CN105368320A - Novel ship bottom anti-fouling paint, and preparation method thereof - Google Patents
Novel ship bottom anti-fouling paint, and preparation method thereof Download PDFInfo
- Publication number
- CN105368320A CN105368320A CN201510904445.7A CN201510904445A CN105368320A CN 105368320 A CN105368320 A CN 105368320A CN 201510904445 A CN201510904445 A CN 201510904445A CN 105368320 A CN105368320 A CN 105368320A
- Authority
- CN
- China
- Prior art keywords
- bottom anti
- ship bottom
- fouling paint
- novel ship
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention provides a novel ship bottom anti-fouling paint, and a preparation method thereof. The novel ship bottom anti-fouling paint comprises, by weight, 30 to 50 parts of grease mud, 20 to 30 parts of iron oxide red powder, 20 to 40 parts of barium sulfate, 4 to 7 parts of 4-isopropylpyridine diphenyl borane, 10 to 20 parts of pengtong, 12 to 18 parts of rosin, 8 to 18 parts of ethyl oxime, and 5 to 8 parts of an accessory ingredient. The novel ship bottom anti-fouling paint is reasonable in composition, high in product quality stability, and excellent in antibacterial effect. The preparation method is simple, is high in production efficiency, low in application cost, simple in operation, and is convenient to realize; the quality of obtained products is stable; and popularization and application value is relatively high.
Description
Technical field
The invention belongs to paint production field, particularly, relate to a kind of novel ship bottom anti-fouling paint, and the preparation method of this novel ship bottom anti-fouling paint.
Background technology
Boats and ships the run into important problem that sails in a mighty ocean is exactly marine life to the attachment of hull bottom and stained.Part marine organisms are with fixed object apposition growth, and the hull bottom of underwater is the main base of biological attachment, and sea organism attachment brings high risks to ship's navigation.Halobiontic attachment can increase the friction resistance of boats and ships to seawater, causes fuel consumption increase, speed of a ship or plane reduction.In addition, bacterium, algae and microorganism etc. even can corrode hull further, cause damage, lead to grave consequences.
Therefore, antifouling varnish for boats and ships is a kind of special coating, it by activeconstituents as stain control agent, and be tentatively discharged in seawater with low-down speed and suppress and stop the marine life such as bacterium, algae and microorganism in the attachment of boats and ships and growth, thus keep boats and ships smooth outer surface and coating intact, under the prerequisite ensureing the normal speed of a ship or plane, reduce oil consumption to greatest extent and extend coating life, reducing unnecessary expenditures for maintenance.
In prior art, usually select antibacterial metal ions (as silver ions, cupric ion, zine ion, organoarsenic etc.) exchange adsorption is to (as zeolite powder, zirconium phosphate powder etc.) on porous carrier, antibacterial components is it can be used as to add in coating, when bacterium contacts, electronegative bacterial cell can attract metal ion to enter cell paste, combine closely with chemical substance electronegative in system, destroy the bioelectricity balance of system when bacterium is copied, cause bacterial body protein denaturation simultaneously, thus destroy breeding, kill bacterium.But cannot avoid Marine Pollution and Heavy Metal Accumulation, fish can eat dead algae, and fish are finally fished for by the mankind and cause heavy metal to enter human body, cause serious consequence.Therefore, international ocean organizational requirements, does not re-use the poisoning thing containing heavy metal in formula.
In addition, acrylic resin, acrylic resin derivative is mainly contained as zinc acrylate resin or acrylate resin, pitch and chlorinated rubber for the resin binder of antifouling varnish at present.But the antifouling varnish being base-material with acrylic resin, acrylic resin derivative, can produce certain stress under seawater and effect of sunlight, causes the loss of adhesion of antifouling varnish, occurs the mechanical deficiencies such as crackle or partial exfoliation, and paint film cracking comes off comparatively common.In addition the cost of manufacture of acrylic resin derivative is higher.Although pitch, chlorinated rubber are with low cost, can not produce mechanical deficiencies, pitch contains carcinogenic substance, and chlorinated rubber uses tetracol phenixin in preparation process, comparatively large to the harm of environment, does not meet environmental requirement.
Summary of the invention
Goal of the invention: in order to overcome above deficiency, the invention provides the preparation method of a kind of novel ship bottom anti-fouling paint and this novel ship bottom anti-fouling paint.
Technical scheme: the invention provides a kind of novel ship bottom anti-fouling paint, in components by weight percent, comprises following component:
In components by weight percent, comprise following component:
Grease mud 30-50 part
Iron oxide red 20-30 part
Barium sulfate 20-40 part
4-isopropyl pyridine diphenylmethyl borine 4-7 part
Boron leads to 10-20 part
Rosin 12-18 part
Second oxime 8-18 part
Auxiliary agent 5-8 part.
Novel ship bottom anti-fouling paint of the present invention, component is reasonable, not containing the heavy metal to pollution of the sea, and stability is good, wherein 4-isopropyl pyridine diphenylmethyl borine is a kind of new type bactericide of bioerodible, and it has the function of anti-bacteria, algae and microorganism growth, and sterilization effect is good, as the environmentally safe navigation ship bottom antifouling paint of one, can replace the compounds such as hypertoxic organoarsenic, organotin, Red copper oxide.
Further, above-mentioned novel ship bottom anti-fouling paint, described auxiliary agent, in components by weight percent, comprises following component:
Dispersion agent 2-3 part
Flow agent 1-3 part
Defoamer 0.3-1 part.
Adjuvant component is reasonable, ensure product with stable quality, and application cost is low.
Further, above-mentioned novel ship bottom anti-fouling paint, described 4-isopropyl pyridine diphenylmethyl borine is purity is 99.82%.Highly purified 4-isopropyl pyridine diphenylmethyl borine can effectively kill bacteria and algae.
Further, above-mentioned novel ship bottom anti-fouling paint, described grease mud is the grease mud of 60-70%.
Further, above-mentioned novel ship bottom anti-fouling paint, described barium sulfate is anhydrous slufuric acid barium.
Further, above-mentioned novel ship bottom anti-fouling paint, described rosin is superfine rosin.Superfine rosin makes described novel ship bottom anti-fouling paint steady quality, reliable.
The present invention also provides a kind of preparation method of novel ship bottom anti-fouling paint, comprises the steps:
(1) get grease mud 30-50 part, iron oxide red 20-30 part, barium sulfate 20-40 part, 4-isopropyl pyridine diphenylmethyl borine 4-7 part, boron leads to 10-20 part, rosin 12-18 part and second oxime 8-18 part, add in dispersion cylinder, high-speed stirring 2-3h;
(2) add 5-8 part auxiliary agent, continue high-speed stirring 1-1.5h;
(3) material in step (2) is added in sand mill carry out grinding 2-3h, through 100-150 mesh sieve;
(4) by material regrind 40-60min unsifted in step (3), through 100-150 mesh sieve;
(5) carry out measuring, packing.
The preparation method of novel ship bottom anti-fouling paint of the present invention, simple for process, production efficiency is high, and application cost is low, simple to operate, be easy to realize.Wherein take gradation to add main material and auxiliary agent, make mixing evenly, and make constant product quality, there is higher application value.
Further, the preparation method of above-mentioned novel ship bottom anti-fouling paint, the rotating speed of described high-speed stirring is more than 1800r/min.High-speed stirring is even, ensures stable and reliable product quality.
Preferred as one of the present invention, the preparation method of above-mentioned novel ship bottom anti-fouling paint, the rotating speed of described high-speed stirring is 1800-2200r/min.The high-speed stirring of 1800-2200r/min is easy to realize, and makes material stirring even simultaneously.
Further, the preparation method of above-mentioned novel ship bottom anti-fouling paint, described step (3), (4) are through 100-150 order vibratory screening apparatus.To be sieved process to the product after grinding by vibratory screening apparatus, level of automation is high, and filtration efficiency is high.
Beneficial effect: compared with prior art, the present invention has the following advantages: novel ship bottom anti-fouling paint of the present invention, and its component is reasonable, and not containing the heavy metal to pollution of the sea, and constant product quality is good, good anti-bacterial effect.The preparation method of novel ship bottom anti-fouling paint of the present invention, simple for process, production efficiency is high, and application cost is low, simple to operate, be easy to realize, the constant product quality of production, has higher application value.
Accompanying drawing explanation
Fig. 1 is the technical process of the preparation method of novel ship bottom anti-fouling paint of the present invention.
Embodiment
By several specific embodiment, will illustrate the present invention further below, these embodiments, just in order to describe the problem, are not a kind of restriction.
Embodiment 1
A preparation method for novel ship bottom anti-fouling paint, as shown in Figure 1, comprises the following steps:
(1) get 30 parts, the grease mud of 60%, iron oxide red 20 parts, anhydrous slufuric acid barium 20 parts, purity be 99.82% 4-isopropyl pyridine diphenylmethyl borine 4 parts, logical 10 parts of boron, superfine rosin 12 parts and second oxime 8 parts, add in dispersion cylinder, with 1800r/min high-speed stirring 2h;
(2) add 5 parts of auxiliary agents, continue with 1800r/min high-speed stirring 1h; Wherein, described auxiliary agent, in components by weight percent, comprises following component: dispersion agent 2 parts, flow agent 1 part and defoamer 0.3 part.
(3) material in step (2) is added in sand mill carry out grinding 2h, through 100 order vibratory screening apparatuss;
(4) by material regrind 40min unsifted in step (3), through 100 order vibratory screening apparatuss;
(5) carry out measuring, packing.
Embodiment 2
A preparation method for novel ship bottom anti-fouling paint, as shown in Figure 1, comprises the following steps:
(1) get 50 parts, the grease mud of 70%, iron oxide red 30 parts, anhydrous slufuric acid barium 40 parts, purity be 99.82% 4-isopropyl pyridine diphenylmethyl borine 7 parts, logical 20 parts of boron, superfine rosin 18 parts and second oxime 18 parts, add in dispersion cylinder, with 2200r/min high-speed stirring 3h;
(2) add 8 parts of auxiliary agents, continue with 2200r/min high-speed stirring 1.5h; Wherein, described auxiliary agent, in components by weight percent, comprises following component: dispersion agent 3 parts, flow agent 3 parts and defoamer 1 part.
(3) material in step (2) is added in sand mill carry out grinding 3h, through 150 order vibratory screening apparatuss;
(4) by material regrind 60min unsifted in step (3), through 150 order vibratory screening apparatuss;
(5) carry out measuring, packing.
Embodiment 3
A preparation method for novel ship bottom anti-fouling paint, as shown in Figure 1, comprises the following steps:
(1) get 40 parts, the grease mud of 63%, iron oxide red 25 parts, anhydrous slufuric acid barium 30 parts, purity be 99.82% 4-isopropyl pyridine diphenylmethyl borine 6 parts, logical 15 parts of boron, superfine rosin 16 parts and second oxime 15 parts, add in dispersion cylinder, with 2000r/min high-speed stirring 2.5h;
(2) add 6 parts of auxiliary agents, continue with 2000r/min high-speed stirring 1.2h; Wherein, described auxiliary agent, in components by weight percent, comprises following component: dispersion agent 2.5 parts, flow agent 2 parts and defoamer 0.5 part.
(3) material in step (2) is added in sand mill carry out grinding 2.5h, through 120 order vibratory screening apparatuss;
(4) by material regrind 50min unsifted in step (3), through 120 order vibratory screening apparatuss;
(5) carry out measuring, packing.
Embodiment 4
A preparation method for novel ship bottom anti-fouling paint, as shown in Figure 1, comprises the following steps:
(1) get 50 parts, the grease mud of 65%, iron oxide red 20 parts, anhydrous slufuric acid barium 30 parts, purity be 99.82% 4-isopropyl pyridine diphenylmethyl borine 7 parts, logical 20 parts of boron, superfine rosin 12 parts and second oxime 18 parts, add in dispersion cylinder, with 1800r/min high-speed stirring 3h;
(2) add 8 parts of auxiliary agents, continue with 1800r/min high-speed stirring 1.5h; Wherein, described auxiliary agent, in components by weight percent, comprises following component: dispersion agent 3 parts, flow agent 3 parts and defoamer 0.8 part.
(3) material in step (2) is added in sand mill carry out grinding 3h, through 150 order vibratory screening apparatuss;
(4) by material regrind 40min unsifted in step (3), through 150 order vibratory screening apparatuss;
(5) carry out measuring, packing.
The above is only several embodiments of invention, and it should be pointed out that for those skilled in the art, under the prerequisite not departing from inventive principle, can also make some improvement, these improvement also should be considered as protection scope of the present invention.
Claims (10)
1. a novel ship bottom anti-fouling paint, is characterized in that: in components by weight percent, comprises following component:
Grease mud 30-50 part
Iron oxide red 20-30 part
Barium sulfate 20-40 part
4-isopropyl pyridine diphenylmethyl borine 4-7 part
Boron leads to 10-20 part
Rosin 12-18 part
Second oxime 8-18 part
Auxiliary agent 5-8 part.
2. novel ship bottom anti-fouling paint according to claim 1, is characterized in that: described auxiliary agent, in components by weight percent, comprises following component:
Dispersion agent 2-3 part
Flow agent 1-3 part
Defoamer 0.3-1 part.
3. novel ship bottom anti-fouling paint according to claim 1, is characterized in that: described 4-isopropyl pyridine diphenylmethyl borine is purity is 99.82%.
4. novel ship bottom anti-fouling paint according to claim 1, is characterized in that: described barium sulfate is anhydrous slufuric acid barium.
5. novel ship bottom anti-fouling paint according to claim 1, is characterized in that: described grease mud is the grease mud of 60-70%.
6. novel ship bottom anti-fouling paint according to claim 1, is characterized in that: described rosin is superfine rosin.
7. a preparation method for novel ship bottom anti-fouling paint as claimed in claim 1, is characterized in that: comprise the steps:
(1) get grease mud 30-50 part, iron oxide red 20-30 part, barium sulfate 20-40 part, 4-isopropyl pyridine diphenylmethyl borine 4-7 part, boron leads to 10-20 part, rosin 12-18 part and second oxime 8-18 part, add in dispersion cylinder, high-speed stirring 2-3h;
(2) add 5-8 part auxiliary agent, continue high-speed stirring 1-1.5h;
(3) material in step (2) is added in sand mill carry out grinding 2-3h, through 100-150 mesh sieve;
(4) by material regrind 40-60min unsifted in step (3), through 100-150 mesh sieve;
(5) carry out measuring, packing.
8. want the preparation method of the novel ship bottom anti-fouling paint described in 7 according to right, it is characterized in that: the rotating speed of described high-speed stirring is more than 1800r/min.
9. the preparation method of novel ship bottom anti-fouling paint according to claim 8, is characterized in that: the rotating speed of described high-speed stirring is 1800-2200r/min.
10. the preparation method of novel ship bottom anti-fouling paint according to claim 7, is characterized in that: described step (3), (4) are through 100-150 order vibratory screening apparatus.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510904445.7A CN105368320A (en) | 2015-12-09 | 2015-12-09 | Novel ship bottom anti-fouling paint, and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510904445.7A CN105368320A (en) | 2015-12-09 | 2015-12-09 | Novel ship bottom anti-fouling paint, and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105368320A true CN105368320A (en) | 2016-03-02 |
Family
ID=55370972
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510904445.7A Pending CN105368320A (en) | 2015-12-09 | 2015-12-09 | Novel ship bottom anti-fouling paint, and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105368320A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106085241A (en) * | 2016-07-14 | 2016-11-09 | 苏州诚晟信息技术有限公司 | A kind of hull bottom antibiotic paint and preparation thereof and application process |
| CN106118392A (en) * | 2016-07-14 | 2016-11-16 | 苏州天键衡电子信息科技有限公司 | A kind of efficiently hull bottom antibiotic paint and preparation thereof and application process |
| CN106189854A (en) * | 2016-07-14 | 2016-12-07 | 苏州诚晟信息技术有限公司 | A kind of novel antirust antibiotic paint and preparation thereof and application process |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5795374A (en) * | 1996-04-17 | 1998-08-18 | Nof Corporation | Coating composition |
| CN101280148A (en) * | 2008-05-06 | 2008-10-08 | 常州市天安特种涂料有限公司 | Long-acting antifouling paint |
| CN101298533A (en) * | 2008-07-01 | 2008-11-05 | 南京建工集团有限公司 | Mildewproof waterproof coating composition |
| CN102408772A (en) * | 2011-11-01 | 2012-04-11 | 东南大学 | Composite varnish and preparation method thereof |
| CN102702977A (en) * | 2012-06-12 | 2012-10-03 | 天长市巨龙车船涂料有限公司 | Anti-fouling paint |
-
2015
- 2015-12-09 CN CN201510904445.7A patent/CN105368320A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5795374A (en) * | 1996-04-17 | 1998-08-18 | Nof Corporation | Coating composition |
| US5795374C1 (en) * | 1996-04-17 | 2002-03-05 | Nof Corp | Coating composition |
| CN101280148A (en) * | 2008-05-06 | 2008-10-08 | 常州市天安特种涂料有限公司 | Long-acting antifouling paint |
| CN101298533A (en) * | 2008-07-01 | 2008-11-05 | 南京建工集团有限公司 | Mildewproof waterproof coating composition |
| CN102408772A (en) * | 2011-11-01 | 2012-04-11 | 东南大学 | Composite varnish and preparation method thereof |
| CN102702977A (en) * | 2012-06-12 | 2012-10-03 | 天长市巨龙车船涂料有限公司 | Anti-fouling paint |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106085241A (en) * | 2016-07-14 | 2016-11-09 | 苏州诚晟信息技术有限公司 | A kind of hull bottom antibiotic paint and preparation thereof and application process |
| CN106118392A (en) * | 2016-07-14 | 2016-11-16 | 苏州天键衡电子信息科技有限公司 | A kind of efficiently hull bottom antibiotic paint and preparation thereof and application process |
| CN106189854A (en) * | 2016-07-14 | 2016-12-07 | 苏州诚晟信息技术有限公司 | A kind of novel antirust antibiotic paint and preparation thereof and application process |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102807796B (en) | Novel environment-friendly anti-fouling coating paint for ocean | |
| CN105368320A (en) | Novel ship bottom anti-fouling paint, and preparation method thereof | |
| CN102807797B (en) | Efficient marine antifouling coating and broad-spectrum controlled-release antifouling agent for same | |
| CN103819986A (en) | Gray marine antifouling paint without copper compound and preparation method of gray marine antifouling paint | |
| CN102977744A (en) | Nano-composite marine anti-fouling coating material and preparation method thereof | |
| WO2001072911A1 (en) | Antifouling paint composition comprising rosin and enzyme | |
| CN101550304A (en) | Environment-friendly marine antifouling coating for finishing boat | |
| CN107286775A (en) | A kind of aqueous antifouling and antibiosis electrically-conducting paint | |
| CN104365668B (en) | Environment-friendly long-life is combined anti-fouling material | |
| CN111286273A (en) | Novel long-acting broad-spectrum antibacterial multifunctional water-based building coating and preparation method thereof | |
| CN101696340A (en) | Strippable anti-fouling paint | |
| CN110358396A (en) | A kind of long-acting controlled release marine antifouling coating | |
| CN101974270A (en) | Antibiotic waterproof coating | |
| CN102939959B (en) | Biological composite material loading nano-silver particle | |
| CN101824261B (en) | Micro-gel surface marine antifouling paint | |
| CN106905780A (en) | A kind of capsicim environmental protection type anti-pollution paint and preparation method thereof | |
| CN107986412B (en) | Modified clay system for controlling harmful algal blooms in aquaculture water | |
| CN103947691B (en) | A kind of hydrogen peroxide/polymeric aluminum sulfate silicate compound cyanophyte inorganic agent and preparation method thereof | |
| CN102952451A (en) | Preparation method of water-based chlorinated polyvinyl chloride anti-corrosive paint | |
| CN108329783B (en) | Marine antifouling paint and preparation method thereof | |
| CN114806307B (en) | Rare earth-based complex environment-friendly marine antifouling paint and preparation method thereof | |
| CN103396712A (en) | Hydrolyzed marine antifouling paint and preparation method thereof | |
| CN108753104A (en) | A kind of hull bottom high-efficiency antimicrobial coating and preparation method thereof | |
| CN110484139A (en) | A kind of capsaicine anti-fouling paint | |
| CN106118337A (en) | A kind of high-quality hull bottom antibiotic paint and preparation thereof and application process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160302 |