CN110484139A - A kind of capsaicine anti-fouling paint - Google Patents
A kind of capsaicine anti-fouling paint Download PDFInfo
- Publication number
- CN110484139A CN110484139A CN201910627078.9A CN201910627078A CN110484139A CN 110484139 A CN110484139 A CN 110484139A CN 201910627078 A CN201910627078 A CN 201910627078A CN 110484139 A CN110484139 A CN 110484139A
- Authority
- CN
- China
- Prior art keywords
- parts
- capsaicine
- fouling
- fouling paint
- marine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- YKPUWZUDDOIDPM-SOFGYWHQSA-N capsaicin Chemical compound COC1=CC(CNC(=O)CCCC\C=C\C(C)C)=CC=C1O YKPUWZUDDOIDPM-SOFGYWHQSA-N 0.000 title claims abstract description 44
- 229960002504 capsaicin Drugs 0.000 title claims abstract description 44
- 239000003973 paint Substances 0.000 title claims abstract description 43
- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 40
- 239000000203 mixture Substances 0.000 claims abstract description 15
- 239000002519 antifouling agent Substances 0.000 claims abstract description 9
- 239000011230 binding agent Substances 0.000 claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- 239000000945 filler Substances 0.000 claims abstract description 5
- 239000000049 pigment Substances 0.000 claims abstract description 5
- 239000004014 plasticizer Substances 0.000 claims abstract description 5
- 239000002904 solvent Substances 0.000 claims abstract description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 24
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 24
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 24
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 24
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 12
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 12
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 12
- 239000003822 epoxy resin Substances 0.000 claims description 12
- 239000012188 paraffin wax Substances 0.000 claims description 12
- 229920000647 polyepoxide Polymers 0.000 claims description 12
- 229920000570 polyether Polymers 0.000 claims description 12
- 229920005989 resin Polymers 0.000 claims description 12
- 239000011347 resin Substances 0.000 claims description 12
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 12
- 235000005074 zinc chloride Nutrition 0.000 claims description 12
- 239000011592 zinc chloride Substances 0.000 claims description 12
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 11
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims description 8
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 claims description 8
- 229940112669 cuprous oxide Drugs 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 abstract description 6
- 238000000576 coating method Methods 0.000 abstract description 6
- 231100000614 poison Toxicity 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 235000002566 Capsicum Nutrition 0.000 abstract description 3
- 239000001390 capsicum minimum Substances 0.000 abstract description 3
- 239000002574 poison Substances 0.000 abstract description 3
- 239000000654 additive Substances 0.000 abstract description 2
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 2
- 235000013305 food Nutrition 0.000 abstract description 2
- 238000003860 storage Methods 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- 240000008574 Capsicum frutescens Species 0.000 abstract 1
- 239000000284 extract Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- YVGGHNCTFXOJCH-UHFFFAOYSA-N DDT Chemical compound C1=CC(Cl)=CC=C1C(C(Cl)(Cl)Cl)C1=CC=C(Cl)C=C1 YVGGHNCTFXOJCH-UHFFFAOYSA-N 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 3
- 239000013535 sea water Substances 0.000 description 3
- 241000208293 Capsicum Species 0.000 description 2
- 241000238586 Cirripedia Species 0.000 description 2
- 241000195493 Cryptophyta Species 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 239000003139 biocide Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 241000251557 Ascidiacea Species 0.000 description 1
- 241001474374 Blennius Species 0.000 description 1
- 241000700670 Bryozoa Species 0.000 description 1
- 241000345998 Calamus manan Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 206010019851 Hepatotoxicity Diseases 0.000 description 1
- 206010029350 Neurotoxicity Diseases 0.000 description 1
- 241000237502 Ostreidae Species 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 206010044221 Toxic encephalopathy Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229930013930 alkaloid Natural products 0.000 description 1
- 150000003797 alkaloid derivatives Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000975 bioactive effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000007686 hepatotoxicity Effects 0.000 description 1
- 231100000304 hepatotoxicity Toxicity 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000007135 neurotoxicity Effects 0.000 description 1
- 231100000228 neurotoxicity Toxicity 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 235000012950 rattan cane Nutrition 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000759 toxicological effect Toxicity 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 230000004584 weight gain Effects 0.000 description 1
- 235000019786 weight gain Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D193/00—Coating compositions based on natural resins; Coating compositions based on derivatives thereof
- C09D193/04—Rosin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1625—Non-macromolecular compounds organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C08K2003/168—Zinc halides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A kind of capsaicine anti-fouling paint, it is characterised in that: its composition is with mass fraction representation are as follows: 16-31 parts of binder, 4-8 parts of plasticizer, 23-42 parts of pigments and fillers, 1-10 parts of capsaicine, 2-4 parts of anti-settling agent, 11-20 parts of solvent.Compared with the prior art, the present invention extracts capsaicine as anti-fouling agent from natural capsicum, is not influenced by temperature, and has the function of good antibacterial, drives away marine attaching organism.Compared with other chemical classes coating additives, capsaicine antifouling paint will not poison aufwuch, lead to biomutation, will not destroy marine food chain or Marine water is caused to pollute.In addition, the storage stability of capsaicine anti-fouling paint is good, there is good matching with other antirust paints etc..
Description
Technical field
The invention belongs to marine fouling organism Prevention Technique fields, and in particular to a kind of capsaicine anti-fouling paint.
Background technique
Ocean is there is up to more than 4500 kinds of marine growths, and wherein marine fouling organism is otherwise known as marine attaching organism, is
Grow the alow general name with the animal on other marine facility surfaces, plant and microorganism.Marine attaching organism is many kinds of,
Middle harm it is larger and more typical have barnacle, oyster, ascidian, seaweed etc., they can be attached to the surface of solids in seawater into
Row growth and breeding, especially in oxygen and sun-drenched surface seawater section.In the seawater due to hull bottom part long period of soaking,
Therefore it is stained seriously by marine organisms, these biologies will increase the self weight and ship resistance of ship, the increased fuel consumption of institute
Expect the CO that the year two thousand twenty will increase 38%-72%2And SO2Discharge amount, increase from global warming；In addition the attachment of marine fouling organism
Process can generate a large amount of acid mediums, accelerate ship outer casing corrosion, shorten hull service life；Furthermore new species can be brought to
Strange land threatens the local ecosystem.Therefore marine biofouling problem is engaged in the weight encountered since Activities of Ocean as the mankind
One of hang-up effectively prevents marine biofouling from becoming domestic and international research hotspot.
It is that marine biofouling problem economy is again efficient in ocean structure external coating antifouling paint in anti-soil technology
Important channel.The mechanism that antifouling paint inhibits marine fouling organism attachment is mainly to rely on the exudation of toxic biocide in system,
Marine fouling organism is killed or inhibited by the toxicological effect of biocide.Traditional antifouling paint generally uses organic tributyl
Organic poisons such as tin (TBT), dichlorodiphenyltrichloroethane (DDT), wherein the coating containing organotin anti-fouling agent is that effect is best
It is most widely used, studies have found that, organotin anti-fouling agent has certain solubility marine, can be to ocean substance and ocean ring
Border damages, and seriously threatens the existence of other marine organisms, therefore International Maritime the convention (IMO) the proposition whole world in 2008
Stop using the antifouling paint containing organotin (TBT)；DDT has efficient insecticidal function, and China's 60-80 age in 20th century is big
Amount uses, but since it is with neurotoxicity, hepatotoxicity wind agitation etc., very big to human body and environmental hazard, nineteen eighty-three, China started to limit
The production and use of DDT.Therefore replace poisonous anti-fouling agent very urgent using new environment-friendly antifouling agent.
Summary of the invention
In order to solve the above technical problems, the present invention provides a kind of capsaicine anti-fouling paints.
To achieve the above object, the present invention is achieved through the following technical solutions: a kind of capsaicine anti-fouling paint, special
Sign is: its composition is with mass fraction representation are as follows: and 16-31 parts of binder, 4-8 parts of plasticizer, 23-42 parts of pigments and fillers,
1-10 parts of anti-fouling agent, 2-4 parts of anti-settling agent, 11-20 parts of solvent.
As a preferred option, above-mentioned anti-fouling agent is capsaicine.
As a preferred option, above-mentioned binder is by 0.1-0.2 parts of epoxy resin, 10-18 parts of rosin resin and chlorination
6-12 parts of polyethers.
As a preferred option, above-mentioned plasticizer is chlorinated paraffin.
As a preferred option, above-mentioned pigments and fillers by 9-16 parts of zinc chloride, 1-2 parts of iron oxide red, 4-8 parts of talcum powder and
9-16 parts of barium sulfate compositions.
As a preferred option, above-mentioned anti-settling agent is Monoral 3300.
As a preferred option, above-mentioned solvent is dimethylbenzene.
As a preferred option, cuprous oxide 30-34 parts is also added.
Beneficial effects of the present invention: capsaicine anti-fouling paint is the bioactive substance extracted from natural capsicum and does not contain
The fluoride of machine heavy metal does not destroy marine organisms chain as repellant.Capsaicine as a kind of stable alkaloid, not by
The influence of temperature, and have the function of antibacterial, drive away marine attaching organism.Compared with other chemical classes coating additives, capsicum
Plain antifouling paint will not poison aufwuch, lead to biomutation, will not destroy marine food chain or cause Marine water dirty
Dye.In addition, the storage stability of capsaicine anti-fouling paint is good, there is good matching with other antirust paints etc..
Specific embodiment
Embodiment 1
A kind of capsaicine anti-fouling paint, it is characterised in that: its composition is with mass fraction representation are as follows: 0.16 part of epoxy resin,
17.52 parts of rosin resin, 11.39 parts of chlorinated polyether, 7.60 parts of chlorinated paraffin, 15.14 parts of zinc chloride, 1.90 parts of iron oxide red,
7.28 parts of talcum powder, 15.03 parts of barium sulfate, 1 part of capsaicine, Monoral 3300 is 3.96 parts, 19.02 parts of dimethylbenzene.
Embodiment 2
A kind of capsaicine anti-fouling paint, it is characterised in that: its composition is with mass fraction representation are as follows: 0.16 part of epoxy resin,
17.17 parts of rosin resin, 11.16 parts of chlorinated polyether, 7.44 parts of chlorinated paraffin, 14.84 parts of zinc chloride, 1.86 parts of iron oxide red,
7.13 parts of talcum powder, 14.73 parts of barium sulfate, 3 parts of capsaicine, Monoral 3300 is 3.87 parts, 18.64 parts of dimethylbenzene.
Embodiment 3
A kind of capsaicine anti-fouling paint, it is characterised in that: its composition is with mass fraction representation are as follows: 0.15 part of epoxy resin,
16.81 parts of rosin resin, 10.93 parts of chlorinated polyether, 7.29 parts of chlorinated paraffin, 14.53 parts of zinc chloride, 1.82 parts of iron oxide red,
6.99 parts of talcum powder, 14.42 parts of barium sulfate, 5 parts of capsaicine, Monoral 3300 is 3.80 parts, 18.25 parts of dimethylbenzene.
Embodiment 4
A kind of capsaicine anti-fouling paint, it is characterised in that: its composition is with mass fraction representation are as follows: 0.15 part of epoxy resin,
16.28 parts of rosin resin, 10.59 parts of chlorinated polyether, 7.05 parts of chlorinated paraffin, 14.07 parts of zinc chloride, 1.77 parts of iron oxide red,
6.76 parts of talcum powder, 13.97 parts of barium sulfate, 8 parts of capsaicine, Monoral 3300 is 3.68 parts, 17.68 parts of dimethylbenzene.
Embodiment 5
A kind of capsaicine anti-fouling paint, it is characterised in that: its composition is with mass fraction representation are as follows: 0.15 part of epoxy resin,
15.93 parts of rosin resin, 10.36 parts of chlorinated polyether, 6.90 parts of chlorinated paraffin, 13.77 parts of zinc chloride, 1.73 parts of iron oxide red,
6.62 parts of talcum powder, 13.67 parts of barium sulfate, 10 parts of capsaicine, Monoral 3300 is 3.60 parts, 17.29 parts of dimethylbenzene.
Experimental example 1
According to the requirement of GB9271 " paint and varnish standard plaque " and GB1727 " paint film is typically prepared method ", matching performance is made
Template, template are general steel plate, prepare the identical template of 60 block size shapes altogether, and be equally divided into six groups；1-5 group template point
The antifouling paint of coating embodiment 1-5 is not corresponded to, and film thickness is controlled at 200 μm or so；6th group of template coating Commercial epoxy ship
Oceangoing ship anti-decaying paint, smearing thickness are controlled at 200 μm or so.
Then, according to the anti-pollution of GB5370 " anti-fouling paint template shallow sea immersion test method " test 1-5 group steel plate.
Testing location is in the offshore sea waters of south China subtropical zone, and the sea area briny environment feature is obvious, and marine animal is many kinds of,
Grow throughout the year vigorous, primary biological has more than 14 kinds of algae such as barnacle, bryozoan, rattan algae and 70 marine animal.
Respectively at interval of 1 month to 1-6 group template carry out surface biological be stained situation detection, and to template increase weight quality into
Row measurement, specific test result is as follows:
Meanwhile during the test, do not find test board it is attached do not find test caused by marine organisms it is dead
Die phenomenon.
By above-mentioned test result it is found that antifouling paint of the present invention has good anti-fouling effect, have to marine attaching organism
Have and good walks quickly and keeps away effect.
The embodiment of cuprous oxide is added, as follows:
Embodiment 6
A kind of capsaicine anti-fouling paint, it is characterised in that: its composition is with mass fraction representation are as follows: 33.52 parts of cuprous oxide,
0.11 part of epoxy resin, 11.59 parts of rosin resin, 7.54 parts of chlorinated polyether, 5.02 parts of chlorinated paraffin, 10.02 parts of zinc chloride, oxygen
Change 1.26 parts of iron oxide red, 4.81 parts of talcum powder, 9.94 parts of barium sulfate, 1 part of capsaicine, Monoral 3300 is 2.62 parts, dimethylbenzene
12.58 parts.
Embodiment 7
A kind of capsaicine anti-fouling paint, it is characterised in that: its composition is with mass fraction representation are as follows: 32.85 parts of cuprous oxide,
0.10 part of epoxy resin, 11.35 parts of rosin resin, 7.38 parts of chlorinated polyether, 4.92 parts of chlorinated paraffin, 9.81 parts of zinc chloride, oxygen
Change 1.23 parts of iron oxide red, 4.72 parts of talcum powder, 9.74 parts of barium sulfate, 3 parts of capsaicine, Monoral 3300 is 2.55 parts, dimethylbenzene
12.33 parts.
Embodiment 8
A kind of capsaicine anti-fouling paint, it is characterised in that: its composition is with mass fraction representation are as follows: 32.17 parts of cuprous oxide,
0.10 part of epoxy resin, 11.12 parts of rosin resin, 7.23 parts of chlorinated polyether, 4.82 parts of chlorinated paraffin, 9.61 parts of zinc chloride, oxygen
Change 1.21 parts of iron oxide red, 4.62 parts of talcum powder, 9.54 parts of barium sulfate, 5 parts of capsaicine, Monoral 3300 is 2.51 parts, dimethylbenzene
12.07 parts.
Embodiment 9
A kind of capsaicine anti-fouling paint, it is characterised in that: its composition is with mass fraction representation are as follows: 31.15 parts of cuprous oxide,
0.10 part of epoxy resin, 10.77 parts of rosin resin, 7.00 parts of chlorinated polyether, 4.67 parts of chlorinated paraffin, 9.31 parts of zinc chloride, oxygen
Change 1.17 parts of iron oxide red, 4.47 parts of talcum powder, 9.24 parts of barium sulfate, 8 parts of capsaicine, Monoral 3300 is 2.43 parts, dimethylbenzene
11.69 parts.
Embodiment 10
A kind of capsaicine anti-fouling paint, it is characterised in that: its composition is with mass fraction representation are as follows: 30.48 parts of cuprous oxide,
0.10 part of epoxy resin, 10.53 parts of rosin resin, 6.85 parts of chlorinated polyether, 4.57 parts of chlorinated paraffin, 9.10 parts of zinc chloride, oxygen
Change 1.14 parts of iron oxide red, 4.38 parts of talcum powder, 9.04 parts of barium sulfate, 10 parts of capsaicine, Monoral 3300 is 2.38 parts, dimethylbenzene
11.44 parts.
Experimental example 2
According to the capsaicine anti-fouling paint of the identical method of experimental example 1 preparation comparative example 1-5, while according to side described in experimental example 1
Method prepares template, divides five groups, is successively named as 7-11 group, and carries out surface life to the template of 7-11 group in identical sea area
Object is stained situation detection, and measures to template weight gain quality, and specific test result is as follows:
Meanwhile during the test, do not find test board it is attached do not find test caused by marine organisms it is dead
Die phenomenon.
By above-mentioned test result it is found that antifouling paint of the present invention has good anti-fouling effect, have to marine attaching organism
Have and good walks quickly and keeps away effect.
The present invention is only disclosed with preferred embodiment above, so it is not intended to limiting the invention, all to use equivalent replacement
Or equivalent transformation mode technical solution obtained, it is within the scope of the present invention.
Claims (8)
1. a kind of capsaicine anti-fouling paint, it is characterised in that: its composition is with mass fraction representation are as follows: 16-31 parts of binder,
4-8 parts of plasticizer, 23-42 parts of pigments and fillers, 1-10 parts of anti-fouling agent, 2-4 parts of anti-settling agent, 11-20 parts of solvent.
2. a kind of capsaicine anti-fouling paint according to claim 1, which is characterized in that the anti-fouling agent is capsaicine.
3. a kind of capsaicine anti-fouling paint according to claim 1, which is characterized in that the binder is by epoxy resin
0.1-0.2 parts, 10-18 parts of rosin resin and 6-12 parts of chlorinated polyether.
4. a kind of capsaicine anti-fouling paint according to claim 1, which is characterized in that the plasticizer is chlorinated paraffin.
5. a kind of capsaicine anti-fouling paint according to claim 1, which is characterized in that the pigments and fillers are by zinc chloride 9-16
Part, 1-2 parts of iron oxide red, 4-8 parts of talcum powder and 9-16 parts of barium sulfate compositions.
6. a kind of capsaicine anti-fouling paint according to claim 1, which is characterized in that the anti-settling agent is Monoral
3300。
7. a kind of capsaicine anti-fouling paint according to claim 1, which is characterized in that can also add 30-34 parts of cuprous oxide.
8. a kind of capsaicine anti-fouling paint according to claim 1, which is characterized in that the solvent is dimethylbenzene.
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