CN103936126B - Modified carbon black/ferric aluminum polysilicate composite blue algae treating agent and manufacturing method thereof - Google Patents
Modified carbon black/ferric aluminum polysilicate composite blue algae treating agent and manufacturing method thereof Download PDFInfo
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- CN103936126B CN103936126B CN201410158521.XA CN201410158521A CN103936126B CN 103936126 B CN103936126 B CN 103936126B CN 201410158521 A CN201410158521 A CN 201410158521A CN 103936126 B CN103936126 B CN 103936126B
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Abstract
The invention discloses a modified carbon black/ferric aluminum polysilicate composite blue algae treating agent. The invention is characterized in that the treating agent is prepared from the following raw materials in parts by weight: 28-30 parts of ferric aluminum polysilicate, 18-20 parts of carbon black, 15-18 parts of sodium stearate, 19-21 parts of Cinnamomum camphora fruit, 17-19 parts of fulvic acid, 16-18 parts of aluminum sulfate, 20-22 parts of calcium oxide, 15-17 parts of sodium carbonate, 2-4 parts of malt, 3-5 parts of angelica, 2-4 parts of gromwell and 1-3 parts of picrorhiza rhizome. The treating agent can efficiently kill blue algae in a short time, and is simple and easy to implement.
Description
Technical field
The present invention relates to water-treatment technology field, be specifically related to a kind of modified carbon black/poly aluminium iron silicate compound cyanophyte treatment agent and preparation method thereof.
Background technology
In recent years, along with the continuous increase of China's size of population and developing rapidly of industrial and agricultural production, water requirement rapidly increases, and water pollutions is more and more serious simultaneously.Water pollutions is that world today's pollution is the most serious, one of pollution that hazardness is maximum, China's quantity of wastewater effluent is large, the pollutent in the rivers and lakes water bodys such as Taihu Lake is caused to grow with each passing day, pollution speed has exceeded the detergent power of lake body self, some of them are phosphorous, a large amount of discharges of nitrogenous compound, accelerate rivers and lakes eutrophication process, cause algae particularly blue-green algae distorted proliferation growth, and form one deck blue-greenish colour at the water surface and have offscum and the wawter bloom of bad smell, release stench, makes water quality degenerate.Large-scale blue algae bloom, is called as " green tide ", exhausts water oxygen gas and cause the death of fish time serious.More seriously, in blue-green algae, some kind (as Microcystis aeruginosa) also can produce Microcystin (microcystins is called for short MCs), containing a large amount of MCs in the green tide of about 50%.MCs, except directly producing except murder by poisoning to fish, people and animals, is also the major incentive of liver cancer.
Blue-green algae harnessing project is a complicated systems engineering.The main method taked the at present manpower and materials that still environmental input is a large amount of outside carry out drawing the mode that dirt removal clearly, resettlement contaminating enterprises etc. transfer the pollution, not from contaminated solution root; In environment improvement, biological process (comprising microbial method, animal law, plant method), the method for all kinds of improvement blue-green algae of chemical method and treatment agent has in succession been there is although domestic, but be still difficult to so far obtain extensively, effectively applying, major cause be that existing Treatment process is single, process is complicated, functional not high.
Summary of the invention
Object of the present invention is just to provide a kind of modified carbon black/poly aluminium iron silicate compound cyanophyte treatment agent and preparation method thereof, to overcome the deficiencies in the prior art.
The object of the present invention is achieved like this:
A kind of modified carbon black/poly aluminium iron silicate compound cyanophyte treatment agent, it is characterized in that, be made up of the raw material of following weight part: poly aluminium iron silicate 28-30, carbon black 18-20, sodium stearate 15-18, fruit of Yellow cinnamon 19-21, fulvic acid 17-19, Tai-Ace S 150 16-18, calcium oxide 20-22, sodium carbonate 15-17, Fructus Hordei Germinatus 2-4, root of Dahurain angelica 3-5, Asian puccoon 2-4, Rhizoma Picrorhizae 1-3.
The preparation method of described a kind of modified carbon black/poly aluminium iron silicate compound cyanophyte treatment agent, is characterized in that comprising the following steps:
(1) Fructus Hordei Germinatus, the root of Dahurain angelica, Asian puccoon, fruit of Yellow cinnamon, Rhizoma Picrorhizae decocted 2-3 hour together in water and filter, getting its filtrate and flood 30 minutes together with carbon black, drying, be ground into powder;
(2) filter residue of step (1) is sent in charring furnace, calcination processing 3-4 hour at 545-650 DEG C, take out and dry, be ground into powder;
(3) by sodium stearate and Tai-Ace S 150 mixing 30-40 minute, add calcium oxide mixing 45-50 minute, then add sodium carbonate mixing 50-60 minute;
(4) by step (1), (2), (3) reaction mass and other remaining components mixing 120-150 minute.
The present invention has following beneficial effect: the present invention adopts herbal medicine to carbon black modified, and raw material sources environmental protection is pollution-free, and the cavernous structure that can not only improve carbon black increases adsorptive power, improves flocculating and purifying performance; And efficiently killing blue-green algae can be realized within the extremely short time, simple.
Embodiment
Described a kind of modified carbon black/poly aluminium iron silicate compound cyanophyte treatment agent, it is characterized in that, be made up of the raw material of following weight part: poly aluminium iron silicate 29, carbon black 19, sodium stearate 18, fruit of Yellow cinnamon 21, fulvic acid 17, Tai-Ace S 150 16, calcium oxide 20, sodium carbonate 15, Fructus Hordei Germinatus 2, the root of Dahurain angelica 3, Asian puccoon 4, Rhizoma Picrorhizae 1.
Making method comprises the following steps:
(1) Fructus Hordei Germinatus, the root of Dahurain angelica, Asian puccoon, fruit of Yellow cinnamon, Rhizoma Picrorhizae decocted 2-3 hour together in water and filter, getting its filtrate and flood 30 minutes together with carbon black, drying, be ground into powder;
(2) filter residue of step (1) is sent in charring furnace, calcination processing 3-4 hour at 545-650 DEG C, take out and dry, be ground into powder;
(3) by sodium stearate and Tai-Ace S 150 mixing 30-40 minute, add calcium oxide mixing 45-50 minute, then add sodium carbonate mixing 50-60 minute;
(4) by step (1), (2), (3) reaction mass and other remaining components mixing 120-150 minute.
Use blue algae treatment agent of the present invention as shown in the table to wastewater suspended substance decontamination effect improving:
Table 1 Composite powdery blue algae treatment agent wastewater suspended substance decontamination effect improving
Claims (1)
1. modified carbon black/poly aluminium iron silicate compound cyanophyte treatment agent, it is characterized in that, be made up of the raw material of following weight part: poly aluminium iron silicate 28-30, carbon black 18-20, sodium stearate 15-18, fruit of Yellow cinnamon 19-21, fulvic acid 17-19, Tai-Ace S 150 16-18, calcium oxide 20-22, sodium carbonate 15-17, Fructus Hordei Germinatus 2-4, root of Dahurain angelica 3-5, Asian puccoon 2-4, Rhizoma Picrorhizae 1-3;
The making method of described modified carbon black/poly aluminium iron silicate compound cyanophyte treatment agent, comprises the following steps:
(1) Fructus Hordei Germinatus, the root of Dahurain angelica, Asian puccoon, fruit of Yellow cinnamon, Rhizoma Picrorhizae decocted 2-3 hour together in water and filter, getting its filtrate and flood 30 minutes together with carbon black, drying, be ground into powder;
(2) filter residue of step (1) is sent in charring furnace, calcination processing 3-4 hour at 545-650 DEG C, take out and dry, be ground into powder;
(3) by sodium stearate and Tai-Ace S 150 mixing 30-40 minute, add calcium oxide mixing 45-50 minute, then add sodium carbonate mixing 50-60 minute;
(4) by step (1), (2), (3) reaction gained material and other remaining components mixing 120-150 minute.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201410158521.XA CN103936126B (en) | 2014-04-18 | 2014-04-18 | Modified carbon black/ferric aluminum polysilicate composite blue algae treating agent and manufacturing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410158521.XA CN103936126B (en) | 2014-04-18 | 2014-04-18 | Modified carbon black/ferric aluminum polysilicate composite blue algae treating agent and manufacturing method thereof |
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| CN103936126A CN103936126A (en) | 2014-07-23 |
| CN103936126B true CN103936126B (en) | 2015-04-01 |
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| CN201410158521.XA Active CN103936126B (en) | 2014-04-18 | 2014-04-18 | Modified carbon black/ferric aluminum polysilicate composite blue algae treating agent and manufacturing method thereof |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105016437A (en) * | 2015-07-22 | 2015-11-04 | 合肥一诺生物科技有限公司 | Blue algae processing agent with water purification function and preparation method thereof |
| CN105104452A (en) * | 2015-07-22 | 2015-12-02 | 合肥一诺生物科技有限公司 | High-efficiency cyanobacteria treating agent, and preparation method thereof |
| NL2031192B1 (en) | 2022-03-09 | 2023-09-19 | Naturalpond B V | Combination for the inhibition of algae bloom-forming organisms |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1966419A (en) * | 2006-11-22 | 2007-05-23 | 哈尔滨工业大学 | Method for removing pollutant of water with synergistic effect of water treatment agent and microwave |
| CN101485339A (en) * | 2008-08-04 | 2009-07-22 | 通州市瑞鑫机械有限公司 | Solution for killing blue algae and preparation method thereof |
| CN101564053A (en) * | 2009-04-28 | 2009-10-28 | 沈阳鸟王旅游发展有限公司 | Algicidal pollution-free fuming agent |
| CN102948435A (en) * | 2011-08-30 | 2013-03-06 | 林治 | Pure plant Chinese herbal medicine aquaculture algae removal pesticide |
-
2014
- 2014-04-18 CN CN201410158521.XA patent/CN103936126B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1966419A (en) * | 2006-11-22 | 2007-05-23 | 哈尔滨工业大学 | Method for removing pollutant of water with synergistic effect of water treatment agent and microwave |
| CN101485339A (en) * | 2008-08-04 | 2009-07-22 | 通州市瑞鑫机械有限公司 | Solution for killing blue algae and preparation method thereof |
| CN101564053A (en) * | 2009-04-28 | 2009-10-28 | 沈阳鸟王旅游发展有限公司 | Algicidal pollution-free fuming agent |
| CN102948435A (en) * | 2011-08-30 | 2013-03-06 | 林治 | Pure plant Chinese herbal medicine aquaculture algae removal pesticide |
Non-Patent Citations (1)
| Title |
|---|
| 粉煤灰基絮凝剂的制备及含酚废水的处理;张慧弟;《中国优秀硕士学位论文全文数据库 工程科技I辑》;20090915(第9期);第21-25页 * |
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Effective date of registration: 20190610 Address after: 242000 Gao Yang village, Huayang Town, Jixi County, Xuancheng, Anhui (National Grain Reserve Bank) Patentee after: Jixi Yuan Dao agricultural industry Science and Technology Ltd. Address before: 241000 international student Park 320, Wuhu economic and Technological Development Zone, Anhui Patentee before: ANHUI ZHONGRI AGRICULTURE ENVIRONMENTAL TECHNOLOGY CO., LTD. |
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