CN103947691B - A kind of hydrogen peroxide/polymeric aluminum sulfate silicate compound cyanophyte inorganic agent and preparation method thereof - Google Patents
A kind of hydrogen peroxide/polymeric aluminum sulfate silicate compound cyanophyte inorganic agent and preparation method thereof Download PDFInfo
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- CN103947691B CN103947691B CN201410159012.9A CN201410159012A CN103947691B CN 103947691 B CN103947691 B CN 103947691B CN 201410159012 A CN201410159012 A CN 201410159012A CN 103947691 B CN103947691 B CN 103947691B
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Abstract
The invention discloses a kind of hydrogen peroxide/polymeric aluminum sulfate silicate compound cyanophyte inorganic agent, it is characterized in that, be made up of the raw material of following weight portion: polymeric aluminum sulfate silicate 26-29, alum 18-20, H
2o
213-15, ligninsulfonate 16-18, Ammonium Persulfate 98.5 14-17, potassium sorbate powder 19-20, sawdust 17-19, cepehalotaxus fortunei root 16-20, corncob 17-21, eucalyptus leaves 10-13, coptis 1-3, golden cypress 2-5; The blue algae treatment agent waste water treatment speed that the present invention obtains is fast, effectively can remove in large-scale shallow water lake the provenance of bloom blue algae of surviving the winter, administer from source to blue-green alga bloom, is a control and the new way controlling harmful algal blooms generation.
Description
Technical field
The present invention relates to water-treatment technology field, be specifically related to a kind of hydrogen peroxide/polymeric aluminum sulfate silicate compound cyanophyte inorganic agent and preparation method thereof.
Background technology
In recent years, along with the continuous increase of China's size of population and developing rapidly of industrial and agricultural production, water requirement rapidly increases, and water pollutions is more and more serious simultaneously.Water pollutions is that world today's pollution is the most serious, one of pollution that harmfulness is maximum, China's quantity of wastewater effluent is large, the pollutant in the rivers and lakes water bodys such as Taihu Lake is caused to grow with each passing day, pollution speed has exceeded the detergent power of lake body self, some of them are phosphorous, a large amount of discharges of nitrogen-containing compound, accelerate rivers and lakes eutrophication process, cause algae particularly blue-green algae distorted proliferation growth, and form one deck blue-green at the water surface and have offscum and the wawter bloom of bad smell, release stench, makes water quality degenerate.Large-scale blue algae bloom, is called as " green tide ", exhausts water oxygen gas and cause the death of fish time serious.More seriously, in blue-green algae, some kind (as Microcystis aeruginosa) also can produce Microcystin (microcystins is called for short MCs), containing a large amount of MCs in the green tide of about 50%.MCs, except directly producing except murder by poisoning to fish, people and animals, is also the major incentive of liver cancer.
Blue-green algae harnessing project is a complicated system engineering.The main method taked the at present manpower and materials that still environmental input is a large amount of outside carry out drawing the mode that dirt removal clearly, resettlement contaminating enterprises etc. transfer the pollution, not from contaminated solution root; In environment improvement, bioanalysis (comprising microbial method, animal law, plant method), the method for all kinds of improvement blue-green algae of chemical method and inorganic agent has in succession been there is although domestic, but be still difficult to so far obtain extensively, effectively applying, main cause be that existing Treatment process is single, process is complicated, functional not high.
Summary of the invention
Object of the present invention is just to provide a kind of hydrogen peroxide/polymeric aluminum sulfate silicate compound cyanophyte inorganic agent and preparation method thereof, to overcome the deficiencies in the prior art.
The object of the present invention is achieved like this:
A kind of hydrogen peroxide/polymeric aluminum sulfate silicate compound cyanophyte inorganic agent, is characterized in that, be made up of the raw material of following weight portion: polymeric aluminum sulfate silicate 26-29, alum 18-20, H
2o
213-15, ligninsulfonate 16-18, Ammonium Persulfate 98.5 14-17, potassium sorbate powder 19-20, sawdust 17-19, cepehalotaxus fortunei root 16-20, corncob 17-21, eucalyptus leaves 10-13, coptis 1-3, golden cypress 2-5.
The preparation method of described a kind of hydrogen peroxide/polymeric aluminum sulfate silicate compound cyanophyte inorganic agent, is characterized in that comprising the following steps:
(1) cepehalotaxus fortunei root, corncob, eucalyptus leaves, the coptis, golden cypress decocted 2-3 hour together in water and filter, getting its filtrate and flood 30 minutes together with sawdust, drying, be ground into powder;
(2) filter residue of step (1) is sent in retort, calcination processing 3-4 hour at 545-665 DEG C, take out and spray H
2o
2mix 50-60 minute, dry, be ground into powder;
(3) by alum and ligninsulfonate mixing 30-40 minute, add Ammonium Persulfate 98.5 mixing 45-50 minute, then add potassium sorbate powder mixing 50-60 minute;
(4) by step (1), (2), (3) reaction mass and other residual componentss mixing 120-150 minute.
The present invention has following beneficial effect: the blue algae treatment agent that the present invention obtains is a kind of environmentally friendly algae-inhibiting agent, waste water treatment speed is fast, the processing time is short, effectively can remove in large-scale shallow water lake the provenance of bloom blue algae of surviving the winter, administering blue-green alga bloom from source, is a control and the new way controlling harmful algal blooms generation.
Embodiment
Described a kind of hydrogen peroxide/polymeric aluminum sulfate silicate compound cyanophyte inorganic agent, is characterized in that, be made up of the raw material of following weight portion: polymeric aluminum sulfate silicate 29, alum 18, H
2o
213, ligninsulfonate 18, Ammonium Persulfate 98.5 14, potassium sorbate powder 20, sawdust 19, cepehalotaxus fortunei root 17, corncob 21, eucalyptus leaves 13, the coptis 1, golden cypress 5.
Preparation method comprises the following steps:
(1) cepehalotaxus fortunei root, corncob, eucalyptus leaves, the coptis, golden cypress decocted 2-3 hour together in water and filter, getting its filtrate and flood 30 minutes together with sawdust, drying, be ground into powder;
(2) filter residue of step (1) is sent in retort, calcination processing 3-4 hour at 545-665 DEG C, take out and spray H
2o
2mix 50-60 minute, dry, be ground into powder;
(3) by alum and ligninsulfonate mixing 30-40 minute, add Ammonium Persulfate 98.5 mixing 45-50 minute, then add potassium sorbate powder mixing 50-60 minute;
(4) by step (1), (2), (3) reaction mass and other residual componentss mixing 120-150 minute.
Use blue algae treatment agent of the present invention as shown in the table to wastewater suspended substance clean-up effect:
Table 1 Composite powdery blue algae treatment agent wastewater suspended substance clean-up effect
Claims (1)
1. hydrogen peroxide/polymeric aluminum sulfate silicate compound cyanophyte inorganic agent, is characterized in that, be made up of the raw material of following weight portion: polymeric aluminum sulfate silicate 26-29, alum 18-20, H
2o
213-15, ligninsulfonate 16-18, Ammonium Persulfate 98.5 14-17, potassium sorbate powder 19-20, sawdust 17-19, cepehalotaxus fortunei root 16-20, corncob 17-21, eucalyptus leaves 10-13, coptis 1-3, golden cypress 2-5;
The preparation method of described a kind of hydrogen peroxide/polymeric aluminum sulfate silicate compound cyanophyte inorganic agent comprises the following steps:
(1) cepehalotaxus fortunei root, corncob, eucalyptus leaves, the coptis, golden cypress decocted 2-3 hour together in water and filter, getting its filtrate and flood 30 minutes together with sawdust, drying, be ground into powder;
(2) filter residue of step (1) is sent in retort, calcination processing 3-4 hour at 545-665 DEG C, take out and spray H
2o
2mix 50-60 minute, dry, be ground into powder;
(3) by alum and ligninsulfonate mixing 30-40 minute, add Ammonium Persulfate 98.5 mixing 45-50 minute, then add potassium sorbate powder mixing 50-60 minute;
(4) by the material obtained by step (1), (2), (3) and other residual componentss mixing 120-150 minute.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410159012.9A CN103947691B (en) | 2014-04-18 | 2014-04-18 | A kind of hydrogen peroxide/polymeric aluminum sulfate silicate compound cyanophyte inorganic agent and preparation method thereof |
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| CN201410159012.9A CN103947691B (en) | 2014-04-18 | 2014-04-18 | A kind of hydrogen peroxide/polymeric aluminum sulfate silicate compound cyanophyte inorganic agent and preparation method thereof |
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| CN103947691A CN103947691A (en) | 2014-07-30 |
| CN103947691B true CN103947691B (en) | 2016-04-27 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105016437A (en) * | 2015-07-22 | 2015-11-04 | 合肥一诺生物科技有限公司 | Blue algae processing agent with water purification function and preparation method thereof |
| CN105104452A (en) * | 2015-07-22 | 2015-12-02 | 合肥一诺生物科技有限公司 | High-efficiency cyanobacteria treating agent, and preparation method thereof |
| CN105645631A (en) * | 2015-12-31 | 2016-06-08 | 鑫泰沣（天津）环保科技发展有限公司 | Water treatment method |
| CN112056329B (en) * | 2020-08-28 | 2021-09-07 | 山东省海洋生物研究院 | Seawater microalgae regulating agent and microalgae phase regulating method using same |
Citations (5)
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| US20060128584A1 (en) * | 2004-06-18 | 2006-06-15 | Garris John P | Calcium hypochlorite compositions |
| CN101381136A (en) * | 2008-10-10 | 2009-03-11 | 仙桃市中楚化工有限责任公司 | High-efficiency broadspectrum flocculant and preparation method thereof |
| CN101468838A (en) * | 2007-12-24 | 2009-07-01 | 鞍钢集团矿业公司 | Method for preparing composite water purification agent |
| WO2009121123A1 (en) * | 2008-04-01 | 2009-10-08 | Ultimate Nominees Pty Ltd | Non-toxic liquids for water treatment |
| CN103253752A (en) * | 2013-05-29 | 2013-08-21 | 滁州友林科技发展有限公司 | High-efficiency flocculant |
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2014
- 2014-04-18 CN CN201410159012.9A patent/CN103947691B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060128584A1 (en) * | 2004-06-18 | 2006-06-15 | Garris John P | Calcium hypochlorite compositions |
| CN101468838A (en) * | 2007-12-24 | 2009-07-01 | 鞍钢集团矿业公司 | Method for preparing composite water purification agent |
| WO2009121123A1 (en) * | 2008-04-01 | 2009-10-08 | Ultimate Nominees Pty Ltd | Non-toxic liquids for water treatment |
| CN101381136A (en) * | 2008-10-10 | 2009-03-11 | 仙桃市中楚化工有限责任公司 | High-efficiency broadspectrum flocculant and preparation method thereof |
| CN103253752A (en) * | 2013-05-29 | 2013-08-21 | 滁州友林科技发展有限公司 | High-efficiency flocculant |
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Effective date of registration: 20180716 Address after: 242000 Gao Yang village, Huayang Town, Jixi County, Xuancheng, Anhui (National Grain Reserve Bank) Patentee after: Jixi Yuan Dao agricultural industry Science and Technology Ltd. Address before: 241000 international student Park 320, Wuhu economic and Technological Development Zone, Anhui Patentee before: ANHUI ZHONGRI AGRICULTURE ENVIRONMENTAL TECHNOLOGY CO., LTD. |
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