion of AES Application Areas, can seem not enough in the pure AES mechanical property in the field of high strength demand, add that AES material cost is fettering its widespread use.
Summary of the invention
Content of the present invention is to provide a kind of glass fibre and strengthens AES resin material and preparation method thereof.
The technical solution used in the present invention is: a kind of glass strengthens AES resin material, is prepared from by weight by following component:
50～90 parts of vinyl cyanide-terpolymer EP rubber-vinylbenzene (AES)
10～40 parts, glass fibre
3～10 parts of compatilizers
0.5～2 part of coupling agent
0.5～0.6 part of ethylene bis stearamide.
Further, in described vinyl cyanide-terpolymer EP rubber-vinylbenzene, the mass content of terpolymer EP rubber is 55%～75%.
Described glass fibre is continuous alkali free glass fibre.
Described compatilizer is styrene-maleic anhydride copolymer (being called for short SMA resin), and its weight-average molecular weight is 0.8 × 10
5～2 × 10
5; The mass content of the maleic anhydride in described styrene-maleic anhydride copolymer is 50%.
Described coupling agent is silane coupling agent or titante coupling agent.
Acid number≤10mgKOH/g, the amine value≤2.5mgKOH/g of described ethylene bis stearamide.
Another object of the present invention is to provide the preparation method of above-mentioned glass enhancing AES resin material, comprises the steps:
(1) by proportioning, vinyl cyanide-terpolymer EP rubber-vinylbenzene and compatilizer, coupling agent, ethylene bis stearamide one are arised to high-speed mixer and mixing 2～10 minutes;
(2) mixed raw material in step (1) is added in twin screw extruder, more continuous alkali free glass fibre is directly added by forcing machine feeding section; Then melt extrude at 210～230 DEG C, obtain glass after tie rod, water-cooled, pelletizing and strengthen AES resin material.
So the present invention has following beneficial effect:
1, the glass that prepared by the present invention strengthens AES resin material and possesses excellent stretching, bending property and balanced mobility, impact property.
2, the use of glass fibre has reduced the cost of AES material, makes AES materials'use scope more extensive.
3, preparation method of the present invention is simple, easy to implement.
The ethylene bis stearamide of the specific acid ammonium value 4, adding in the present invention, itself and compatilizer SMA, coupling agent produce synergy, make the interface binding power of AES and glass fibre reach maximum, thereby significantly improve the mechanical property of material.
Embodiment
Further set forth the present invention below in conjunction with some embodiment.
Terpolymer EP rubber mass content in the present embodiment in vinyl cyanide-terpolymer EP rubber-vinylbenzene (AES) used is 55%～75%.
Compatilizer is styrene-maleic anhydride copolymer (being called for short SMA resin), and its weight-average molecular weight is 0.8 × 10
5～2 × 10
5; The mass content of the maleic anhydride in described styrene-maleic anhydride copolymer is 50%.
Acid number≤10mgKOH/g, the amine value≤2.5mgKOH/g of ethylene bis stearamide (EBS), purchased from rich commerce and trade company limited of Beijing Star.
Glass fibre is that continuous alkali free glass fibre is EDR14-1000-988A, purchased from Zhejiang Jushi Group Co., Ltd..
Coupling agent is selected organo silane coupling agent KH-550(Nanjing Xu Yang Chemical Co., Ltd.) and titante coupling agent 105(Guangzhou Pu Fan Chemical Co., Ltd.).
Embodiment 1
1,50 parts of AES are placed in to high-speed mixer and mixing 2 minutes together with 10 parts of compatilizer SMA, 2 parts of coupling agent KH-550,0.6 part of ethylene bis stearamide EBS;
2, the raw material mixing is placed in to twin screw extruder, then 40 parts of continuous alkali free glass fibre EDR14-1000-988A40 parts are directly added by forcing machine feeding section; Then through melt extruding, tie rod, water-cooled, pelletizing, obtain glass and strengthen AES resin material; Wherein, the length-to-diameter ratio of twin screw extruder is 40:1; Barrel Temperature Setting is: 210 DEG C of district's temperature, two 215 DEG C of district's temperature, three 215 DEG C of district's temperature, four 220 DEG C of district's temperature, five 220 DEG C of district's temperature, six 225 DEG C of district's temperature, seven 225 DEG C of district's temperature, eight 230 DEG C of district's temperature, 225 DEG C of head temperatures; Screw speed is 450 revs/min.
Embodiment 2
1,90 parts of AES are placed in to high-speed mixer and mixing 10 minutes together with 3 parts of compatilizer SMA, 0.5 part of coupling agent KH-550,0.5 part of ethylene bis stearamide EBS;
2, the raw material mixing is placed in to twin screw extruder, then is that EDR14-1000-988A40 part directly adds by forcing machine feeding section by 10 parts of continuous alkali free glass fibres; Then through melt extruding, tie rod, water-cooled, pelletizing, obtain glass and strengthen AES resin material; Wherein, the length-to-diameter ratio of twin screw extruder is 40:1; Barrel Temperature Setting is: 210 DEG C of district's temperature, two 215 DEG C of district's temperature, three 215 DEG C of district's temperature, four 220 DEG C of district's temperature, five 220 DEG C of district's temperature, six 225 DEG C of district's temperature, seven 225 DEG C of district's temperature, eight 230 DEG C of district's temperature, 225 DEG C of head temperatures; Screw speed is 450 revs/min.
Embodiment 3
1,70 parts of AES are placed in to high-speed mixer and mixing 5 minutes together with 5 parts of compatilizer SMA, 1 part of coupling agent KH-550,0.6 part of ethylene bis stearamide EBS;
2, the raw material mixing is placed in to twin screw extruder, then is that EDR14-1000-988A40 part directly adds by forcing machine feeding section by 25 parts of continuous alkali free glass fibres; Then through melt extruding, tie rod, water-cooled, pelletizing, obtain glass and strengthen AES resin material; Wherein, the length-to-diameter ratio of twin screw extruder is 40:1; Barrel Temperature Setting is: 210 DEG C of district's temperature, two 215 DEG C of district's temperature, three 215 DEG C of district's temperature, four 220 DEG C of district's temperature, five 220 DEG C of district's temperature, six 225 DEG C of district's temperature, seven 225 DEG C of district's temperature, eight 230 DEG C of district's temperature, 225 DEG C of head temperatures; Screw speed is 450 revs/min.
Embodiment 4
1,80 parts of AES are placed in to high-speed mixer and mixing 8 minutes together with 3 parts of compatilizer SMA, 105,0.5 part of ethylene bis stearamide EBS of 1.5 parts of coupling agents;
2, the raw material mixing is placed in to twin screw extruder, then is that EDR14-1000-988A40 part directly adds by forcing machine feeding section by 20 parts of continuous alkali free glass fibres; Then through melt extruding, tie rod, water-cooled, pelletizing, obtain glass and strengthen AES resin material; Wherein, the length-to-diameter ratio of twin screw extruder is 40:1; Barrel Temperature Setting is: 210 DEG C of district's temperature, two 215 DEG C of district's temperature, three 215 DEG C of district's temperature, four 220 DEG C of district's temperature, five 220 DEG C of district's temperature, six 225 DEG C of district's temperature, seven 225 DEG C of district's temperature, eight 230 DEG C of district's temperature, 225 DEG C of head temperatures; Screw speed is 450 revs/min.
Embodiment 5
1,55 parts of AES are placed in to high-speed mixer and mixing 10 minutes together with 10 parts of compatilizer SMA, 105,0.6 part of ethylene bis stearamide EBS of 2 parts of coupling agents;
2, the raw material mixing is placed in to twin screw extruder, then is that EDR14-1000-988A40 part directly adds by forcing machine feeding section by 35 parts of continuous alkali free glass fibres; Then through melt extruding, tie rod, water-cooled, pelletizing, obtain glass and strengthen AES resin material; Wherein, the length-to-diameter ratio of twin screw extruder is 40:1; Barrel Temperature Setting is: 210 DEG C of district's temperature, two 215 DEG C of district's temperature, three 215 DEG C of district's temperature, four 220 DEG C of district's temperature, five 220 DEG C of district's temperature, six 225 DEG C of district's temperature, seven 225 DEG C of district's temperature, eight 230 DEG C of district's temperature, 225 DEG C of head temperatures; Screw speed is 450 revs/min.
In each embodiment, each component and weight part are shown in Table 1 above:
Table 1 is the formula of embodiment 1-5:
| ? | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| AES | 50 | 90 | 70 | 80 | 55 |
| Alkali free glass fibre EDR14-1000-988A continuously | 40 | 10 | 25 | 20 | 35 |
| Compatilizer SMA | 10 | 3 | 5 | 3 | 10 |
| Coupling agent KH-550 | 2 | ? | 1 | ? | ? |
| Coupling agent 105 | ? | 0.5 | ? | 1.5 | 2 |
| Ethylene bis stearamide EBS | 0.6 | 0.5 | 0.6 | 0.5 | 0.6 |
Prepared glass in above-described embodiment 1-5 is strengthened to AES resin material and is first injection molded into by standard size the standard batten of test use, then carry out performance test according to the listed testing standard of table 2 below; Select common AES resin, wherein terpolymer EP rubber content is 10-90% simultaneously, is injection molded into the standard bar of test use as a comparison case.
Table 2: performance test methods:
| Performance index | Test condition | Testing method |
| Melt index | 220℃，2.16kg | ASTM D1238 |
| Tensile strength | 5mm/min | ASTM D638 |
| Flexural strength | 1.25mm/min | ASTM D790 |
| Modulus in flexure | 1.25mm/min | ASTM D790 |
| Simply supported beam notched Izod impact strength | 23℃ | ASTM D6110 |
In the standard batten of the various embodiments described above and comparative example, the performance test results of pure AES resin sample sees the following form shown in 3:
Table 3: test result
| Performance | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Comparative example |
| Melt index, g/10min | 8.2 | 29.4 | 12.6 | 14 | 10.5 | 38.4 |
| Tensile strength, MPa | 126 | 67.7 | 104 | 89.4 | 118 | 52.0 |
| Flexural strength, MPa | 162 | 76.3 | 146 | 130 | 154 | 65.2 |
| Modulus in flexure, MPa | 8249 | 3410 | 6395 | 5628 | 7448 | 2331 |
| Simply supported beam notched Izod impact strength, kJ/m 2 | 9.2 | 17.8 | 11.4 | 13.5 | 11.3 | 2.4 |
As can be seen from Table 3, glass prepared by embodiment of the present invention 1-5 strengthens AES resin material owing to being to strengthen AES by glass fibre, thereby has significantly improved tensile strength, flexural strength and the modulus in flexure of material.From embodiment 1, compared with comparative example, shock strength, tensile strength, flexural strength and modulus in flexure that the glass of embodiment 1 strengthens AES resin material all improve 2.5-4 doubly compared with the AES resin in comparative example.In addition, the mobility of AES resin material prepared by embodiment 1-5 and comparative example all belongs to normal interval, can say that AES resin material prepared by the present invention has still kept balanced mobility.
Claims (7)
1. glass strengthens an AES resin material, it is characterized in that: be prepared from by weight by following component:
50～90 parts of vinyl cyanide-terpolymer EP rubber-vinylbenzene
10～40 parts, glass fibre
3～10 parts of compatilizers
0.5～2 part of coupling agent
0.5～0.6 part of ethylene bis stearamide.
2. a kind of glass according to claim 1 strengthens AES resin material, it is characterized in that: in described vinyl cyanide-terpolymer EP rubber-vinylbenzene, the mass content of terpolymer EP rubber is 55%～75%.
3. a kind of glass according to claim 1 strengthens AES resin material, it is characterized in that: described glass fibre is continuous alkali free glass fibre.
4. a kind of glass according to claim 1 strengthens AES resin material, it is characterized in that: described compatilizer is styrene-maleic anhydride copolymer, and its weight-average molecular weight is 0.8 × 10
5～2 × 10
5; The mass content of the maleic anhydride in described styrene-maleic anhydride copolymer is 50%.
5. a kind of glass according to claim 1 strengthens AES resin material, it is characterized in that: described coupling agent is silane coupling agent or titante coupling agent.
6. a kind of glass according to claim 1 strengthens AES resin material, it is characterized in that: acid number≤10mgKOH/g, the amine value≤2.5mgKOH/g of described ethylene bis stearamide.
7. the glass as described in claim 1-6 any one strengthens the preparation method of AES resin material, it is characterized in that: comprise the steps:
(1) by proportioning, vinyl cyanide-terpolymer EP rubber-vinylbenzene and compatilizer, coupling agent, ethylene bis stearamide one are arised to high-speed mixer and mixing 2～10 minutes;
(2) mixed raw material in step (1) is added in twin screw extruder, more continuous alkali free glass fibre is directly added by forcing machine feeding section; Then melt extrude at 210～230 DEG C, obtain glass after tie rod, water-cooled, pelletizing and strengthen AES resin material.
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| CN201410269723.1A CN104045957A (en) | 2014-06-17 | 2014-06-17 | Glass fiber reinforced AES (Acrylonitrile-Ethylene-Propylene-Diene Monomer-Styrene) resin material and preparation method thereof |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104452094A (en) * | 2014-12-06 | 2015-03-25 | 常熟江南玻璃纤维有限公司 | Production process of glass fiber composite |
| CN104452095A (en) * | 2014-12-06 | 2015-03-25 | 常熟江南玻璃纤维有限公司 | Preparation method of glass fiber composite |
| CN104452096A (en) * | 2014-12-06 | 2015-03-25 | 常熟江南玻璃纤维有限公司 | Production process of glass fiber composite |
| CN104480629A (en) * | 2014-12-06 | 2015-04-01 | 常熟江南玻璃纤维有限公司 | Preparation method of glass fiber composite material |
| CN104480630A (en) * | 2014-12-06 | 2015-04-01 | 常熟江南玻璃纤维有限公司 | Preparation process of glass fiber composite material |
| CN104480631A (en) * | 2014-12-06 | 2015-04-01 | 常熟江南玻璃纤维有限公司 | Method used for producing glass fiber composite material |
| CN105369471A (en) * | 2015-12-15 | 2016-03-02 | 常熟江南玻璃纤维有限公司 | Technology for producing glass fiber composite |
| CN105647023A (en) * | 2014-11-10 | 2016-06-08 | 合肥杰事杰新材料股份有限公司 | Glass fiber reinforced AES resin material and preparation method thereof |
| CN106147103A (en) * | 2015-04-01 | 2016-11-23 | 合肥杰事杰新材料股份有限公司 | A kind of fiberglass reinforced AES resin material and preparation method thereof |
| CN106280191A (en) * | 2015-06-11 | 2017-01-04 | 合肥杰事杰新材料股份有限公司 | A kind of fiberglass reinforced AES resin material and preparation method thereof |
| CN106928623A (en) * | 2017-03-20 | 2017-07-07 | 安徽江淮汽车集团股份有限公司 | A kind of flame-retarding high performance AES PVC composites and preparation method thereof |
| CN107254133A (en) * | 2017-07-21 | 2017-10-17 | 安徽江淮汽车集团股份有限公司 | A kind of fire-retardant AES composite material of high tenacity and preparation method thereof |
| CN112480587A (en) * | 2020-11-27 | 2021-03-12 | 武汉金发科技有限公司 | High-weather-resistance flame-retardant ASA material for injection molding and preparation method and application thereof |
| CN112745619A (en) * | 2020-12-22 | 2021-05-04 | 金发科技股份有限公司 | Reinforced and toughened AES/PBAT alloy material and preparation method and application thereof |
| CN114196157A (en) * | 2021-11-30 | 2022-03-18 | 金发科技股份有限公司 | AES/POK alloy material, preparation method and application |
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| CN103740027A (en) * | 2013-12-27 | 2014-04-23 | 安徽科聚新材料有限公司 | Glass fiber reinforced AES composite material and preparation method thereof |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105647023A (en) * | 2014-11-10 | 2016-06-08 | 合肥杰事杰新材料股份有限公司 | Glass fiber reinforced AES resin material and preparation method thereof |
| CN104452095A (en) * | 2014-12-06 | 2015-03-25 | 常熟江南玻璃纤维有限公司 | Preparation method of glass fiber composite |
| CN104452096A (en) * | 2014-12-06 | 2015-03-25 | 常熟江南玻璃纤维有限公司 | Production process of glass fiber composite |
| CN104480629A (en) * | 2014-12-06 | 2015-04-01 | 常熟江南玻璃纤维有限公司 | Preparation method of glass fiber composite material |
| CN104480630A (en) * | 2014-12-06 | 2015-04-01 | 常熟江南玻璃纤维有限公司 | Preparation process of glass fiber composite material |
| CN104480631A (en) * | 2014-12-06 | 2015-04-01 | 常熟江南玻璃纤维有限公司 | Method used for producing glass fiber composite material |
| CN104452094A (en) * | 2014-12-06 | 2015-03-25 | 常熟江南玻璃纤维有限公司 | Production process of glass fiber composite |
| CN106147103A (en) * | 2015-04-01 | 2016-11-23 | 合肥杰事杰新材料股份有限公司 | A kind of fiberglass reinforced AES resin material and preparation method thereof |
| CN106280191A (en) * | 2015-06-11 | 2017-01-04 | 合肥杰事杰新材料股份有限公司 | A kind of fiberglass reinforced AES resin material and preparation method thereof |
| CN105369471A (en) * | 2015-12-15 | 2016-03-02 | 常熟江南玻璃纤维有限公司 | Technology for producing glass fiber composite |
| CN106928623A (en) * | 2017-03-20 | 2017-07-07 | 安徽江淮汽车集团股份有限公司 | A kind of flame-retarding high performance AES PVC composites and preparation method thereof |
| CN107254133A (en) * | 2017-07-21 | 2017-10-17 | 安徽江淮汽车集团股份有限公司 | A kind of fire-retardant AES composite material of high tenacity and preparation method thereof |
| CN112480587A (en) * | 2020-11-27 | 2021-03-12 | 武汉金发科技有限公司 | High-weather-resistance flame-retardant ASA material for injection molding and preparation method and application thereof |
| CN112745619A (en) * | 2020-12-22 | 2021-05-04 | 金发科技股份有限公司 | Reinforced and toughened AES/PBAT alloy material and preparation method and application thereof |
| CN112745619B (en) * | 2020-12-22 | 2022-10-04 | 金发科技股份有限公司 | Enhanced and toughened AES/PBAT alloy material as well as preparation method and application thereof |
| CN114196157A (en) * | 2021-11-30 | 2022-03-18 | 金发科技股份有限公司 | AES/POK alloy material, preparation method and application |
| CN114196157B (en) * | 2021-11-30 | 2023-11-14 | 金发科技股份有限公司 | AES/POK alloy material, preparation method and application |
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Application publication date: 20140917 |